Dyeing and Colour Fastness Properties of Silk and Cotton Fabrics Dyed With Eucalyptus Bark Extract

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RMUTP RESEARCH JOURNAL

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✭ DYEING AND COLOUR FASTNESS PROPERTIES OF SILK AND COTTON FABRICS DYED
WITH EUCALYPTUS BARK EXTRACT ✭ °“√§«∫§ÿ¡·≈–°“√μ√«® Õ∫§ÿ≥¿“æ°“√º≈‘μ™‘Èπ à«π¬“π¬πμå ¬ÿ∑∏ ‰°¬«√√≥å 21
✭ THE LEARNING STYLES OF STUDENTS OF RIT, CHOTIWET CAMPUS ¢ÕßΩÉ“¬ª√–°—π§ÿ≥¿“æ ‚√ßß“πºŸâ√—∫®â“ߺ≈‘μ
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✭ FACTORS AFFECTING THE STUDENTS’ ACHIEVEMENT RESEARCH METHODOLOGY SUBJECT, ·≈–ºâ“ΩÑ“¬∑’ˬâÕ¡¥â«¬πÈ” °—¥®“°‡ª≈◊Õ°¢Õßμâπ¬Ÿ§“≈‘ªμ— 
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PROGRAM FOR COURSES OF PHYSICAL FITNESS ✭ °“√ ”√«®·∫§∑’‡√’¬ “¬„¬„π√–∫∫·Õ°μ‘‡«‡μÁ¥ ≈—¥®å æπ“≈’ ™’«°‘¥“°“√ ·≈–§≥– 59
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EFFICIENCY CONTROL
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Academic Articles: ✭ ªí®®—¬∑’Ë¡’§«“¡ —¡æ—π∏å°—∫º≈ —¡ƒ∑∏‘Ï∑“ß°“√‡√’¬π„π«‘™“√–‡∫’¬∫«‘∏’«‘®—¬ ∑√ß ‘√‘ «‘™‘√“ππ∑å 79
✭ TECHNOLOGY TRANSFER ON BANANA FLOUR AND FOOD PRODUCTS ¢Õßπ—°»÷°…“¡À“«‘∑¬“≈—¬‡∑§‚π‚≈¬’√“™¡ß§≈æ√–π§√ «‘∑¬“‡¢μ‚™μ‘‡«™
✭ SIMULATIONS IN SHEET METAL FORMING INDUSTRY FOR THE 21st CENTURY
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‡√◊ËÕß  ¡√√∂¿“æ∑“ß°“¬
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¡À“«‘∑¬“≈—¬‡∑§‚π‚≈¬’√“™¡ß§≈æ√–π§√ Rajamangala University of Technology Phra Nakhon ∫∑§«“¡«‘™“°“√


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RMUTP Research Journal, Vol. 1, No. 1, May 2007 41
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Dyeing and Colour Fastness Properties of Silk and Cotton Fabrics
Dyed with Eucalyptus Bark Extract
Rattanaphol Mongkholrattanasit*
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1
Department of Textile Chemistry, Faculty of Textile Engineering, Technical University of Liberec.
2
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Abstract
This research was concerned with dye extraction from the bark of eucalyptus and
application for silk and cotton fabric dyeing. Silk and cotton fabrics were treated with pre-
mordanting process before dyeing experiments, in order to facilitate dye absorbency of fabrics
such as silk dyeing at 90°C for 40 minutes and pH 4, cotton dyeing at 60°C for 40 minutes
and pH no adjustment. The best result was achieved when liquor ratio between fabric and dyed
solution as 1:30 was employed. Silk dyed in the solution extracting from the bark of eucalyptus
with mordant compound displayed yellow to brown colour except fabric using fesrrous (Fe)
mordant exhibiting the shade of dark brown to grey. For cotton fabric, the shade of yellow to
orange was obtained, except fabric using ferrous (Fe) mordant displaying the shade of pale
grey to gray. Silk and cotton fabrics treated with pre-mordanted and dyeing process has presented
the properties of colour fastness to washing, water and perspiration from good to very good
level whereas colour fastness to light and rubbing was from fair to good level.
§” ”§—≠ :  ’¬âÕ¡∏√√¡™“μ‘ ¬Ÿ§“≈‘ªμ—  ¡Õ√å·¥π∑å ‰À¡ ΩÑ“¬
Key words : Natural dye, Eucalyptus, Mordant, silk, Cotton
*ºŸâπ‘æπ∏åª√– “πß“π ‰ª√…≥’¬åÕ‘‡≈Á°∑√Õπ‘° å pholm123@yahoo.com ‚∑√. 085-833-0323
phra nakhon41-49 41 5/11/07, 3:36 PM
42 «“√ “√«‘™“°“√·≈–«‘®—¬ ¡∑√.æ√–π§√ ªï∑’Ë 1 ©∫—∫∑’Ë 1 情¿“§¡ 2550
1. Introduction of Fastness: ISO 105-F: 1985) were used with-
The natural dyes may have, a wide range out further purification. Potassium aluminium
of shades, which can be obtained from various sulphate hydrate (AlKO8S2.12H2O), Copper
parts of plants including roots, barks, leaves, sulphate hydrate (CuSO4.5 H2O), Stannous
flowers and fruits (Allen, R.M.L, 1971). They chlorine hydrate (SnCl2. 2 H2O), Iron (II)
normally require mordants, which are metallic sulphate hydrate (FeSO4.7 H2O), Sodium
salts of aluminum, iron, chromium, copper and carbonate (Na2CO3) (Italma (Thailand) Co,
others, for ensuring the reasonable fastness of Ltd). Acetic acid (CH3COOH) (Lab Scan Asia
the colour to sunlight and washing (Robertson, Co, Ltd) and Non ionic soap (Matapon X -
S.M., 1973). The metal ions can act as electron 80) (Ilin Enterprise Co, Ltd).
acceptors to electron donor to form co-ordinate
bonds with dye molecules, which are insoluble 2.2 Extracting
in water. Lately, there has been increasing The eucalyptus bark was cut into small
interest in the natural dyes, as public becomes pieces by blender. Then eucalyptus bark was
aware of ecological and environmental pro- the raw material for dye extraction was at
blems related to the use of synthetic dyes. As 100 °C for 1 hour and liquor ratio of material:
the use of natural dyes cuts down significantly water was 1:40. The eucalyptus bark extract
on amount of toxic effluent resulting from the solution (natural dye solution) obtained in this
synthetic dye process. Thai natives still use study was reddish brown colour.
natural dyes in home industries as well as in
hansdicraft works. In Thailand, a number of 2.3 Dyeing Method
different types of plants are employed for Silk and cotton fabrics were dyed with
dyeing (Moeyes Marjo, 1993). One of the plant the natural colouring matter extracted from
uses for dyeing is eucalyptus, although eucalyptus bark at liquor ratio 1:30, was heated
eucalyptus has been used in paper industry, at different durations (10-60 minutes), and
oil eucalyptus and textile dyeing. In this study, different temperatures (30-100 °C). The dyed
the effect of temperature, time, pH, the kind samples were rinsed with cold water, washed
of mordant and colour fastness of silk and in a bath of liquor ratio 1:30 using 1 g/l of
cotton fabrics dyed with eucalyptus bark were non-ionic soaping agent (Matappon X-80) at
investigated. 50 °C for 10 minutes, then rinsed and finally
dried at ambient temperature. They were
2. Experimental measured for K/S value by spectrophotometer.
2.1 Materials The pH values were recorded with pH meter
Multifiber D.W. type, silk and cotton and adjusted with dilute solution of sodium
fabrics (Standard Adjacent Fabrics for Staining carbonate and acetic acid, then varying the pH
phra nakhon41-49 42 5/11/07, 3:36 PM
RMUTP Research Journal, Vol. 1, No. 1, May 2007 43
values as 4, 5, 6 and 7 respectively though measured using a spectrophotometer (Spec-
process at 90 °C and 60 °C for silk and cotton traflash SF 600 Datacolor) interfaced to a
fabrics respectively for 40 minutes, the liquor digital PC under illuminant D65 with a 10°
ratio was 1:30, when finished, measured the standard observer. Colour strength, K/S, was
K/S value by spectrophotometer. calculated from the reflectance values using
Kubellka-Munk equation as follows: K/S =
2.4 Mordanting Method (1-R)2/ 2R. Where R is the decimal fraction
The optimal condition for mordant of the reflection of the dye fabric, K is the
application on silk and cotton were investigated absorption coefficient and S is scattering
which in pre-mordant process at 30 °C for coefficient (K. McLaren, 1976). Colour change
10 minutes and then quantity of mordant and colour staining were assessed using grey
substance was 0.1 % owf., then passed thought scale.
dyeing process at 90 °C and 60 °C for silk
and cotton fabrics respectively for 40 minutes, 3. Results and discussion
the liquor ratio was 1:30. They were measured 3.1 Factors affecting dyeing of silk and
for K/S value by spectrophotometer. cotton fabric with eucalyptus bark
extract
2.5 Colour Fastness Test 3.1.1 Effect of temperature for dyeing
With regard to the dyestuff properties on silk and cotton fabrics
of the dyeing agent, the ability of mordanting From the experiment to find the optimal
agent to fix on a fiber is the important temperature for dyeing silk and cotton fabric,
requirement. Obviously, this relates to the the experimental result is shown in Table 1.
colour fastness properties, which normally test From Table 1, dyeing silk and fabric in
according to ISO standard test. These tests eucalyptus extracted from bark showed that
including colour fastness to light colour fastness the increasing temperature can increase the K/
to washing, colour fastness to water, colour S value until reaching 90°C. The appearance
fastness to perspiration, and colour fastness to colour of silk which dyed in eucalyptus bark
rubbing. The test results were expressed in grey extract was brown colour. The dyed cotton
scale terms instead of the K/S value. According fabric showed that the increasing temperature
to the standard grey scale for color change can increase the K/S value until reaching
and grey scale for colour staining. 60 ° C the K/S value was constant. The
appearance colour of the dyed in eucalyptus
2.6 Characterization bark extract was yellowish orange. The result
The reflectance value and the corre- from Table 1 fabric can be plotted as Figure 1.
sponding K/S values for the dyed samples was
phra nakhon41-49 43 5/11/07, 3:36 PM
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3.1.2 Effect of time for dyeing on in the order of dyeing using Fe> Cu> Al> un-
silk and cotton fabrics mordant> Sn, however, the K/S value of the
From experiment, the suitable time for cotton fabric increased in the order of dyeing
dyeing silk and cotton were found the result using Sn> Fe> Cu> Al> un-mordant.
is shown in Table 2. From Table 2, when the
time in dyeing silk and cotton fabrics was 3.3 Colour fastness
increased, the K/S value increased. After 40 The rating of fastness (light, rubbing,
minutes, the K/S value was constant. The result water, washing, and perspiration fastness) of
can be illustrated as Figure 2. pre-mordant and un-mordant cotton and silk
fabrics dyed with eucalyptus bark are show
3.1.3 Effect of pH value for dyeing in Table 5 to Table 10 respectively. It was
on silk and cotton fabrics found that the properties of colour fastness,
The experiment is to find the suitable washing water and perspiration in good to very
pH value for dyeing silk and cotton fabric. good whereas colour fastness to light and
The result of experiment can be concluded as rubbing was in fair to good.
following Table 3. From the pH value experi-
ment, the pH value of eucalyptus bark dyed 4. Conclusions
was 6.2. From Table 3, pH value at 4.0 was The purpose of this study is to investi-
the best result for dyeing silk fabric when gate the effect of temperature, time, pH and
compared with the other pH value. When mordant type on dyeing properties and colour
increasing pH value, K/S value was declined. fastness of silk and cotton fabrics dyed with
Without adjusting pH value when dyed cotton, eucalyptus bark extract solution. It was found
gained darken hue value than the other pH that silk and cotton fabric were treated with
value. The K/S value declined when pH value pre-mordanting process before dyeing experi-
increased, as seen in Figure 3. ments, in order to facilitate dye absorbency
of fabric such as silk dyeing at 90 °C for 40
3.2 Effect of using difference type of mor- minutes and pH 4, cotton dyeing at 60 °C for
dant for silk and cotton dyeing 40 minutes and pH no adjustment. The best
The experiment is to find the suitable result was achieved when liquor ratio between
condition for pre-mordant process and for fabric and dyed solution as 1:30 was employed.
dyeing process of cotton and silk fabric. The The K/S values of silk fabric increased in the
results are shown in Table 4. The K/S are order of dyeing using Fe> Cu> Al> un-mordant>
shown in Table 4. It was found that the K/ Sn, however, the K/S value of the cotton fabric
S values of pre-mordant silk and cotton fabrics increased in the order of dyeing using Sn> Fe>
were higher than those of un-mordanted fabrics Cu> Al> un-mordant. Silk dyed in the solution
except pre-mordanted on silk fabric with from bark of eucalyptus showed the shade of
SnCl2. The K/S values of silk fabric increased yellow-brown, excepting using ferrous (Fe)
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RMUTP Research Journal, Vol. 1, No. 1, May 2007 45
showing the shade of dark brown-grey. For
cotton fabric showed the shade of yellow-
orange, accepting using ferrous (Fe) showed
the shade of pale grey. The fastness properties
of silk and cotton fabric after treated with pre-
mordant and dyeing process. It presented the
fastness, washing, water and perspiration on
good to very good level but the fastness to
light and rubbing on fair to good level.
Table 1 The ΔL*, Δa*, Δb* and K/S
Figure 1. K/S value dyed silk and cotton
value of dyed silk and cotton fa-
fabrics by varying temperature
brics by varying temperature of
of dyeing
dyeing
Dyeing Colour measurement (Silk fabric) Table 2 The ΔL*, Δa*, Δb* and K/S
Temperature (°C) ΔL* Δa* Δb* K/S
value of dyed silk and cotton fa-
for 1 Hour
30 -13.62 5.86 14.87 1.6038
brics by varying time of dyeing
40 -17.00 7.21 17.58 2.1647 Dyeing time Colour measurement (Silk fabric)
50 -19.51 8.21 18.02 2.2658 (minutes) ΔL* Δa* Δb* K/S
60 -20.40 8.60 18.08 2.2720 (90°C for cotton)
70 -24.43 10.27 19.39 3.0013 10 -20.44 8.60 18.08 2.2720
80 -26.45 11.70 20.31 3.3310 20 -27.48 10.61 18.66 3.3477
90 -30.58 12.92 20.18 4.0187 30 -26.93 10.65 18.65 3.3563
100 -30.59 12.93 20.18 4.0169 40 -30.56 12.91 20.15 4.0180
Dyeing Colour measurement (Cotton fabric) 50 -30.59 12.90 20.17 4.0160
Temperature (°C) ΔL* Δa* Δb* K/S 60 -30.60 12.87 19.96 4.0157
for 1 Hour Dyeing time Colour measurement (Cotton fabric)
30 -14.89 8.39 19.19 1.0615 (minutes) ΔL* Δa* Δb* K/S
40 -15.79 8.56 19.07 1.0600 (90°C for cotton)
50 -16.85 9.33 18.72 1.0654 10 -11.86 5.51 13.49 0.5883
60 -16.35 9.83 18.80 1.0674 20 -12.00 6.58 15.22 0.6544
70 -17.73 7.81 17.33 1.0674 30 -13.59 7.68 16.65 0.8059
80 -13.98 7.94 15.95 0.7553 40 -16.30 9.81 18.80 1.0674
90 -14.30 7.92 15.98 0.7736 50 -16.85 9.33 18.72 1.0654
100 -14.68 7.59 15.64 0.8004 60 -15.79 8.56 19.07 1.0600
Remark: Light source = D65, Observe degree = 10°, K/
S (λ = 400 nm)
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Figure 2. K/S value dyed silk and cotton
fabrics by varying time of dyeing
Table 3 The ΔL*, Δa*, Δb* and K/S Table 4 The DL*, Da*, Db* and K/S
value of dyed silk and cotton fa- value for pre-mordanting and
brics by varying pH value of dyeing dyeing of silk and cotton fabrics
Dyeing pH Colour measurement (Silk fabric)
Silk Fabric ΔL* Δa* Δb* K/S
value ΔL* Δa* Δb* K/S
Un-mordant -43.35 15.68 18.73 5.7061
No adjusted -30.57 12.88 20.12 4.0157
4 -43.35 15.68 18.73 5.8372 AlKO S or Al
8 2
-36.39 12.34 21.94 5.8372
5 -38.07 14.61 18.17 4.2163 CuSO or Cu
4
-38.68 8.00 21.35 6.4992
6 -30.00 11.38 18.45 2.7612 FeSO4 or Fe -48.55 3.98 9.18 7.1239
7 -27.89 10.93 17.67 2.3321 SnCl2 or Sn -23.48 9.09 22.22 3.6380
Dyeing pH Colour measurement (Cotton fabric) Cotton fabric ΔL* Δa* Δb* K/S
value ΔL* Δa* Δb* K/S
Un-mordant -16.33 9.85 19.12 1.0618
No adjusted -16.33 9.85 19.12 1.0618
AlKO8S2or Al -14.66 6.86 19.10 1.3222
7 -14.89 8.30 19.10 1.0610
8 -14.68 7.59 15.63 0.8000 CuSO4 or Cu -20.27 8.70 18.79 1.5357
9 -14.30 7.92 15.90 0.7735 FeSO or Fe
4
-27.23 4.91 11.13 1.6502
10 -13.98 7.90 15.90 0.7730 SnCl2 or Sn -25.94 5.75 28.12 4.4001
Remark: Light source = D65, Observe degree = 10°, K/ Remark: Light source = D65, Observe degree = 10°, K/
S (λ = 400 nm) S (λ = 400 nm)
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RMUTP Research Journal, Vol. 1, No. 1, May 2007 47
Table 5 The result of colour fastness to Table 7 The result of colour fastness to
light (Standard: ISO 105-B02: washing (Standard: ISO 105-CO6
1994) A1S: 1994)
Dyeing description Colour change Dyeing
Mordant
Silk fabric description
Un mordant 4-5 Silk fabric Un Al Cu Fe Sn
Al mordant 4-5 Colour change 4-5 4-5 4 4-5 4
Cu mordant 4-5 Colour staining
Fe mordant 4-5 -Acetate 4-5 4-5 4-5 4-5 4-5
Sn mordant 4-5 -Cotton 4-5 4-5 4-5 4-5 4-5
Cotton fabric -Nylon 4-5 4-5 4-5 4-5 4-5
Un mordant 3 -Polyester 4-5 4-5 4-5 4-5 4-5
Al mordant 3 -Acrylic 4-5 4-5 4-5 4-5 4-5
Cu mordant 3 -Wool 4-5 4-5 4-5 4-5 4-5
Fe mordant 3 Cotton fabric Un Al Cu Fe Sn
Sn mordant 3 Colour change 3-4 3-4 4 3-4 4
Colour staining
Table 6 The result of colour fastness to -Acetate 4-5 4-5 4-5 4-5 4-5
rubbing (Standard: ISO105-X12: -Cotton 4-5 4-5 4-5 4-5 4-5
-Nylon 4-5 4-5 4-5 4-5 4-5
2001) -Polyester 4-5 4-5 4-5 4-5 4-5
Colour staining -Acrylic 4-5 4-5 4-5 4-5 4-5
Dyeing -Wool 4-5 4-5 4-5 4-5 4-5
Warp direction Weft direction
description
Dry Wet Dry Wet
Silk fabric Table 8 The result of colour fastness to
Un mordant 4 3-4 4 3-4 water (Standard: ISO 105-EO1:
Al mordant 3-4 3 3-4 3
Cu mordant 3-4 3 3-4 3
1994)
Fe mordant 3-4 3 3-4 3 Dyeing
Mordant
Sn mordant 3-4 3 3-4 3 description
Cotton fabric Silk fabric Un Al Cu Fe Sn
Un mordant 4-5 4-5 4-5 4-5 Colour change 4-5 4-5 4 4-5 4
Al mordant 4-5 4 4-5 4 Colour staining
Cu mordant 4-5 4 4-5 4 -Acetate 4-5 4-5 4-5 4-5 4-5
Fe mordant 4-5 4 4-5 4 -Cotton 4-5 4-5 4-5 4-5 4-5
Sn mordant 4-5 4 4-5 4 -Nylon 4-5 4-5 4-5 4-5 4-5
-Polyester 4-5 4-5 4-5 4-5 4-5
Remark: Un = Un mordant, Al = AlKO8S2, Cu = CuSO4, -Acrylic 4-5 4-5 4-5 4-5 4-5
Fe = FeSO4 and Sn = SnCl2 -Wool 4-5 4-5 4-5 4-5 4-5
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Table 8 (Con.) The result of colour fastness Table 10 The result of colour fastness
to water (Standard: ISO 105-EO1: to perspiration (alkaline solution)
1994) (Standard: ISO 105-EO4: 1994)
Dyeing
Mordant Dyeing
description Mordant
Cotton fabric Un Al Cu Fe Sn description
Silk fabric Un Al Cu Fe Sn
Colour change 4 4 4-5 4-5 4-5
Colour staining Colour change 4-5 4 4-5 4 4-5
Colour staining
-Acetate 4-5 4-5 4-5 4-5 4-5
-Acetate 4-5 4-5 4 4-5 4-5
-Cotton 4 4-5 4-5 4-5 4-5
-Nylon 4-5 4-5 4-5 4-5 4-5 -Cotton 4-5 4-5 4 4-5 4-5
-Nylon 4-5 4-5 4 4-5 4-5
-Polyester 4 4-5 4-5 4-5 4-5
-Polyester 4-5 4-5 4 4-5 4-5
-Acrylic 4 4-5 4-5 4-5 4-5
-Wool 4 4-5 4-5 4-5 4-5 -Acrylic 4-5 4-5 4 4-5 4-5
-Wool 4-5 4-5 4 4-5 4-5
Cotton fabric Un Al Cu Fe Sn
Table 9 The result of colour fastness to
Colour change 4 4 4 4 4
perspiration (acid solution) (Stan- Colour staining
dard: ISO 105-EO4: 1994) -Acetate 4-5 4-5 4-5 4-5 4-5
-Cotton 4-5 4-5 4-5 4-5 4-5
Dyeing
Mordant -Nylon 4-5 4-5 4-5 4-5 4-5
description
-Polyester 4-5 4-5 4-5 4-5 4-5
Silk fabric Un Al Cu Fe Sn
-Acrylic 4-5 4-5 4-5 4-5 4-5
Colour change 4-5 4-5 4-5 4 4
-Wool 4-5 4-5 4-5 4-5 4-5
Colour staining
-Acetate 4-5 4-5 4-5 4-5 4-5 Remark: Un = Un mordant, Al = AlKO8S2, Cu = CuSO4,
-Cotton 4-5 4-5 4-5 4-5 4-5 Fe = FeSO4 and Sn = SnCl2
-Nylon 4-5 4-5 4-5 4-5 4-5
-Polyester 4-5 4-5 4-5 4-5 4-5 5. Acknowledgements
-Acrylic 4-5 4-5 4-5 4-5 4-5 In addition, my special thankfulness is
-Wool 4-5 4-5 4-5 4-5 4-5 for Intertek Testing Services (Thailand) Co.,
Cotton fabric Un Al Cu Fe Sn Ltd. in allowing the authors to utilize laboratory
Colour change 4 4-5 4 4 4-5
facilities.
Colour staining
-Acetate 4-5 4-5 4-5 4-5 4-5 Many thank go to my friends and
-Cotton 4-5 4-5 4-5 4-5 4-5 colleagues, whose names are not mentioned
-Nylon 4-5 4-5 4-5 4-5 4-5 here, who have contributed suggestions and
-Polyester 4-5 4-5 4-5 4-5 4-5 courteous assistance during the experiment of
-Acrylic 4-5 4-5 4-5 4-5 4-5
my research.
-Wool 4 4-5 4-5 4-5 4-5
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RMUTP Research Journal, Vol. 1, No. 1, May 2007 49
6. References 5. Hohn and Margaret Cannon. 1994. Dye
1. Allen, R.L.M. 1971. Colour Chemistry. Plants and Dyeing. London: The Herbert
London: Nelson. Press Limited.
2. Collier, Billie J. and Epps, Helen H. 1999. 6. K. McLaren. 1976. The development of
Textile Testing and Analysis. 6 th ed. the CIE 1976 (L*a*b*) uniform colour-
New Jersey: Prentice-Hall, Inc. space and colour difference formula.
3. Duff, D. G. and Sinclair, R. S. 1989. Gilesûs Journal of the Society of Dyers and
Laboratory Couse in Dyeing. 4 th ed. Colourists. 92 (4).
West Yorkshire: Society of Dyers and 7. Moeyes Marjo. 1993. Natural Dyeing in
Colourists. Thailand. Bangkok: White Lotus.
4. Giles, C. H. 1971. A Laboratory Couse 8. Robertson, S. M. 1973. Dyes from Plants.
in Dyeing. 2 nd ed.: West Yorkshir: Society New York: Van Nostrand Reinhold.
of Dyers and Colourists.
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