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Dieletric Properties
Dieletric Properties
Dieletric Properties
ABSTRACT: The dielectric properties of 15 vegetables and fruits were measured at 2450MHz from 5 to 130 8C. Equa-
tions were developed as a function of temperature, ash, and either moisture content or water activity, and compared to
literature equations. Dielectric constant of vegetables and fruits decreased with temperature and ash content. How-
ever, ash was not a factor in the equations produced separately for fruits. Dielectric loss factor changed quadrically
with increasing temperature: first decreasing and then increasing. This transition temperature decreased with ash
content. Ash increased the dielectric loss factor. Garlic and potato gave unusual results, which could be explained by
the behavior of solutions of inulin and potato starch, respectively.
Keywords: vegetables, fruits, dielectric properties, dielectric constant, loss factor
Introduction the exact samples used. Because of this, they were limited to a max-
Food Engineering and Physical Properties
234 JOURNAL OF FOOD SCIENCE—Vol. 68, Nr. 1, 2003 © 2003 Institute of Food Technologists
Further reproduction prohibited without permission
Dielectric properties of vegetables and fruits. . .
measured. The sample holder was sealed to prevent any moisture Table 1—The moisture, water activity, and ash content (wet
loss as steam. A thin metal sheet was placed between the sample basis) of samples.
and the spring to prevent the spring digging into the sample. Sample % Moisture aw % Ash
The sample (a cylinder 2.5 cm × 2.5 cm) was initially refrigerated Vegetables
to 5 °C and the oil in the jacketed sample holder cooled the sample broccoli 92.37 0.999 0.93
holder and probe to 5 °C. The sample was placed in the sample carrot 89.97 0.996 0.78
holder after everything had reached 5 °C. The first measurement garlic 57.30 0.983 1.48
parsley 87.75 0.997 1.47
was made when the temperature reading was stable. The oil bath
parsnip 79.67 0.993 0.97
was then increased to 5 °C above the temperature of measurement. potato 75.19 0.990 0.85
When the sample reached the desired temperature, the dielectric radish 95.82 1.000 0.63
properties were measured and the oil temperature increased anoth- spinach 90.35 0.994 1.56
er 5 °C. Thus, the temperature difference in the sample is from the turnip 93.84 0.998 0.53
yam 81.50 0.993 0.93
stated temperature to 5 °C warmer. It took 5 to 6 min for the oil bath Fruits
to raise the temperature of the sample holder 5 °C. The entire run apple 84.89 0.990 0.26
took 2.5 to 3 h. A temperature range of 5 to 135 °C was measured in banana 76.67 0.985 0.72
5 °C intervals at 2450MHz. All measurements were performed in corn 78.86 0.995 0.61
triplicate, with fresh samples. cucumber 95.89 1.000 0.39
pear 83.78 0.992 0.28
A sample was bored from most of the vegetables and fruits. The
exceptions were leafy vegetables and corn, which were chopped using
a blender, and garlic, which was mashed. The probe and sample
holder was stabilized so that the probe could not be moved any time method to employ when the data are expected to exhibit significant
during calibration or measurement. The sample holder (Figure 1) was random errors (Calay and others 1995). The equations and all pre-
removed from the probe for calibration with the short, then replaced dictors included in the equations had a significance of p < 0.001.
for the rest of the calibration and sample measurements. Calibration Quality of fit was assessed from adjusted coefficient of determina-
was performed using a short, air, and water before every test. The tion (R2adj) of the equation. The data were analyzed using JMPin
Dielectric Constant
The dielectric constant of vegetables and fruits decreased as
temperature increased (Figure 2). Most of the water in vegetables
Table 2—Predictive equations for the dielectric constant and the loss factor of the samples at 2450MHz.
Dielectric constant
Overall ⬘ = 38.57 + 0.1255·T + 0.4546·M – 14.54 · A – 0.0037 · M · T+0.07327 · A · T
Vegetables ⬘ = –243.6 +1.342·T + 4.593·M – 426.9 · A + 376.5 ·A2 – 0.01415 · M · T – 0.3151 · A · T
Fruits ⬘ = 22.12 + 0.2379·T + 0.5532·M – 0.0005134 · T2 – 0.003866 · M · T
Dielectric loss factor
Overall ⬙ = 17.72 – 0.4519 · T + 0.001382 · T2 – 0.07448 · M + 22.93 · A – 13.44·A2 + 0.002206 · M · T + 0.1505 ·A · T
Vegetables ⬙ = –100.02 – 0.1611 · T +0.001415 · T2 + 2.429 · M – 378.9 · A + 316.2 · A2
Fruits ⬙ = 33.41 – 0.4415 · T + 0.001400 · T2 – 0.1746 · M + 1.438 · A + 0.001578 · M · T + 0.2289 · A · T
T = temperature (°C), M = moisture (%), A = wet basis ash (%)
and fruits exists as free water, and the dielectric constant of free Corn and cucumber were grouped together with fruits rather
water decreases with temperature (Mudgett 1995); thus, this was than with vegetables. This was done because, physiologically, they
anticipated. are fruits. However, from the R2adj it was not clear if they fit better
The higher the moisture content, the higher the dielectric con- with the fruits or with the vegetables.
stant. This was expected, since water is a strong polar solvent in The average percent error of prediction was 6.20% for dielectric
most foods and reorients in response to changes in field polarity; constant. The best fit was for cucumber (0.94%). The largest outlier
therefore, it is the major component of the food that contributes to was spinach (12.17%). Potato showed a very different trend from the
the dielectric constant (Ryynanen 1995). Using water activity as the rest of the samples with a sudden increase from 65 to 70 °C. This
independent variable instead of moisture content did not change corresponds to the gelatinization point of potato starch, which is 62
R2adj of the equations considerably: a change occurred only in the to 68 °C (Whistler and Daniel 1985). A suspension of 20% potato
third decimal place. Therefore, only equations using moisture con- starch with and without salt was measured to see if the dielectric
tent are presented. constant increases as gelatinization takes place (Figure 3). A sim-
Food Engineering and Physical Properties
Ash was negatively related to dielectric constant (Eq. 1, Table 2). ilar increase was observed for potato starch as for whole potato.
In general, the higher the ash content, the lower the dielectric con- When salt was added, the gelatinization temperature slightly in-
stant (Figure 2). Ash is mostly composed of salts that bind water creased. Roebuck and others (1972) observed that gelatinized starch
molecules and decrease their ability to reorient themselves in re- has a higher dielectric constant than a starch suspension with the
sponse to the changing electromagnetic field direction. This low- same water content. They explained this through hydrogen bond
ers the dielectric constant (Hasted and others 1948). stabilization that facilitates polarization of water molecules by the
Similar trends were observed when vegetables and fruits were electromagnetic field.
evaluated as 2 separate groups: the dielectric constant increased Another unusual sample was the garlic. Dielectric constant of
with increasing moisture. The dielectric constant of vegetables garlic increased up to 55 °C as opposed to the other samples that,
decreased with ash content (Eq. 2, Table 2). However, ash was not in general, decreased as temperature increased. Garlic contains
found to be significant in affecting the dielectric constant of fruits approximately 30% oligofructosaccharides, mainly in the form of
(Eq. 3, Table 2). This may be because of the low levels of ash present inulin (Van Loo and others 1995). These oligosaccharides bind
in the fruits (0.26 to 0.71%) as compared to the vegetables (0.53 to water. The dielectric constant of bound water increases as temper-
1.56%). Separating the fruits and vegetables increased the R2adj of ature increases (Calay and others 1995). Gels of 20 and 41% inulin
the equations, which may be due to differences in the physiolog- gels were measured to see if they cause similar trends (Figure 4). The
ical structure between fruit and vegetables (Eq. 2 and 3, Table 2). 41% inulin sample matched garlic very closely and showed the same
increasing then decreasing trend with temperature. Funebo and
Ohlsson (1999) suspected that pectin, which is another high molec-
ular weight hydrophilic compound, may bind water, causing predic-
Figure 3—Temperature dependence of dielectric constant and Figure 4—Temperature dependence of dielectric constant and
dielectric loss factor of potato and potato starch suspensions dielectric loss factor of different concentrations of inulin in
at 2450MHz comparison to garlic at 2450MHz
Table 3—Predictive equations for the dielectric constant and the loss factor of individual vegetables and fruits as a function
of Temperature at 2450MHz
Dielectric constant Dielectric loss factor Transition
a b c a b c temperature
a+bT+cT2 a+bT+cT2 R2adj (°C)
Vegetables
broccoli 74.18 –0.1208 –0.0005129 0.989 20.89 –0.02420 0.001174 0.915 10.3
carrot 77.94 –0.2068 0 0.906 21.68 –0.1040 0.0016 0.927 32.5
garlic 43.47 0.1743 –0.001143 0.848 19.62 –0.09577 0.001250 0.957 38.3
parsley 56.42 –0.08378 0 0.646 16.45 –0.04048 0.001434 0.938 14.1
parsnip 65.31 –0.1323 0 0.928 22.40 –0.1385 0.001332 0.893 52.0
potato – – – – 17.79 –0.1357 0.001370 0.893 49.5
radish 77.31 –0.2166 0 0.909 20.36 –0.1825 0.001517 0.846 60.1
spinach – – – – 14.17 –0.02897 0.001176 0.989 12.3
turnip 66.93 –0.1528 0 0.727 17.99 –0.1965 0.001471 0.907 66.8
yam – – – – 17.59 –0.1192 0.001371 0.899 43.5
Fruits
apple 64.63 –0.05240 –0.0005831 0.960 17.23 –0.2407 0.001348 0.974 89.3
banana 68.73 –0.08229 –0.0005706 0.994 21.28 –0.1536 0.001450 0.895 53.0
corn 60.86 –0.03792 –0.0005502 0.950 19.02 –0.1355 0.001004 0.883 67.5
cucumber 77.82 –0.2136 0 0.992 18.41 –0.2474 0.001746 0.916 70.9
pear 71.06 –0.05229 –0.0008304 0.896 20.95 –0.2498 0.001453 0.854 86.0
tive equations to produce unexpectedly low numbers based on the others (1995) were higher than the predicted values, and the pre-
water content of the sample. diction became worse as the temperature increased (Figure 5). Pre-
Our data were fit into literature equations to see how closely they dictions by Funebo and Ohlsson (1999) were higher than the mea-
creased with moisture (Figure 6). The moisture-dielectric loss factor therefore it acted as if it had less ash. There is no specific literature
relationship reported in the literature is complex. Funebo and available about inulin; however, methylcellulose, cellobiose, and
Ohlsson (1999) indicated that dielectric loss factor peaked at a other sugars have been shown to bind salt (Braudo 1985). This hap-
moisture content between 44 and 67% at 2800 MHz. Nelson (1987) pens due to “coordination centers” composed of hydroxyl groups
found that dielectric loss factor of grains decreased linearly with attracting cations. Southgate (1978) indicates that some dietary
moisture content at 20, 300, and 2450 MHz. Dielectric loss factor of fibers also bind ions. Broccoli and carrot had lower transition tem-
maple syrup also decreases with increasing moisture content (35 to peratures than predicted, as if the samples had higher ash.
98%) at 2450 MHz (Favreau and other 1997). For low moisture con- The dielectric loss factor increased with ash content as expect-
tent foods, dielectric loss factor usually increases with increasing ed (Figure 6). Ash increases the dielectric loss factor by increasing
moisture content until 20 to 30%, levels off, and may decrease for the ionic component of the dielectric loss factor. Equations that
higher moisture contents in the dielectric and the microwave region predict dielectric loss factor of each vegetable and fruit as a func-
(Schiffman 1995). At high moisture levels, it was reported that di- tion of temperature were produced with higher R2adj values (Table
electric loss factor increased with increasing moisture content at 3). Unlike for the dielectric constant, these were all quadratic equa-
3000 MHz (Bengtsson and Risman 1971). This occurs because the tions.
effect of moisture content on the dielectric loss factor is both fre- The loss factor was predicted with an average error of 13.22%.
quency and temperature dependent. Literature also shows that it is more difficult to predict loss factor
The dielectric loss factor decreases then increases with increasing than dielectric constant (Sun and others 1995, Calay and others
frequency (Mudgett 1995). The dielectric loss factor is the sum of 2 1995). Best predicted samples were parsnip (3.76%) and corn
components: ionic, ⬙, and dipole, ⬙d loss. This minima occurs be- (4.43%). The worst were yam (27.0%) and potatoes (24.47%), which
cause of the opposite effects of ionic and dipole loss. The curves for were both lower than would be predicted. Dielectric loss factor of
both losses shift to higher frequencies at higher temperatures thus potatoes was similar to the loss factor of a 20% starch suspension
as temperature increases at 2450 MHz, the dipole loss decreases with 1% salt (Figure 3). Both yam and potato are high starch vege-
and ionic loss increases. For apples, this minima shifted from 1000 tables. The dielectric loss factor of starch-salt solutions is lower than
MHz at 22 °C to 2000 MHz at 60 °C (Feng and others 2002). This would be predicted based on salt content because of a starch-salt
explains both the fact that the dielectric loss factor decreases then interaction (Bircan and Barringer 1998). Therefore, the dielectric loss
Food Engineering and Physical Properties
increases with temperature, and the fact that the loss factor decreas- factor of the high starch vegetables is lower than would be predicted
es with increasing moisture below 34 °C but increases above it. based on the ash content.
Dielectric loss factor of fruits and vegetables changed as a sec- When the vegetables and fruits were separated into 2 separate
ond-degree function of temperature (Figure 6). They first decreased groups, the R2adj values improved (Eq. 5 and 6). The dielectric loss
with temperature then increased. Because of the difference in tem- factor decreased with temperature at temperatures lower than
perature dependence of the dipole and ionic loss components, the 56.9 °C for vegetables.
dielectric loss factor of an ionic solution generally decreases as the The data for dielectric loss factor were compared to equations in
temperature increases to an intermediate transition point and then the literature. Equation of Calay and others (1995) predicted our
increases with temperature (Mudgett 1995). The transition temper- data with an average error of 34.91%. Their predictions had high
atures, Tt, where the dielectric loss factor changes from decreasing errors at high temperatures and did not reflect the increasing loss
to increasing with temperature were calculated for our data. Tran- factor with temperature. The predictions were better at tempera-
sition temperatures decreased with ash concentration. There was tures below 55 °C. The equation did not contain a T2 term to reflect
a negative linear relationship between transition temperatures and the curved nature of the response of dielectric constant to temper-
ash (R2 = 0.9687) (Figure 7). Garlic, carrot, and broccoli were clearly ature. Sun and others (1995) could not produce an equation that
outliners and were deleted. Without their deletion, the R2 was could reasonably predict dielectric loss factor of fruits and vegeta-
0.7292. Garlic had a higher transition temperature than predicted, bles.
Figure 7—The effect of ash on transition temperatures at Figure 8—Comparison of measured to predicted values of
2450MHz. The data from carrot, broccoli and garlic were the dielectric loss factor of banana using literature equa-
deleted to obtain the correlation. tions at 2450MHz
All available equations were used to predict the dielectric loss rials. J Micro Pow 6:107-23.
Bircan C, Barringer SA. 1998. Salt-starch interactions as evidenced by viscosi-
factor of banana as an example (Figure 8). Eq. 4 and Calay and oth- ty and dielectric property measurements. J Food Sci 63(6):983-6.
ers (1995) produced predictions close to the measurements under Braudo EE. 1985. Starch as a functional component of food systems. Die Nahr
9:885-94.
55 °C. However, above this temperature, Calay and others (1995) Calay RK, Newborough M, Probert D, Calay PS. 1995. Predictive equations for the
predicted that the dielectric loss factor decreases with temperature, dielectric properties of foods. Int J Food Sci Tech 29:699-713.
Favreau D, Sosle V, Raghavan GSV. 1997. Dielectric properties of maple sap and syr-
where the measured values increase. This may be due to the data up at 2.45 GHz . J Micro Pow EE 32(2):96-100.
used to produce their equation. Using only low temperature data, Feng H, Tang J, Cavalieri RP. 2002. Dielectric properties of dehydrated apples as af-
fected by moisture and temperature. Trans ASAE 45(1):129-35.
the increase in the dielectric loss factor at higher temperatures can Funebo T, Ohlsson T. 1999. Dielectric properties of fruits and vegetables as a func-
not be seen. Funebo and Ohlsson (1999) predicted the dielectric loss tion of temperature and moisture content. J Micro Pow EE 34(1):42-54.
factor of banana almost constant with temperature. Their equations Garcia A, Torres JL, Prieto E, De Blas M. 2001. Dielectric properties of grape juice at
0.2 and 3 GHz. J Food Eng 48:203-11.
did not contain a quadratic temperature term or consider ash as a Hasted JB, Ritson DM, Collie CH. 1948. Dielectric properties of aqueous ionic solu-
factor. tions. Part I and II. J Chem Phys 16:1-21.
Kuang W, Nelson SO. 1997. Dielectric relaxation characterizxation of fresh fruits and
vegetables from 3 to 20 GHz. J Micro Pow EE. 32(2):114-22.
Conclusions Mohsenin NN. 1986. Physical properties of plant and animal materials. New York:
Gordon and Breach Science Publishers. 95 p.