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Spontaneous Combustion Conversion
Spontaneous Combustion Conversion
Dr. D. P. Mishra
• It is the most important cause of fires in coal mines across the world.
• In Indian coal mines, 80% of the coal fires occur due to spontaneous
combustion.
• The main reason is that the Indian coal seams are thicker and there
is a tendency of coal to spontaneous heating during depillaring
operation.
• History of coal mines fires can be traced back to the year 1865, when
the first fire was reported in Raniganj Coelfields.
• Over 140 years, fires have been reported from both Jharia and
Raniganj coalfields.
– opencast mines,
– coal stockpiles,
– transportation and
China
• In China, coal fires are a severe problem, which is the world‟s largest coal
producer with an annual output around 2.5 billion tons.
• It has been estimated that some 10-200 million tons of coal uselessly burn
annually.
• Over 100 major fire areas are listed, which extend over a belt across the
entire north China.
• They are concentrated in the states of Xinjiang, Inner Mongolia and Ningxia.
Germany
• In Planitz, a part of the city of Zwickau, a coal seam that had been
burning since 1476 could only be quelled in 1860.
• There are 45 fire zones known in Pennsylvania, the most well known
being the fire in the Centralia Mine in the hard coal region of
Columbia.
Indian scenario
• Coal mine fires in India have survived since the second and third
decade of 20th century. However, the history of first happening of
coal mine fires in India has not been accurately recorded.
• Over 140 years fires have been reported from both Jharia and
Raniganj coal fields.
• History of coal mines fires can be traced back to the year 1865, when
the first fire was reported in Raniganj Coalfields.
• In Jharia coalfield the first fire occurred in 1916 at Bhowra Colliery.
• In the independent India mine fires were known to have existed in the
coal mines in
– Margarita in Assam,
– Venkatesh Khani Mine in Singareni in Andhra Pradesh,
– Mahakali Colliery in Chandrapura in Maharashtra,
– Talcher Colliery in Talcher Coalfield in Orissa,
– RCF in West Bengal and JCF in Jharkhand, etc.
• In 1966 there were 64 coal mine fires out of which 32 were in JCF
and 19 in RCF. The number increased to 82 in 1976.
• The number of the fires increased further and was about 196
covering an area of about 30 sq km in 1994.
MECHANISM OF SPONTANEOUS COMBUSTION
• Like all other oxidation reactions, the interaction of oxygen with coal
is an exothermic with production of a small quantity of heat.
• The heat from oxidation normally varies from 2.0 to 4.0 Cal/ml of
O2 absorbed at N.T.P.
• 3rd Step: Decomposition of these groups too (at temp. > 100°C),
production of CO, CO2, H2, H2O and high degree hydrocarbons
(ethane, ethylene, propylene) and heat generation.
• It has been established that pyrite present in coal might assist the
oxidation of its carbonaceous content by breaking down coal into
smaller fragments and exposing larger surface area to the air, as well
as by elevating the temp. due to heat liberated from its own oxidation.
• The reaction of iron pyrites with oxygen and moisture gives products
of larger volume than the original pyrite hence opening more pore
area of exposure for oxygen, which is a exothermic reaction.
• It also yields reaction product having greater volume than the actual
pyrite, with the result that would break open any coal in which they
are engrafted and thus exposing a greater surface of coal to the air.
• Moisture content
• Bacteria
• Other minerals
Extrinsic Factors (Atmospheric, Geological and Mining Conditions)
Climatic conditions:
• Temperature
• Moisture/relative humidity
• Barometric pressure
• O2 conc.
Geological factors
• Coal seam and surrounding strata condition
• Seam thickness
• Seam gradient
• Caving characteristics
• Faulting and other geological disturbances
• Coal outbursts
• Friability
• Depth of cover
Mining factors
• Mining methods
• Rate of advance
• Pillar conditions
• Roof condition
• Crushing
• Packing
• Presence of timber or other organic waste material in abandoned areas
or dumps
• Leakage
• Multi-seam working
• Coal losses
• Worked out areas
• Heat from machines
• Stowing
• Ventilation system and airflow rate
• Ventilation pressure
• Method of stockpiling and stockpile compaction
1. Coal Characteristics
a. Rank of coal
• Coals of different ranks have different capacities to absorb O2.
• The rate of oxidation decreases with increase in rank of coal.
• Lower rank coals containing higher moisture, O2 and volatile content are
more easily oxidized and hence, the risk of sp. combustion is higher in lower
rank coals.
b. Presence of pyrites
• Presence of iron pyrite (FeS2) increases the potential of coal for sp.
combustion, particularly when the pyrite concentration exceeds 2% and
when it is in very finely divided state.
• Pyrite accelerates sp. combustion by swelling and causing disintegration of
coal mass, thereby increases the surface area available for oxidation.
• It easily oxidizes by its own in presence of O2 of the air and moisture at
ordinary atmospheric temp. according to the following equation:
2FeS2 + 7O2 + 16 H2O = 2H2SO4 + 2FeSO4 . 7H2O + 316 × 2 kcal
• The oxidation of pyrites has only a promoting effect on auto-oxidation of
coal.
c. Area of exposed coal surface
• Exposed surface area as well as internal surface area (pore spaces) of coal
is a significant factor influencing its self heating.
• The entire pore surfaces in coal may be above 80 m2/g.
• The smaller the coal particle, the greater the exposed surface area in
contact with the air and the greater will be the rate of oxidation and tendency
towards sp. combustion.
• The rate of oxidation increases with increasing fineness of coal.
• The rate of heating has been found to be proportional to the cube root of the
specific internal surface area of coal (Schmidt, 1945).
• In case of an average bituminous coal, it is generally considered that the
danger of sp. combustion is slight for sizes larger than 38mm.
• In case of weathered coal, the exposed surface of coal reaches the stage of
saturation and no further interaction with O2 at ambient temperature occurs.
e. Petrographic composition of coal
• Coal constituents the macroconstituents like vitrain, clarain, durain and
fusain influence the liability of coal to spontaneous heating.
• Liability of spontaneous combustion decreases in the order: vitrain-clarain-
durain-fusain content.
g. Moisture content
• Moisture inherent in coal, present in the surrounding oxidizing atmosphere,
or produced from oxidation of coal in the early stages of oxidation influences
the oxidation process. It acts as a catalytic agent.
• The high moisture coals have higher tendency of spontaneous heating.
• Nandy et al. (1967) had shown that there is an optimum moisture level of
around 5% in coal showing maximum spontaneous heating tendency.
h. Oxygen content
• The liability of coal to sp. heating is directly related to its O2 content.
• With coals having O2 content less than 2%, the oxidation rate is not large
enough to cause any appreciable increase in temperature.
i. Ash content
• Ash present in coal generally decreases the oxidation rate which is also
influenced by the mineral composition of the ash.
• Coals with low thermal conductivity are more liable to spontaneous heating.
2. Geological Factors
a. Seam thickness
• Thick coal seams are more prone to sp. combustion because the working of
these seams is invariably accompanied by high losses of coal in the goaf
area.
• The unmined part which is left in the goaf is more prone to sp.combustion
since it is exposed to sluggish ventilation flow.
• In some coal seams, coal is left in the roof or floor. Some of the roof coals
drop in the gob, which will eventually be sealed off. This coal can get access
to air either by waste “breathing” or by leakage.
• Coal in the floor breaks when the floor heaves, which exposes the coal to air
flow.
• Also in thick coal seams, certain bands within the seam can be more liable
to sp. combustion than other bands.
• At greater depth, the excessive rock pressure acting on coal pillars results in
their crushing and thereby increases the surface area of coal exposed to
oxidation, which help in increasing sp. heating.
f. Faulting
• Presence of faults in coal seams allow air and water to migrate into the coal
seams and helps in development of heating in coal mines.
• Any grinding of coal along the fault plane may lead to self-heating.
g. Coal friability
• Friable coals tend to produce coal fines which, due to larger surface area,
have a greater tendency to sp. combustion.
3. Mining Factors
a. Mining methods
• Longwall advancing leaves extracted areas lying between the entries
serving the working places.
• The ventilating pressure differences will encourage airflow across these
areas with the accompanying problem of incomplete combustion.
• In high-risk situations, a retreat system of working is preferable.
c. Rate of advance
• The rate of mining and advance rate of the face determine the time in which
the broken coal in the gob is exposed to ventilation air.
• If the rate of advance is slow, and time taken in entering and leaving a panel
is excessive, the oxidation may occur to an unacceptable degree and a gob
fire could result.
d. Pillar size
• Pillar size should be sufficient to prevent crushing.
• Pillars that have been standing for a long time are prone to heating,
particularly when they are liable to crushing.
• Pillar crushing can create air leakage paths leading to the flow of air through
the coal. Loose coal is usually produced by pillar spalling or crushing. When
associated with sluggish ventilation, these areas are hazardous.
• It is the period between the onset of first oxidation and the timepoint when
one can detect by the senses.
• During incubation period, one does not detect heating during one’s passage
through mine workings.
The incubation period varies widely depending on
For low-rank coals, the incubation period generally varies between 3 and 6
months.
Under adverse conditions, the period can be less than 2 weeks, especially
with low-rank coals.
2. The indication period
• The end of the incubation period is the beginning of the indication period.
• The indication period is often of very small duration lasting sometimes only a
few hours and end with the appearance of ‘fire stink’.
• The fire stink can be easily recognized by its characteristic petrolic smell.
• In open fires, seams seldom burn with a bright flame but they glow
developing bluish-white clouds of smoke.
DETECTION OF SPONTANEOUS COMBUSTION
• Detection of sp. combustion in its early stage is very much essential for its
prevention. Earlier a fire is detected; easier it is to deal with.
• Reliance has been placed on these indications in the past for early
detection of sp. heating.
• Usually the first indication of a heating that can be detected by the human
senses is the characteristic odour of the gob stink in the air coming from the
suspected area.
• In the initial stages of heating, the smell resembles that of petrol but as the
heating progresses it changes to kerosene and later to a tarry odour.
• A strong smell indicates that the heating has made sufficient headway.
• The characteristic smell normally found in a coal fire area, once experienced
can never be forgotten and can not be missed.
HAZE
• In the initial stage of heating, as the moisture released from coal come in
contact with the cooler ventilating air and thereby condense, making haze
like formation.
• Haze is visible a little away from the seat of fire i.e. near the intake side of
the ventilation.
• Typical signs are poor visibility of the mine environment in the vicinity of
heating.
• Caused due to condensation of water vapour released from coal due to sp.
heating & formation of water droplets on the roofs, walls, timber supports or
any other cooler surfaces in its vicinity.
SOUND
• At times typical creaking sound (from collapse of strata or due to crack
formation in them) may be heard behind the stopping or barriers, which
could be indicative of advancement of fire.
SMOKE IN AIRWAYS
• Smoke can only be observed above the ignition temperature of coal when
fire has set in.
Limitations:
• Haze or sweating of the strata may give misleading information giving false
alarm at places where there are chances for the humid return air to meet the
comparatively cooler intake air. For this reason haze formation or sweating
of the strata are taken more seriously in dry mines and with coals of lower
moisture content (< 5%).
• The early physical symptoms may be totally missed, even in dry mines
depending on the mine environment and the rate of progress of heating.
• Even today gob stink is considered a very useful warning for recognising the
onset of incipient heating or the advancement of fire in coal mines. But
physical symptoms like gob stink also, can not detect heating at a very early
stage, at least not up to 120°C or so.
• One can not access the degree of heating from smell alone which demands
measuring quantitative changes that occur during the heating of coal.
2. Conducting thermal survey using thermal devices
• Thermocouples or thermistors left in gob areas. However, they too have met
with very little success to the present time with following demerits:
– First, their wiring is unlikely to withstand the mechanical stresses of an active
caving zone, even when sheathed.
– Secondly, the thermal conductivity of crushed rock is low. Hence, the
temperature even within a metre of an active centre of heating may indicate no
abnormal condition.
3. Monitoring gas concentrations in return airways and sealed-off areas
and their trend analysis
• Monitoring the quality of air in a mine is the modern, most widespread and
dominant method of detecting sp. heating.
• Sampling the air downstream from a fire or from within a newly sealed area
and plotting the trends is the primary method of tracking the behaviour of
fire.
• As the gases emitted vary with the phases of oxidation, time and
temperature, it is necessary to employ skilled interpretation of those trends.
FIRE INDICES / Susceptibility indices of spontaneous combustion
Ratio Name
• CO/ ΔO2 Graham's Ratio or Index for
Carbon Monoxide (ICO)
First, that the air has been supplied with 20.93% O2 and 79.04% inert gases
(excepting 0.03% CO). That 79.04 per cent contains traces of other gases but
is referred to simply as N2.
20.93 N
2
79.04
• As CO2 may be produced from other sources or may be lost in air due to
sorption by coal or by solution in water, CO is the most reliable indicator of
heating.
• By 1914, Ivon Graham recognized the importance of CO as an early
indicator of sp. heating of coal and the equally vital influence of O2 that was
consumed.
• He first suggested the index CO/ΔO2, now known as Graham's Ratio or
Graham's Index or the Index for Carbon Monoxide (ICO).
Typical values of the carbon CO/ O2 deficiency ratio for underground coal
mines are given below:
• Its accuracy becomes suspect if very little O2 has been consumed, i.e.
Graham's Ratio is unreliable if the oxygen deficiency, ΔO2, is < 0.3 %.
– if the air supplied to the fire is not fresh: it occurs if the fire is fed by air
that has migrated through old workings and contains blackdamp (de-
oxygenated air).
Young's Ratio
• CO2 is the most prolific of the gases produced in mine fires. Hence, the
values of CO2 /ΔO2 will be much higher than CO/ ΔO2.
• Hence a simultaneous rise in CO2 / ΔO2 and fall in CO/ ΔO2 indicates further
development of the fire.
• Thus, the extraneous origin of CO2 as well as its solubility in water make the
interpretation anomalous at times.
Willett's Ratio
• This ratio was introduced by Dr. H.L. Willett in 1951 with specific reference
to situations where there is a higher than usual evolution of CO by ongoing
low temp. oxidation.
CO produced %
Black damp Combustible gas
besides the analysis of CO, to understand the magnitude and extent of fire.
• This ratio can be used only as a supplementary index along with other fire
indices.
Jones and Tricket Ratio (JTR)
• Jones-Tricket Ratio is used as a measure of reliability of sample analysis
and also as an indicator of the type of fuel involved.
• It can be used for the gaseous products of both fires and explosions.
• Jones and Tricket Ratio (JTR), giving the relationship between the products
of combustion with O2 deficiency is defined as below:
• However, the CO/CO2 rises rapidly again as a fire becomes fuel-rich and is
an excellent indicator of this condition.
• It is, however, subject to variations in CO and CO2 that are not caused by
the fire.
C/H Ratio
• C/H ratio of the mine gases was introduced by Ghosh and Banerjee (1967)
for assessing the intensity of fire, along with O2 consumption values that
indicate extensity character of it.
• They argued that in case of burning of fuel (mainly compound of C and H2 in
varied proportion) the temp. determines the extent to which the C and H2
part of it would burn.
• At low temp, the H2 part may burn completely but there would be a lot of
unburned C deposited as soot.
• In case of rapid burning of CH4, the C/H ratio calculated from the product
gases is always less than 3, which is the maximum value for complete
combustion of CH4.
• Likewise, the maximum attainable C/H value for complete burning of
bituminous coal lies between 16-20, depending on the type of coal.
• Higher C/H values indicate burning of the cellulose bodies (i.e. timber etc.
having higher C/H values) while lower values indicate partial burning of coal.
• Thus, the degree or intensity of burning of coal may be adjudged from the
value of C/H ratio of the product gases obtained.
PREVENTION OF SPONTANEOUS COMBUSTION
• Control of ventilation:
A. Mining layout
• Proper mine layout design is very important for prevention of sp. heating.
• Panels must be of a size which would permit complete extraction within the
incubation period.
• When working seams by bord and pillar method, the size and shape of the
pillars must be sufficient to avoid excessive crushing at edges and corners.
• Side bolts can be used and low viscosity grouts may be injected to maintain
the integrity of pillars.
• Efficient clearance of the fragmented coal from the face and good
housekeeping should be practiced in mines that have a history of sp.
combustion.
• In case of longwall advancing, the gate side packs should be made airtight.
The points which should be considered for ventilation and leakage control to
prevent sp. heating are as follows:
• Ventilation pressure should not be unduly high so that air leakage through
crushed pillars or defective stoppings or seals of sealed areas does not take
place.
• Doors, stoppings, and regulators should be properly sited. Unnecessary
stopping and starting of main and booster fans should be avoided.
• Air leakage into sealed areas through fractures extending from the surface
should be prevented by artificial sealing using sand.
• When a panel has ceased production and is to be sealed off, the ventilation
pressure difference should be balanced across the old panel.
D. Inhibitors
• In storage areas and surface stock piles, certain chemical agents can be
applied to the coal surface to hinder the penetration of O2 into coal by
sealing the surface pores and thereby stopping initiation of auto-oxidation of
coal at ambient temperatures.
• Surface stock piles can also be sealed off by consolidation and bitumen.
E. Inspections
• On idle days, all districts liable to sp. heating should be inspected at least
once by competent persons.