No.: Test Booklet Code TARA 5265689 This Booklet contains 24 pages. P Do not open this Test Booklet until you are asked to do so. 1 1 12, 13, 14, 15, 10. Important Instructions : ‘The Answer Sheet is inside this Test Booklet. When you are directed to open the Test Booklet, take out the Answer Sheet and fill in the particulars on side-1 and side-2 carefully with blue/ black ball point pen only. ‘The testis of 3 hours duration and Test Booklet contains 180 questions. Each question carries 4 marks. For each correct response, the candidate will get marks. For each incorrect response, one mark will be deducted from the total scores. The maximum marks are 720, Use Blue/Black Ball Point Pen only for writing particulars on this page/ marking responses. Rough work is to be done on the space provided for this purpose in the Test Booklet only. ‘On completion of the test, the candidate must hand over the Answer Sheet to the invigilator before leaving the Room/ Hall. The candidates are allowed to take away this Test Booklet with them. ‘The CODE for this Booklet is P. Make sure that the CODE printed on Side-2 of the Answer Sheet is the same as that on this Booklet. In case of discrepancy, the candidate should immediately report the matter to the Invigilator for replacement of both the Test Booklet and the Answer Sheet. The candidates should ensure that the Answer Sheet is not folded. Do not make any stray marks on the Answer Sheet. Do not write your Roll No. anywhere else except in the specified space in the Test Booklet/ AnswerSheet Use of white fluid for correction is NOT permissible on the Answer Sheet. Each candidate must show on demand his/her Admit Card to the Invigilator. No candidate, without special permission of the Superintendent or Invigilator, would leave his/her seat. The candidates should not leave the Examination Hall without handing over their Answer Sheet to the Invigilator on duty and sign the Attendance Sheet twice. Cases where a candidate has not signed the Attendance Sheet second time will be deemed not to have handed over Answer Sheet and dealt with as an unfair means case. Use of Electronic/ Manual Calculator is prohibited. ‘The candidates are governed by all Rules and Regulations of the examination with regard to their conductin the Examination Hall. All cases of unfair means will be dealt with as per Rules and Regulations of this ‘examination No partof the Test Booklet and Answer Sheet shall be detached under any circumstances. ‘The candidates will write the Correct Test Booklet Code as given in the Test Booklet/ Answer Sheet in the Attendance Sheet. ‘Name of the Candidate (in Capitals) : RollNumber —_ = in figures in words Centre of Examination (in Capitals). Candidate's Signature : Invigilator’s Signature Fascimile signature stamp of CentreSuperintendent:P 2 1. HgCly and 1, both when dissolved in water containing I~ ions the pair of species formed is : () Bgl, Q) Hgl,I> 6) Hell @ Healy, 1 2, Predict the correct intermediate and product in the following reaction H,C-C=CH = 6 intermediate ——+ product Pk “ © () A: HyC-C=CH, Bz HyC—C-CHy SO, o 7 @ A: HyC-C=CHy OH @) A: HyC-C-CH, i ° WF AL HyC-C=CH, B: HyC-C-CHy OH ow 3. Thecorrect statement regarding electrophile is (1) Blectrophile is a negatively charged species and can form a bond by accepting a pair of electrons from a nucleophile 2) Flectrophile is a negatively charged species and can form a bond by accepting a pair of electrons from another electrophile @) _ Electrophiles are generally neutral species and can form a bond by accepting a pair of electrons from a nucleophile 6) Electrophile can beeither neutral or positively charged species and can form a bond by accepting a pair of electrons from a nucleophile 4. Which of the following pairs of compounds is isoelectronic and isostructural ? (i) > BeCl, XeF, Q) Tel XeF, 2) Bry, Xel Fy XeF, 5. 8 The species, having bond angles of 120° 1s : (PH, Q cr @ Nc @ BC Which of the following is a sink for CO? (1) Haemoglobin @)_ Micro organisms present in the soil @) Oceans @ Plants Which one of the following pairs of species have th same bond order ? @) O,NO @)_0,No+ @__ NCO @ 3,03 Of the following, whichis the product formed whe cyclohexanone undergoes aldol condensatio followed by heating ? Name the gas thatcan readily decolourise acidifie, KMnO, solution : (Co, @_ 50, @ No, @) P0510. Which oneis the wrong statement? i de-Brogte’s wavelengthis givenby = —_, mo where m=mass of the particle, » = group velocity ofthe particle. ®) The uncertainty principle is AExAt>hY/, @) _ Halffilled and fullfilled orbitals have greater stability due to greater exchange energy, greater symmetry and more balanced arrangement. @ ___ Theenergy of 2s orbital is less than the energy of 2p orbital in case of Hydrogen like atoms. 11. Correct(increasing order for the wavelengths of ‘sorptiop in the visible region for the complexes of Co? @_[Co(en)sP*,[Co(NHy)6}°*, [Co HO) * @)— [Co(H,O)g}°*,[Co (en)3}°*, [Co (Na) * @ — [Co(H,O),F*, [Co(NH,),F*, [Co (en) * (8) [Co(NH3)6}°*, [Co (en)3}**, [Co (H,0).* 12. The correct order of the stoichiometries of AgCI formed when AgNO; in excess is treated with the complexes: CoCh,6NH, CoCh,5 NHy, CoCl,4 NH; respectively (1) 1AgCl,3 AgCl,2 Agcl (2)__3AgCl 1 AgCl 2 AgCl SAgCl, 2 AgCl 1 Aj (@)__ 2AgCL3Agcl, 1 Agcl 13. Which oneis the most acidic compound ? OH a qd). Ne CH; OH ® OH a ® f | SS No, OH OnN, NO} #) NO, 14, 15. 16. v7. 18. P ‘The correct increasing order df basic strength for the following compounds is: NH, NH, NH), NO; CH: 0) o° ay Q) ucm<1 Q M CH,~CH=CH, > CH,—C CH>CH=CH @) CH=CH > CHj-C = CH > CH)=CH, > CH3-CH,, @ CH=CH > CH=CH, > CH,—C=CH > CH, -CH, (@ CH—-CH, > CH)=CH, > CH,~C=CH > CHECH The heating of phenyl-methyl ethers with HT produces. (1) ethyl chlorides @ _ iodobenzene @_ phenol @ benzene