Unifaq laboratorio

clc,clear,clf
n=input('ingrese el numero de iteraciones n=');
x1=[linspace(0.0001,0.5,(8*n)/10)
linspace(0.50001,0.999999999,(2*n)/10)];
x2=ones(1,length(x1))-x1;
x11=0:0.1:1;
%CONSTANTES A,B,C DE ANTOINE
%ETANOL
A1=8.04494;B1=1554.3;C1=222.65;
%AGUA
A2=7.96681;B2=1668.21;C2=228;
%PRESION CONSTANTE
P=520;%mmHg
T1=B1/(A1-log10(P))-C1;
T2=B2/(A2-log10(P))-C2;
for k=1:n
syms T
Pvp1(k)=10^(A1-(B1/(C1+T)));
Pvp2(k)=10^(A2-(B2/(C2+T)));
x0=[x1(k) x2(k)];
T0=T+273.15;
R=[0.9011 0.6744 1 0.92];
Q=[0.848 0.540 1.20 1.4];
v1=[1 1 1 0 ];
v2=[0 0 0 1 ];
v=[v1;v2]';
a=[0 0 986.5 1318;0 0 986.5 1318;156.4 156.4 0 353.5;300 300 -229.4 0];
r=R*v;
q=Q*v;
fs=(x0.*r)/(sum(r.*x0));
fa=(x0.*q)/(sum(q.*x0));
z=10;
L=(z/2)*(r-q)-(r-1);
lngc=(log(fs./x0)+(z/2)*q.*log(fa./fs)+L-(fs./x0).*sum(L.*x0));
X1=v1./(sum(v1));
X2=v2./(sum(v2));
om1=(X1.*Q)./sum(X1.*Q);
om2=(X2.*Q)./sum(X2.*Q);
tmn=eval(exp(-a./T0));
for i=1:4
j=1;
while j <= 4
s1(j)=(om1(j)*tmn(i,j))./(sum(om1.*tmn(:,j)'));
s2(j)=(om2(j)*tmn(i,j))./(sum(om2.*tmn(:,j)'));
j=j+1;
end
lnr1(i)=Q(i)*(1-log(sum(om1.*tmn(:,i)'))-(sum(s1)));
lnr2(i)=Q(i)*(1-log(sum(om2.*tmn(:,i)'))-(sum(s2)));
end
V=[v1(1) v2(1) v1(2) v2(2) v1(3) v2(3) v1(4) v2(4)];
for i=1:4
X(i)=(x0(1)*v1(i)+x0(2)*v2(i))/(sum([x0 x0 x0 x0].*V));
end
for i=1:4
m0(i)=X(i)*Q(i)/(sum(X.*Q));
 end
for i=1:4
j=1;
while j <= 4
s1(j)=(m0(j)*tmn(i,j))./sum(m0.*tmn(:,j)');
j=j+1;
end
lnrk(i)=Q(i)*(1-log(sum(m0.*tmn(:,i)'))-(sum(s1)));
end
lnR1=sum(v1.*(lnrk-lnr1));
lnR2=sum(v2.*(lnrk-lnr2));
lngr=[lnR1 lnR2];
lng=lngc+lngr;
g=exp(lng);
y1(k)=(x1(k)*Pvp1(k)*g(1)/P);
y2(k)=(x2(k)*Pvp2(k)*g(2)/P);
f=(y1(k)+y2(k))-1;
df=diff(f,T,1);
e=10^-6;d=1;
T=(T2+T1)/2;
while d > e
To=T-eval(f./df);
d=abs(eval(f));
T=To;
end
Tt(k)=T;
y1(k)=eval(y1(k));
y2(k)=eval(y2(k));
Pvp1(k)=eval(Pvp1(k));
Pvp2(k)=eval(Pvp2(k));
fprintf('%5.4f %8.4f %10.4f %8.4f %8.4f %8.4f %8.4f %8.4f
\n',x1(k),x2(k),Pvp1(k),Pvp2(k),Tt(k),y1(k),y2(k),y1(k)+y2(k))
end
subplot(1,2,1),plot(x1,y1,x11,x11,'-r'),xlabel('X1 ETANOL
(L)'),ylabel('Y1 ETANOL (V)'),title('DIAGRAMA X1 VS
Y1'),legend('UNIFAQ'),grid
subplot(1,2,2),plot(x1,Tt,'-g',y1,Tt,'-b'),xlabel('X1.Y1'),ylabel('T
ºC'),title('DIAGRAMA VS
X1.Y1'),legend('x1(Lìquido)UNIFAQ','y1(Vapor)UNIFAQ'),grid