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Things To Look Up in Green
Things To Look Up in Green
Summary of Talks
Color definitions/notes:
Things to look up in green
uhhh...and i guess that’s it for now
Monday
Plenary:
Friday
Pseudo Jahn Teller Effect Metal Alkoxides Interest from case where SO coupling much
larger than JT coupling (SO vs PseudoJT)
Vibronic structure helps explain this.
CaOCH3 (X2A1), decently high A state. SO split about 67 cm-1.
matrix constructed from PSJ coupling (off diagonal) and something else...
Use 2 approraches to simplifying hamiltonian matrix – both make 3x3 a 2x2 using replace-
ments, or make some approximations.
So in essence the theory did not account for PJT and SO, but with re-worked matrix it
agrees quite well!