Atomic Structure CPP-1

Numerical Type

1. Calculate the velocity of an electron (in cm/sec) placed in III orbit of H atom. Also calculate the no. of revolution
/sec. round the nucleus.

2. What is the principle quantum number of H atom orbital if the electron energy is -3.4 eV? Also report the angular
momentum of electron.

3.  18 1
The ionisation energy of He is 19.6  10 J  atom
+ +2
. Calculate the energy of the first stationary state of Li .

4. Calculate the frequency of the spectral line emitted when the electron in n=3 in H atom de-excites to the ground
state.

5. o
The IP1 of H is 13.6 eV. It is exposed to electromagnetic waves 0f 1028 A and gives out induced radiation. Find the
wavelength of these induced radiations.

6. Calculate the energy emitted when electrons of 1 g atom of hydrogen undergo transition giving the spectral lines of
lowest energy in the visible region of its atomic spectra.

7. What transition in the hydrogen spectrum would have the same wavelength as the Balmer Transition n = 4 to n = 2
+
of the He spectrum?
+
8. Find the quantum number “n” corresponding to the excited state of He ion if on transition to the ground state that
the ion emits two photons in succession with the wavelength 108.5 and 30.4 nm.

9. A gas of identical H-like atom has some atoms in the lowest (ground) energy level A and some atoms in a
particularupper (excited) energy level B and there are no atoms in any other energy level. The atoms of the gas
make transition to a higher energy level by absorbing monochromatic light of photon energy 2.7 eV. Subsequently,
the atoms emit radiation of only six different photons energies. Some of the emitted photons have energy 2.7 eV.
Some have more, and some have less than 2.7 eV.
i) Find the principle quantum number of initially excited level B.
ii) Find the ionisation energy for the gas atoms.
iii) Find the maximum and the minimum energies of the emitted photons.

10. An electron beam can undergo diffraction by crystals. Through what potential should a beam of electrons be
o
accelerated so that its wavelength becomes equal to 1.54 A ?

11. The vapours of Hg absorb some electrons accelerated by a potential difference of 4.5 V because of which light is
emitted. If the full energy of single incident electron is supposed to be converted into light emitted by single Hg
atom, find the wave number of the light.

12. The photoelectric emission requires a threshold frequency  0 . For a certain metal 1  2200 A and 2  1900 A
o o

produce electrons with a maximum kinetic energy K . E1 and K . E 2 . If K . E 2  2 K . E1 , calculate  0 and

corresponding  0 .

-1
13. The binding energy of electrons in a metal is 250 kJ mol . What is the threshold frequency of metal?

14. o
Light of wavelength 2000 A falls on an aluminium surface (work function of aluminium 4.2 eV). Calculate:
a. The kinetic energy of the fastest and slowest emitted photoelectron.
b. Stopping potential
c. Cut off wavelength for aluminium.

th
15. According to Bohr’s theory, the electronic energy of H atom in n Bohr’s orbit is given by
 19
21.76  10
En   2
joule . Calculate the longest  of light that will be needed to remove an electron from III
n
+
Bohr’s orbit of He ion.

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Atomic structure CPP1

16. hv
The dissociation of I 2  2 I utilizes one photon per iodine molecule dissociated. The maximum  for this is 4995
o
A . Calculate number of moles of I 2 dissociated per kJ of photon energy.

+
17. Find the velocity of photoelectron liberated by electromagnetic radiations of wavelength 18 nm from stationary He
ion in the ground state.

18.  10
The circumference of first Bohr’s orbit is 3.32  10 m . If the circumference represents one wavelength, what is
the velocity of the electron in this orbit.

19. Compare the energy of n=5 to n=4 transition of an electron plus nucleus Z=3 with the energy of n=2 to n=1
transition for an electron plus nucleus with Z=2.
20. 1/ 2
 150 
Show that de Broglie wavelength of electron accelerated through V volt is nearly given by  ( A ) 
o
.
 V 
 

21. State True or False

a. Anode rays are protons.
b. Nucleus always contain protons.
c.The grater the difference in energy between two levels, the lower the wavelength of the light emitted, when an
electron moves between them.
d. For a given valuer of l , the shape of orbital is independent of the value of n .
e. Cu+2 is diamagnetic.
f. Spectral lines would be seen for a 2px – 2px transition.
g. Simultaneous and precise determination of velocity and position of a particle is impossible.
h. Anode rays are ionised gaseous atoms.
i. Cathode rays on striking matter gives X-rays.

22. A bulb emits light of  1987.5 A . The bulb is rated as 150 watt and 8% of the energy is emitted as light. How
o

many photons are emitted by the bulb per second?

23. o
Iodine molecule dissociates into atoms after absorbing light of 1987.5 A . If one quantum of radiation is absorbed
-1
by each molecule, calculate the kinetic energy of iodine atoms. (Bond energy of I 2 = 240.92 kJ mol )

24. O 2 undergoes photochemical dissociation into one normal oxygen atom and one oxygen atom, 1.967 eV more
-1
energetic than normal. The dissociation of O 2 into normal atoms of oxygen requires 498 kJ mol . What is the
maximum wavelength effective for photochemical dissociation of O 2 ?

25. A certain dye absorbs light of  = 4530 A and then fluorescence light of 5080 A . Assuming that under given
o o

conditions 47% of the absorbed energy is re-emitted out as fluorescence, calculate the ratio of quanta emitted out
to the number of quanta absorbed.

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 Atomic structure CPP1

Answer Key
1. 2. n = 2; 3.  18 1 4. 1
v= 7.29  10 cm / sec , 44.1  10 J  atom 2.92  10 sec
7 15

 34 1
No. of revolution = mvr = 2.1  10 J sec
2.44  10
14

5. 1028, 1216,6568 A
o 6. Hint: 3-2 jump, Energy 7. n1 = 1 and n2 = 2 8. n1 = 2; n2 = 5
released = 182.5 kJ
9. i. nA=2 nB=4 10. 63.3V 11. 1 12. 1
3.63  10 m  0  1.1483  10 sec ;
6 15

ii. 14.4 eV
 0  2612.6 A
o
iii.Emax=13.5; Emin=0.7
eV
13. 1 14. i. 2 eV;0 15. 16. 3
6  10 4.175  10
14 o
sec 2055 A m ole
ii. 2 V
o
iii. 2970 A
17. 1 18. 1 19. E1/E2 = 0.0675 20.
2.3  10 m sec 2.193  10 m sec
6 6

21. a. F, b. T, c. T, d. T, 22. 23.  19 24.

12  10 6  10
18 o
J 1740.2 A
e. F, f. F, g. F, h. T, i. T
25. 0.527

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