function s=mv(v,Tr,pr)

R = 82.06; %gas constant (cm^3*atm)/(mol*k)

Tc = 304; %critical temperature in kelvin
Pc = 72.9; % critical pressure in atm
a = (27/64)*((R^2)*(Tc^2)/Pc);
b = (R*Tc)/(8*Pc);
T = (Tc*Tr);
P = (Pc*pr);
s = (((P+(a/v^2))*(v-b))-(R*T));

clear all
clc
tr = [1.1 1.3 2];
h = 0;
for pr = 0.1:0.1:10
h = h+1;
pr_list(h,1) = pr;
Pc = 72.9; % critical pressure in atm
R=82.06;
for i = 1:3
Tc = 304; %critical temperature in kelvin
T = (Tc*tr(i));
P = (Pc*pr);
v=100;
vsolve=fzero(@mv,v,[],tr(i),pr);
v=vsolve;
Z(h,i) = (P*v)/(R*T);
end
end
disp(' compressibility factor for')
disp(' pr Tr=1.1 Tr=1.3 Tr=2.0')
disp([pr_list Z])
plot(pr_list,Z(:,1),'ko',pr_list,Z(:,2),'rx',pr_list,Z(:,3),'bd')
xlabel('reduced pressure')
ylabel('compressibility factor')
title('variation of compressibilty with varying Tr and Pr')
legend('Tr =1.1','Tr =1.3','Tr=2.0')

compressibility factor for

pr Tr=1.1 Tr=1.3 Tr=2.0

0.1000 0.9761 0.9845 0.9957

0.2000 0.9512 0.9687 0.9915

0.3000 0.9252 0.9526 0.9873

0.4000 0.8980 0.9362 0.9832

0.5000 0.8694 0.9194 0.9791

0.6000 0.8391 0.9023 0.9751

0.7000 0.8069 0.8848 0.9712

0.8000 0.7722 0.8670 0.9673

0.9000 0.7346 0.8488 0.9635

1.0000 0.6930 0.8303 0.9598

1.1000 0.6464 0.8115 0.9561

1.2000 0.5932 0.7924 0.9526

1.3000 0.5331 0.7731 0.9492

1.4000 0.4773 0.7538 0.9458

1.5000 0.4460 0.7346 0.9426

1.6000 0.4358 0.7158 0.9395

1.7000 0.4361 0.6977 0.9365

1.8000 0.4417 0.6809 0.9337

1.9000 0.4501 0.6658 0.9310

2.0000 0.4603 0.6528 0.9284

2.1000 0.4717 0.6424 0.9260

2.2000 0.4838 0.6346 0.9237

2.3000 0.4965 0.6295 0.9216

2.4000 0.5095 0.6269 0.9197

2.5000 0.5228 0.6264 0.9179

2.6000 0.5363 0.6279 0.9163

2.7000 0.5500 0.6309 0.9149

2.8000 0.5638 0.6353 0.9137

2.9000 0.5777 0.6407 0.9127

3.0000 0.5917 0.6470 0.9119

3.1000 0.6057 0.6541 0.9112

3.2000 0.6197 0.6619 0.9108

3.3000 0.6338 0.6701 0.9106

3.4000 0.6478 0.6788 0.9106

3.5000 0.6619 0.6878 0.9108

3.6000 0.6760 0.6971 0.9112

3.7000 0.6901 0.7068 0.9118

3.8000 0.7041 0.7166 0.9126

3.9000 0.7182 0.7266 0.9137

4.0000 0.7322 0.7368 0.9149

4.1000 0.7463 0.7472 0.9163

4.2000 0.7603 0.7576 0.9179

4.3000 0.7743 0.7682 0.9197

4.4000 0.7883 0.7789 0.9217

4.5000 0.8023 0.7896 0.9239

4.6000 0.8162 0.8004 0.9263

4.7000 0.8301 0.8113 0.9289

4.8000 0.8440 0.8223 0.9316

4.9000 0.8579 0.8332 0.9345

5.0000 0.8718 0.8443 0.9375

5.1000 0.8856 0.8553 0.9407

5.2000 0.8995 0.8664 0.9441

5.3000 0.9133 0.8775 0.9476

5.4000 0.9270 0.8886 0.9512

5.5000 0.9408 0.8998 0.9550

5.6000 0.9545 0.9110 0.9589

5.7000 0.9683 0.9221 0.9629

5.8000 0.9820 0.9333 0.9671

5.9000 0.9956 0.9445 0.9713

6.0000 1.0093 0.9558 0.9757

6.1000 1.0229 0.9670 0.9802

6.2000 1.0366 0.9782 0.9848

6.3000 1.0502 0.9894 0.9894

6.4000 1.0638 1.0007 0.9942

6.5000 1.0773 1.0119 0.9991

6.6000 1.0909 1.0231 1.0040

6.7000 1.1044 1.0344 1.0091

6.8000 1.1179 1.0456 1.0142

6.9000 1.1314 1.0568 1.0194

7.0000 1.1449 1.0680 1.0246

7.1000 1.1583 1.0793 1.0299

7.2000 1.1717 1.0905 1.0353

7.3000 1.1852 1.1017 1.0408

7.4000 1.1986 1.1129 1.0463

7.5000 1.2119 1.1241 1.0519

7.6000 1.2253 1.1353 1.0575

7.7000 1.2387 1.1465 1.0632

7.8000 1.2520 1.1577 1.0689

7.9000 1.2653 1.1689 1.0746

8.0000 1.2786 1.1801 1.0805

8.1000 1.2919 1.1912 1.0863

8.2000 1.3052 1.2024 1.0922

8.3000 1.3185 1.2136 1.0982

8.4000 1.3317 1.2247 1.1041

8.5000 1.3449 1.2358 1.1102

8.6000 1.3581 1.2470 1.1162

8.7000 1.3713 1.2581 1.1223

8.8000 1.3845 1.2692 1.1284

8.9000 1.3977 1.2803 1.1345

9.0000 1.4109 1.2915 1.1407

9.1000 1.4240 1.3026 1.1469

9.2000 1.4371 1.3136 1.1531

 9.3000 1.4503 1.3247 1.1594

9.4000 1.4634 1.3358 1.1657

9.5000 1.4765 1.3469 1.1719

9.6000 1.4895 1.3579 1.1783

9.7000 1.5026 1.3690 1.1846

9.8000 1.5157 1.3800 1.1910

9.9000 1.5287 1.3911 1.1973

10.0000 1.5417 1.4021 1.2037

>>