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CICEQ - Vol17 - No4 - pp437-449 - Oct-Dec - 2011 PDF
CICEQ - Vol17 - No4 - pp437-449 - Oct-Dec - 2011 PDF
CICEQ - Vol17 - No4 - pp437-449 - Oct-Dec - 2011 PDF
www.ache.org.rs/CICEQ
Chemical Industry & Chemical Engineering Quarterly 17 (4) 437−449 (2011) CI&CEQ
There is often a negative attitude among the of the area, plant profile, speed and direction of domi-
population in the society about the risk concept. They nant wind were used as the input of mathematical
have considered it as a sign of damage, danger and models to calculate the pollutant concentration in 50
negative effects as well as fail probability toward km radius of the power plant [5]. In 1999, Akash et al.
achieving the predefined goals of the considered pro- used the analytical hierarchy process to select an
ject [1]. Britain Standards Institute knows risk as com- optimal system for electricity generation. In this study,
bination of occurrence and results of a hazardous a cost and benefit hierarchical structure was separa-
event [2]. Risk assessment determines the qualitative tely designed for various plants. Afterward, by com-
analysis of risk potential regarding the sensitivity or parison of different cost and benefit analysis results, it
vulnerability of the surrounding environment [3]. In ge- was concluded that solar and aquatic power plants
neral, there are currently more than 70 risk assess- are the most suitable ones for energy generation in
ment methods in the world, which are divided into two Jordan [6]. In 2002, Twardowska and Szczepanska
qualitative and quantitative groups [4]. Among re- conducted a study regarding environmental risk as-
search studies conducted around the world regarding sessment of solid waste in a power plant fly ash. Re-
risk assessment of power plants, a study carried out sults indicated that waste should not be treated as the
in the Harvard Center can be mentioned. In this re- same way as a natural raw material, even those con-
search, air emissions data (antimony, arsenic, ba- sidered non-hazardous [7]. In 2009, Vaurio showed
rium, chromium, and so on), geographic information how risk assessment could be used to control errors
and enhance human factors [8]. Dai et al. (2007)
Correspondening author: A.A. Pouriyeh, Department of Mecha- examined spatial distribution of radionuclide existing
nic, Ashkezar Branch, Islamic Azad University, Yazd, Iran. in soils around a coal-fired power plant, in Baoji, a city
E-mail: a.s.pouriyeh@gmail.com
Paper received: 20 January, 2011 of China. They presented the obtained results using a
Paper revised: 10 June, 2011 map demonstrated the concentration of radionuclide
Paper accepted: 11 July, 2011
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S.A. JOZI, A.A. POURIYEH: HEALTH-SAFETY AND ENVIRONMENTAL RISK ASSESSMENT… CI&CEQ 17 (4) 437−449 (2011)
through the area [9]. In general, as regards, power lution; air, soil, water and noise as well as vibration
plant risk assessment is a global issue, so a lot of re- and heat stress on the power plant personnel were in-
search has been carried out by scientists all over the vestigated. It is worth noting that although there are
world [10–14]. some researches regarding health-safety risk assess-
In recent decades, much attention has been fo- ment of power plants [21], but there has been no re-
cused by researchers on multi-criteria models in com- search considering health-safety and environmental
plex decision-making situation. Through such deci- risk assessment simultaneously.
sions, instead of using a measure of optimality, mul-
tiple measurement criteria are applied [15]. Analytical MATERIAL AND METHODS
hierarchy process (AHP) is one of the most important
multi-criteria methods [16]. The method was proposed Study area
by Thomas L. Saaty in 1980, for multi-criteria decision
The scope of the area was determined by over-
making circumstances. In current research to conduct
laying the political-administrative divisions of Yazd-Sa-
the risk assessment of Yazd combined cycle power
dough and Yazd-Ardakan sub-basins and specifying
plant, AHP method was used as one of the multiple
their common boundary. It should be noted that the
attribute decision making methods. For preparation of
study area is located between latitudes 31°-32°30’ N
hierarchical structure, first of all, four levels including:
and longitudes 52°54’-56°15’ E (Figure 1). Since,
goals, criteria, sub-criteria and options should be de-
Yazd combined cycle power plant is located on one of
fined [17,18]. Converting the considered problem into
the industrial provinces of Iran, thus, the need for the
the hierarchal structure is the most important part of
electricity will be felt in the region. Considering that
the method [19]. Therewith, by analyzing difficult and
the power plant is situated in the central zone of Iran
complex issue in the form of a hierarchy, it will be sim-
which has been suffered from severe earthquakes
plified and easier to understand by human mind [20].
over a long time period as well as conditions like dry
Study ahead focuses on identification of Yazd
climate, water shortages and lack of inhabitants, arid
combined cycle power plant risks from health, safety
lands development in the vicinity of the power plant,
and environment points of view using multi criteria
identification and classification of the power plant risks
decision making method. Thereby, the impacts of pol-
caused crisis in the region are essential.
Figure 1. The risk assessment study area of Yazd combined cycle power plant in Iran.
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S.A. JOZI, A.A. POURIYEH: HEALTH-SAFETY AND ENVIRONMENTAL RISK ASSESSMENT… CI&CEQ 17 (4) 437−449 (2011)
First step: parameters related with environmental 30 min based on the physiological system of the hu-
risks man ear (approved by Executive Regulations – Article
Yazd combined cycle power plant consumes gas 2: how to prevent noise pollution).
and gas oil fuels. In order to analyze produced pollu- Tests related with environmental risks
tants (CO2, CO, NOx (nitrogen oxides) and SO2) the In order to sound measurement of Yazd com-
gas analyzer device (model Testo 350xl made in UK), bined cycle power plant with the aim of determining
which has sensors to measure various air parame- the personnel exposure to noise, CEL-440B2 octave
ters, was used and all experiments were performed band sound level meter (made in UK), A-weighted
using topical tests. Industrial wastewater of Yazd network and spatial distribution method were applied.
combined cycle power plant equaled to19 m3/h is con- The measured parameters include Leq (equiva-
ducted into the surface evaporation pond. For exami- lent sound level) and Lmax (maximum sound pres-
nation of the plant industrial wastewater through the sure level in each measuring courses). Noise mea-
years 2008–2009, two samples were randomly taken surement stations and the main sources of sound in
from the beginning (the wastewater entrance in to the Yazd combined cycle power plant are presented in
evaporation ponds) and end of the evaporation ponds. Table 1.
It should be mentioned that experiments were perfor- To investigate the plant equipment vibration and
med on 52 pollutants (see Appendix) using different its effect on personnel, first of all, vibrating environ-
methods (atomic absorption, photometer, titration, bar ments were identified and measured using TV300
graph, etc.). To examine the sanitary effluent of the time oscillator device (Table 2).
power plant treated by activated sludge method and To analyze and calculate thermal stress of the
consumed for irrigation of the power plant green spa- power plant personnel, the WBGT (wet bulb goysan
ces, some experiences were carried out on effluent temperature) index and the mini lab machine manu-
quality – BOD (biochemical oxygen demand), COD factured by UK were used at different parts of the po-
(chemical oxygen demand), DO (dissolved oxygen), wer plant including turbine hall combined cycle, cool-
TDS (total dissolved solids), TSS (total suspended ing tower (5 main directions), g11 and g12 turbine
solids) and other pollutants (Appendix). kraft regarding the exposure time (6-8 h). Considering
Environmental noise study of Yazd combined the heterogeneous workplace atmospheric conditions
cycle power plant was performed in 8 main and subsi- measurements were carried out in the chest.
diary directions within a distance of 40 m away from
equipment center using Cell440 sound meter device WBGT = 0.7Tnw + 0.3Tg , roofed environment
manufactured by Casllacell (England Co.). The status WBGT = 0.7Tnw + 0.2Tg + 0.1Ta ,
of the sound pressure level (SPL) was evaluated non-roofed environment (1)
using A-weighted network of sound level meters for
Table 1. Noise measurement stations of Yazd combined cycle power plant (2009)
439
S.A. JOZI, A.A. POURIYEH: HEALTH-SAFETY AND ENVIRONMENTAL RISK ASSESSMENT… CI&CEQ 17 (4) 437−449 (2011)
Table 2. Vibration measurement stations of Yazd combined cycle power plant (2009)
where Tg is the Goysan thermometer temperature loss, skeleton and muscular disorders, skin and respi-
value, Tnw is the natural wet bulb temperature and Ta ratory diseases, vision loss, accident, electric shock
is the amount of ambient temperature. and illness resulting from exposure to magnetic field
over a long term. Technological risks, considering
Second step: performing risk assessment using
sensitivity of the power plant performance and equip-
analytical hierarchy process (AHP)
ment include deposition and corrosion of the equip-
The study was carried out with the aim of in- ment, fuel contamination leading to reducing the life
vestigation of Yazd combined cycle power plant health, of the equipment, the plant foundation subsidy due to
safety and environmental risks. equipment vibration, the error of the control system as
Therefore, after identifying the plant activities well as the operator, fire and explosion.
and situation it was determined that the plant acti- Activities of Yazd combined cycle power plant
vities cause some risks on the power plant personnel affect the socio-economic and biophysical environ-
and the surrounded environment. The environment ment of the region. Risks affecting the socio-econo-
imposes some hazardous and risks on the plant ac- mic environment include power generation, job crea-
tivities as well. Thereby, in the current study, the cri- tion, health hazardous on inhabitants living around
teria and sub-criteria were determined based on the the plant due to pollutants generation, effects on agri-
indoor as well as the surrounding environment risks. cultural land around the area as well as impact on the
Sub-criteria applied to carry out the evaluation land use regarding being bare land adjacent to the
reflect the advantage of AHP Method in dealing with power plant which cannot consider any other land
combination of criteria, qualitative and/or quantitative uses for it. The power plant activity has some impacts
[19]. It should be mentioned that the pair wise compa- on the biophysical environment of the area including
rison is base on the AHP method [22]. The pair wise effect on quantity and quality of water, soil and air,
comparison could be done in different numeric, gra- energy consumption for power generation as well as
phical and verbal forms using Expert Choice software the power plan impact on natural habitat of the area,
[23]. noise pollution and induces of seismicity caused by
As regards, the purpose of the current study is the power plant activity. Also considering the esta-
risk assessment of Yazd combined cycle power plant blishment situation of the power plant risks like the
considered risks available in indoor and surrounding environment heat, shortage of underground water re-
environment of the power plant, a variety of sub-cri- sources and earthquake threat the power plant acti-
teria including health-safety risks, technological risks, vity.
the affected environment risks as well as the environ- After drawing the hierarchical structure, risks
mental factors influenced the power plant were se- and effects of the power plant associated with each
lected. Ultimately, each sub-criterion was divided into level corresponding to its target level were compared
the sub-sub-criteria. Safety and health risks include pair-wisely. The methodology is so that using 9 point
risks and diseases caused by thermal stress, hearing judgment scale of Saaty, one score was assigned to
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S.A. JOZI, A.A. POURIYEH: HEALTH-SAFETY AND ENVIRONMENTAL RISK ASSESSMENT… CI&CEQ 17 (4) 437−449 (2011)
each pair-wise comparison [24]. Then, with importing of free chlorine, formaldehydes, cyanide, cobalt, chro-
of pair wise comparison table in to the Expert Choice mium, fluoride, molybdenum, nickel and ammonium
software the relative importance of criteria were cal- were raised at the end of the evaporation ponds
culated and the weight of final risk was obtained by during the year as well. Comparison of the pollutants
aggregating of multiplied criteria in options weight. with the standard of the discharging to the absorbent
wells indicated that levels of copper, free chlorine,
RESULT AND DISCUSSION cadmium, zinc, arsenic, magnesium, phosphate, sul-
fate, BOD and COD are higher than the standard li-
Environmental and safety-health risks of Yazd power mits. The above mentioned pollutants are produced
plant by washing of the power plant equipment such as boi-
The results of tests conducted on air pollutants lers, converters, condenser and cooling tower caused
generating at different parts of Yazd combined cycle soil and underground pollutions (Figure 3).
power plant as well as comparison with environmental The sanitary effluent of the power plant, after
standards suggested that according to the following being treated using activated sludge method, is con-
tables, the amount of CO are beyond the standard sumed for irrigation of the green space. The results of
limits in most measuring stations including the gasses the conducted experiments during 2008-2009 and
exhausted from Alstom G13 and G14 chimneys, Die- their comparison with allowable water consumption
sel Emergency Alstom 1 and 2, emergency diesel of standard for agriculture and irrigation suggested that
gas house fire pump no. 1 and 2. The highest and the levels of arsenic, selenium, vanadium and molyb-
lowest CO concentrations are equal to 156 and 496 denum are beyond the permitted standard (Table 5).
ppm related to emergency diesel of gas house fire According to Figure 4, all the other pollutants are less
pump no. 1 and Alstom G14 (gas fuel), respectively. than the standard limit but dissolved oxygen (DO).
The amount of NOx (382 ppm) is higher than the stan- Higher levels of heavy metals than the standard limit
dard limit (350 ppm) just in emergency diesel of gas are caused due to washing of the workshop floor,
house fire pump no. 1 occurred due to the usage of cleaning the plant parts and equipments using orga-
fossil fuels (Table 3). All experiments were carried out nic materials like thinner, gasoline and toluene collec-
with different techniques including atomic absorption, ted by the wastewater network and transferred to the
Photometry, titration, bar graph etc., on the pollutants wastewater treatment plant.
compounds and industrial wastewater of the power It is worth noting that due to the high volume of
plant during the years 2008 and 2009 that was avoided the results obtained from industrial and sanitary efflu-
mention of their names considering the breadth of the ent of the power plant, here are a few outline samples.
information (52 pollutants) (Table 4). Results of Yazd combined cycle power plant
Results of the measurements conducted on 52 noise assessment carried out in 8 main and subsi-
pollutants of the industrial effluent generated by the diary directions as well as their comparison with noise
power plant through 2008-2009 and their comparison pollution standard presented by Environmental Con-
with each other suggested that the amount of cya- servation Department of Iran determined allowable
nide, the formaldehydes, lithium, manganese, nickel, noise limit as 75 dB showed that noise levels at all
molybdenum, selenium were increased at the begin- stations is less than the standard limit. The highest
ning of the evaporation pond (input of effluent in to the measured amount was reported from the western part
evaporation ponds) in 2009 (Figure 2). The amounts of the power plant equaled to 72.8 db (Table 6).
Table 3. Carbon monoxide measurement results in Yazd combined cycle power plant (2009)
The amount of CO The standard limitation of The amount of The standard limitation of
Sampling location Sampling location
pollutant, ppm CO pollutant, ppm CO pollutant, ppm CO pollutant, ppm
G13 Alstom (with 165 150 G14 Alstom (with gas 177 150
natural gas fuel) oil fuel)
Emergency diesel 355 150 Emergency diesel of 250 150
1 Alstom gaseous fire pomp
house - No. 2
Emergency diesel 385 150 Emergency diesel of 469 150
2 Alstom gaseous fire pomp
G14 Alstom (with 156 150 house - No. 1
gas fuel)
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S.A. JOZI, A.A. POURIYEH: HEALTH-SAFETY AND ENVIRONMENTAL RISK ASSESSMENT… CI&CEQ 17 (4) 437−449 (2011)
Table 4. Results of industrial wastewater pollutants for Yazd combined cycle power plant
Measurement results
Measurement results The standard value for
obtained from evapo- Measurement
No. Pollutant substance, mg/l obtained from evapora- discharge to the ab-
ration pond ending method
tion pond ending 2009 sorbent well, mg/l
2008
Figure 2. Test results obtained from industrial effluent of power plant in terms of mg/l (at the beginning of evaporation ponds) 2008-2009.
Test results of safety and health section of Yazd lues for the power plant sound pressure level (SPL) is
combined cycle power plant higher than the limits determined by AOE (allowable
ACGIH (American Conference of Governmental occupational exposure) standards (8 h SPL standard)
Industrial Hygienists) determines the threshold limit in most parts of the plant such as G14Alstom gene-
value (TLV) for an eight-hour shift equal to 85 dB. rator, Turbine Hall Alstom, G11 and G12, Turbine
Thereby, the results showed that the measured va- Kraft and CW pump workshops, i.e., more than 50%
of the measured stations (Figure 5).
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S.A. JOZI, A.A. POURIYEH: HEALTH-SAFETY AND ENVIRONMENTAL RISK ASSESSMENT… CI&CEQ 17 (4) 437−449 (2011)
Figure 3. Comparison results of power plant industrial effluent with discharge to absorbent well standards 2008-2009.
Table 5. Pollutants result of Yazd combined cycle power plant sanitary effluent after treatment using activated sludge (2008-2009)
Treatment plant output of sanitary wastewater, mg/l Agriculture and irrigation uses
Pollutant substance Measurement method
2008 2009 standard, mg/l
Arsenic (As) 0.38 0.32 0.1 Atomic absorption
Molybdenum (Mo) 0.001 9.8 0.01 Photometry
selenium (Se) 0.29 0.91 0.1 Atomic absorption
Vanadium (V) 0.34 0.034 0.1 Atomic absorption
Dissolved oxygen (DO) 8.3 8.6 2 Titration
Figure 4. Comparison of power plant sanitary output effluent with agricultural and irrigating standards 2008-2009.
Table 6. Noise assessment results of Yazd combined cycle power plant related to day measurement (2009); sampling duration: 30 min;
standard from 7 am till 10 pm: 75 dB(A)
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S.A. JOZI, A.A. POURIYEH: HEALTH-SAFETY AND ENVIRONMENTAL RISK ASSESSMENT… CI&CEQ 17 (4) 437−449 (2011)
The investigation of the plant vibration and com- perature of study area reaches above 42 °C in sum-
parison of results with ACGIH standard (2005) within mer (Table 8).
the standard exposure time (2 h) revealed that the
AHP Structure
acceleration rate imposed on the personal’s body in
Kraft, combined cycle sections and Alstom are unde- After identification of the various aspects of the
sirable and higher than the standard limits at all sta- power plant including safety - health and environ-
tions. Such noted situation is caused due to the ac- ment, the hierarchal structure of the power plant risks
tivity of the equipments such as generators and were designed. The risks of the surrounding and in-
turbines (Table 7). door environment were considered within the designed
According to the results obtained from mea- structure. Technological risk including equipment se-
suring the thermal stress index (WBGT) for the power dimentation and corrosion as well as pollution of con-
plant personnel and comparison with the ACGIH sumed fuel, foundation subsidence caused by equip-
standard it was determined that the thermal stress ment vibration, operator, control system error, fire and
rate is higher than the standard limits in sections like explosion were selected regarding the sensitivity of
Cooling tower G11 and G12, Kraft and Alstom. It the operations and equipments. Among factors ef-
should be mentioned that this problem is caused by fected on safety and health risks of the plant, thermal
operation of turbines as well as personnel's outdoor stress, noise, ergonomics, vibration, harmful radia-
activities in the summer. It is worth to note that tem- tion, chemicals, light and magnetic field exposure can
Table 7. Vibration measurements results of Yazd Combined Cycle Power Plant (2009)
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S.A. JOZI, A.A. POURIYEH: HEALTH-SAFETY AND ENVIRONMENTAL RISK ASSESSMENT… CI&CEQ 17 (4) 437−449 (2011)
Table 8. The measurement results of WBGT index in Yazd combined cycle power plant (2009); standard value: 28 °C
be noted, which lead to risk of diseases including There is possibility of checking on the judgments
hearing loss, skeletal and muscle irritations, skin and consistency in Expert Choice environment. A method
respiratory illnesses, vision loss and long-term patient presented by Saaty for examination of judgments
respectively. Due to the activity of Yazd combined consistency is called inconsistency ratio (IR) [25].
cycle power plant, the socioeconomic and biophysical Thereby, the ratio is calculated for each set of the pair
environments are impressed which power generation, wise comparison, which must be lower than 0.1 [26],
job creation, hazards on health, the impressibility of otherwise the software will alarm to user [27].
water quality and quantity, soil characteristic and air Calculation results of Yazd combined cycle
quality can be mentioned. Considering the establish- power plant risks according to the severity and possi-
ment situation of the power plant, risks such as the bility of risk numbers suggested that fire and explo-
heat of the environment, lack of underground water sion, earthquake, the error of the control system and
resources and earthquake threaten the activity of operator, with weights equal to 26, 20.4 and 13.8
plant (Figure 6). have respectively the highest intensity among the
By importing the pair wise comparison matrix in power plant risks while the lowest one belongs to the
to the Expert Choice software, the weights of the risks “impact on land use” with total weight of zero. On the
were calculated according to the occurrence intensity other hand the hearing loss and vision and under-
and probability using Eigenvector method. Using the ground quantity with total weights of 14.4, 10 and 9.9
product of the criteria weights, the rate and priority of have the highest risk probabilities respectively. Mean-
the risks were specified in different environments. while, sediment and equipment corrosion with weight
Figure 6. The hierarchy structure for risk assessment of Yazd combined cycle power plant.
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S.A. JOZI, A.A. POURIYEH: HEALTH-SAFETY AND ENVIRONMENTAL RISK ASSESSMENT… CI&CEQ 17 (4) 437−449 (2011)
of 0.2 has the lowest risk probability. In technology also due to the plant activity and water harvesting
sector, “fire and explosion“ with weight of 20.4 has the from underground water supplies, the drop in the
highest intensity and the power plant foundation sub- groundwater levels will have the highest intensity and
sidence with weight of 2.9 has the highest ecological probability of occurrence. Consequently, the most im-
risk probability. Nonetheless, the fire and explosion portant risk affecting the biophysical environment of
with weight of 16.32 is considered the most important the area is the “effect on groundwater quantity”, which
ecological risk of the power plant. Among the power has a weight equal to 25.74. Considering the power
plant health and safety risks, electric shock with weight situation which is located on the region with the mo-
of 1.8 and personnel’s hearing loss with weight of derate- seismic intensity risk (equal to 0.25 g) and
14.4, respectively have the highest intensity and pro- due to existence of the main fault of Yazd located on
bability nevertheless the hearing loss with weight of a radius of 15 km far from the power plant, the earth-
12.96 is the most important health and safety risks of quake has the highest intensity with weight of 26.
the power plant (Figure 7). Regarding the situation of Ardakan-Yazd Sub-basin
The power generation has the highest intensity declared critical and has been had 4.2 m drop in un-
and probability as a result of industrialization of re- derground water, “groundwater drop” with weight of
gions and the increasing need of industries and com- 4.7 has the most probability and the area’s ground-
munities for energy. Thus, the most important socio- water drop with weight of 51.7 was determined as the
economic risk is electricity generation owing the weight most important risk affected the power plant activity
of 1.9. As regards, the highest water rate harvested (Table 9).
by people is obtained from digging deep wells and
Table 9. The amount of risk rate in different sectors of Yazd combined cycle power plant
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S.A. JOZI, A.A. POURIYEH: HEALTH-SAFETY AND ENVIRONMENTAL RISK ASSESSMENT… CI&CEQ 17 (4) 437−449 (2011)
Table 9. Continued
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S.A. JOZI, A.A. POURIYEH: HEALTH-SAFETY AND ENVIRONMENTAL RISK ASSESSMENT… CI&CEQ 17 (4) 437−449 (2011)
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APPENDIX
Table A1. A variety of pollutants existed in industrial and sanitary effluent of Yazd combined cycle power plant in 2008-2009
No. Pollutant name Pollutant abbreviation No. Pollutant name Pollutant abbreviation
1 Silver Ag 27 Nitrite No2
2 Aluminum ALl 28 Nitrate NO3
3 Arsenic As 29 Phosphate Po4
4 Bor B 30 Lead Pb
5 Barium Ba 31 Selenium Se
6 Beryllium Be 32 Sulfide H2S
7 Calcium Ca 33 Sulfite SO3
8 Cadmium Cd 34 Sulfate SO4
9 Free chlorine Cl 35 Vanadium V
10 Chloride CL 36 zinc Zn
11 Formaldehyde CH20 37 Oil and grease O&G
12 Phenol C6H50H 38 Detergent MBAS
13 Potassium cyanide CN 39 Biological oxygen demand BOD5
14 Cobalt Co 40 Chemical oxygen demand COD
15 Chromium cr+6 41 Dissolve oxygen DO
16 Chromium Cr+3 42 Total dissolved solid TDS
17 Copper CU 43 Total suspended solid TSS
18 Fluoride F 44 Sedimentable substances SS
19 Iron Fe 45 - pH
20 Mercury Hg 46 Radioactive materials -
21 Lithium Li 47 Turbidity NTU
22 Magnesium Mg 48 Color TCU
23 Manganese Mn 49 Temperature T
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No. Pollutant name Pollutant abbreviation No. Pollutant name Pollutant abbreviation
24 Molybdenum Mo 50 Gastrointestinal coliform -
25 Nickel Ni 51 Total coliform MPN
26 Ammonium NH4 52 Parasite egg -
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