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GM 1
GM 1
Subject: Chemistry
o
Q. 4.1 A conductivity cell filled with 0.01 M KCl gives at 25 C the
o
resistance of 604 ohms. The conductivity of KCl at25 C is 0.00141
1
cm 1 . The same cell filled with 0.01M AgNO3 gives a resistance
Molar conductivity m ?
cell constant b
K KCl =
R R
KCl KCl
1
b K
KCl
R KCl 0.00141
604 0 .8515cm
b 0.8516 4 1 1
K soln 1.304
10 cm
R soln 6529
Molar Conductivity,
4
K soln 1000 1.304 10 1000
m
C 0.001
1 2 1
130.4 cm mol
o
Q. 4.2 A conductivity cell filled with 0.01 M KCl gives at 25 C the
Subject: Chemistry
1 1
Conductivity of KCl solution K KCl 0.01286 cm
Concentration C 0.005 M HCl
Resistance of HCl solution R sol 529ohm( )
cell constant
Conductivity =
Resistance
b
K KCl =
R KCl
1
b K
KCl
R KCl 0.01286
85.5 1.1cm
b 1.1 3 1 1
K soln 2.08
10 cm
R soln 529
ohm
Molar Conductivity,
3
Ksoln 1000 2.08 10 1000
m (HCl)
C 0.005
1 2 1
416 cm mol
o
Q. 4.3 The molar conductivity of 0.05M BaCl 2 solution at 25 C is 223
1 2 1
cm mol . What is its molar conductivity?
1 1
( 0.01115 cm )
1
Answer : Molar conductivity m
223
cm 2mol 1
Subject: Chemistry
Conductivity k ?
k 1000
m
C
m C 223 0.05 1 1
k
0.01115 cm
1000 1000 .
o 3 1 1
Q. 4.4 The conductivity of 0.02M AgNO 3 at 25 C is 2,428 10 cm
1 2 1
What is its molar conductivity? (121.4 cm mol )
Answer : Concentration of solution = C = 0.02 M AgNO3
Molar conductivity
m
?
3
k 1000 2.428 10 1000
m
C 0.02
1
121.4 cm 2mol 1 (or 121.4 Scm 2mol 1)
1 2 1
Q. 4.5 A conductivity cell filled with 0.02M H 2SO 4 is 618 cm mol , what
1 2 1
Molar conductivity m
618 cm mol
Cell constant b ?
k 1000
m
C
m C 618 0.02 1
k
0.01236 cm 1
1000 1000
Subject: Chemistry
cell constant b
Now, k =
R soln R soln
1
b
k R
soln 0.01236
122 1.51cm .
o
Q. 4.6 A conductivity cell filled with 0.02M AgNO 3 gives at 25 C a
1
Cell constant b 2.3 cm
Molar conductivity
m
?
cellconstant b 2.3
Conductivity of soln k =
1 1
0.002429 cm
1 2 1
121.5 cm mol
1 2 1
concentration?(271.3 cm mol )
Answer : Given:
1 2 1
149.7
0(NH Cl)
4
cm mol
1 2 1
248.1 cm
0(Na OH)
4
mol
© Tata ClassEdge. All rights reserved Page 4 of 18
MHSB Chapter Exercise Solutions
Subject: Chemistry
1 2 1
126.5
0(NaCl) cm mol
0(NH 4OH) ?
By Kohlrausch’s law,
0 0
0(NH Cl)
4
NH4
Cl
… (i)
0 0
0(NaOH)
Na
OH
… (ii)
0 0
0(NaCl)
Na
Cl
… (iii)
Adding equation (i) and (ii) and subtracting equation (iii) we get
equation I.
0(NH OH)
4 0(NH
Cl)
4
0(NaOH) 0(NaCl) I
1 2 1
271.3 cm mol
0(NH 4OH) ?
By Kohlrausch’s law,
0 0
0(AgI)
Ag
I
…I
© Tata ClassEdge. All rights reserved Page 5 of 18
MHSB Chapter Exercise Solutions
Subject: Chemistry
0 0
0(NaI)
Na
l
… (i)
0 0
0(AgNO3 )
Ag
I
… (ii)
0 0
0(NaNO
3)
Na
NO 3
… (iii)
Adding equation (i) and (ii) and subtracting equation (iii) we get
equation I.
0(AgI) 0(NaI)
0(AgNO 3) 0(NaNO )3
1 2 1
138.8 cm mol
Q.4.9 Estimate the mass of copper metal produced during the passage of
5A current through CuSO 4 solution for 100 minutes. The molar mass
Mass of Cu deposited ?
Reduction half reaction at cathode:
Cu (aq) 2e Cu (s)
= 5 6000
= 3000 C
Q
Number of moles of electrons passed =
F
C
30000
mol
96500
1
C mol
Subject: Chemistry
=0.3109 mol
1 mol
0.5
2 mol
Q. 4.10 How long will it take to produce 2.415g of Ag metal from its salt
solution by passing a current of 3A? How many moles of electrons
1
are required? Molar mass od Ag is 107.9 g mol . (12 min, 0.02238
1
mol e )
Answer : Electric current = I = 3A
Mass of Ag produced =2.415 g
1
Molar mass of Ag = Atomic mass of Ag = 107.9 g mol
Time = t =? Number of moles of electrons =?
Reduction half reaction at cathode:
Ag (aq) e
Ag
(s)
Mass of Ag formed
Number of moles of Ag formed
Molar mass of Ag
© Tata ClassEdge. All rights reserved Page 7 of 18
MHSB Chapter Exercise Solutions
Subject: Chemistry
2.415
mol
107.9
= 0.02238 mol
From the reaction,
1 mole of Ag requires 1 mole of electrons
0.02238 mole of Ag will require, 0.02238 mol electrons
1 mole of electrons carries a charge of 96500 C.
0.02238 mole of electrons will carry of charge, 0.02238 96500 =
2160 C
Quantity of electricity passed = Q =2160 C
Let I be the current strength and t be time of electrolysis.
Then,
Q=I t
Q 2160 720
t
720s =
min 12min.
I 3 60
Subject: Chemistry
1
Molar mass of Cu = 63.5 g mol
Strength of current = I =?
1 Faraday = 96500 C = 1 mol electrons
1 mol Cu = Molar mass of Cu = 63.5 g
Reduction half reaction:
2
Cu 2e Cu
Q 7199
Current, I = 2A
t 3600
Current strength = I = 2A
Moles of electrons required = 0.0746 mol
Q. 4.12 A current of 6 amperes is passed throughAlCl3 solution for 15
Subject: Chemistry
Al3
(aq) 3e
Al (aq)
t
Quantity of electricity passed = Q = I
= 6 900 = 5400 C
Q 5400
Number of moles of electrons =
F 96500
= 0.05596 mol
From half reaction,
3 moles of electrons deposit 1 mole Al
0.05596 moles of electrons will deposit,
0.05596
= 0.01865 mol Al
3
Now,
0.01865 mole Al weighs 0.504 g
0.504
1 mole Al will weigh, = 27 g
0.01865
1
Hence molar mass of Al is 27 g mol
Q. 4.13 How many moles of electron are required for the reduction of
Zn 2
2e
Zn
2
1 mole of Zn requires 2 moles of electrons
Subject: Chemistry
2
3 moles of Zn will require, 3 2 = 6 moles of electrons.
1 mol of electrons = 1 F
6 mol of electrons = 6F
1 mol of electrons = 1 F
3 mol of electrons = 3F
Subject: Chemistry
Q. 4.15 Calculate the amounts of Na and chlorine gas produced during the
electrolysis of fused NaCl by the passage of 1 ampere current for 25
1
Molar mass of Cl2 71g mol
(ii) 2Cl
Cl 2e
2(g)
(Oxidation half reaction)
= 0.01554 23 = 0.3572 g Na
g mol 1
Mol
Subject: Chemistry
Mass of Mg produced =?
Volume of Cl 2 at NTP produced =?
(i) Mg 2e
Mg (Reduction half reaction)
(ii) 2Cl Cl
2
+2e (Oxidation half reaction)
=2 3600 = 7200 C
1 Faraday = 1 mol electrons
Subject: Chemistry
Q 7200
Number of moles of electrons passed = 0.07461 mol
F 96500
From half reaction (i),
2 moles of electrons deposit 1 mole of Mg
0.07461moles of electrons will deposit,
0.07461 1
0.037305 mol Mg
2
Mass of Mg = Moles of Mg Molar mass of Mg
0.037305 24 0.8953 g Mg
3
= 835.6 cm
respectively. (0.5447 g)
Answer : Mass of Zn deposited = WZn = 0.561 g
© Tata ClassEdge. All rights reserved Page 14 of 18
MHSB Chapter Exercise Solutions
Subject: Chemistry
Mass of Cu deposited =?
Mass of Zn produced
Mole ration of Zn
1
0.5
2
1
Similarly, mole ratio of Cu 0.5
2
Mole of Cu produced mole ratio of Cu
moles of Zn produced mole ratio of Zn
moles of Cu produced
mole ratio of Cu
mole of Zn produced
mole ratio of Zn
0.5 3
0.5 8.578 10
8.578 10 3 mol cu
Mass of Cu produced
= mole of Cu molar mass of Cu
3
= 8.578 10 63.5
= 0.5447 g Cu
© Tata ClassEdge. All rights reserved Page 15 of 18
MHSB Chapter Exercise Solutions
Subject: Chemistry
Q. 4.18 Two electrolytic cells one containing AlCl 3 solution and the other
1
mol respectively. (4.36g)
Answer : Mass of Al deposited = 1.2 g
(i) Al (aq)
3e Al (s) (Half reaction in AlCl3 cell)
1 mol 3 mol 1 mol
2
(ii) Zn (aq) 2e Zn (s) (Half reaction in ZnSo 4 cell)
1.2
Number of moles of Al deposited =0.04444 mol.
27
Hence 0.1333 moles of electrons are passed through both the cells in
The series.
From reaction (ii),
2 moles of electrons deposit 1 mol Zn
0.1333 moles of electrons will deposit,
0.1333
=0.06665 mol Zn
2
© Tata ClassEdge. All rights reserved Page 16 of 18
MHSB Chapter Exercise Solutions
Subject: Chemistry
mol g mol1
Q. 4.19 Write the cell reaction and calculate the standard potential of the cell
Ni (s) | Ni 2 (1 M)| |C l (1 M)|C l 2(g, 1 atm)| Pt
0 0
E Cl2
1.36V and E Ni
0.25V (1.61V)
1
At RHE( Cl 2(g) e Cl (aq) ) 2(Reduction at cathode)
2
2
Ni(s) Cl2(g) Ni (aq) 2Cl (aq)
(over all cell reaction)
The standard emf is given by,
0 0 0
E cell
E cathode E anode
E 0 Cl /Cl
E 0Ni 2
/ Ni
2
1.36 ( 0.25)
Q. 4.20 Write the cell reaction and calculate the emf of the cell.
2
Identify anode and cathode. Name the right hand side electrode.
(0.368V)
Subject: Chemistry
At RHE Hg Cl
2 2(s)
2e 2Hg 2Cl
(I) (aq)
(Reduction at cathode)
2
Pb(s) Hg 2Cl
2(s) Pb (aq) 2Hg(I) 2Cl (aq) (Overallcellreaction)
0
Left hand electrode is anode since E 2
is less and right-hand
Pb /Pb
0
electrode has ( E cal ) higher, hence, it is cathode.
The right-hand electrode is a calomel electrode,
0.242 ( 0.126)
0.368 V