CAREER POINT JEE Main Online Paper

JEE Main Online Exam 2019

Questions & Solutions
12th April 2019 | Shift - II
(Memory Based)
CHEMISTRY
Q.1 What is the C.N. of Co and Al in [Co(en)2Cl]Cl and K[Al(C2O4)3]
(1) 5, 6 (2) 6,5 (3) 6, 6 (4) 3, 3
Ans. [1]

Q.2 Which one is correct for Be w.r.t. B ?

(1) less nuclear charge and lesser I.E. (2) more nuclear charge and more I.E.
(3) more nuclear charge and lesser I.E. (4) less nuclear charge and more I.E.
Ans. [4]

Q.3 Which of the following have same radius ?

(1) Ti, Hf (2) Sc, Ni (3) Mo, W (4) Mn, Re
Ans. [3]

Q.4 What causes temporary hardness and by boiling it what compound is formed ?
(1) Mg(HCO3)2, Mg(OH)2 (2) Mg(HCO3)2, MgCO3
(3) Ca(HCO3)2, CaO (4) Ca(HCO3)2, Ca(OH)2
Ans. [2]

Q.5 Which statement is wrong regarding Li ?

Δ
(1) LiNO3 ⎯
⎯→ LiNO2 + O2
(2) Li when dissolve in water form LiOH.2H2O
(3) Li is least reactive of all the alkali metal
(4) Li in aq. solute having max. hydration energy
Ans. [1]

Q.6 Which statement is correct ?

(1) Pig iron is obtained from cast iron
(2) Al and Fe are obtained from Hall-Heroult Process
(3) when bauxite react with conc. NaOH form sodium meta aluminate and sodium silicate
(4) Blistar formation in Cu is due to CO2 evolution
Ans. [3]

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Q.7 Which statement is wrong regarding glycogen ?

(1) In glucose, α-glycosidic linkanges are present (2) sometimes found in yeast and fungi
(3) in animal cell (4) similar to the structure of amylose
Ans. [4]

Q.8 The maximum bond length between C – C is

(1) C60 (2) C70 (3) Graphite (4) Diamond
Ans. [4]

Q.9 Constituents of photochemical smog is-

(1) NO2 (2) SO2 (3) O2 (4) acroline
Ans. [1]

Q.10 Correct order of conductivity among A, B and C is-

(A) 0.1 M HCOOH (B) 0.1 M CH3COOH (C) 0.1 C6H5COOH
(1) A > B > C (2) A < B < C (3) A = B = C (4) A > C > D
Ans. [4]

⊕ Θ
N 2 Cl NH2

Q.11 + Product is

(1) N=N–N (2) N=N NH2

(3) N=N (4) NH2

NH2
Ans. [2]

Q.12 Write the IUPAC name of following compound ?

C

C C≡C

C C C C

C C

C
C
(1) (3, 5)-dimehtyl-4-propyl hept-1-en-6-yne (2) (3, 5)-dimethyl-4-propyl hept-1-yne-6-ene
(3) (4, 5)-diethyl-3-propyl oct-1-en-6-yne (4) (3,3)-dimehtyl-1-oct-4-yne
Ans. [1]

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Q.13 When m-cresol reacts with propargyl bromide in presence of K2CO3 and aceton then formed
OH
OH OH O
(1) (2) CH3 (3) (4)
CH3 CH3 CH3
Ans. [4]

Q.14 In H-atom electron is moving in second excited state. If radius in this orbit is 4.75 Å then de-Broglie
wavelength in this orbit will be-
(1) 9.106 Å (2) 7.32 Å (3) 6.34 Å (4) 3.56 Å
Ans. [1]

Q.15 For which reaction Kp ≠ Kc

(1) C + O2 CO2 (2) 2C + O2 2CO
(s) (g) (g) (s) (g) (g)

(3) N2 + O2 2NO (4) H2 + I2 2HI

(g) (g) (g) (g) (g) (g)

Ans. [2]

Q.16 The lowest energy 2s orbital is present in-

(1) Li (2) H (3) Na (4) K
Ans. [4]

Q.17 Solubility of Cd(OH)2 in pure water is 1.84 × 10–5 M. Calculate its solubility in a buffer solution of pH = 12.
(1) 2.7 × 10–9 M (2) 2.49 × 10–10 M (3) 2.7 × 10–11 M (4) 2.7 × 10–12 M
Ans. [2]

Q.18 2N2O5 → 4NO2 + O2

If concentration of N2O5 changes from 3M to 2.75 M in 30 min. Then rate of appearance of NO2 will be-
(1) 8.33 × 10–3 M min–1 (2) 1.67 × 10–2 M min–1
(3) 1.67 × 10–3 M min–1 (4) 8.33 × 10–2 M min–1
Ans. [2]

Q.19 Which of the following is incorrect -

(1) ΔGº < 0, Keq. > 1 (2) ΔGº > 0, Keq. > 1 (3) ΔGº = 0, Keq. = 1 (4) ΔGº > 0, Keq. < 1
Ans. [2]

Q.20 25 g hydrocarbon on combination with excess O2 produces of hydrocarbon 88 gm CO2 and 9 gm H2O, then
mass of C and H in the hydrocarbon are-
(1) 24, 1 gm (2) 22, 3 gm (3) 23, 2 gm (4) 20, 5 gm
Ans. [1]

Q.21 0.6 gm urea is present in 1.8 gm glucose to form 100 ml solution at 27ºC osmotic pressure of solution is-
(1) 27.06 atm (2) 30 atm (3) 40 atm (4) 15 atm
Ans. [1]

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Q.22 In SC, BCC and FCC ratio of number of atoms per unit cell is given by-
(1) 1 : 2 : 3 (2) 1 : 2 : 4 (3) 4 : 2 : 1 (4) 1 : 1 : 3
Ans. [2]

Q.23 A diatomic ideal gas is expanded at constant pressure. If work done by the system is 10 J, then calculate the
heat absorbed-
(1) 40 J (2) 20 J (3) 35 J (4) 15 J
Ans. [3]

Δ
Q.24 X⎯
⎯→ MnO 2 + Y
Y + H2SO4 + NaCl → Z (pungent smelling gas). Identify X, Y and Z.
(1) X = K2MnO4, Y = KMnO4, Z = Cl2 (2) X = KMnO4, Y = O2, Z = Cl2
(3) X = KMnO4, Y = K2MnO4, Z = Br2 (4) X = KMnO4, Y = K2MnO4, Z = SO2
Ans. [1]

Q.25 Half life of radioactive element 'A' is 30 min while 'B' is 20 min. Calculate ratio of number of nuclei decayed
of A and B after 60 min.
7 5 6 1
(1) (2) (3) (4)
6 6 7 1
Ans. [3]

Q.26 ⎯ ⎯4 +⎯
X ⎯HgSO ⎯⎯→ ⎯NaBH
H 2SO 4
⎯⎯ ⎯4 → ⎯ZnCl
⎯⎯ 2 +HCl
⎯
⎯→ ppt (in 5 Mts.)
X is-
(1) CH3 – C ≡ C – H (2) CH3 – CH = CH2 (3) CH ≡ CH (4) CH2 = CH2
Ans. [1]

CH 3COO ) 2 Hg + H 2 O + NaBH 4
Q.27 2-chloro-1-phenylbutane ⎯NaO
⎯⎯ ⎯⎯→ X ⎯(⎯
Et / EtOH
⎯⎯⎯⎯⎯⎯⎯ ⎯→ Product ?
OH OH

(1) Ph (2) Ph
Ph
Ph
(3) (4)
OH OH
Ans. [1]

CH3 CH3

Q.28 Polymer is-

n
(1) poly tertiary butylene (2) poly isobutylene
(3) poly isobutane (4) poly isopropylene
Ans. [2]

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Q.29 Dihedral angle between H′ and H′′ in given structure ?

H
29º H′′
H
H′

H
(1) 29 (2) 151 (3) 149 (4) 58
Ans. [3]

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