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Extraction of the Essential Oil Limonene from Oranges.

Chemistry Department
Outreach Team.
Ahmed Saleh, Denefield school, Reading 2008

Steam Distillation of Orange Peel The Distillation Extraction of Limonene from the
Distillate
Low molecular weight water Initially an oily water / limonene mixture can be
immiscible compounds can seen condensing on the glassware at a
be separated from natural distillation temperature of 98 C. The
products by steam temperature will rise to 100oC as the distillate Limonene, an alkene, is
distillation. In this case steam composition approaches pure water. extracted into a low density
distillation is used to isolate water immiscible solvent (ether).
the essential oil limonene
from the orange peel.
The lower layer is the
Limonene is concentrated in the peel of an remaining aqueous distillate
orange. The orange peel has two distinct layers,
the skin and the pith. Limonene Is not distributed
evenly between these two layers. Experimentation
has shown that only minimal quantities of
limonene can be extracted from the white pith.
This outer skin Limonene’s structure
accounts for two –
Pith thirds of the mass
Skin of the peel. The
best yields of Orange peel cut into small pieces,
limonene are placed into 100 mL of water
Mass of Orange Peel obtained by using Evaporation of the Solvent
only this outer skin.
Limonene can be
To finalise the
The yield of limonene is about 1% using this observed as an
extraction, the ether
outer skin. This is a large yield compared to oily suspension in
layer (b.pt. 37oC)
other essential oil extractions, where yields the final distillate
Heat was evaporated on
can range from 1-0.01 % by mass. (80 mL).
a water bath to
leave the limonene
Essential oils can be steam distilled from flowers, leaves, fruits, barks and woods (b.pt. 176oC).

Essential oils are


found in many limonene (150mg)
household products, obtained from 15 g
ranging from high end of orange peel skin.
cosmetics to basic The limonene has
cleaning materials. an intense aroma of
oranges
Lavender Patchouli Bergamot Cinnamon

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