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Adv Soln PDF
1. (A ),( D)
Case A
Since the liquid is frictionless, it doesn’t rotate
So we have 2 mgsin θ-f= 2ma
F*R=(2/3)mR2
Solving these 2 equations we get a=(3/4) gsin θ
For kinetic energy
2. (B), (D)
𝟏⁄
𝐪𝐥 𝒑 𝟑
Substituting the value of 𝑬𝟎 as 𝟑
we get r as [ ] 𝒙
𝟐𝛑𝛆𝟎 𝐱 𝟐𝒒𝒍
3. (A),(D)
Susbstituting the known values, we get the difference in area of the upper and
lower pistons, Au – Al = 10 cm2
From equation 1, it is clear that Pg is constant throughout the process.
Work done on the piston is due to the gravitational force.
B. Wpiston = - mpistong(h2-h1) = - ( 5 × 10 × 0.25) = -12.5 J
C. Watm = Patm ΔV = -Patm( Au – Al )( h2 – h1 ) = -25 J
D. Since the process is infinitesimally slow , ΔKE = 0.
So the total work done on the system is 0.
Wgas + Watm + Wpiston = 0
So,Wgas = 37.5 J
4. (B) (C)
Substituting in λ
4πao=2πaon/z
Put n=4 we get z=2
For de-excitation
1/ λ = Rz2[1/n22 - 1/n12] where n1=4 and n2= 3,2,1
Substituting we get 36/7R for n2= 3
4/3R for n2= 2 and 4/15R n2= 1
6. (A)
u = -( 2f-f/3)
=-5f/3
1/(-f) = 1/v + 3/(-5f)
1/v = 3/5f-1/f = -2/5f
v = -5f/2
I=f/2
SECTION 2
SINGLE DIGIT INTEGER
7) 5
First find g at surface of planet
gp’ /gp=R2/(R+2R)2 ge’= ge(1-d/r) [Put d=r/2]
9 gp’= gp ge’= ge/2
ge’=gp’
(9/2)ge=gp
gp=9x10/2=45
8) 2
9) 2
Assume that at time t, only x length remains on the horizontal tube. Then
the pulling force on the rest of the chain is given by
F=M*(h/l)*g
So a= (M*(h/l)*g)/(M*(x+h)/l)=hg/(x+h)
-v(dv/dx)=hg/(x+h)
-ʃvdv=ʃhgdx/(x+h)
Here v varies from 0 to v and x varies from l-h to 0
v2/2=hgln(l/h)
v2=2hgln(l/h)
So kinetic energy=k=(1/2)*m*v2
k=mhgln(l/h)
substituting values of m,h and l we get k=ln2
so ek=2
10) 8
11. 7
P1=200kPa
P2=500kPa
P1=Patm+kΔx1/A
P2=Patm+kΔx2/A
P2-P1=300kPa=3×105Pa
P2-P1=k(Δx2-Δx1)/A=k(ΔV2-ΔV1)/A2,
Where ΔV1=V1-V0 and ΔV2=V2-V0, where V0 is the volume of the
system when the spring is uncompressed.
Therefore, k/A2=(P2-P1)/(ΔV2-ΔV1) =30000/(V2-V1)=3×107N/m5
At any instant, P=Patm+Ppiston+kΔx/A, or
P-P1=3×107×(V-V1), where V is the volume at that instant.
Thus, P=200000+3×107×(V-0.01)
Work done by the air during expansion,
∫ 𝑃𝑑𝑉=2×105×0.01+3×107×(0.02×0.02/2-0.01×0.01/2)-
(3×107×0.01×0.01)
=2000+4500-3000=3500J
Therefore, the answer is 7
12. 8
Since the electric field in the x direction must not depend on the value of
the electric flux associated with the two surfaces perpendicular to the x
direction cancels out each other. A similar argument follows for the y
direction as well.
Hence only the z component of the electric field provides flux.
z component of the electric field is:
Ez= E0 z ǩ
Therefore, flux entering the cube (z=0) is zero, since the field is 0 at that
surface.
Flux leaving the cube (z = +a) = E0 a × a2 ǩ = E0 a3
𝑞𝑛𝑒𝑡
Using Gauss’ theorem φ =
𝜀0
Therefore, qnet = φ ε0 = ε0 E0 a3
So, x = 8
13. 4
Let the intensity of the source be Io, then intensity at any point with phase
difference Δθ will I=4Iocos2(Δθ/2). Hence initial intensity at P is 4Io
At P with the glass slabs inserted
¾×4Io = 4Iocos2(Δθ/2)
⇒ Δθ=2nπ ± (π/3) also Δθ= (2π/λ) Δx
Hence Δx= λ(n ± (1/6)) , from the data about the 8th maxima and 9th minima
we get
8 λ < Δx < [(2×9) – 1] λ /2
⇒ 8 λ < λ(n ± (1/6)) < [(2×9) – 1] λ /2
The only value of n satisfying the above condition is n=8 and Δx= λ(8 +
(1/6))=49 λ/6
Let µ2 be the refractive index of the lower glass slab with respect to vacuum
then 1.2= µ2/(4/3)
⇒ µ2=1.6
Considering the two glass slabs Δx=t(µ1-1)-t(µ2-1)
Hence Δx=t(µ1-µ2)
49 λ/6 = t (2.3-1.6)
⇒t=7×10-6
k=7 and so k-3=4
14. 5
SECTION 3- PASSAGE
Passage 1
15) B 16) B 17) C
𝐹 = 𝑘∆𝑥 = 𝑘 (√𝑙 2 + 𝑥 2 − 𝑙)
F=2FCosƟ
𝐹𝑟 = 2𝑘 (√𝑙 2 + 𝑥 2 − 𝑙)
𝑥 ≪< 𝑙;
𝐹𝑟 = 2𝑘𝑙((1 + 𝑥 2 /𝑙 2 )1/2 − 1) 𝑥⁄𝑙
𝐹𝑟 = 2𝑘𝑥(1 + 𝑥 2 /𝑙 2 − 1)
3 3
𝐹𝑟 = 2𝑘𝑥 ⁄ 2 = 𝑘𝑥 ⁄ 2
2𝑙 𝑙
3
𝑎 = −𝑘𝑥 ⁄ 2 ⇒ 𝑤 2 = 𝑘⁄ 2
𝑚𝑙 𝑚𝑙
𝑤 = (√𝑘⁄ 2 )
𝑚𝑙
2𝑛 𝑘𝐴𝑖 4⁄
𝐸𝑛 =
4𝑙2
𝑘𝐴𝑜 4⁄
𝐸𝐴𝑛 =
4𝑙 2
𝐸(𝐴) = 𝐸𝑛
⇒ 2𝑛 𝑘𝐴4 4
⁄ 2 = 𝑘𝐴𝑜 ⁄ 2
4𝑙 4𝑙
⇒ 2𝑛 𝐴𝑖 4 = 𝐴𝑖 4
𝑛⁄
⇒ 𝐴𝑛 = 𝐴𝑖 2 4
Passage 2
18) C 19) B 20) D
V=IZ
=√2*104 sin (100t + π/4)
V across R =104 sin 100t
V across L= 104 sin (100t + π/2)
Since inductors are similar, voltage across the two coils are similar
No of turns in primary coil = No of turns in secondary coil
Chemistry
21. [A,C,D]
xAP0A + xBP0B = 700 …..(i)
x”AP0A + x”BP0B = 0.30P0A + 0.70P0B =600 ….(ii)
If moles of A & B initially are x & y then
x=0.75x(2/3)(x+y) + 0.30x(1/3)(x+y)
27. [1]
Dissolved [Zn(OH)2] = [Zn+2 ]aq + [Zn(OH)2]+ aq + [Zn(OH)2]aq + [Zn(OH)3]- +
[Zn(OH)4]2-.
Now, [Zn(OH)2]aq = 10-6M in saturated solution.
So, [Zn(OH)]+ = 10-6x 10-7/[OH-] = 10-13/[OH-]
Similarly, [Zn+2 ] = 10-17/[OH-]2 ,
[Zn(OH)3]- = 10-3[OH-]
[Zn(OH)4]2-=K5[Zn(OH)3]-
[OH-] =(10-2M-1)[OH-]2
29. [4]
CH3
+
CH3 CH3
CH3
+
CH3 CH3
H2O
CH3
*
CH3
*
OH
S.I = 22 = 4
30. [6]
ClO3- + 2H2 + 4e- ClO- + 4OH- ; 𝝙G1o
ClO- + H2O + e- ½ Cl2 + 2OH- ; 𝝙G2o
½ Cl2 + e- Cl- ;𝝙G3o
ーーーーーーーーーーーーーーーーーーーーーーー
ClO3- + 3H2 O+ 3e- Cl- + 6OH- ; 𝝙Go
ーーーーーーーーーーーーーーーーーーーーーーー
∴ 𝝙Go =𝝙G1o + 𝝙G2o +𝝙G3o
-6FEo = -4F x 0.54 - 1F x 0.45 - 1F x 1.07
∴Eo = +3.68/6 = +0.61V
∴10xEo = 6V
31. [6]
C12H22O11 + H2O → C6H12O6 + C6H12O6
mol 0.0125 0 0
0.0125-x x x
ΔP=0
Δv=
q=
P
3
At 1 : P = 10 atm T = 400K V = V1
At 2: P = 10 atm T = 800K V= V2=2V1
At 3: P = ? T=T3 V= V3 = V2 = 2V1
Therefore, W12 = -𝑃𝛥𝑉= -nRT = -400R
W23 = 0 [Since 𝛥𝑉 = 0]
Between 3 & 1, TV𝛾 − 1 = Constant
T3× (2V1)𝛾 − 1= 400 (V1)𝛾 − 1
T3 = 400×(1/2)2/3 = 252K
W31 = 𝛥𝑈31 =nCv(T1 - T3) = 3/2 R (400-252) = 222R
W12-31 = W12 + W 23 + W31 = -178 R
35. [C]
36. [C]
37. [D]
38. [A]
2 K2MnF6 + 4 SbF5 → 4 K[SbF6] + 2 MnF3 + F2
39. [D]
(A) XeF2
(B) 24 XeF2 + (B) S8 → 24 Xe + 8SF6
(C) XeF2 + SbF5 → [XeF]+[SbF6]-
40. [B]
(A) F2 gives O2 gas (C) H2O2 in acidic medium form CrO5 not O3
(B) KI + 3O3 → KIO3 + 3O2
H2
XeF2 Xe + 2HF
(A) (B) (C)
H2
XeF2 + H2O Xe + HF + O2
(B) (C) (D)
3O2 ⇌ 2O3 ; 5O3 + 2KOH → 2KO3(orange solid) + 5O2 + H2O
(D) (E)
Electrolysis
HF + KF → KHF2 (molten) F2
(C) (G)
Mathematics
41.
Sol: A
42.
Sol: A,B,D
43.
ANS a,c
Solution :
Therefore c = -ab/(a+b)
44.
ANS : b,c
Solution :
R1 = /(s-a) (radius of excircle)
On substituting the values in the equation we get ,
S - a = 125
S - b = 25
S-c=5
On adding all three of them we get ,
3s - 2s = 155
s=155
Therefore perimeter = 2s = 310.
We got the value for s . Now using the above relation ,
a=30 b=130 c=150
ANS : a,c
46.
Ans:(b),(c)
Since variable x is present at exactly two positions in each of the matrices,the
maximum power of x in D(x) is x2.
Let D(x)=ax2+bx+c
Using any three of the given values of D(x),we get ,
D(x)=2x2+5x-2
Integer type
47. 0.25
Substitute-
n.exp(n)=cos(y)
sin(y)=k
ln(k)=x
48. 6
y2 = 4x ( t2 ,2t )
2ym = 4
m = 1/t
M(normal) = -1/m
y- 2t = -t ( x-t2 )
=> t3+ (-x+2) t - y=0
Slope -t1 = -t2 = -2
t1 = t2 = 2
t3 + (-x+2)t - y ÷ ( t2 - 4t +4.)
(-x +14 )t -y -16 is the remainder .
But it has to be 0 for the divident to be a perfect multiple of divisor. So on
equating x=14 y= -16
Therefore 3|x+y| = 6
49. 2
50. 9
Property of conics distance from the focus = e times the distance between point
and the directrix x = a/e.
So distances are a - ex and a + ex .
So a + ex = 2 (a - ex )
= x = a/3e
e= 3/5.
So x =25/9 .
y= 814/9
So on differentiating the equation of ellipse and substituting the points we get
the corresponding slope . With the slope and points we are able to find the
equation of tangent .
M = -2/7
Y- 814/9 = - 2/7(x - 25/9 )
Putting y= 0 we get ,
X=9
51. 3
L=lim1/x0((1+(1/x))/(1-(1/x))1/(1/x)-e2)x2
Replace 1/x with h.
L=limh0 ((1+h)/(1-h))1/h-e2)/h2
Use (1+x)1/x=e(1-x/2 + 11x2/24
L=limh0 (e2(1-h/2+11h2/24-...)(1+h/2+11h2/24+....)-e2) /h2
L=limh0(e2 (1 - h2 /4+22h2 /24)-e2 )/h2
L=limh0 e2 (2h2 /3)/h2
L=2e2 /3
52. 1.00
The area is given by the following integral
4 ,0-ln2-,2,e-−x .−1.dx=4(1−ln2) .
A=4
Therefore A/4 = 1.00
53. 3.46
We have ,|x−1|-1.=,,y−2.-2. = ,|z−3|-3.
,x−1-1.=,y−2-2. = ,z−3-3.
,x−1-−1.=,y−2-2. = ,z−3-3.
,x−2-1.=,y−2-−2. = ,z−3-3.
,x−1-1.=,y−2-2. = ,z−3-−3.
Intersection points with plane x+y+z= 18
Are (3,6,9) , (-2,8,12) , (7,-10,21)
Therefore area S = 36,-3.
Taking ,-3 .=1.73
S/18 = 3.46
54. 5.
I:
General Property:The circles defined in the above question passes through the
foci of the respective ellipses.Therefore T1 ,T2 are foci of E1 and T3 ,T4 are foci of E2
.Then Quadrilateral specified in problem is a rhombus.
,x-a.,cos-θ.+ ,y-b.,sin-θ.=1
,x-3.,cos-θ.+ ,y-5.,sin-θ.=1
Slope, m=4=− ,5-3.,cot-θ.
,cot-θ.=−,12-5.
Solving for sin ϴ and cos ϴ, the equation of the tangent becomes,
4x – y = 13
To find the intersection points R and S, put y = -5 and y = 5,to get
R = (2,-5) and S = (,9-2.,5)
So the length RS = ,-,(2−,9-2.)-2.+,(5+5)-2..= ,5,-17.-2.
II.
58.B 59.C 60.B
6=0(2)+6(1)=1(2)+4(1)=2(2)+2(1)=3(2)+0(1)
No of 2s No of 1s No of permutations
0 6 1
1 4 5!4!=5
2 2 4!2!2!=6
3 0 3!3!=1
Total =13
f(6)=13
Now,
f(f(6))=f(13)
No of 1s No of 2s No of permutations
13 0 1
11 1 12
9 2 55
7 3 120
5 4 126
3 5 56
1 6 7
total=377
sof(f(6))=377
f(1)=1
f(2)=2
f(3)=3
f(4)=5
By taking higher values of n in f(n), we always get more value of f(n).Hence, f(x) is
one-one ,clearly f(x) is into.