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Milk Powder

Chapter · January 2015


DOI: 10.1016/B978-0-12-384947-2.00465-7.

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Kalyankar S.D., Deshmukh M.A., Chopde S.S., Khedkar C.D., Lule V.K. and Deosarkar S.S. (2016) Milk
Powder. In: Caballero, B., Finglas, P., and Toldrá, F. (eds.) The Encyclopedia of Food and Health vol. 3, pp. 724-
728. Oxford: Academic Press.

© 2016 Elsevier Ltd. All rights reserved.


Author's personal copy

Milk Powder
SD Kalyankar, MA Deshmukh, and SS Chopde, Government College of Dairy Technology, Udgir, India
CD Khedkar, College of Dairy Technology, Pusad, India
VK Lule, National Dairy Research Institute (NDRI), Karnal, India
SS Deosarkar, College of Dairy Technology, Pusad, India
ã 2016 Elsevier Ltd. All rights reserved.

Introduction Today, MP is usually made by spray-drying. Alternatively,


the milk can be dried by drum (roller)-drying and freeze-dry-
Milk is a nutritious food. Raw milk from healthy cows is sup- ing. Freeze-drying preserves almost all the nutrients in milk but
posed to contain relatively few bacteria. Drinking of raw milk of it is very expensive.
healthy cows reduces the health risk but it is highly perishable. China, the United States, and France are the major markets
In history, mankind has made various attempts to preserve and for dried milk products. New Zealand is the largest exporter of
concentrate milk so as to extend its shelf life. Marco Polo in the MP. Even though the United States, Australia, Argentina, and
thirteenth century reported that soldiers of Kublai Khan carried European regions are the largest producers of MP, they do not
a dried milk on excursions. The belief is that part of the fat was fall in to the category of largest exporters. The United Kingdom,
removed from the milk before drying and dehydration was Germany, the Netherlands, and Brazil are the major importers
accomplished by solar heating. The first usable commercial of the MP.
production of milk powder (MP) was invented by the Russian
chemist M. Dirchoff in 1832. In 1850, Birdseye concentrated
milk with added sugar until a solid was obtained. In 1855, T. S. Definition and Composition
Grimwade filed a patent on process of drying of milk, though
William Newton had patented a vacuum-drying process as early The internationally agreed definition of the MP is “milk prod-
as 1837. The real beginning of the concentrated and dried dairy ucts which can be obtained by the partial removal of water
product industry began in the nineteenth century when Nicolas from milk. The fat and/or protein content of the milk may have
Appert, a French inventor, described his procedure for concen- been adjusted, only to comply with the compositional require-
trating and drying milk. In 1909, Nicolas Appert developed ments in Section 3 of Codex Standard, by the addition and/or
dried milk in tablet form by air-drying of milk solids concen- withdrawal of milk constituents in such a way as not to alter
trated to a ‘dough’ consistency. During the second half of the the whey protein to casein ratio of the milk being adjusted.”
nineteenth century, attempts were made to produce a dried The standard specifies that only milk and cream are permit-
milk, which involved the addition of other dry products to ted as raw materials for MP. However, the protein content of
concentrated milk. Sugar, cereal products, and sodas, singly or the powder may be decreased by addition of lactose or
in combinations, were added. increased by addition of skim milk or partially skim milk or
The MP is a perfect solution to those who lack immediate by addition of the retentate or permeate obtained from the
access to adequate refrigeration facilities. MP results from treatment of milk by ultrafiltration (UF). The standard also lists
extracting water content out of milk. The main purpose of other permitted additives from within the following groups:
converting milk into MP is to convert the liquid perishable stabilizers, emulsifiers, acidity regulators, anticaking agents,
raw material to a product that can be stored without substan- and antioxidants. No other additives are sanctioned. Standards
tial loss of quality, preferably for some years. The MP has are also provided for thresholds for contaminants, production
various applications in confectionaries, bakeries, infant hygiene, and product labeling. The composition of different
formulas, nutritional foods, etc. types of powder is depicted in Table 1.
Production of MP has become an increasingly important
segment of the dairy industry, which is expected to grow further
because of its features such as better keeping quality, less storage Technology of MP Manufacture
space, and lower transportation costs, which result in attractive
economics and convenience during industrial and domestic The MPs are dairy products from which the water has been
formulation of composite foods. Nonfat dry milk serves the removed to the greatest extent possible, thus creating hurdles
same purpose for milk solids-not-fat that traditionally butter in the growth of microorganisms. Production of MP consists of
has done for milk fat. The ultimate aim of the industry is to the processing steps like reception, clarification, cooling and
obtain dry products, which if recombined with water give little storage, standardization, heat treatment, evaporation, homog-
or no evidence of detrimental change compared to the original enization, drying, and packaging as shown in Figure 1.
liquid product. Various names have been applied to the same Raw milk plays an important role in deciding the quality of
dry milk product. For example, nonfat dry milk also has been MP. Milk should be of high chemical, sensory, and bacterio-
called skim MP (SMP), dried skim milk, nonfat dry milk solids, logical quality. At reception point, chemical and bacteriologi-
and dehydrated skim milk. Dry whole milk, dry cream, dry cal tests are carried out before selection of raw milk. High
buttermilk, and others frequently are called dried or powdered microbial load in raw milk adversely affects the solubility of
whole milk, according to their identities. MP. After reception, the milk may be clarified or treated in

724 Encyclopedia of Food and Health http://dx.doi.org/10.1016/B978-0-12-384947-2.00465-7


The Encyclopedia of Food and Health, (2016), vol. 3, pp. 724-728
Author's personal copy
Milk Powder 725

Table 1 Composition of milk powders

Powder form

Skim milk
No. Constituents Whole milk powder Partly skim milk powder powder

1. Milk fat Minimum 26% and less than 42% More than 1.5% and less than 26% 1.5% m/m
m/m m/m
2. Minimum milk protein in milk solids- 34% m/m 34% m/m 34% m/m
not-fata
3. Maximum watera 5% m/m 5% m/m 5% m/m
a
The water content does not include water of crystallization of the lactose; the milk solids-not-fat content includes water of crystallization of the lactose.
Source: Codex Alimentarius Commission (2011). Milk and milk products (2nd ed.). FAO & WHO.

Raw milk concentrated prior to drying; usually, a continuous multiple


effect evaporator is used. The concentrate is not always homog-
enized, especially in the case of spray-dried powders. Homog-
Receiving, selection and clarification enization of concentrated milk increases its viscosity, which
leads to coarse droplets during atomization. The concentrated
milk is generally dried by roller-drying or spray-drying method.
Storage of chilled milk There have been attempts to develop completely new dry-
ing methods. However, only spray-drying and roller-drying
methods are used for industrial production of MP. In the case
Standardized milk of roller-drying, concentrated milk comes in direct contact with
the hot drum surface, resulting in some irreversible changes
such as caramelization of lactose, Maillard’s browning, and
Heat treatment denaturation of proteins, which decrease the solubility of the
powder.
Spray-drying in the dairy industry dates back to around
1800, but it was not until 1850 that it became possible in
Concentrate milk by evaporation
major scale to dry milk. All processes, however, required addi-
tion of sugar, sulfuric acid, or alkali, so that the end product
Homogenization
could not be considered pure. One of the first spray-drying
patents was applied for in 1901 by the German Mr. Stauf, who
sprayed the milk by nozzles into a chamber with warm air. The
first real breakthrough, however, was in the United States in
Drying
1913, when the American Mr. Grey and the Dane Mr. Jensen
developed a nozzle spray dryer and started to produce and sell
drying installations on a commercial scale. The first rotary
Packaging of milk powder
atomizer was developed by the German Mr. Kraus in 1912,
but not until 1933, when the Danish engineer Mr. Nyrop filed
his world patent, which was the real breakthrough of atomiza-
Storage tion. The basis for the modern MP industry, formed by these
Figure 1 Generalized scheme for production of milk powder. pioneers, has led to new developments, and the spray-drying
equipment installed nowadays is in most cases very sophisti-
bactofuge to reduce the contamination by particulate matter cated and involves a highly technical and technological design.
and bacteria. Nowadays, microfiltration technique is used for The feed is pumped from the product feed tank to the atomiz-
manufacture of low-heat powders with very low bacterial ing device, located in the air disperser at the top of the drying
loads. To avoid subsequent growth of psychotropic bacteria, chamber. The drying air is drawn from the atmosphere via a
clarified milk is stored under refrigeration until it ultimately filter by a supply fan and is passed through the air heater to the
heat-treated. Raw milk is standardized by adding calculated air disperser. The atomized droplets meet the hot air and the
amount of skim milk or cream. Standardization of the protein evaporation takes place, while cooling of the air happens
content involves addition of either permeate from the UF of simultaneously. After the spray is dried in the drying chamber,
skim milk or retentate to reduce protein content, or retentate is the majority of the dried product falls to the bottom of the
added to increase the protein content. chamber and enters a pneumatic conveying and cooling sys-
The heat treatments eliminate all the pathogenic organisms. tem. The fines, which are the particles with a small diameter,
It also destroys saprophytic microorganisms, inactivates will remain in the air, and it is therefore necessary to pass the
lipases, and activates SH groups of b-lactoglobulin, thus air through cyclones to separate them. The fines leave
increasing resistance to autoxidation during storage. Milk is the cyclone at the bottom via a locking device and enter the

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726 Milk Powder

pneumatic system, too. The air passes from the cyclone to the dry form, and the ‘straight-through’ process, where instantiza-
atmosphere via the exhaust fan. The two fractions of powder are tion is accomplished during drying.
collected in the pneumatic system for conveying and cooling Dry MP is the starting material for the rewetting procedure.
and are passed through a cyclone for separation, after which The powder is dispersed in the wetting chamber and gains a
they are bagged off. The instrumentation comprises indication water content of 5–10%, causing powder particle agglomera-
of the temperature of the inlet and outlet air, as well as auto- tion. The agglomerated product is transferred to the vibrating
matic control of the inlet temperature by altering the steam fluid bed dryer and cooler, where it is redried in a hot air
pressure and amount of oil or gas to the air heater and automatic stream at 90–120  C and immediately cooled to approximately
control of the outlet temperature by altering the amount of feed 10  C. The final product from the fluid bed dryer has a water
pumped to the atomizing device. The spray-drying process has content <4% (2–4%). Hot air, blown upward through the fine
become a highly acceptable method for drying milk. After dry- perforated plate of the fluid bed dryer, ‘fluidizes’ the powder
ing, it is essential to cool the powder immediately to a temper- and carries the smallest powder particles or fines to the
ature below the melting point of fat to maintain better flavor, cyclone, where separation takes place. The air is discharged
body characteristics, and long shelf life. into the atmosphere after heat and solids have been recovered
The production of SMP slightly differs from the whole MP and the fines are returned to the start of the process. Instantiza-
(WMP). Pasteurization is the most intensive heat treatment by tion process is complicated in the case of WMP as the surface of
low-temperature method to achieve the minimal detrimental particles is covered with milk fat layer. Free fat forms a hydro-
heat-induced changes like serum protein denaturation. phobic layer on the particle surfaces, impregnating them and
Homogenization is omitted and the milk can be concentrated decreasing their water-binding capability. In order to prevent
to higher solid contents. Sometimes, vitamin A preparations this and improve the recombination properties, powder parti-
are added by dry mixing. SMP is susceptible to humidity and cles are lecithinated by adding lecithin mixed with butter oil
heat-induced changes, which can intensify the adverse effect on during instantization. In this process, the powder is dried in
the powder quality; therefore, it must be promptly cooled. two stages and the fines are recirculated to the wet zone. The
Powder should be packed in suitable containers that protect lecithinated powder should be cooled and packed in a suitable
it from moisture, air, light, etc. Common wrappings are paper, material to protect the agglomerates from breaking down.
multilayer boxes or bags with a polyethylene layer inside,
metal barrels with polyethylene bags inside, or tins covered
with aluminum foil at the contact surface. When planning the Properties of MP
quantity of wrapping material, it is necessary to consider the
bulk density of the product, because it is highly affected by The important properties of MP are particle size, shape and
processing parameters and techniques. When the product is surface density, flowability, dissolution, insolubility, and whey
intended for long storage, it is packaged in an atmosphere of protein nitrogen (WPN) index. These properties decide the
inert gas, mostly nitrogen, or in a partial vacuum (4.0–5.3 KPa) quality and the suitability of MP in specific applications.
to avoid oxidative changes of fat and other components. Prop-
erly produced and packed milk power, with low oxygen con-
Particle Size
tent, is stored at ambient temperature.
Particle size is an important physical property of MP and can
relate to its appearance, reconstitution, and flow characteris-
Instantization tics. Particle size in MP can affect powder reconstitution prop-
erties. Difference in particle size can lead to stratification of the
Instant MP has better reconstitution properties than other MPs. powder with the higher solids concentrated at the top, which
The instantization process patented by Peebles significantly will affect reconstitution of the dry product. Wettability and
improved the quality and economical aspects of the drying dispersibility of MP can also be influenced by particle size.
technology. The principal purpose of instantizing is to improve Dispersibility decreases as percentage of fine particles below
the rate and completeness of reconstitutability of MP. The aim 90 mm increases. Flowability also depends on particle size and
of spray-drying process is to produce particles with a big sur- shape. Large particles tend to flow more easily than smaller
face/mass ratio. The reconstitution of small particles of powder particles. Shape and size of the particles will affect the closeness
in water is, however, difficult and requires intensive mixing for of the particle pack, which in turn will affect the powder bulk
their dispersion. One of the major objectives of new innova- density. The particle of MP generally consists of a continuous
tions in the area of spray- and fluid bed-drying is to produce mass of amorphous lactose and other low-molar-mass compo-
instant powder by effecting agglomeration. Agglomeration nents in which fat globules, casein micelles, and serum pro-
provides the structure of porous aggregates, which disperse teins are embedded. The particles also contain vacuoles of
readily and quickly without vigorous agitation to produce occluded air where particle surfaces are not in contact. The
stable reconstituted milk. The properties of dried products surface of spray-dried particles not only is usually smooth but
improved positively by the instantizing process include wetta- also may be wrinkled. Conditions such as higher inlet air
bility, penetrability, sinkability, dispersibility, and dissolvabil- temperature and larger temperature differences between the
ity. The process permits a better equilibrium among these hot air and powder particles may contribute to wrinkles. The
variables. An effective agglomeration is achieved by either presence of particles of different morphology in the same sam-
rewet or straight-through methods: the rewet process, where ple can be attributed to the different drying conditions to which
the instantization is carried out after the powder is obtained in the individual particles were exposed. Particle size can be

The Encyclopedia of Food and Health, (2016), vol. 3, pp. 724-728


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Milk Powder 727

influenced by the milk characteristics, processing conditions, minutes. Generally, a small part does not dissolve. After a
and the type of equipment used in the drying process. Atomiza- solution is obtained, it may take about a day before its com-
tion parameters influence product shape and size distribution of position, especially the salt distribution, has more or less
powder particles making it possible to control powder particle reached equilibrium. This process may be accelerated by heat-
size. A spray-dried particle using centrifugal atomization will ing the reconstituted milk to 50–60  C and then cooling it
give a larger particle than the pressure nozzle atomization. again.
Spray-dried powder particles usually are spherical with diame-
ters in the range of 10–250 mm. Rapid dispersion requires a
Insolubility
particle size of approximately 150–200 mm diameter. The parti-
cles in agglomerated MP are larger and irregular in shape and Insolubility can be estimated in various ways. The powder is
contain very few separate small particles. Agglomeration causes dissolved in water under standardized conditions (concentra-
an increase in the amount of air incorporated between the tion, temperature, and duration and intensity of stirring) and
powder particles. The air is replaced by water during reconstitu- centrifuged. The supernatant is removed and replaced by water
tion. Hence, the agglomerates are readily dispersed and dissolve and is centrifuged again before reading the volume of insoluble
quickly. residue. The result is called the insolubility index. In WMP,
aggregates of coagulated protein with entrapped milk fat glob-
ules may float to the surface; the quantity involved usually is
Density
more than the sediment. Hence, the insolubility found closely
Bulk density is a very complex product property for MP and is depends on the method used.
of great importance for economical and functional reasons.
High bulk density is desirable for reducing shipping and pack-
Whey Protein Nitrogen Index
aging costs. On the other hand, low bulk density, as seen in
agglomerated products, influences other powder properties It measures the amount of heat treatment the powder has
such as flowability and instant characteristics. Bulk density is received during processing. Whey proteins are denatured or
the weight of a volume unit of powder and is usually expressed altered by heat. The test measures the amount of undenatured
in g/cm3, kg/m3, or g/100 ml. Bulk density is usually deter- whey protein present in the powder. After application of low
mined by measuring the volume of 100 g of powder in a centrifugal forces under specified conditions, a high value
250 ml graduated cylinder after exposure to compaction by indicates that the whey proteins are more soluble and product
standardized tapping. The bulk density of nonfat dry milk is therefore more soluble. WPN is expressed as milligram (mg)
has a wide range, from 0.18 to 1.25 g ml 1. Regular spray- undenatured WPN per gram of nonfat MP with a moisture
dried nonfat dry milk is approximately 0.50–0.60 g ml 1, content of 3.16%. Casein and the heat-denatured whey
while roller-dried nonfat dry milk is 0.30–0.50 g ml 1. The proteins are removed by filtration after precipitation of
bulk density of the final powder is a result of particle density the reconstituted milk with NaCl. The filtrate contains all
(occluded air and density of the solids) and the interstitial air. undenatured whey proteins. By adding HCl, the proteins dena-
Bulk density can be influenced by many different factors, ture and develop turbidity depending on the concentration of
which include density of the solids, amount of air entrapped the whey proteins. The turbidity is measured as percentage
in the particles (occluded air) or the particle density, and transmittance, in a spectrophotometer at a wavelength of
amount of interstitial air (air between the particles). Occluded 420 nm. By using the standard curve, this reading can be con-
air is one of the most important factors for controlling bulk verted directly into milligram undenatured whey protein N/g
density. powder (WPN).

Flowability
Sensory Evaluation of MP
Flowability is the ability of a powder to flow freely without
forming lumps or aggregates. It can be measured as the time In order to determine the temperature sensitivity of a reaction,
necessary for a given volume of powder to leave a rotary drum. a Q10 model is often employed. This describes how much
Flowability depends upon particle size and shape, density, and faster a reaction will go if the product is held at temperatures
electrical charge. Larger particles flow more easily than smaller differing by 10  C; Q10 models can be used to predict quality
particles with a diameter of <90 mm. Flowability can consider- and nutrient loss, as well as shelf life of a product.
ably be improved by adding some inert very fine powders such MPs, particularly SMP, are manufactured in large quantities
as SiO2, Na–Al–silicate, or Ca3 (PO4)2. Such additions are in the flush season and subsequently used in lean period in
applied, for instance, in MP for coffee machines. reconstituted form to maintain milk supply. It has become an
important export commodity. MP has been graded on the basis
of bacterial, physicochemical, reconstitutional (i.e., when the
Dissolution
powder is dispensed in water to prepare reconstituted milk),
When dissolving MP in water, it is dispersed, implying that the and organoleptic properties. These properties are basic ele-
powder particles will become fully wetted, which may take ments of quality specifications. During drying, care should be
some time. Subsequently, the soluble components dissolve, taken to preserve the natural properties of the original raw
and the colloidal particles (fat globules and casein micelles) milk. Evaluation of MP on the basis of its sensory characteris-
become dispersed in the solution. This will take several tics plays an important role toward its consumer acceptance.

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728 Milk Powder

Desirable Attributes and Defects in MPs 1. Browned or darkened: When the defect is present, the normal
creamy color has been replaced by a distinct brown. The
Whole Milk Powder defect is usually associated with an old, stale flavor.
Upon rehydration, WMP should have clean, rich, sweet, fresh, 2. Scorched: Discoloration due to browning of the milk solids
and pleasant flavor. Sensory defects may be due to use of either is usually associated with the roller process. The powder
poor quality ingredients, manufacturing conditions, drying may vary from light to dark brown.
method, or abusive storage conditions. The development of 3. Lack of uniformity: This defect may be due to either partial
storage-based defects in WMP is most difficult to control. This discoloration after packaging or partial scorching during
relatively rapid onset of off-flavors in WMP is primarily a func- the manufacturing.
tion of the generation of lipid oxidation products. The product
should be free-flowing to some extent with absence of lumps.
The presence of hard lumps is a serious defect in WMP. The color Skim Milk Powder
of WMP depending on the source of fat varies from white to deep
yellow. Tactile properties of WMP vary with the method of The flavor of good quality SMP, when reconstituted, should be
manufacture, degree of concentration, particle size, and porosity similar to that of fresh skim milk, that is, normally a flat taste
after drying. Spray-dried WMP may be extremely fine and uni- because of practically no fat in it. Otherwise, the flavor is clean,
form throughout, but two powder defects that may occasionally sweet, and pleasant and may have a slightly cooked or heated
be noted are lumpy and caked. Some common quality defects perception. The common flavor defects of SMP are stale/stor-
encountered in WMP and their characteristics are the following. age, neutralizer, oxidized, and scorched. Instant SMP is usually
quite granular, the product pours readily somewhat like that of
Flavor defects corn meal. SMP prepared by spray-drying process is very fine,
1. Stale: This is a characteristic age defect associated with light, and dusty and has flow characteristics similar to the flow
protein. This defect closely resembles the musty flavor com- of corn meal. Scorched off-flavor is developed due to exposure
mon to casein. This defect is observed in MP after storage of MP to abnormally high heat during processing. Cake for-
for 9 months. When the defect is intense, it may be accom- mation is the most frequently occurring defect related to tex-
panied by a darkening of the product. ture of SMP. Sometimes, the defect is so serious that the
2. Rancid: Rancid WMP has bitter, soapy, unclean taste, which product looks as hard as a rock. The color of SMP should be
is persistent after the sample has been chewed up and spit uniform and showing complete absence of foreign specks,
out. The reason may be insufficient temperature used for scorched particles, and browning. The product should have a
fore warming and the lipase enzyme that remains active and creamy white or light yellow color.
causes rancidity.
3. Oxidized/tallow: It is the most troublesome flavor defect of
See also: Condensed Milk; Dairy Products: Dietary and Medical
WMP. Many factors are responsible for the development of
Importance; Protein: Food Sources.
this defect such as temperature, light, moisture, acidity,
metallic salts, condensation, and type of packaging.
4. Scorched: This flavor is produced in products that have
been subjected to excessive heat during the drying stage Further Reading
or have been permitted to remain in the drying chamber
for too long period of time. It is usually accompanied by a Caric M (1994) Concentrated and dried dairy products. New York: VCH Publishers.
large number of scorched specks in the product and some- Carunchia Whetstine ME and Drake MA (2007) The flavor and flavor stability of skim
and whole milk powders. In: Cadwallader KR, Drake MA, and McGorrin R (eds.)
times by a dark discoloration typical of overheating. Flavor chemistry of dairy products, pp. 217–252. Washington, DC: ACS Publishing.
Codex Alimentarius Commission (2011) Milk and milk products, 2nd ed. FAO & WHO,
Body and texture defects Rome, Italy.
1. Lumpy: A lumpy powder lacks homogeneity. This defect is Hall CW and Hedrick TI (1971) Drying milk and milk products, 2nd ed. Westport, CT:
AVI Publishers, 338 pp.
found frequently in the spray process product. Lump for-
Hunziker OF (1947) Condensed milk and milk powder, 7th ed. La Grange, IL: OF Hunziker.
mation is due to insufficient drying, dripping from spray Kieseker FG (1982) Recombined evaporated milk. In: Proceedings of the of seminar an
nozzles, or exposure to moisture-laden air. Hard lumps recombined milk and milk products, pp. 79–88. Brussels: IDF.
ranging in size from a grain of wheat upward may be Nieuwenhuijse JA and vanBoekel MAJS (2003) Protein stability in sterilised milk and
interspersed throughout. milk products. In: Fox PF and McSweeney PLH (eds.) Advanced dairy chemistry.
Proteins, vol. 1, pp. 947–974. New York: Kluwer 3rd ed., Part B.
2. Caked: Usually, this defect is not observed in WMP, but Patton S (1952) Studies of heated milk. 4. Observations on browning. Journal of Dairy
when it does occur, the product loses its powdery consis- Science 35: 1053.
tency and becomes a rock-like solid. When the mass is Singh H and Newstead B (1992) Aspects of proteins in milk powder manufacture.
broken up, it remains in chunks, thus failing to return to In: Fox PF (ed.) Advanced dairy chemistry, pp. 735–765. New York: Elsevier
Applied Science.
the original powder state. This defect is serious since such
milk solids have lost their sales value for human
consumption.
Relevant Websites
Color defects
www.fao.org/docrep/018/i3396e/i3396e.pdf.
Normal dry whole milk is light yellow in color but varies http://lait.dairy-journal.org/articles/lait/abs/2004/03/L03998/L03998.html.
reasonably with the color in the fat from a creamy white to a www.nutritiondata.self.com/facts/dairy-and-egg-products/84/2.
deep yellow: www.usdec.files.cms-plus.com/dgn/abstractpdfs/nutrcompofsmp.pdf.

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