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Milk Powder
Milk Powder
Milk Powder
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Milk Powder
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Kalyankar S.D., Deshmukh M.A., Chopde S.S., Khedkar C.D., Lule V.K. and Deosarkar S.S. (2016) Milk
Powder. In: Caballero, B., Finglas, P., and Toldrá, F. (eds.) The Encyclopedia of Food and Health vol. 3, pp. 724-
728. Oxford: Academic Press.
Milk Powder
SD Kalyankar, MA Deshmukh, and SS Chopde, Government College of Dairy Technology, Udgir, India
CD Khedkar, College of Dairy Technology, Pusad, India
VK Lule, National Dairy Research Institute (NDRI), Karnal, India
SS Deosarkar, College of Dairy Technology, Pusad, India
ã 2016 Elsevier Ltd. All rights reserved.
Powder form
Skim milk
No. Constituents Whole milk powder Partly skim milk powder powder
1. Milk fat Minimum 26% and less than 42% More than 1.5% and less than 26% 1.5% m/m
m/m m/m
2. Minimum milk protein in milk solids- 34% m/m 34% m/m 34% m/m
not-fata
3. Maximum watera 5% m/m 5% m/m 5% m/m
a
The water content does not include water of crystallization of the lactose; the milk solids-not-fat content includes water of crystallization of the lactose.
Source: Codex Alimentarius Commission (2011). Milk and milk products (2nd ed.). FAO & WHO.
pneumatic system, too. The air passes from the cyclone to the dry form, and the ‘straight-through’ process, where instantiza-
atmosphere via the exhaust fan. The two fractions of powder are tion is accomplished during drying.
collected in the pneumatic system for conveying and cooling Dry MP is the starting material for the rewetting procedure.
and are passed through a cyclone for separation, after which The powder is dispersed in the wetting chamber and gains a
they are bagged off. The instrumentation comprises indication water content of 5–10%, causing powder particle agglomera-
of the temperature of the inlet and outlet air, as well as auto- tion. The agglomerated product is transferred to the vibrating
matic control of the inlet temperature by altering the steam fluid bed dryer and cooler, where it is redried in a hot air
pressure and amount of oil or gas to the air heater and automatic stream at 90–120 C and immediately cooled to approximately
control of the outlet temperature by altering the amount of feed 10 C. The final product from the fluid bed dryer has a water
pumped to the atomizing device. The spray-drying process has content <4% (2–4%). Hot air, blown upward through the fine
become a highly acceptable method for drying milk. After dry- perforated plate of the fluid bed dryer, ‘fluidizes’ the powder
ing, it is essential to cool the powder immediately to a temper- and carries the smallest powder particles or fines to the
ature below the melting point of fat to maintain better flavor, cyclone, where separation takes place. The air is discharged
body characteristics, and long shelf life. into the atmosphere after heat and solids have been recovered
The production of SMP slightly differs from the whole MP and the fines are returned to the start of the process. Instantiza-
(WMP). Pasteurization is the most intensive heat treatment by tion process is complicated in the case of WMP as the surface of
low-temperature method to achieve the minimal detrimental particles is covered with milk fat layer. Free fat forms a hydro-
heat-induced changes like serum protein denaturation. phobic layer on the particle surfaces, impregnating them and
Homogenization is omitted and the milk can be concentrated decreasing their water-binding capability. In order to prevent
to higher solid contents. Sometimes, vitamin A preparations this and improve the recombination properties, powder parti-
are added by dry mixing. SMP is susceptible to humidity and cles are lecithinated by adding lecithin mixed with butter oil
heat-induced changes, which can intensify the adverse effect on during instantization. In this process, the powder is dried in
the powder quality; therefore, it must be promptly cooled. two stages and the fines are recirculated to the wet zone. The
Powder should be packed in suitable containers that protect lecithinated powder should be cooled and packed in a suitable
it from moisture, air, light, etc. Common wrappings are paper, material to protect the agglomerates from breaking down.
multilayer boxes or bags with a polyethylene layer inside,
metal barrels with polyethylene bags inside, or tins covered
with aluminum foil at the contact surface. When planning the Properties of MP
quantity of wrapping material, it is necessary to consider the
bulk density of the product, because it is highly affected by The important properties of MP are particle size, shape and
processing parameters and techniques. When the product is surface density, flowability, dissolution, insolubility, and whey
intended for long storage, it is packaged in an atmosphere of protein nitrogen (WPN) index. These properties decide the
inert gas, mostly nitrogen, or in a partial vacuum (4.0–5.3 KPa) quality and the suitability of MP in specific applications.
to avoid oxidative changes of fat and other components. Prop-
erly produced and packed milk power, with low oxygen con-
Particle Size
tent, is stored at ambient temperature.
Particle size is an important physical property of MP and can
relate to its appearance, reconstitution, and flow characteris-
Instantization tics. Particle size in MP can affect powder reconstitution prop-
erties. Difference in particle size can lead to stratification of the
Instant MP has better reconstitution properties than other MPs. powder with the higher solids concentrated at the top, which
The instantization process patented by Peebles significantly will affect reconstitution of the dry product. Wettability and
improved the quality and economical aspects of the drying dispersibility of MP can also be influenced by particle size.
technology. The principal purpose of instantizing is to improve Dispersibility decreases as percentage of fine particles below
the rate and completeness of reconstitutability of MP. The aim 90 mm increases. Flowability also depends on particle size and
of spray-drying process is to produce particles with a big sur- shape. Large particles tend to flow more easily than smaller
face/mass ratio. The reconstitution of small particles of powder particles. Shape and size of the particles will affect the closeness
in water is, however, difficult and requires intensive mixing for of the particle pack, which in turn will affect the powder bulk
their dispersion. One of the major objectives of new innova- density. The particle of MP generally consists of a continuous
tions in the area of spray- and fluid bed-drying is to produce mass of amorphous lactose and other low-molar-mass compo-
instant powder by effecting agglomeration. Agglomeration nents in which fat globules, casein micelles, and serum pro-
provides the structure of porous aggregates, which disperse teins are embedded. The particles also contain vacuoles of
readily and quickly without vigorous agitation to produce occluded air where particle surfaces are not in contact. The
stable reconstituted milk. The properties of dried products surface of spray-dried particles not only is usually smooth but
improved positively by the instantizing process include wetta- also may be wrinkled. Conditions such as higher inlet air
bility, penetrability, sinkability, dispersibility, and dissolvabil- temperature and larger temperature differences between the
ity. The process permits a better equilibrium among these hot air and powder particles may contribute to wrinkles. The
variables. An effective agglomeration is achieved by either presence of particles of different morphology in the same sam-
rewet or straight-through methods: the rewet process, where ple can be attributed to the different drying conditions to which
the instantization is carried out after the powder is obtained in the individual particles were exposed. Particle size can be
influenced by the milk characteristics, processing conditions, minutes. Generally, a small part does not dissolve. After a
and the type of equipment used in the drying process. Atomiza- solution is obtained, it may take about a day before its com-
tion parameters influence product shape and size distribution of position, especially the salt distribution, has more or less
powder particles making it possible to control powder particle reached equilibrium. This process may be accelerated by heat-
size. A spray-dried particle using centrifugal atomization will ing the reconstituted milk to 50–60 C and then cooling it
give a larger particle than the pressure nozzle atomization. again.
Spray-dried powder particles usually are spherical with diame-
ters in the range of 10–250 mm. Rapid dispersion requires a
Insolubility
particle size of approximately 150–200 mm diameter. The parti-
cles in agglomerated MP are larger and irregular in shape and Insolubility can be estimated in various ways. The powder is
contain very few separate small particles. Agglomeration causes dissolved in water under standardized conditions (concentra-
an increase in the amount of air incorporated between the tion, temperature, and duration and intensity of stirring) and
powder particles. The air is replaced by water during reconstitu- centrifuged. The supernatant is removed and replaced by water
tion. Hence, the agglomerates are readily dispersed and dissolve and is centrifuged again before reading the volume of insoluble
quickly. residue. The result is called the insolubility index. In WMP,
aggregates of coagulated protein with entrapped milk fat glob-
ules may float to the surface; the quantity involved usually is
Density
more than the sediment. Hence, the insolubility found closely
Bulk density is a very complex product property for MP and is depends on the method used.
of great importance for economical and functional reasons.
High bulk density is desirable for reducing shipping and pack-
Whey Protein Nitrogen Index
aging costs. On the other hand, low bulk density, as seen in
agglomerated products, influences other powder properties It measures the amount of heat treatment the powder has
such as flowability and instant characteristics. Bulk density is received during processing. Whey proteins are denatured or
the weight of a volume unit of powder and is usually expressed altered by heat. The test measures the amount of undenatured
in g/cm3, kg/m3, or g/100 ml. Bulk density is usually deter- whey protein present in the powder. After application of low
mined by measuring the volume of 100 g of powder in a centrifugal forces under specified conditions, a high value
250 ml graduated cylinder after exposure to compaction by indicates that the whey proteins are more soluble and product
standardized tapping. The bulk density of nonfat dry milk is therefore more soluble. WPN is expressed as milligram (mg)
has a wide range, from 0.18 to 1.25 g ml 1. Regular spray- undenatured WPN per gram of nonfat MP with a moisture
dried nonfat dry milk is approximately 0.50–0.60 g ml 1, content of 3.16%. Casein and the heat-denatured whey
while roller-dried nonfat dry milk is 0.30–0.50 g ml 1. The proteins are removed by filtration after precipitation of
bulk density of the final powder is a result of particle density the reconstituted milk with NaCl. The filtrate contains all
(occluded air and density of the solids) and the interstitial air. undenatured whey proteins. By adding HCl, the proteins dena-
Bulk density can be influenced by many different factors, ture and develop turbidity depending on the concentration of
which include density of the solids, amount of air entrapped the whey proteins. The turbidity is measured as percentage
in the particles (occluded air) or the particle density, and transmittance, in a spectrophotometer at a wavelength of
amount of interstitial air (air between the particles). Occluded 420 nm. By using the standard curve, this reading can be con-
air is one of the most important factors for controlling bulk verted directly into milligram undenatured whey protein N/g
density. powder (WPN).
Flowability
Sensory Evaluation of MP
Flowability is the ability of a powder to flow freely without
forming lumps or aggregates. It can be measured as the time In order to determine the temperature sensitivity of a reaction,
necessary for a given volume of powder to leave a rotary drum. a Q10 model is often employed. This describes how much
Flowability depends upon particle size and shape, density, and faster a reaction will go if the product is held at temperatures
electrical charge. Larger particles flow more easily than smaller differing by 10 C; Q10 models can be used to predict quality
particles with a diameter of <90 mm. Flowability can consider- and nutrient loss, as well as shelf life of a product.
ably be improved by adding some inert very fine powders such MPs, particularly SMP, are manufactured in large quantities
as SiO2, Na–Al–silicate, or Ca3 (PO4)2. Such additions are in the flush season and subsequently used in lean period in
applied, for instance, in MP for coffee machines. reconstituted form to maintain milk supply. It has become an
important export commodity. MP has been graded on the basis
of bacterial, physicochemical, reconstitutional (i.e., when the
Dissolution
powder is dispensed in water to prepare reconstituted milk),
When dissolving MP in water, it is dispersed, implying that the and organoleptic properties. These properties are basic ele-
powder particles will become fully wetted, which may take ments of quality specifications. During drying, care should be
some time. Subsequently, the soluble components dissolve, taken to preserve the natural properties of the original raw
and the colloidal particles (fat globules and casein micelles) milk. Evaluation of MP on the basis of its sensory characteris-
become dispersed in the solution. This will take several tics plays an important role toward its consumer acceptance.
Desirable Attributes and Defects in MPs 1. Browned or darkened: When the defect is present, the normal
creamy color has been replaced by a distinct brown. The
Whole Milk Powder defect is usually associated with an old, stale flavor.
Upon rehydration, WMP should have clean, rich, sweet, fresh, 2. Scorched: Discoloration due to browning of the milk solids
and pleasant flavor. Sensory defects may be due to use of either is usually associated with the roller process. The powder
poor quality ingredients, manufacturing conditions, drying may vary from light to dark brown.
method, or abusive storage conditions. The development of 3. Lack of uniformity: This defect may be due to either partial
storage-based defects in WMP is most difficult to control. This discoloration after packaging or partial scorching during
relatively rapid onset of off-flavors in WMP is primarily a func- the manufacturing.
tion of the generation of lipid oxidation products. The product
should be free-flowing to some extent with absence of lumps.
The presence of hard lumps is a serious defect in WMP. The color Skim Milk Powder
of WMP depending on the source of fat varies from white to deep
yellow. Tactile properties of WMP vary with the method of The flavor of good quality SMP, when reconstituted, should be
manufacture, degree of concentration, particle size, and porosity similar to that of fresh skim milk, that is, normally a flat taste
after drying. Spray-dried WMP may be extremely fine and uni- because of practically no fat in it. Otherwise, the flavor is clean,
form throughout, but two powder defects that may occasionally sweet, and pleasant and may have a slightly cooked or heated
be noted are lumpy and caked. Some common quality defects perception. The common flavor defects of SMP are stale/stor-
encountered in WMP and their characteristics are the following. age, neutralizer, oxidized, and scorched. Instant SMP is usually
quite granular, the product pours readily somewhat like that of
Flavor defects corn meal. SMP prepared by spray-drying process is very fine,
1. Stale: This is a characteristic age defect associated with light, and dusty and has flow characteristics similar to the flow
protein. This defect closely resembles the musty flavor com- of corn meal. Scorched off-flavor is developed due to exposure
mon to casein. This defect is observed in MP after storage of MP to abnormally high heat during processing. Cake for-
for 9 months. When the defect is intense, it may be accom- mation is the most frequently occurring defect related to tex-
panied by a darkening of the product. ture of SMP. Sometimes, the defect is so serious that the
2. Rancid: Rancid WMP has bitter, soapy, unclean taste, which product looks as hard as a rock. The color of SMP should be
is persistent after the sample has been chewed up and spit uniform and showing complete absence of foreign specks,
out. The reason may be insufficient temperature used for scorched particles, and browning. The product should have a
fore warming and the lipase enzyme that remains active and creamy white or light yellow color.
causes rancidity.
3. Oxidized/tallow: It is the most troublesome flavor defect of
See also: Condensed Milk; Dairy Products: Dietary and Medical
WMP. Many factors are responsible for the development of
Importance; Protein: Food Sources.
this defect such as temperature, light, moisture, acidity,
metallic salts, condensation, and type of packaging.
4. Scorched: This flavor is produced in products that have
been subjected to excessive heat during the drying stage Further Reading
or have been permitted to remain in the drying chamber
for too long period of time. It is usually accompanied by a Caric M (1994) Concentrated and dried dairy products. New York: VCH Publishers.
large number of scorched specks in the product and some- Carunchia Whetstine ME and Drake MA (2007) The flavor and flavor stability of skim
and whole milk powders. In: Cadwallader KR, Drake MA, and McGorrin R (eds.)
times by a dark discoloration typical of overheating. Flavor chemistry of dairy products, pp. 217–252. Washington, DC: ACS Publishing.
Codex Alimentarius Commission (2011) Milk and milk products, 2nd ed. FAO & WHO,
Body and texture defects Rome, Italy.
1. Lumpy: A lumpy powder lacks homogeneity. This defect is Hall CW and Hedrick TI (1971) Drying milk and milk products, 2nd ed. Westport, CT:
AVI Publishers, 338 pp.
found frequently in the spray process product. Lump for-
Hunziker OF (1947) Condensed milk and milk powder, 7th ed. La Grange, IL: OF Hunziker.
mation is due to insufficient drying, dripping from spray Kieseker FG (1982) Recombined evaporated milk. In: Proceedings of the of seminar an
nozzles, or exposure to moisture-laden air. Hard lumps recombined milk and milk products, pp. 79–88. Brussels: IDF.
ranging in size from a grain of wheat upward may be Nieuwenhuijse JA and vanBoekel MAJS (2003) Protein stability in sterilised milk and
interspersed throughout. milk products. In: Fox PF and McSweeney PLH (eds.) Advanced dairy chemistry.
Proteins, vol. 1, pp. 947–974. New York: Kluwer 3rd ed., Part B.
2. Caked: Usually, this defect is not observed in WMP, but Patton S (1952) Studies of heated milk. 4. Observations on browning. Journal of Dairy
when it does occur, the product loses its powdery consis- Science 35: 1053.
tency and becomes a rock-like solid. When the mass is Singh H and Newstead B (1992) Aspects of proteins in milk powder manufacture.
broken up, it remains in chunks, thus failing to return to In: Fox PF (ed.) Advanced dairy chemistry, pp. 735–765. New York: Elsevier
Applied Science.
the original powder state. This defect is serious since such
milk solids have lost their sales value for human
consumption.
Relevant Websites
Color defects
www.fao.org/docrep/018/i3396e/i3396e.pdf.
Normal dry whole milk is light yellow in color but varies http://lait.dairy-journal.org/articles/lait/abs/2004/03/L03998/L03998.html.
reasonably with the color in the fat from a creamy white to a www.nutritiondata.self.com/facts/dairy-and-egg-products/84/2.
deep yellow: www.usdec.files.cms-plus.com/dgn/abstractpdfs/nutrcompofsmp.pdf.