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Classification, Labelling & Safety Data Sheet Part II - CLASSIFICATION

of Hazardous Chemical R2013 – Duty of principal supplier to classify chemical


CLASS 2013 1. Classify chemical – according to list of classified
Apply to – chem supply for workplace only chemical
2. If chem classify as not listed – classify accdg
Not apply to physical, health & enviro hazard (Ind. Code prac)
- Radioactive materials (Atomic Energy Licensing Act 3. DG found inconsistency – determine classification
1984 [ACT 304]) based on classified chem list
- Schedule waste (Enviro schdle waste Quality R2005) 4. Principal supplier shall follow DG order
- Cosmetics - Control of Drugs & Cosmetic R1984 5. Fine not exceed RM10K / imprison not exceed 1yr
- RnD chemical – not for sale in market, not exceed / both – if principal supplier not follow duty (1,2,4)
5kg, lack info on safe use by supplier 6. Fine not < RM1k every day / part of day – if
- Manufacture item other than fluid/particle - form to continue not follow duty
specific shape/design, use in normal condition (not
release chem tht has physical hazard & risk)
- Pesticide – Pesticides Act 1974 [Act 149] Part III - PACKAGING
- Chemical tht need to export – store in storage area
Packaging requirement of hazardous chemical

Terms Meaning  Use Container packaging –ensure chem not escape


Hazardous Hazard chem under R4 unless safety device is fitted into container
chemical  Strong fastening – able to hold chem & meet
Occu health doctor Medical practitioner – rgister w DG normal stress + strain handling
Safety Data Sheet Hazard chem latest info  Materials not cause adverse attack – tht mix w
Signal word Indicate relative level of severity hzrd
chem & cause harmful compound
& label
Warning Less hazard  Good replaceable fastening design – ensure
Danger More severe hazard packaging repeatedly fastened w/o chem escape
Hazard categories Divison of criteria hazard  Fine < RM10K / <1 yr imprison / both – if
Hazard class Nature of physical, health/enviro supplier not follow requirement
hzrd  Fine < RM1K everday / part of day – if
CAS Registered no. Chemical abstracts Service Registry continue not follow requirement
No.
Supplier Supply chemical – principal & Apply fine to – packaging requirement, seal
subsidiary supplier packaging, label packaging, hazard pictogram,
Subsidiary supplier Repack, distribute / retails chemical
hazard statement, dimension label, affixing &
Principal supplier Formulate, manufacture, imports,
recycle/ reformulate chem tagging of label, Confidential business
Chemical recipient Receive chem information
Product identifier Name/no. use on label – provide
unique means to identify hzrd
Hazard Consist – class & category hazard
Seal of Packaging
classification
Hazard statement Describe degree of hazard  Packaging initially closed w seal – once packaging
Precautionary Recommend measure to minimize/
open, seal is broken & cannot be repaired (botol
statement prevent adverse effect frm exposure
Hazard pictogram Label & graphic composition
spaghetti)
Industry Code of Practice on Chemicals Classification
Practice & Hazard Communication
Part IV - LABELLING Dimension of Label

Duty to label packaging of hazardous chemical  Under R8 – specified in 4th schedule

Standard container Container 125ml & below


1. Product identifier 1. Product identifier
2. Supplier identification 2. Supplier identification
Affixing & tagging of Label
3. Signal words 3. Signal words
 Subject need to sub regulations if hazard packing…
4. Hazard statement 4. Hazard statement
5. Hazard pictogram 5. Hazard pictogram Container
6. Precautionary 6. “Read Safety Data Contain another container
statement Sheet before use” - Label shall be affixed to 1/more surfaces of
container – so label can b read horizontally
 Follow industry code of practice & national & when container is in normal position
English language  For container ≤125ml – label shall be affixed in
 Only use one – either Danger or Warning such manner deemed reasonable by supplier
 All hazard need to mention (descending order)  If not practicable to affix a label bcz of nature of
 Update label every 3months – If hazard is more container – packaging need to tag w label.
dangerous than before
*Fine same w packaging requirement*

Requirement of hazard pictogram Part VII – CONFIDENTIAL BUSINESS


 Black symbol on white background – red border & INFORMATION
sufficient width (clear to see) Info on hazardous chemical
 Diamond shape – side titled 45˚ to horizontal
 1/15 of surface area – not less than 100 mm2  Supplier may omit info in Safety Data Sheet
o Name of hazardous chemical
Rules of precedence of hazard pictogram & statement o Composition & ingredients of chemical
on label
 Replace info w generic name of chemicals/
 Use for more than 1 hazard pictogram on a label allowable concentration range of ingredients – if
info is omitted
Physical Hazard  DG/ Occu Health Dr./ person who use chem – may
 Eg – if there are “exploding bomb”, “flame” & request in writing from a principal supplier – for
“flame over circle” = only use “exploding bomb” - disclosure information
Except – case that has more than 1 hazards  Upon request, Principal Supplier shall disclose
 Use both hazard – if Self-reactive chem type B & information to DG, Occu Health Dr. / person use
organic peroxides B –“exploding bomb” & “flame”
 Information only use – for protection of safety &
health of employees
Health hazard  Person who use information other than main
 “Skull & crossbones” , “exclamation mark” = use purpose – shall commit offence & fine RM10K &
only “Skull & crossbones” imprisonment – not exceed 1 yr or both
 If skin irritation – “corrosion”, “exclamation mark”
= use only “corrosion”
 If respiratory & skin sensitization, corrosion,
serious eye damage, eye irritation /combination - Part VIII - REVOCATION
“Health hazard”. “exclamation mark” = use “health
The Occupational Safety & Health (Classification,
hazard”
Packaging & Labelling of Hazardous Chemicals)
Regulation 1997 [P.U (A) 143/1997] are revoked
 Use more than 1 hazard statement on a label
 REVOKE FROM CPL
 “very toxic to aquatic life w long term effect”, “very
toxic aquatic life” – use “very toxic to aquatic life w
long term effect”
 “causes severe skin burn & eye damage”, “cause
serious eye damage” – use “causes severe skin
burn & eye damage”
COMBINED HAZARD STATEMENTS

 Fatal if swallowed / in contact w skin


 Fatal if swallowed / inhaled
 Fatal if in contact w skin/ inhaled
 Toxic if swallowed / in contact w skin
 Toxic if swallowed / inhaled
 Toxic if in contact w skin / inhaled
 Toxic if swallowed, in contact w skin / inhaled
 Harmful if swallowed / in contact w skin
 Harmful if swallowed / inhaled
 Harmful if in contact w akin / inhaled
 Harmful if swallowed, in contact w skin / inhaled
 Causes skin & eye irritation

DIMENSION OF LABEL
Content of Packaging Dimension of Label (mm)
≤3L If practicable – at least 52 x 74

3 L ≥ 50 L ≥ 74 x 105
50 L ≥ 500 L ≥ 105 x 148
≥ 500 L ≥ 148 x 210

CUT-OFF VALUE OF CONCENTRATION


Hazard Class Cut-off Value
Acute toxicity At 1 % or more (≥ 1%)
Skin Corrosion / irritation At 1 % or more (≥ 1%)
Serious eye damage / eye At 1 % or more (≥ 1%)
irritation
Respiratory sensitization At 0.1 % or more (≥ 0.1%)

Skin sensitization At 0.1 % or more (≥ 0.1%)


Germ cell mutagenicity At 0.1 % or more (≥ 0.1%)
(category 1)
Germ cell mutagenicity At 1 % or more (≥ 1%)
(category 2)
Carcinogenic At 0.1 % or more (≥ 0.1%)
Reproductive toxicity At 0.1 % or more (≥ 0.1%)
Specific target organ At 1 % or more (≥ 1%)
toxicity – single exposure
Specific target organ At 1 % or more (≥ 1%)
toxicity – repeated
exposure
Aspiration Hazard At 10 % or more (≥ 10%)
Hazardous to the aquatic At 1 % or more (≥ 1%)
environment

Made 30 Sept 2013 – Datuk Richard Riot Anak Jaem


(Minister of HR)
Hazard Pictogram

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