[&)Perstorp Formox Determination of methanol in formaldehyde solutions by density 1 Scope and field of application “This test method covers the determination of methanol in formaldehyde solutions. Wis Iterative test method to the GC-etermination (dac, no. D4.4.4), which is more accurate, 2 References 2.1 Walker J. Formaldehyde, ed. 3 1964, page 86-91 3 Summary of test method ‘The density of the formaldehyde solution is determined either with a chain balance or with an electrical balance, By knowing the formaldehy:le concentration (determined by either the test method in doc, no. D4.4.1 or D4.4.2), the methanol content can be determined from a graph. 4 Interferences No interferences are known, 5 Apparatus 5.1 Chain balance for determination of density, required accuracy to the 4" decimal (type Westphal or an electronic balance) 5.2. Ordinary laboratory equipment 6 Reagents 6.1 on-exchanged water 7 Hazards For hazard information and guidance, see the chapter Safety Aspects and the supplier's Material Safety Data Sheet. 8 Sampling ‘Sampling is described in section 3, doc. no. D4.3.1 ~ lanaiyses: jelermination of methanol in formaldehyde jutions by density ais on tae ae yecember2, 1999 fi (4)_| maTFie 4.5 | densCH3OH 991202.doc,[@Perstorp Formox 9 Calibration Calibrate the balance at the density of water being 1.0000 at 4 *C. 9.1 Calibrate the balance at the calibration points in Table t. "Temperature," Density 10 0957 | 15 0.9991 20 (0.9982 25 0.9970 Table 1 10 Procedure 10.1 Measure the density of the sample. 11 Calculations 11.1 Calculate the weight percent of methanol from the graphs on pages 3-4 12 Expression of results Report the methanol content in % (w/w) to one decimal place, e.g. 0.5 % (wh). 43 Precision 13.1 Repeatability ~ Repeatability has not been determined for this test method, 13.2 Reproducibility - Reproducibility has not been determined for this test method, ay ition aa ‘nm —_” [Analyses for formaldehyde plants. cemper2, 1999 P| prove 7 Determination of methanol in formaldehyde Trio kb solutions by density 4.5 I densCH3OH 991202.doo.DOP EOEVES HOCHOSUOD SPF SLE AG SOOT 1s v'c0d___opfyopreuuioy ut oveLjeUl Jo LONeU HEI BEET Tea 3g ‘SUBIE OA GOPTEWIO] 10] SOBATEU ei vousal von: ere sett we sueh vt so 60 $801 so of ze ve ob ” %0- %t %2 Ee (yin) 2% uojuod jouRHON E xou1o4 dioysiag FE] (1) % ‘wonenuosues ophyopreunios