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Ebalance Pink Crib Sheet PDF
Ebalance Pink Crib Sheet PDF
Energy Balances with Molar Quantities (heat-of-formation method) CinChE, pp. 7-4 to 7-14
ni nt ( )
d n Uˆ
∑ n Hˆ
i =1
i i − ∑
i = ni +1
n i Hˆ i ± Q ± W S =
dt
sys
(7.1d)
(nUˆ ) ( )
ni nt
∑
i =1
ni Hˆ i − ∑ n Hˆ
i = ni +1
i i ± Q ± WS = sys , f − n Uˆ sys , i (7.1i-a)
D. Energy Balance for Problems with reactions in Project 5 and Final Exam.
1. Differential Balance above for continuous process at steady state.
2. Integral Balance above for batch, semi-batch, or semi-continuous process.
3. Global Assumptions: Nelgect ∆KE and ∆PE, Mixture are ideal solutions.
4. Hˆ j = ∆Hˆ of , j 25 C ,1 atm, Phoj + ∆Hˆ j Ti , Pi , Phi ⇐ 25 C ,1 atm, Phoj for each j
5. Ref. States must be Hˆ ko = 0 for each pure element k that make up the compounds.
6. MUST pick= T o 25=
C , P o 1 atm, and stable Pho of pure j . ∆Hˆ o in Table B.1.
j j j f, j
7. Repr esent each pur e-jth ∆Hˆ j functional for m, using the following or der ing:
a. Table, if available. For water , F&R Tables B.5, B.6 and/or B.7.
b. Graph, if available. PH Diagram for the pure component.
c. Equation, a sensible ∆Ĥ for no phase change (see CinChE p. 7-17); otherwise,
a combination of sensible and latent specific enthalpy changes.
ˆ Table B.8 or B.9, B.2,
ˆ − T ∂V dP
Ti Pi
Sensible: =
∆Hˆ j ∫
Tj
Cˆ PPh, j dT + ∫ Pj
V ∂T
P
and then B.10, or
model in EZ Setup
exact differential
from calculus for
enthalpy change.
Something you
must memorize.
exact differential
from calculus for
internal energy. for eos, use Aspen HYSYS