CHETTINAD VIDYASHRAM R.A, PURAM, CHENNAI-28 CYCLE TEST -I [2018-19] DATE, :18,06.2018 CLASS: XII TIME: 1 HOUR: SUBJECT: CHEMISTRY MARKS :30 1, Write the equation for the preparation of 1-iodobutane from but-I-ene, ny 2. How is 1-propoxy propane synthesised from Propan-1-ol? uy) 3. Explain Kolbe’s reaction. ul 4, Explain the term Polymer. WW 5. Haloalkanes react with KCN to form alkyl cyanides as main product while ‘AgCN forms isocyanides as the chief product, Explain, (2 6. Discuss the main purpose of vulcanization of rubber. Ri a) What are enantiomers? Draw the structures of the possible enantiomers of 3-methylpent-I-ene. 'b) Why is chloroform stored in dark coloured bottle completely filled to keep air out? BI 8, How are the following conversions cattied out? a) Toluene to benzyl alcohol b) Benzene to diphenyl ©) Aniline to chlorobenzene BI a) Alcohols are comparatively more soluble in water than hydrocarbons of comparable molecular mass. Explain, ) Give the equation of reactions for the preparation of phenol from cumene. BI 10. Write the names and structures of the monomers of the following polymers: a) Dacron b) Neoprene c) Buna-S 81 11. Answer the following: 4) Amange the compounds of each set in order of reactivity towards SN2 displacement: 2-Bromo-2-methylbutane, 1-Bromopentane , 2-Bromopentane b) Grignard reagents should be prepared under anhydrous conditions. Explain,c) A hydrocarbon CHjo does not react with chlorine in dark but gives a single monochloro compound CsHsCI in bright sunlight. Identify the hydrocarbon, d) Write the IUPAC name of HG, Hy W ar Hye ©) Complete: SoH peroxide a 12, a) Write the mechanism of acid dehydration of ethanol to yield ethene. b) lustrate with examples the limitations of Williamson synthesis for the preparation of certain type of ethers. 5] {5} seek© CHETTINAD VIDYASHRAM SUBJECT: CHEMISTRY. CYCLE TEST-1-KEY STD:XII 1, . Explain Kolbe’s reaction. Write the equation for the preparation of 1-iodobutane from but-I-ene. HBr=peroxide CHsCH,CH=CH 5 cy, CH,CH,CH:Br“3CH,CHCH,CHaL 4 . How is 1-propoxy propane synthesised from Propan-1-ol? re soc, CH,CERCHy-O11 253 CIACH,CH,-ClL CH)CH)CEb-OH “5 CHiCH)CH:-ONa CHjCH,CHy-Cl + CEjCH,CE-ONa-> CH,CH,CH,-O-CH,CH,CH, OR HySO4 433 2. CH,CH,CH-OH "5 CHyCH,CH;-O-CH,CH;CHs . YH la A COOH NaOH. () CO,, OO & 2-Hydroxybenzote aicid (Galicylie acid) . Explain the term Polymer. mM It is defined as very large molecules having high molecular mass(10°- 107u). . Haloalkanes react with KCN to form alkyl cyanides as main product while AgCN forms isocyanides as the chief product, Explain. Ql KCN is predominantly ionic and provides cyanide ions in solution. Although both carbon and nitrogen atoms are in a position to donate electron pairs, the attack takes place mainly through carbon atom and not through nitrogen atom since C-C bond is more stable than C-N bond. However, AgCN is mainly covalent in nature and nitrogen is feree to donate electron pair forming isocyanide as the main product. . Discuss the main purpose of vulcanization of rubber. [2] Natural rubbern becomes soft at high temperature and brittle at low temperature and shows high water absorption capacity. It is soluble in. non-polar solvents and is non-resistant to attack by oxidising agents. To impove upon these physical properties , the process of vulcanization is carried out,