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© Siemens AG 2016

Process Analytics

Emission
Monitoring
Guidance Book

Edition
Brochure 2016 www.siemens.com/processanalytics
© Siemens AG 2016

Content

Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 Emission Control Guidelines driven by UNFCCC . . . . . . . . 20


Siemens Product Portfolio for European "air quality" directives and standards . . . . . . . . . 20
Continuous Emission Monitoring . . . . . . . . . . . . . . . . . . . . . 4
Directives for stationary source emissions . . . . . . . . . . . . . . . 20
Gas analyzers . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 IED Directive 2010/75/EU . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20
ULTRAMAT 23 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 IPPC Directive 2008/1/EC . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21
ULTRAMAT 6 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 WID Directive 2000/76/EC . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21
OXYMAT 6 / ULTRAMAT/OXYMAT 6 . . . . . . . . . . . . . . . . . . . . . 6 LCPD Directive 2001/80/EC . . . . . . . . . . . . . . . . . . . . . . . . . . . 25
SIPROCESS UV600 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6 EN 14181
FIDAMAT 6 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7 Quality Assurance for Automated Measuring Systems (AMS). 27
LDS 6 (in-situ principle) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7 EN 15267
Certification of Automated Measuring Systems (AMS) . . . . . . 28
Gas analyzer systems . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
Emission monitoring guidelines in
Set CEM CERT. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
The USA . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 29
Set CEM 1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
China . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31
Total mercury analyzer system HM-1400 TRX . . . . . . . . . . . . . 10
Hong Kong. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32
Dust, opacity and volume flow measurement devices. . . . 11
India. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32
D-R 220 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11
Malaysia . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32
D-R 290 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11
The Philippines . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34
D-R 320 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12
Singapore . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34
D-R 800 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12
Australia . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35
D-RX 250 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
South Korea . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36
D-FL 100 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
Thailand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36
D-FL 220 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14
Vietnam . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37
D-ISC 100 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14
Other regions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37
Components for system integration . . . . . . . . . . . . . . . . . . 15
Appendices . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 38
Sample probe . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15
List of analyzer conformities with regulations . . . . . . . . . . . . 38
Heated sample lines . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15
Application questionnaires for CEM applications . . . . . . . . . . 39
Sample conditioning system . . . . . . . . . . . . . . . . . . . . . . . . . . 15
Other services for gas analysis from Siemens Process
Analyzer shelters . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15 Analytics . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 39
Emission data management systems . . . . . . . . . . . . . . . . . . 16
Regional Siemens solutions . . . . . . . . . . . . . . . . . . . . . . . . . . . 16
Emission data management solutions . . . . . . . . . . . . . . . . . . 16
D-EMS 2000 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17
D-EMS 2000 CS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18
Extended scope of supply . . . . . . . . . . . . . . . . . . . . . . . . . . . 19
After sales support . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19

2 Emission Monitoring
© Siemens AG 2016

Introduction

The need to monitor and report emissions from chemi- One of the first tasks set by UNFCCC was for signatory
cal manufacturers, power generation and waste incin- nations to establish national inventories of greenhouse gas
eration processes has long been accepted as a legiti- (GHG: carbon dioxide, methane, nitrous oxide, fluorinated
mate demand placed upon industry to protect our gases) emissions and removals. Inventories must be
environment. Recent environmental legislations set updated regularly and submitted by the parties.
stricter limits on various atmospheric pollutants from
industrial installations. 2 commitment periods have been agreed:
During 1st period (2008-2012) target was to reduce emis-
UNFCCC sions by an average of 5% below 1990 levels. In actual 2nd
period (2013-2020) parties who joined this period commit-
The United Nations Framework Convention on Climate ted to reduce emissions by at least 18% below 1990 levels.
Change (UNFCCC) is an international treaty negotiated at
the UN conference held in Rio de Janeiro in June 1992. It At the Paris climate conference (COP21) in December
entered into force in 1994 and, as of March 2014, has 196 2015, 195 countries adopted the first-ever universal,
parties. legally binding global climate deal.

The objective of the treaty is to stabilize greenhouse gas The Paris agreement sets out a global action plan to put
concentration in the atmosphere at a level that would pre- the world on track to avoid dangerous climate change by
vent dangerous interferences with the climate system. The limiting global warming to well below 2°C. It is due to
treaty is not legally binding but provides a framework for enter into force in 2020.
negotiating specific international treaties (called "proto-
cols") that may set binding limits on greenhouse gases. This document outlines Siemens capability to help the cli-
ents meet their obligations under the relevant laws as, e.g.
The parties met annually from 1995 in conferences to in Europe, the Industrial Emissions Directive 2010/75/EU.
assess progress in dealing with climate change. In 1997, Alternatively, if emissions monitoring needs are less
the Kyoto Protocol was concluded and established legally demanding and not part of a controlled process, we can
binding obligations for developed countries to reduce their still supply suitable solutions.
greenhouse gas emissions.

Emission Monitoring 3
© Siemens AG 2016

Siemens Product Portfolio for


Continuous Emission Monitoring

Whether you need the individual components for your


emissions monitoring project or a fully integrated system,
Siemens can deliver the solution.

Siemens diverse and state of the art solutions for continu-


ous emissions monitoring not only help our customers in
complying with the regulatory requirements and standards
but also in improving the overall operational efficiency of
your plant and specific processes while taking an active
role in protecting the environment.

A global issue

For decades, governmental and public pressure exists to


stop global warming by reducing emissions of gaseous and
particle pollutants into the atmosphere. Sources in ques-
tion are conventional coal fired power plants, heavy indus-
try applications such as cement or aluminium plants,
chemical processes, marine engine exhaust gases and
many more.

International and national directives have been developed


and are continuously tightened to limit and reduce the
level of still permitted pollutant concentrations. Continu-
ous monitoring of emitted pollutants is the key pre-condi-
tion to determine the level of emissions from a source and
to ensure compliance with existing legal requirements.

Siemens as leading CEMS provider

Continuous emission monitoring systems (CEMS) are the


equipment of choice for this challenge. Siemens, as an
international leader in providing extractive and in-situ con-
tinuous process gas analyzers, process gas chromato-
graphs as well as customized analyzer systems to all kinds
of industries, is also your key partner in planning, manu-
facturing, installing and servicing CEMS worldwide.

With our wide product portfolio and extensive application


expertise, we offer standard or customized CEMS solutions
to all kind of industries in all parts of the world.

Global support

CEMS are used to ensure and prove full compliance with


legal requirements. Thus, reliable operation and trustable
results are of utmost importance. The global presence of
the Siemens service organization offers optimum support
in this aspect through fast response time onsite if required.
Furthermore, our service specialists are acquainted with
the local and regional requirements, standards and direc-
tives and may advise and support our customers in rele-
vant objectives.

4 Siemens Product Portfolio for Continuous Emission Monitoring


© Siemens AG 2016

Gas analyzers

ULTRAMAT 23 ULTRAMAT 6

ULTRAMAT 23 is an extremely economical and space sav- ULTRAMAT 6 determines up to four infrared active gas
ing multi-component gas analyzer also suitable for emis- components in a single unit. Designed for demanding
sion monitoring. It uses NDIR technology for monitoring applications, the device meets highest standards with
up to three infrared active components and optionally regards to reliability and measuring quality.
electrochemical or paramagnetic cell for oxygen
measurement.

Highlights and benefits Highlights and benefits

◾ Automatic calibration function using ambient air. ◾ Optical couplers and the optional use of optical filters
Check with calibration gases only once a year. increases the selectivity and allows correct measure-
◾ Menu-guided operation with plain text allows users ments even in complex gas mixtures and with lower
and service personnel to operate the device detection limits.
immediately ◾ The analyzer can be used even for measurements in
◾ Logbook information supports preventive gas mixtures with corrosive components
maintenance – by use of appropriate materials
◾ Multi-layer detectors ensure high selectivity and – by design: E. g. detector does not come in contact
reduced water vapor interference with the sample gas.
◾ QAL 1 approval ◾ QAL 1 approval

Technical data (selected) Technical data (selected)


Measurement Concentration of up to four com- Measurement Concentration of CO, NO, SO2
ponents simultaneously CO, NO, and other
SO2, O2 Measuring principle Non-dispersive infrared (NDIR)
Measuring principle Non-dispersive infrared (NDIR) spectroscopy
spectroscopy; electrochemical Typical measuring ranges CO: 0 ... 50 mg/m3
cell; paramagnetic for CEM NO: 0 ... 100 mg/m3
Typical measuring ranges CO: 0 ... 1501)/2502) mg/m3 SO2: 0 ... 75 mg/m3
for CEM NO: 0 ... 1001)/4002) mg/m3 Ambient temperature 5 ... 45 °C
SO2: 0 ... 200 mg/m3 Protection class IP20 (rack unit), IP65 (field unit)
O2: 0 … 5/0 … 25 Vol%; Output 0/2/4 ... 20 mA; 6 x relay; RS 485
0 ... 2/0 ... 100 % Option: PROFIBUS DP and PA
Ambient temperature 5 ... 45 °C Conformities See table (Appendix 1)
Protection class IP20
Output 0/2/4 ... 20 mA; 8 x relay; RS 485
Option: PROFIBUS DP and PA
Conformities See table (Appendix 1)
1)
One and two IR-components 2)
Three IR-components

Siemens Product Portfolio for Continuous Emission Monitoring 5


© Siemens AG 2016

Gas analyzers

OXYMAT 6 SIPROCESS UV600

OXYMAT 6 measures oxygen using the paramagnetic alter- SIPROCESS UV600 is an extractive UV-based gas analyzer
nating pressure technology. This enables perfect linearity to measure up to three components simultaneously. It is a
and allows parameterization of minimal measuring ranges. specialist for extremely selective NO measurement with
small measuring ranges and also suited to determined
other UV-active gases, e.g. NO2, SO2 and H2S.

Highlights and benefits Highlights and benefits

◾ The analyzer can be used even for measurements in ◾ Simultaneous measurement of NO and NO2 with sub-
gas mixtures with corrosive components sequent compilation
– by use of appropriate materials ◾ NO2 converter not required (lower maintenance
– by design: E. g. detector does not come in contact effort)
with the sample gas. ◾ Measurement not affected by H2O and CO2
◾ No moving parts for long lifetime at low mainte- ◾ Measurement of very low NO concentration (measur-
nance efforts ing range 0 to 15 mg/m3)
◾ Fast response time ◾ QAL 1 approval
◾ QAL 1 approval

Technical data (selected) Technical data (selected)


Measurement Concentration of O2 Measurement Concentration of up to three
Measuring principle Paramagnetic alternating pres- components simultaneously: NO,
sure principle NO2, SO2, H2S
Typical measuring ranges 0 ... 5 Vol% and 0 ... 25 Vol% Measuring principle UV resonance absorption spec-
for CEM trometry
Ambient temperature 5 ... 45 °C Typical measuring ranges NO: 0 ... 15 to 0 ... 1 400 mg/m3
Protection class IP20 (rack unit); IP65 (field unit) for CEM NO2: 0 ... 20 to 0 ... 2 000 mg/m3
Output 0/2/4 ... 20 mA; 6 x relay; RS 485 SO2: 0 ... 25 to 0 ... 2 600 mg/m3
Option: PROFIBUS DP and PA H2S: 0 ... 40 to 0 ... 1 500 mg/m3
Conformities See table (Appendix 1) Ambient temperature 5 ... 45 °C
Protection class IP40
Output 4 x 0/4 ... 24 mA; 8 x relay;
ULTRAMAT/OXYMAT 6 RS 485; Ethernet (LAN)
ULTRAMAT/OXYMAT 6 multi-component gas analyzer com- Conformities See table (Appendix 1)
bines the analytical benches of both analyzers in one 19"
rack providing one oxygen channel and one channel for up
to two IR-active components.

6 Siemens Product Portfolio for Continuous Emission Monitoring


© Siemens AG 2016

FIDAMAT 6 LDS 6

FIDAMAT 6 gas analyzer is suitable for the determination LDS 6 diode laser gas analyzer is based on the specific light
of the total hydrocarbon content (THC) in air and in flue absorption principle of different gas components which is
gases as well as in solvent recovery processes and cement unaffected by cross-interferences. LDS 6 is suitable for fast
plants. in-situ measurements of gas concentrations in process and
flue gases.

Highlights and benefits Highlights and benefits

◾ Measuring range down to 0 to 15 mg/m3 ◾ In-situ measurement at process conditions


◾ Low fuel consumption ◾ Highly selective (no cross interferences)
◾ Auto-start and safety shutdown ◾ Insensitive to dust and misalignment
◾ Suitable for measurements in the presence of corro- ◾ Real-time measurement
sive gases ◾ No sample conditioning required
◾ Options for internal sample gas pump ◾ Self-calibration by built-in reference cell
◾ Non-plugging capillary sample inlet ◾ Minimum maintenance requirements
◾ QAL 1 approvals for HCl, NH3, and H2O

Technical data (selected) Technical data (selected)


Measurement Total hydrocarbon content Measurement Concentration of NH3, NH3/H2O,
(CnHm) H2O, HCl, HCl/H2O, HF, HF/H2O,
Measuring principle Flame ionization CO/CO2
Typical measuring ranges 0 ... 15 mg/m3 Measuring principle Tunable diode laser absorption
for CEM spectrometry
Ambient temperature 5 ... 45 °C Typical measuring ranges NH3: 0 ... 15 mg/m3 and
Protection class IP20 for CEM 0 ... 20 mg/m3
Output 0/2/4 ... 20 mA; 6 x relay; RS 485 HCl: 0 ... 15 mg/m3 and
Option: PROFIBUS DP and PA 0 ... 90 mg/m3
Conformities See table (Appendix 1) HF: 0 ... 5 mg/m3
CO/CO2: 0 ... 5 Vol %/ 0 ... 10 Vol %
Ambient temperature 5 ... 45 °C
Protection class IP20
Output 4 ... 20 mA; 6 x relay (per chan-
nel); Ethernet for Service and
Maintenance
Conformities See table (Appendix 1)

Siemens Product Portfolio for Continuous Emission Monitoring 7


© Siemens AG 2016

Gas analyzer systems

Set CEM CERT


Set CEM CERT can be equipped with two continuous gas
analyzers providing the most common technologies in
emission monitoring: ULTRAMAT 23 (NDIR) and
SIPROCESS UV600 (UV). This allows to determine CO, NO,
SO2, NO2 and O2. The system also includes a NOx converter,
a sampling probe, a heated sample gas line, a two stage
sample gas cooler and a gas pump.

The innovative CEMS meets the quality standards


EN 14956, EN 15267 and EN 14181 (QAL 1/2/3, AST)
which are stipulated by the actual EU directives to be
applied for testing the suitability of a device or system.

Application
Emission monitoring of
◾ Power plants
◾ Cement plants
Set CEM CERT is a standardized and EN 15267 certified
◾ Steel and aluminium plants
continuous emission monitoring system, which is suitable
◾ Waste incineration plants
for use in plants which need to comply with European and
◾ Glass melting furnaces
respective national legislation: 2001/80/EC and
◾ Monitoring of greenhouse gas emissions as part of the
IED 2010/75/EU; in Germany: 13th BImSchV, 27th BImSchV
EU Emission Trading Scheme (ETS)
and TA Luft.

Highlights and benefits Technical data (selected)


Measurement CO, NO, SO2, NO2, O2
◾ Complete modular package including gas analyzer Analyzer ULTRAMAT 23 and
ULTRAMAT 23 and SIPROCESS UV600, sampling SIPROCESS UV600
probe, heated sample lines, gas cooler, gas pump, Measuring principle NDIR, NDUV, paramagnetic, elec-
and NOx converter trochemical cell
◾ Approved measuring ranges can be selected to allow Typical measuring ranges CO: 0 ... 150 mg/m3 1)
a wide range of applications for CEM NO: 0 ... 100 mg/m3 1)
◾ Easy to configure and cost efficient in purchase and SO2: 0 ... 400 mg/m3
maintenance NO2: 0 ... 50 mg/m3 1)
◾ Sample probe, gas cooler and NOx converter select- O2: 0 ... 25 Vol%
able from leading suppliers Ambient temperature 5 ... 40 °C
◾ Versions for indoor or outdoor installation Protection class IP54
◾ Tested and QAL 1 approved measuring ranges to Output 0/2/4 ... 20 mA; 8 x relay; RS 485
select a variety of ranges for use in different areas of Option: PROFIBUS DP and PA
application Conformities See table (Appendix 1)

1)
Depending on configuration

8 Siemens Product Portfolio for Continuous Emission Monitoring


© Siemens AG 2016

Set CEM 1
Main system components
◾ Sampling probe and sample gas line
◾ Gas analyzers
◾ Air conditioning unit
◾ NO2/NO converter
◾ Single or double signal processing
◾ Power supply modules
◾ Condensate collecting vessel
◾ Coalescence filter (option)

Sampling probe
The heated sampling probe (DIN flange DN 65, PN 6,
power consumption 400 VA) is supplied with a weather
protection hood and a 2 µm filter. The maximum dust con-
centration at the sampling point is 2 g/m3 and the maxi-
mum sample gas temperature is 600 °C.
Set CEM 1 is a standardized high performance automatic
Heated sampling line
measuring system for monitoring the emission compo-
The sampling line is heated and regulated at 200 °C,
nents in flue gases of preferably large combustion plants.
energy consumption is 100 VA/m. The inner wall is
It reliably covers all requirements associated with sam-
PTFE 4/6 coated, maximum length is 35 m, optional more.
pling, sample preparation, and gas analysis.

Highlights and benefits Technical data (selected)


Integrated analyzers ULTRAMAT 23, LDS 6, OXYMAT 6
◾ Complete modular package including sampling probe, Measuring principle NDIR; laser spectroscopy; para-
heated sample lines, gas cooler, gas pump, NOx con- magnetic alternating pressure;
verter and ULTRAMAT 23 (NDIR), LDS 6 (in-situ diode electrochemical cell
laser) and OXYMAT 6 gas analyzers Typical measuring ranges CO: 0 ... 150 mg/m3 1)
◾ Expandable (option) to integrate a second for CEM NO: 0 ... 100 mg/m3 1)
ULTRAMAT 23 analyzer SO2: 0 ... 400 mg/m3 1)
◾ Easy to configure and cost efficient in purchase and CO2: 0 ... 5 %
maintenance HCl: 0 ... 15 mg/m3
◾ Available with or without sampling probe HF: 0 ... 5 mg/m3
◾ Simultaneous determination of up to eight compo- NH3: 0 ... 20 mg/m3
nents possible, including HCl, HF and NH3 H2O: 0 ... 15 (30) Vol%
◾ Configuration possible for in-situ measurements with- O2: 0 ... 5/0 ... 25 Vol%
out sampling and sample preparation Ambient temperature 0 ... 35 °C
◾ Simple operation: Large display, several languages, Sample gas temperature Max. 600 °C
intuitive operation Protection class IP54
◾ Very easy to maintain: Maintenance-friendly cabinet Output 0/2/4 ... 20 mA; relay; RS 485
design with hinged frame; digital display of mainte- LDS 6: Ethernet (RJ 45)
nance requests Option: PROFIBUS DP and PA
Power supply 115 V/230 V/400 V modules
Conformities See table (Appendix 1)
1)
Depending on number of components (ULTRAMAT 23)

Siemens Product Portfolio for Continuous Emission Monitoring 9


© Siemens AG 2016

Gas analyzer systems

Total mercury analyzer system HM-1400 TRX


Technical data (selected)
Measurement Concentration of total Hg in sam-
ple gas in µg/Nm3
Sample gas Ambient air, stack gas, process
gas
Sample gas flow rate Min. 70 l/h
Normal 100 l/h
Max. 130 l/h
Sample gas pressure (rel.) -50 ... +50 hPa
Sample gas temperature 0 ... 250 °C
Measuring principle Determination of the Hg° con-
centration of the extracted and
conditioned sample gas by help
of a dual beam UV CVAAS pho-
tometer. Ionic Hg-compounds
are converted to Hg° inside a
thermal converter.
Typical measuring ranges 0 ... 45/0 ... 75 to
Measuring system for fully-automatic and continuous mer- for CEM 0 ... 500 µg/Nm3
cury analysis in flue gas stacks gas by measuring mercury Duct diameter > 0.5 m
vapor (without wet chemistry). The system uses the Protection class IP40 (IP54)
extractive measuring principle and includes sampling Outputs 2 x 0/4 ... 20 mA; 4 x relay
probe and sampling line. Sample probe Sample probe with inside heated
filter element and inlet for heat-
Application ed test gas, Pt100 temperature
◾ Waste incineration plants (municipal, industrial, clinical sensor, controlled by
waste) HM-1400 TRX, 230 V L, N, PE,
50/60 Hz, 650 VA
◾ Sewage sludge incineration
Sample line Temperature controlled 200 °C
◾ Steelworks with scrap metal reconditioning
heated sample line, IP5; Power
◾ Contaminated soil burning plants supply 230 V L,N,PE, 50 ... 60 Hz,
◾ Crematoriums 100 VA/m
◾ Mercury mines and refineries Conformities See table (Appendix 1)
◾ Fluorescent light bulb recycling plants

Highlights and benefits

◾ Maintenance-free (6 months) dry reactor


◾ Conversion of the sample gas into mercury vapor by a
combination of thermal and dry chemical treatment
◾ Continuous vapor measurement in a photometer
◾ High operational safety
◾ Low cross sensitivities
◾ No fail-safe instrument air required
◾ Detection of mercury vapor using a dual beam UV
photometer
◾ Simple operation by keypad-display
◾ Three month maintenance interval
◾ Larger measuring ranges with dilution device (option)
◾ Integrated system to generate reference gas (option)

10 Siemens Product Portfolio for Continuous Emission Monitoring


© Siemens AG 2016

Dust, opacity and volume flow measurement devices

D-R 220 Optical dust and opacity monitor D-R 290 Dust concentration monitor

System for in-situ monitoring of dust emissions on smaller System for monitoring small to medium dust concentra-
plants and in process applications. The system uses the tions, e.g. 20 mg/m3 @ 5 m measuring path length. The
double pass light attenuation principle. device uses the double-pass light attenuation principle.

System components System components


Measuring head, reflector, purge air supply unit and zero Measuring unit, reflector, purge air supply unit, terminal
point reflector. box with power supply.

Highlights and benefits Highlights and benefits

◾ In-situ measuring principle directly in flue gas flow ◾ In-situ measuring principle, continuous measurement
◾ Digital operation with microprocessor ◾ Semi-conductor source with long service life
◾ Adjustable limit value ◾ Super-wide band diode, which provides more stable
◾ Two contact switch outputs measuring results in comparison to devices with con-
◾ Measuring value integral 4/15/64 seconds ventional LEDs
◾ Internal event memory ◾ Automatic function tests with correction of measured
◾ PC-interface for easy maintenance values in relation to soiling
◾ Results shown as opacity or extinction ◾ Optics and electronics in a hermetically sealed unit -
◾ No weather protection covers needed no smoke gas can enter device
◾ Measured value display by means of the D-ISC 100 ◾ Easy adjustment without additional equipment
universal operating and display unit ◾ Measured value display by means of the D-ISC 100
universal operating and display unit

Technical data (selected) Technical data (selected)


Measurement Opacity, extinction Measurement Opacity, extinction
Measuring principle Transmission Measuring principle Transmission
Typical measuring ranges 0 ... 25/50/100 % OP Typical measuring ranges 0 ... 20 to 0 ... 100 % OP
for CEM 0 ... 0.2/0.4 ... 1.6 Ext for CEM 0 ... 0.1 to 0 ... 2.0 Ext
0 ... 160 mg/m3 0 ... 80 to 0 ... 5 000 mg/m3 dust
0 ... 4 000 mg/m3 dust1) Flue gas temperature Above dew point to 250 °C,
Flue gas temperature Above dew point to 200 °C, opt. to 1 000 °C
opt. to 500 °C Flue gas pressure -50 ... +20 hPa, opt. higher
Flue gas pressure -50 ... +10 hPa, opt. higher Ambient temperature -40 ... +60 °C
Ambient temperature -20 ... +50 °C Duct diameter 1 ... 12 m, opt. to 18 m
Protection class IP65; supply unit: IP65 Protection class/Ex IP65/opt. Ex
Output 0/4 ... 20 mA; 2 x relay Output 0/4 ... 20 mA; 2 x relay
Purge air supply Integrated Modbus RTU, bi-directional
Conformities See table (Appendix 1) Purge air supply Appr. 80 m3/h; protection IP55
1)
With reference to 1 m path length after gravimetric calibration Conformities See table (Appendix 1)

Siemens Product Portfolio for Continuous Emission Monitoring 11


© Siemens AG 2016

Dust, opacity and volume flow measurement devices

D-R 320 High-sensitivity measurement


at lowest concentrations of dust D-R 800 Measuring device for dust concentration

Dust monitor ideally suited for monitoring smallest to me- Innovative measuring device with laser technology to
dium dust concentrations using the single side installation. monitor small to medium dust emission according to the
The device uses the backscattering principle. actual European regulations. The device uses the forward
scattering principle.
System components
Measuring head, universal control unit, supply unit with System components
integrated purge air supply. Measuring lance, supply unit with integrated purge air
supply, mounting flange 130/240/500 mm.

Highlights and benefits Highlights and benefits

◾ Easy installation on a standard flange ◾ Easy installation on one side of the duct
◾ Easy start up without adjustment ◾ Long lifetime, no moving parts inside the duct
◾ No wetted parts inside the stack ◾ Hermetically sealed electronic housing against
◾ Automatic background light compensation without exhaust gas
light trap ◾ Integrated display: Measuring value, threshold value,
◾ Convenient operation, remote access possible parameter in probe
◾ Integrated purge air monitoring and control ◾ Automatic switching of measuring ranges according
◾ Data transfer via Modbus to 17th BImSchV
◾ Automatic control functions
◾ Measured value display by means of the D-ISC 100
universal operating and display unit

Technical data (selected) Technical data (selected)


Measurement Dust concentration Measurement Dust concentration
Measuring principle Back scattering Measuring principle Forward scattering
Typical measuring ranges 0 ... 5 mg/m3 to 0 ... 200 mg/m3 Typical measuring ranges 0 ... 10 mg/m3 to 0 ... 200 mg/m3
for CEM for CEM
Flue gas temperature 0 ... 600 °C Flue gas temperature Above dew point up to 220 °C
Flue gas pressure -50 ... +50 hPa, opt. higher Flue gas pressure -50 ... +10 hPa
Ambient temperature -40 ... +60 °C Ambient temperature -20 ... +50 °C
Protection class IP65 Duct diameter 0.4 ... 8 m
Output 0/4 ... 20 mA; 2 x relay; Protection class IP65
Modbus RTU, bi-directional Output 2 x 0/4 ... 20 mA, 4 x relay;
Purge air supply Internal blower with protection Modbus RTU (RS 485)
IP65 Purge air supply Integrated into supply unit
Conformities See table (Appendix 1) Conformities See table (Appendix 1)

12 Siemens Product Portfolio for Continuous Emission Monitoring


© Siemens AG 2016

D-RX 250 Combined probe sensor D-FL 100 Volume flow measuring system

Single rod measurement probe for simultaneous measure- System to measure flow rate in dry emissions with a probe
ment of dust concentration (triboelectic), volume flow, using the differential pressure principle.
temperature and absolute pressure.
System components
System components Low probe, differential pressure transducer, absolute pres-
Probe, transmitter, differential pressure transmitter, con- sure transducer, temperature transducer, cross-over cock,
trol and evaluation unit. evaluation unit.

Highlights and benefits Highlights and benefits

◾ Only one probe/installation opening in the exhaust ◾ Measurement of flue gas velocity
gas channel ◾ Calculation of volume flow at standard conditions
◾ Compact design, no moving/consumable parts ◾ Adjustable parameters
◾ Continuous conversion to normalized dust concentra- ◾ Automatic back-purging device (optional)
tion in mg/Nm3 and to normalized volume flow in ◾ Versions with or without counter-support and for
Nm3/h point measurement
◾ LCD display in mg/Nm3, Nm3/h, °C and hPa, one ana- ◾ Three months maintenance interval
log output for each measurement value ◾ Probes: 0.4 - 2 m/up to 4 m/up to 8 m
◾ Parameterization at the control unit without the need ◾ Options: Display and control unit, weather protection
of a PC or other tools cover, special design in other materials, dP transducer
◾ Remote connection of control and evaluation unit via in Ex-version
two-wire bus interface up to 1 000 m

Technical data (selected) Technical data (selected)


Measurement Dust concentration, volume Measurement Flue gas volume flow, flue gas
flow, abs. pressure, temperature velocity
Measuring principle Triboelectric (dust), differential Measuring principle Differential pressure
pressure (volume flow) Typical measuring ranges 0 ... 3 000 000 m3/h
Typical measuring ranges 0 ... 10 to 0 ... 500 mg/Nm3 for CEM 2 ... 50 m/s
for CEM 0 ... 9 999 999 Nm3/h Flue gas temperature Above dew point to 450 °C;
0 ... 200 °C, optional 0 ... 350 °C opt. to 850 °C
800 ... 1 300 hPa Flue gas pressure -200 ... +200 hPa; opt. higher
Flue gas temperature/pressure Above dew point to 200 °C, Ambient temperature -20 ... +50 °C
opt. 350 °C/-200 ... +200 hPa Duct diameter 0.4 ... 8 m
Ambient temperature -20 ... +50 °C Protection class/Ex IP 65/opt. Ex
Protection class IP65 Output 0/4 ... 20 mA; 2 x relay;
Output 4 x 0/4 ... 20 mA; 7 x relay; Modbus RTU, RS 485
Modbus RTU, RS 485 Purge air for back purging 6 ... 8 bar
Purge air supply Internal blower (if requ.)
Conformities See table (Appendix 1) Conformities See table (Appendix 1)

Siemens Product Portfolio for Continuous Emission Monitoring 13


© Siemens AG 2016

Dust, opacity and volume flow measurement devices

D-FL 220 Volume flow measuring system D-ISC 100 Operating and display unit

System for ultrasonic (transit time difference) measuring Universal operating and display unit in stainless steel field
of flow rate and volume flow, especially for wet and housing for the new generation sensors, e.g. D-FL 100,
aggressive smoke emissions in waste incineration D-FL 220, D-R 220, D-R 290 or D-R 320.
applications.

System components
Two measuring heads, two purge flanges, two mounting
flanges, purge air unit, terminal box for power supply.

Highlights and benefits Highlights and benefits

◾ In-situ measuring principle ◾ Easy set-up and automatic detection of up to eight


◾ Measurement possible below dew point and for high connected sensors
dust concentrations ◾ Uniform parameterization of various sensors
◾ Continuous measurement of volume flow and gas ◾ Large LC Display for measured value display
velocity ◾ Comfortable operation and handling via keyboard
◾ Automatic zero point and reference point control ◾ USB interface for local device operation
◾ Remote access possible, digital interface ◾ Modular design, expansion slots and slot for external
◾ Measured value display by means of the D-ISC 100 converter available
universal operating and display unit ◾ Easy update via SD memory card
◾ Very low maintenance ◾ Remote support via intranet/internet
◾ Power supply 24 V DC/2 A for one directly connected
sensor
Technical data (selected)
Measurement Gas volume flow, gas velocity,
temperature
Measuring principle Acoustic propagation delay Technical data (selected)
Typical measuring ranges 0 ... 3 000 000 m3/h Application Operating and display unit
for CEM 0 ... 40 m/s Output 0/4 ... 20 mA; 3 x relay
0 ... 400 °C Digital input 1
Flue gas temperature 0 ... 300 °C; opt. higher Service interface USB; TCP/IP
Flue gas pressure -50 ... +20 hPa; opt. higher Ambient temperature -20 ... +50 °C; opt. -40 ... +60 °C
Ambient temperature -20 ... +50 °C Housing Stainless steel
Measuring head: -40 ... +70 °C Protection class IP65
Duct diameter 0.5 ... 13 m, temp. dependent Options 4 slots for expansion modules:
Protection class IP65 Modbus RTU, analog outputs,
Output 0/4 ... 20 mA; 2 x relay; analog inputs, digital inputs
Modbus RTU Interface converter, e.g. for
Purge air supply Appr. 80 m3/h, IP55 PROFIBUS DP
Conformities See table (Appendix 1)

14 Siemens Product Portfolio for Continuous Emission Monitoring


© Siemens AG 2016

Components for system integration

Sample probe Sample conditioning system

A CEM system usually consists of an extractive measuring With all analysis applications it is important to present the
device and uses a sample probe for extracting samples of gas to the analyzers in a clean (free from particulate and
flue gas. However, for some measuring components there moisture) and temperature controlled condition to ensure
are also in-situ analysis solutions available. Depending on accurate and trouble free operation. For this reason a fully-
process conditions, gas matrix (measuring ranges, and configured sample conditioning system is provided along
interferants, e. g. water, aerosols content) cold- or hot- with heated sample probe and transport lines to ensure
extractive sampling methods are used. preservation of sample gas quality.

For hot-extractive sampling a typical stack-gas sample Analyzer shelters


probe is supplied with a one meter stainless steel insertion
probe and a heated ceramic filter element with two micron As part of our system integration services, we can provide
pore size. For optimum performance, the filter is thermo- a CEM packaged as a basic rack system for mounting in a
statically regulated to at least 180 °C. Optionally ATEX typical switch or control room. Frequently, such systems
rated probes, suitable for safe-area operation, are avail- need to be mounted closer to the discharge point, in the
able. The probe and filter are typically mounted on a field or at the base of a stack. Our capability extends to
DN 65/PN 6 flange and all gas-wetted components are providing "simple" weather-proof GRP enclosure through
manufactured from stainless steel. The whole assembly is to customized steel shelters with a full range of ancillary
designed for operation in harsh and rugged environments components to ensure ease of operation and technicial
and can be supplied with an optional weatherproof cover. convenience.

Electrical heating is particularly secure and robust with no


external elements or wiring. The complete filter unit is
brought up to operating temperature in a controlled fash-
ion to prevent premature burn-out of the heater elements
and is automatically controlled. An alarm is available to
signify an over/under temperature alarm condition.
Ceramic cartridge filters in a wide range of pore sizing are
available to suit various applications. The probe assembly
is also provided with a test gas port, enabling the whole
sample transport system to be challenged for integrity and
response time as required.

Heated sample lines

For the sample transport line, typically a 20 m thermostati-


cally controlled, trace heated and insulated line, running at
180 °C is included. The sample line is generally 4/6 mm
diameter PTFE with stainless steel braiding and is available
up to a maximum length of 54 m. Outer sheath is typically
of 43 mm diameter, waterproof and flame retardant Poly-
amide with CFC-free thermo-fleece insulation layer. Ther-
mostatic control with Pt100 or K-type temperature sensor
ensures optimum control and stability. Line consumption
is approximately 100 - 120 W/m. The sample line should be
routed so as to provide a consistent downward slope from
the probe to the analyzer shelter avoiding any hollows in
which condensed water vapor can collect.

Siemens Product Portfolio for Continuous Emission Monitoring 15


© Siemens AG 2016

Emission data management systems

For emission data management, Siemens may provide Modular system


both, dedicated regional as well as international solu- The system is modular and relies on proven standard com-
tions. Please contact your local Siemens Process ponents. The data acquisition is done via the industry stan-
Analytics sales organization for appropriate solution. dard PROFIBUS.

Dedicated regional Siemens solutions Significant new features of version 6.0


◾ Expandable multilingualism
Examples for dedicated Siemens solutions available in ◾ Freely adjustable actual value and compression cycles
some regions are CEM System Manager (CSM), EMIDATE ◾ Easy access to stored data (graphs and tables)
Software, or US Data Acquisition System (DAS) also for ◾ Data of various emission servers can be visualized in
CEM applications. one picture
◾ Acknowledgment for messages including alerting (digi-
CEM System Manager (CSM, Siemens UK) tal output, PC)
On power generation plants, typically three separate con-
trol systems exist: Data Acquisition System (DAS) solutions (Siemens USA)
◾ Process control system for control and monitoring of all The DAS solution from Siemens USA is suitable for 40 CFR
the plant items 60, 63 and 75 and includes: one PC, local rack mount and
◾ Emissions monitoring system (gas analyzers) to provide industrial type EMC station manager software for commu-
the necessary continuous measurement of the compo- nications with a Siemens S7 1200 PLC.
nents of the exhaust gases
◾ Data acquisition and operating system to record the DURAG emission data management solutions
data from the emissions monitoring analyzers and gen-
erate the necessary reports to comply relevant emis- Family of modular data acquisition and handling systems
sions directive (DAHS) for management of environmental and process
data according to European & US-EPA regulations:
Three in one, MCERTS approved ◾ D-EMS 2000
Until now, these systems have often been supplied by dif- – TÜV certified according to EN 15267
ferent manufacturer with limited interfacing possibilities. – MCERTS certified
This is why Siemens UK developed CEM System Manager ◾ D-EMS 2000 CS
(CSM) which is a MCERTS approved emissions reporting – Price effective compact system for small and middle
package and is an integral part of our PCS7 distributed sized plants
control system. It brings together three separate systems – TÜV certified according to EN 15267
into one, enabling you not only to comply with the envi- ◾ D-DAS 2010
ronmental regulations but also to improve the operational – Cost effective system
efficiency of your plant. – MCERTS certified
◾ D-DAS 2000
EMIDATE Software (Siemens Austria) – Cost effective system
The software solution EMIDATE from Siemens Austria col- – Excellent cost/performance ratio
lects, monitors, evaluates and stores all emission related ◾ UTAS Dr. Lasinger
values and plant states. This allows the monitoring of pol- – Cost effective system for the Austrian Market
lutants to permissible limits. The results are graphically – ÖNORM M9412-2 certified by TÜV Austria
visualized and stored.

TÜV-certified
The current version 6.0 was certified by TÜV Austria based
on:
◾ ÖNORM M9412-1:2008 (System 3)
◾ ÖNORM M9412-2:2008
◾ ONR 19412-1:2012

16 Siemens Product Portfolio for Continuous Emission Monitoring


© Siemens AG 2016

D-EMS 2000
Data acquisition, evaluation and reporting according to: Highlights and benefits
◾ European Industrial Emissions Directive (IED)
◾ Windows based DAHS with modern designed software
2010/75/EU
running on a standard PC
◾ US EPA 40 CFR Part 60,63 & 75
◾ User friendly, menu-driven software available in 19
◾ GHG Emission Monitoring (European-, UNFCCC- Guide-
languages
lines, etc.)
◾ Data communication unit with internal data storage
◾ Country-specific requirements
system for up to 96 days for high data availability
◾ Handling of up to 320 analog/640 binary in- and out-
Management for
puts, resolution one second
◾ Emission data
◾ Interfaces for hardwired 0(4) to 20 mA and/or bus
◾ Water data
communications TCP/ IP, OPC UA, Modbus RTU/TCP,
◾ Greenhouse gas (GHG) data
PROFIBUS, Elan etc.
◾ Ambient air data
◾ Encrypted database on two Hard Disk Drive/Solid State
◾ Meteorological data
Drive as Raid-1-Array
◾ Process data etc.
◾ Menu leaded screens for representation of current,
prognostic and historic measured data in bar graph/
Approvals
chart form
◾ Suitability-tested by TÜV in accordance with German
◾ Free configurable screen masks, time diagrams and
TA Luft, 1st, 2nd, 13th, 17th, 27th, 30th and
reports on customer request
31st BImSchV as well as the European Directives
◾ Automatic alarm and information system with com-
2010/75/EU, 2000/76/EC and 2001/80/EC considering
ment functionality
EN 14181
◾ Communication with customer data network incl.
◾ QAL 1 approved according to EN 15267
interface to MS-Excel
◾ MCERTS certified
◾ Automatic data transfer to authority via standard
remote communication if required
◾ Providing of relevant data in the internet/intranet for
person in charge, authority or public
◾ Remote Service Interface for cost effective service and
support

4-20 mA,
Ring memory Modbus,
6 years int, day PROFIBUS,
+ protocols OPC, ELAN Ring memory
> 32 days
30 days 1 min + 1 s
1 ... 8

Ring memory
> 32 days

4-20 mA, D-EMS 4-20 mA, D-MS D-EMS 2000 D-EMS 2000 D-EMS 2000
Modbus, 2000 CS Modbus, 500 KE Client Client Client
PROFIBUS, PROFIBUS,
OPC, ELAN OPC, ELAN

TCP/IP TCP/IP

Authority Internet Ring memory


> 5 years
Individual values
Protocols
System
Raid 1

Backup on Radio
HD/SSD clock
System Workstation D-EMS 2000

Siemens Product Portfolio for Continuous Emission Monitoring 17


© Siemens AG 2016

Emission data management systems

D-EMS 2000 CS
Price effective compact system for data acquisition and Technical data (selected)
handling for small and middle sized plants Computer Intel based Dual core PC with
windows 7 & 8, 2 GB RAM and
Options 120 GB SDD
Three device types are available: Input/ouput Up to three cards
◾ 19" 3HU rack with monitor/keyboard/mouse Combined card:
4 AI/8 DI/2 AO/4 DO
◾ 19" 1HU unit with slide-in keyboard and retractable
Input card: 8 AI/15 DI
monitor
Output card(s): 8 AO and 16 DO
◾ Desktop version with monitor/keyboard/mouse
Bus system connection Modbus RTU, PROFIBUS,
Elan OPC UA
Applications
Analog-/digital input: 12/24
Emissions evaluation computer for small to medium-sized
Analog-/digital output: 12/24
installations in all types of plants and industries Interfaces 1 x VGA, 2 x USB, 1 x RJ 45
3 x serial (RS 232 or RS 485)
BNC for DCF77-radio clock
Highlights and benefits
Ambient temperature 5 ... 40 °C
◾ Compact system, no additional evaluation PC required Protection class IP20
◾ Modern flash memory technology instead of hard Operating voltage 115/230 V AC/50/60 Hz/100 VA
disks
◾ Independently operating module for acquisition, long-
term storage, calculation and visualization of environ-
mental and process data
◾ Instrument for monitoring officially prescribed limit
values with automatic logging
◾ Continuous monitoring of one to twelve components
connected via bus communication or hard wired
◾ Windows based and certified D-EMS 2000 software
◾ All modules from the D-EMS 2000 system are usable
◾ Excellent cost/performance ratio

D-EMS 2000 D-EMS 2000 D-EMS 2000


Client Client Client

4-20 mA, Modbus, PROFIBUS, OPC, ELAN TCP/IP

Authority Internet Ring memory


6 years int, day
+ protocols
30 days 1 min + 1 s

Backup on Radio
HD/SSD clock

18 Siemens Product Portfolio for Continuous Emission Monitoring


© Siemens AG 2016

Extended scope of supply After sales support

Documentation We realize that the purpose of an emissions monitoring


system is to enable our customers to comply with the law.
The system will be supplied with individual component Therefore the focus of our after-sales offer is on risk miti-
operating and maintenance manuals along with project gation. Every aspect of our support and training portfolio
specific documentation comprising: is intended to minimize the risk of downtime and to ensure
◾ System schematic that any problem is rectified as quickly as possible. Given
◾ System piping diagrams the stringent limits (and penalties for non-compliance)
◾ System operating & maintenance manual applied by the environment agencies to permissible down-
◾ Individual analyzer manuals time of a CEMS, we think it is critical that the supplier of
◾ Maintenance schedule the CEMS should play their part in making sure that these
◾ Factory test & calibration certificates limits are not reached.

Commissioning and start-up Examples for risk mitigations are:

Should your project be a new-build or upgrade, we can Helpdesk (technical and telephone support)
provide installation services as part of our project managed Rapid access to trained staff in the event of a problem
delivery. A typical scope would include site survey, prepa-
ration of installation drawings, materials supply and man- Field service
agement services. Alternatively, our assigned project team Response to site in the event that a site visit is needed to
can coordinate with your nominated contractor to ensure solve the problem
a seamless process. Installation services will be subject to a
separate offer. Spares and repairs
We compile our spares lists to include items that genu-
Not included, but available at our standard service rates, inely reduce the risk of downtime, because they can be
we offer the services of project trained commissioning changed on site and avoid the need for sending equipment
engineer to assist with start-up and first-level operator off site for repair
training.
Planned maintenance
Reducing the risk of unscheduled downtime

Service level agreements


Bringing the above elements together into a contract that
defines the expectations of both parties

Training
Enabling your operational staff to be the first line of diag-
nosis and repair

Siemens Product Portfolio for Continuous Emission Monitoring 19


© Siemens AG 2016

Emission Control Guidelines driven by UNFCCC


European "air quality" directives and standards

EC
Council
US
EPA
Chinese
Guidelines

UNFCCC

Effective monitoring, reporting and verification of green- Directives for stationary source emissions
house gas (GHG) emissions is critical for tracking progress
towards the achievement of emission reduction targets. Industrial Emissions Directive (IED) 2010/75/EU
The ultimate goal of the UN Framework Convention on Cli-
mate Change (UNFCCC) is to stabilize atmospheric concen- The IED (Industrial Emissions Directive of November 24,
trations of GHGs at a level which prevents dangerous 2010 on the integrated pollution prevention and control)
human interference with the climate system. is the integrated approach to avoid or minimize polluting
All parties and member states to the UNFCCC, its Kyoto emissions in the atmosphere, water and soil, as well as
Protocol and Paris Agreement are required to report annu- waste from industrial and agricultural installations, with
ally on their GHG emissions. Therefore emission control the aim of achieving a high level of environmental and
guidelines and Quality Assurance (QA) and Quality Control health protection.
(QC) Systems have been developed and implemented in
different parts of the world to ensure these targets. The IED came into force on January 6, 2011 and is now
transposed into national law of EU member states. The
European "air quality" directives and standards long IED recasts seven former, separate existing directives
related to industrial emissions as annexes of the IED, see
European policy concerning the protection of the environ- table below.
ment has steadily grown in importance. In particular, the
Treaty of Amsterdam (1997) has made a high-level of envi- This provides a single, central document for industry. The
ronmental protection including air quality one of the top former directives are now replaced by the IED.
priorities. The European Community has aimed to develop
an overall strategy and adopted new directives which refer
to issues of ambient air quality as well as to stationary
source emissions or automotive fuel quality and even to
pollutant emission from ships.
Previous legislation Actual recast Effective
Integrated Pollution Prevention & Control 2008/1/EC Industrial Emissions Directive (IED) 2010/75/EU Jan 7, 2014
Large Combustion Plant Directive (LCPD) 2001/80/EC Industrial Emissions Directive (IED) … Annex V Jan 1, 2016
Waste Incineration Directive (WID) 2000/76/EC Industrial Emissions Directive (IED) … Annex VI Jan 7, 2014
Solvents Directive 1999/13/EC Industrial Emissions Directive (IED) … Annex VII Jan 7, 2014
3 Titanium Dioxide Directives 78/176/EEC, 82/883/EEC, Industrial Emissions Directive (IED) … Annex VIII Jan 7, 2014
92/112/EEC

20 Emission Control Guidelines driven by UNFCCC


© Siemens AG 2016

About 52 000 industrial and agricultural plants with a high Directive 2008/1/EC, IPPC - Directive concerning
pollution potential are affected by the new directive. Main Integrated Pollution Prevention and Control (Recast as
focus is on reduction and monitoring of emissions of SO2, IED 2010/75/EU)
NOx and dust by consequent use of best available tech-
nique (BAT). The IPPC is a framework directive and applies an inte-
grated environmental approach to the regulation of cer-
Industrial installations must use BAT to achieve a high gen- tain industrial activities as a whole. It applies to about
eral level of protection of the environment as a whole, 45 000 industrial installations in the EU, ranging from
which are developed on a scale that allows implementa- refineries, metal, mineral and chemical industries to brew-
tion in the relevant industrial sector, under economically eries and from intensive pig farms to cement works. It
and technically viable conditions. The European Commis- requires each installation to have a operating permit con-
sion must adopt BAT conclusions containing the emission taining emission limit values and other conditions based
levels associated with the BAT. These conclusions shall on the application of best available techniques (BAT).
serve as a reference for the drawing up of permit
conditions. Interaction between IPPC and LCPD: Any stricter require-
ments under IPPC overrule other minimum requirements.
BAT documents are used as basis for the approval pro-
cedure. These requirements shall ensure that plant opera- Directive 2000/76/EC Waste Incineration Directive, WID
tors apply BAT consistently and thus comparable competi- (Recast as Annex VI of IED 2010/75/EU)
tion conditions are generated in the industry.
The aim of the directive is to prevent or limit, as far as
The emission limit values were significantly reduced by practicable, negative effects on the environment of the
IED, in particular for large combustion plants and are struc- incineration and co-incineration of waste, in particular pol-
tured according to the kind of fuel as follows: lution by emissions into air, soil, surface and groundwater
◾ Combustion plants using solid fuels and the resulting risks to human health. The WID covers
◾ Combustion plants using liquid fuels the incineration of hazardous waste and non-hazardous
◾ Combustion plants using gaseous fuels waste but excludes exemptions for vegetable waste, radio-
◾ Gas turbines and gas engines active waste and animal carcasses.

The WID applies not only to facilities intended for waste


incineration ("dedicated incineration plants") but also to
"co-incineration" plants: facilities whose main purpose is to
produce energy or material products and which use waste
as a regular or additional fuel, this waste being thermally
treated for the purpose of disposal. The directive does not
cover experimental plants for improving the incineration
process and which treat less than 50 t of waste per year.

Emission Control Guidelines driven by UNFCCC 21


© Siemens AG 2016

European "air quality" directives and standards

Emission limit values [mg/Nm3] for waste incineration plants, standardized at 11 % O2, mineral waste oil at 3 % O2
European directive IED 2010/75/EU German legislation: 17th BImSchV
Specials/ Limit values, Limit values, Limit values, Limit values,
Limit values, Limit values,
Thermal input ½ h average, ½ h average, ½ h average, annual
daily average daily average
(100 %)1) (97 %)1) (100 %)1) average
10 30 10 5 20
Dust
< 50 MW 10 20
TOC 10 20 10 10 20
HCl 10 60 10 10 60
HF 1 4 2 1 4
SO2 incl. SO3 50 200 50 50 200
150 400 100
NO2 incl. NO > 6 t/d 200 400 200
< 50 MW 200 400
Hg 0.033) 0.053) 0.013)
150 (95 % at
CO 50 (97 %)2) 1002) 50 100
10 min)2)
NH3 If SCR or SNCR is used 10 15
1)
Either all validated ½ h averages do not exceed the 100 % limit values or 97 % of the validated ½ h averages do not exceed 97 % limit values.
2)
For CO:
a) 97 % of all daily averages do not exceed daily average limit value.
b) Either all validated ½ h averages do not exceed the 100 % limit values or 95 % of the 10-minutes values do not exceed 10-minutes limit value.
3)
Continuous mercury measurement may be set to non-mandatory, if measuring values reliably will be below 20 % of limit values.

Emission limit values according to WID for co-incineration

In case of co-incineration of waste of up to 40 % (IED


guideline) or 25 % (17th BImSchV, Germany) of heat
release the following formula (mixing rule) is to be applied
whenever a specific total emission limit value C has not
been defined.
If the heat release from the waste incineration is above
40 % (IED 2010/75/EU) or 25 % (17th BImSchV, Germany),
co-incineration plant shall be treated as a normal waste
incineration. If the heat release from the waste incinera-
tion is less than 10 % of the total heat release, it will be set
to 10 %.

C: Total emission limit value


Vwaste: Exhaust gas volume resulting from the incineration
of waste only
Cwaste: Emission limit values set for incineration plants
Vproc: Exhaust gas volume resulting from the plant process
Cproc: Emission limit values as laid down for certain
industrial sectors, e. g. large combustion plants

22 Emission Control Guidelines driven by UNFCCC


© Siemens AG 2016

Combustion plants
Emission limit values Cprocess [mg/Nm3] for combustion plants co-incinerating waste, new plants
European Directive IED German legislation:
Thermal input 2010/75/EU 17th BImSchV
General fuel type Fuel
[MW] Limit value, Limit value,
daily avarage daily average
< 50 50
Solid fuel with the exception of
50 ... 300 20
biomass (O2 content = 6 %)
> 300 10 (peat: 20)
< 50 50
Dust Biomass (O2 content = 6 %) 50 ... 300 20 10
> 300 20
< 50 50
Liquid fuels (O2 content = 3 %) 50 ... 300 20
> 300 10
Black coal 1300
< 50 Lignite Not included 1000
Fluidized bed 350
Black coal, lignite 400
Solid fuel with the exception of 50 ... 100 400 (peat: 300)
Fluidized bed 350
biomass (O2 content = 6 %) Peat 300
100 ... 300 Fluidized bed 250 200
200
SO2 Fluidized bed 200 200
> 300
150 150
Natural wood 200
< 50 Not included
350
Biomass (O2 content = 6 %)
50 ... 300 200 200
> 300 150 150
< 50 Not included 850
50 ... 100 350 350
Liquid fuels (O2 content = 3 %)
100 ... 300 200 200
> 300 150 150
< 10 500
Not included 400
10 … 50
Fluidized bed 300
Solid fuel with the exception of 300
50 ... 100 300
biomass (O2 content = 6 %) Peat 250
100 ... 300 200 200
Lignite 200 200
> 300
150 150
400
< 50 Not included
NO2 Natural wood 250
Biomass (O2 content = 6 %) 50 ... 100 250 250
100 ... 300 200 200
> 300 150 150
350
< 50 Not included
Light heating oil 250
300
Liquid fuels (O2 content = 3 %) 50 ... 100 300
Light heating oil 200
100 ... 300 150 150
> 300 100 100
< 50 150
Solid fuel with the exception of
50 … 100 150
biomass (O2 content = 6 %)
CO > 100 200
Biomass (O2 content = 6 %) 250
Liquid fuels (O2 content = 3 %) 80
TOC 10
20
HCl
Fluidized bed 100
HF 1
Hg 0.03

Emission Control Guidelines driven by UNFCCC 23


© Siemens AG 2016

European "air quality" directives and standards

Emission limit values [mg/Nm3] for cement and lime plants, new plants
European Directive IED German legislation:
Specials 2010/75/EU 17th BImSchV
Daily average Daily average
Dust 30 10
TOC 10 10
HCl 10 10
HF 1 1
SO2 50 50
Cement plants 200
NO2 500
Lime plants 350
Hg 0.03 0.03
NH3 If SCR or SNCR is used 30
CO To be defined locally To be defined locally
Emission limit values [mg/Nm3], daily averages, for human crematories
German legislation:
European Directive IED
27th BImSchV
2010/75/EU
Daily average
Dust 10
TOC To be defined locally 20
CO 50

24 Emission Control Guidelines driven by UNFCCC


© Siemens AG 2016

Directive 2001/80/EC, LCPD - Directive on the limitation and other industrial processes running on solid, liquid or
of emissions of certain pollutants into the air from gaseous fuel. The LCPD covers all combustion installations
Large Combustion Plants (Recast as Annex V of with a rated thermal output exceeding 50 MW irrespective
IED 2010/75/EU) the type of fuel used with the exception of waste.

The LCPD aims to reduce acidification, ground level ozone The directive shall apply only to combustion plants
and particles throughout Europe by controlling emissions designed for production of energy with the exception of
of sulfur dioxide (SO2), nitrogen oxides (NOx) and dust those which make direct use of the products of combus-
(particulate matter PM) from large combustion plants tion in manufacturing processes. The directive entered into
(LCPs) in power stations, petroleum refineries, steelworks force on November 27, 2001.

Emission limit values [mg/Nm3], daily averages, for combustion plants using solid fuels with the exception of gas turbines and gas
engines, standardized at 6 % O2, new plants
German legislation:
European Directive IED
Thermal input and fuel 13th BImSchV
2010/75/EU, Limit values
Limit values
In general 400
400
Fluidized bed 350
50 ... 100 MW
Biomass 200 200
Peat 300 400
In general 200 200
Biomass 200 200
SO2 100 ... 300 MW
Indigenous fuel 200 300
Peat 300 200
In general 150 150
Fluidized bed 200 200
> 300 MW
Bio fuels 250
Indigenous fuel 150 400
In general 300 300
50 ... 100 MW Lignite 400 400
Biomass, peat 250 250
NO2 In general 200 200
100 ... 300 MW
Biomass, peat 200 200
In general 150 150
> 300 MW
Lignite 200 200
50 … 100 MW In general 150
CO
> 100 MW In general 200
TOC > 50 MW Bio fuels 10
Hg > 50 MW In general 0.03
50 ... 100 MW In general 20
100 ... 300 MW In general 20
Dust 10
In general 10
> 300 MW
Biomass, peat 20
50 ... 100 MW In general 20
Dust 100 ... 300 MW In general 20 10
> 300 MW In general 10

Emission Control Guidelines driven by UNFCCC 25


© Siemens AG 2016

European "air quality" directives and standards

Emission limit values [mg/Nm3], daily averages, for combustion plants using liquid fuels with the exception of gas turbines and
gas engines, standardized at 3 % O2, new plants
European Directive IED German legislation:
Thermal input and fuel 2010/75/EU 13th BImSchV
Limit values Limit values
50 ... 100 MW 350 350
SO2 100 ... 300 MW 200 200
> 300 MW 150 150
50 ... 100 MW In general 300
50 ... 100 MW Heating oil, T > 483.15 K or p > 1.8 Mpa 250
50 ... 100 MW Heating oil, T = 383.75 ... 483.15 K or 300
200
NO2 p = 0.05 ... 1.8 Mpa
50 ... 100 MW Heating oil, T < 383.75 K or p < 0.05 Mpa 180
100 ... 300 MW In general 150 150
> 300 MW In general 100 100
CO > 50 MW In general 80
50 ... 100 MW In general 20
Dust 100 ... 300 MW In general 20 10
> 300 MW In general 10
Emission limit values [mg/Nm3], daily averages, for combustion plants using gaseous fuels with the exception of gas turbines and
gas engines, standardized at 3 % O2, new plants
European Directive IED German legislation:
Thermal input and fuel 2010/75/EU 13th BImSchV
Limit values Limit values
In general 35 35
Liquified gas 5 5
SO2 > 50 MW
Coke oven gas 400 350
Blast furnace gas 200 200
In general 200
50 ... 100 MW 100
Natural gas 100
NO2 In general 100
100 ... 300 MW 100
Natural gas 200
> 300 MW In general 100 300
In general 80
CO > 50 MW Coke oven gas, blast furnace gas 100
Natural gas 100 50
In general 5 5
Dust > 50 MW Blast furnace gas 10 10
Steel industry gas 30
Emission limit values [mg/Nm3], daily averages, for combustion plants of gas turbines and gas engines, standardized at 15 % O2,
new plants (In Germany: gas engines standardized at 5 % O2)
European Directive IED German legislation:
Thermal input and fuel 2010/75/EU 13th BImSchV
Limit values Limit values
< 50 MW Single GT 120
< 70 % load 50 50
NO2
> 50 MW Single GT, η > 35 % 50 50 ... 75
Gas engines @ 5 % O2 75 200
In general 100 100
CO > 50 MW
Gas engines @ 5 % O2 100 250
Liquified gas 5
Coke oven gas 350
Dust > 50 MW
Blast furnace gas 200
In general gaseous fuel 35

26 Emission Control Guidelines driven by UNFCCC


© Siemens AG 2016

EN 14181 Quality Assurance for EN 14181 defines which characteristics automatic measur-
Automated Measuring Systems (AMS) = ing equipment must possess, and how they must be cali-
Continuous Emission Monitoring Systems (CEMS) brated and maintained. In addition to the calibration func-
tion, the measuring uncertainty - which plays a decisive
The above stated European directives including the new role in the validation of the measured values obtained dur-
IED stipulate that sampling and analyzing of pollutants ing continuous monitoring - is also determined from the
must be carried out in accordance with CEN standards. The data of the calibration experiment. In addition, the require-
relevant standard is EN 14181 which has been compiled by ments for the uncertainty of the measured values obtained
the technical committee CEN/TC 264 (air quality). It is a with the measuring equipment, which are defined in the
European standard related to the quality assurance of EU directives relating to fossil power plants, waste inciner-
automated monitoring systems (AMS) = continuous emis- ation plants and waste co-incineration plants, are checked
sion monitoring systems (CEMS) used for measuring emis- using a method described in the standard.
sions from sites operating under the IED. It was approved
by CEN on November 3, 2003 and officially released in July The validated average value is defined as the value calcu-
2004. A revised version was released in 2015. lated from the standardized and referenced average value
by subtracting the standard deviation (standard uncer-
tainty) at the daily limit value of the standardized values
determined by calibration in accordance with EN 14181.

EN 14181 is divided into four main sections and defines


three Quality Assurance Levels (QAL) and one Annual Sur-
veillance Test (AST):

QAL 1: Requirements for use of automatic measuring


equipment that has had its suitability tested according to
EN 15267 and EN ISO 14956

QAL 2: Requirements for installation of automatic measur-


ing equipment (AMS/CEMS), calibration of AMS/CEMS
using the standard reference measuring method (SRM),
determination of measuring uncertainty/variability of AMS/
CEMS and check for observance of preset measuring
uncertainties

QAL 3: Continuous quality assurance by the operator (drift


and precision of the AMS/CEMS, verification on control
card)

AST: Annual surveillance test including SRM measure-


ments to check the uncertainty of the AMS values

Main objective Responsible


Suitability test of equipment before
QAL 1 Instrument supplier
purchase (certification)
Correct installation and calibration
QAL 2
of AMS
Ongoing quality assurance during
QAL 3 Instrument end user
plant operation
Anual check of measuring uncer-
AST
tainty (calibration)

Emission Control Guidelines driven by UNFCCC 27


© Siemens AG 2016

European "air quality" directives and standards

EN 15267 The second part then specifies the requirements for test-
Certification of Automated Measuring Systems (AMS) = ing. Any test laboratory wishing to evaluate AMS must
Continuous Emission Monitoring Systems (CEMS) become accredited to ISO 17025 and must use EN 15267-3
as well as reference-method standards during the labora-
Since 2008 the EN 15267 is the actual guideline to certify tory and field tests. The field tests themselves must comply
AMS/CEMS in Europe. It is a harmonization and re-working with the major requirements of EN 14181.
of the former "type testing" procedures in Germany and
the UK. CEN developed EN 15267 because there has been After successfully carrying out the extensive laboratory
a growing need for a unified set of standards for testing and at least three months field tests, the accredited test
and certifying AMS/CEMS to support the requirements of laboratory has to present the test report for evaluation and
EC directives and the quality assurance standard technical examination:
EN 14181. a) in Germany: to the LAI committee
b) in UK: to SIRA
The EN 15267 is divided into three parts: With positive assessment, the certificate is issued by the
German or UK EPA for a period of five years. It will be pub-
Part 1: General principles lished:
EN 15267-1 describes the principles of the certification a) in Germany: in the German Federal Gazette and then on
procedure and the roles and responsibilities of the the website www.qal1.de
involved institutions (manufacturer, testing institute, certi- b) in UK: on the website of SIRA/MCERTS
fication body, competent authority)
Validity of EN 15267-3 based QAL 1 approvals for man-
Part 2: Manufacturers QM system ufacturer is in principle 5 years. It can be enhanced after
EN 15267-2 refers to initial and yearly repeated assess- yearly EN 15267-2 assessment.
ment of the manufacturer’s quality system for design and
manufacturing. During the annual audits, any changes to During the annual audits, inevitably necessary changes of
the hardware and/or software of the measuring systems the hardware and/or software of the AMS/CEMS compared
are reviewed and confirmed by further research, if to the versions tested during QAL 1 procedure are
necessary. The manufacturer has to record all performed reviewed and confirmed by further research, if necessary.
modifications in a technical logbook. The manufacturer has to record all performed modifica-
tions in a technical logbook. The modifications are classi-
Part 3: Performance criteria and test procedures fied into the following categories:
EN 15267-3 defines the performance criteria and test pro- ◾ Type 0: No measurable influence on the measuring
cedures for QAL 1 of AMS/CEMS that measure gaseous system
emissions, dust and flow rates from stationary sources. ◾ Type 1: No significant influence
It consists of two main parts: The first part specifies the ◾ Type 2: Significant influence. A partial or complete
performance specifications which complete AMS/CEMS (for review by the test institute and at least a supplement to
extractive CEMS consisting of defined and tested sample QAL 1 approval may be necessary
probe, sample line, sampling unit, analyzer, etc.) must
achieve during the laboratory tests and field tests.

28 Emission Control Guidelines driven by UNFCCC


© Siemens AG 2016

Emission monitoring guidelines in the USA

The Clean Air Act (CAA) and EPA 40 CFR 75


This chapter establishes basic requirements for the moni-
The Clean Air Act is the comprehensive federal law that toring, recordkeeping, and reporting of sulfur dioxide
regulates air emissions from stationary and mobile sources (SO2), nitrogen oxides (NOX), and carbon dioxide (CO2)
and authorizes EPA (Environmental Protection Agency) to emissions, volumetric flow, and opacity data from affected
protect public health and public welfare and to regulate units.
emissions of hazardous air pollutants.
The regulations include general requirements for the
In this context, EPA set National Ambient Air Quality installation, certification, operation, and maintenance of
Standards (NAAQS) for six principal pollutants considered continuous emission or opacity monitoring systems. Speci-
harmful to public health and the environment. fications for the installation and performance of continu-
ous emission monitoring systems, certification tests and
These standards are listed in Title 40 CFR Part 50: procedures, and quality assurance tests and procedures
Sulfur oxides § 50.4/5 are included in appendices A and B to this part. Criteria for
PM § 50.6/7 alternative monitoring systems and provisions to account
Carbon monoxide § 50.8 for missing data from certified continuous emission moni-
toring systems or approved alternative monitoring systems
Ozone § 50.9/10
are also included in the regulation.
Nitrogen oxides § 50.11
Lead § 50.12
40 CFR 60 (NSPS)
This chapter establishes New Source Performance Stan-
The Clean Air Act also gives EPA the authority to limit
dards (NSPS). NSPS are federal standards promulgated for
emissions of air pollutants coming from sources like
major and minor emission sources. NSPS are emission
chemical plants, utilities, and steel mills. Individual states
standards that are progressively tightened over time to
may have stronger air pollution laws, but they may not
achieve a steady rate of air quality improvement without
have weaker pollution limits than those set by EPA.
unreasonable economic disruption. NSPS imposes uniform
requirements on new and modified sources through the
Code of Federal Regulations (CFR)
nation. These standards are based on the best demon-
strated technology (BDT). BDT refers to the best system of
The CFR is the codification of the general and permanent
continuous emissions reduction that has been demon-
rules published in the Federal Register by the executive
strated to work in a given industry.
departments and agencies of the Federal Government. CFR
is divided into 50 titles, which represent areas subject to
40 CFR 60 is broken down into sections and subparts cov-
federal regulation.
ering performance standards for specific industry station-
ary source requirements for monitoring, reporting, and
Title 40 CFR
testing. Over time there have been added several appendi-
Title 40 CFR arranges mainly environmental regulations
ces and performance specifications (reference test meth-
that were promulgated by the US Environmental
ods) associated with 40 CFR 60.
Protection Agency (EPA), based on the provisions of United
States laws.
Typical industries and the respective subparts for emis-
sions compliance (Standards of Performances) are:
Chapter one (related to EPA) of title 40 is divided into sev-
eral subchapters (A-J , N, O, Q, R, U) with each subchapter Subpart E Incinerators
then divided into parts. Subchapter C covers "Air Programs" Subpart F Portland cement plants
in parts: Parts 75, 63, 60 and 50 (et al.) refer to emission Subpart J Petroleum refineries
monitoring aspects. Some of them are described in the Subpart GG Stationary gas turbines
following. Subpart AA Steel plants: Electric arc furnaces
Subpart Aaa Steel plants; Electric arc furnaces and
argon-oxygen decarburization

Emission Control Guidelines driven by UNFCCC 29


© Siemens AG 2016

Emission monitoring guidelines in the USA

40 CFR 63 (NESHAPS) Similar to the European QAL 2 and QAL 3 are the following
This chapter establishes National Emission Standards for EPA 40CFR60 QA/QC performance specifications:
Hazardous Air Pollutants (NESHAPS). NESHAPS are emis- ◾ 40 CFR 60, Appendix A, Test Method 1 through 29
sions standards set by the United States EPA for an air pol- ◾ 40 CFR 60, Appendix B, Performance Specifications 1
lutant not covered by NAAQS that may cause an increase through 9
in fatalities or in serious, irreversible, or incapacitating ◾ 40 CFR 60, Appendix F, CGAs and RATAs (Relative Accu-
illness. racy Testing Audits ) SW-846 Test Methods, 0010
through 0061
NESHAPS are listed in ◾ 40 CFR 266, Appendix IX, Cal Error (CE) and Relative
Subpart LLL Portland cement Accuracy Test Audits (RATA)
Subpart UUU Refinery
Subpart EEE Waste combustors Responsibilities
The owner/operator of the stationary source is responsible
Subpart DDDDD Boilers and process heaters
for submitting a QA/QC plan that fully complies with the
intent of the relevant stationary source performance
specification, monitoring & reporting requirements. The
Quality Assurance and Quality Control (QA/QC) perfor-
state agency reviews and approves or denies the plan.
mance specifications
The CEMS supplier is responsible to the owner operator for
Similar to the European QAL 1 are the QA/QC performance
supplying (engineering & integration) a CEMS. The owner/
specifications in the US, except that most of the methods
operator is responsible for the certification of the CEMS in
and technologies are based on laboratory instrumentation
order to obtain a permit.
and test methods that typically must be adapted to online
process gas analyzers. Within each "stationary source
(type) performance specification (PS)" is a section that
covers the issue of "Emissions Monitoring & Reporting" and
is relevant to the entire CEMS (AMS) installation,
monitoring, maintenance, and data reporting. This section
will reference all related EPA methods and performance
specifications.

Examples are:
Oxygen (O2) EPA Method 3A, PS 3
Carbon dioxide (CO2) EPA Method 3A, PS 3
Sulfur dioxide (SO2) EPA Method 6C, PS 2
Oxides of nitrogen (NOx) EPA Method 7E, PS 2
Carbon monoxide (CO) EPA Method 10, PS 4
Total hydrocarbons (THC) EPA Method 25A, PS 8
HR (Highly Reactive) VOCs PS 9

30 Emission Control Guidelines driven by UNFCCC


© Siemens AG 2016

Emission monitoring guidelines in China

Emission Standard of Air Pollutants for Thermal Power ◾ The standard distinguishes existing and new sources for
Plants (GB 13223-2011) SO2 and NOx emissions; it provides a two-and-a-half year
grace period for existing sources.
This standard was adopted by China’s Ministry of Environ- ◾ Hg emissions will be controlled for the first time, start-
mental Protection (MEP) on July 18, 2011, and has been ing January 1, 2015.
effective since January 1, 2012. The standard stipulates
limitations on concentrations of air pollutants in emissions New sources
from thermal power plants, including soot, SO2, NOx, mer- From January 1, 2012, new thermal power boilers and gas
cury and mercury compounds. The standard does not turbines must be controlled under the limits of soot, sul-
apply to thermal power plants using domestic waste or fur dioxide, nitrogen oxides emissions and blackness of
hazardous waste as fuels. smoke (see table).

Existing sources
Compared to the earlier version, which was established in
From July 1, 2014, existing thermal power boilers and gas
2003, the standard makes the following major improve-
turbines must be controlled under the limits of soot, sulfur
ments:
dioxide, nitrogen oxides emissions and blackness of smoke
◾ The standards for soot, SO2, and NOx have been tight-
(see table).
ened considerably.
Mercury and mercury compounds
Emission limit values in China, basic regions
From January 1, 2015, coal-fired boilers must be con-
Type of plant Limits
and fuel
Pollutant Conditions
[mg/m3]
trolled under the limits of mercury and mercury com-
Soot All 30 pound emissions as shown in the table.
New boiler 100/2001)
SO2 Normal and key regions
Coal fired Existing boilers 200/4001)
boilers NO2 All 100/2002) Thermal power boilers and gas turbines located in key
Hg/Hg regions shall implement special air pollutant emission
All 0.03
compounds limits set forth in the following table. The geographic
Soot All 30 scope of key regions, timeline of the special limits are sub-
New boilers and
gas turbines
100 ject to MEP’s further regulation.
SO2
Existing boilers and
Oil-fired boilers 200 Emision limit values in China, key regions
gas turbines
or gas turbines Type of plant Limits
New oil-fired boilers 100 Pollutant Conditions
Existing oil-fired and fuel [mg/m3]
NO2 200 Soot All 20
boilers
Gas turbines 120 Coal fired SO2 All 50
Natural gas boilers boilers NO2 All 100
5
and gas turbines Hg /Hg compounds All 0.03
Soot
Other gas-fired boilers Soot All 20
10
and gas turbines Oil-fired boilers SO2 All 50
Natural gas boilers or gas turbines Oil-fired boilers 100
35 NO2
and gas turbines
Gas-fired boilers SO2 Gas turbines 120
Other gas-fired boilers
or gas turbines 100 Soot All 5
and gas turbines
Gas-fired boilers SO2 All 35
Natural gas boilers 100
or gas turbines Gas boilers 100
Other gas-fired boilers 200 NO2
NO2 Gas tubines 50
Narural gas turbine 50
Coal-fired, oil-
Other gas-fired gas
120 fired, gas-fired
turbines Smoke degree All 1
Coal-fired, oil- boilers or gas
fired, gas-fired Smoke turbines
All 1
boilers or gas degree
turbines Test procedures for CEMS in China
1)
To be located in Guangxi Zhuang Autonomous Region, Chongqing
Municipality, Sichuan Province and Guizhou Province, where the lim-
its will be implemented with coal-fired boilers. Test procedures for CEMS of flue gas emitted from station-
2)
Implementing limits on W-type thermal power generation boilers or ary sources have to follow Chinese guidelines HJ/T76-2007:
furnace chamber flame boilers, circulating fluidized bed (CFB) boil- Specifications and test procedures for continous emission
ers, and boilers put into operation as of December 31, 2003 or
through the construction project’s environmental impact report’s ap- monitorin systems for SO2, NOx and particulate material
proval of coal-fired power boilers. flue gas emitted from stationary sources.
Emission Control Guidelines driven by UNFCCC 31
© Siemens AG 2016

Emission monitoring guidelines in Hong Kong, India and Malaysia

Emission monitoring guidelines in Hong Kong Emission monitoring guidelines in Malaysia

The emission limits applied for power plants in Hong Kong The Environmental Quality (Clean Air) Regulations 1978
are stipulated in BPM 7/1(2014) issued by Environmental and subsequent revisions specify activities and pollutants
Protection Department, Air Policy Group. that are to be monitored and their limit values. The
activities specified in the regulations and subsequent
A license to be granted for each power plant under the Air revisions are (see also table on next page):
Pollution Control Ordinance, the Authority, i.e. the Director
of Environmental Protection. ◾ Heat and power generation
◾ Production and processing of ferrous metals (iron and
The emissions to be controlled are oxygen, carbon steel mills)
monoxide, particulates (opacity), sulphur dioxide, nitrogen ◾ Production and processing of non-ferrous metals with a
oxides, ammonia (for gas-fired gas turbines) and smokes. capacity ≥ 0.5 tons per day for lead or cadmium or
Different limits are imposed on the types of power plants. ≥ 2 tons per day for other metals
◾ Oil and gas industries: Refineries (all sizes); natural gas
Emission monitoring guidelines in India processing and storage, storage and handling of petro-
leum products
To date in India, pollution standards exist for ambient air ◾ Non-metallic (mineral) industry:
quality only but do not for stack emissions from e.g. power – Cement production (all sizes)
plants or other industrial plants, except particulate matter. – Manufacture of glass including glass fibre with a melt-
PM standards, however, are higher compared to those ing capacity ≥ 1 ton of products per day
implemented in the USA or EU. – Manufacture of ceramic products by firing, in particu-
lar roofing tiles, bricks, refractory bricks, tiles, stone-
In November 2013 the Central Pollution Control Board ware or porcelain with a production capacity
published a comprehensive document "Specifications and ≥ 10 tons of product per day
Guidelines for Continuous Emissions Monitoring Systems ◾ Chemical and petrochemical industry (all sizes)
(CEMS) for PM measurement with special reference to ◾ Waste incinerators (all sizes)
emission trading programs". The purpose of this document ◾ Palm oil mills (all sizes)
is to serve as a technical specification for accurate, reliable
measurement of particulate matter using continuous emis-
sions monitoring systems (CEMS) with reference to their
use to support an emissions trading scheme.

The intention for the future is, to (a) revise the emission
standards for PM, and (b) to introduce emission standards
for other pollutants from stationary sources.

32 Emission Control Guidelines driven by UNFCCC


© Siemens AG 2016

Emission limit values in Malaysia


Limit value
Sources, activities Source capacity Fuel type Pollutants Data frequency
[mg/m3]
Solid & liquid SO2 500
10 ... 100 MW
fuels NO2 500
SO2 500
100 ... 300 MW
NO2 500
SO2 500
≥ 300 MW
NO2 500
All sizes CO 200
Heat & power All sizes Total PM 50
½ h average
generation SO2 35
Gaseous fuels NO2 350
All sizes
in general CO 50
Total PM 5
NO2 150
Combustion turbines ≥ 10 MW Gaseous fuels
CO 100
NO2 200
Combustion turbines ≥ 10 MW Liquid fuels
CO 100
SO2 500
Sinter plants
NO2 400
Iron & steel mills (all (waste gas from the sintering plant)
Total PM 50
sizes) production & ½ h average
Blast furnaces (3 % O2) Total PM 50
processing
Basic oxygen furnaces Total PM 50
Electric arc furnaces Total PM 20
SO2 500
Sinter plants
NO2 400
(waste gas from the sintering plant)
Non-ferrous metals Total PM 50
production & Production of copper and zinc Total PM 20 ½ h average
processing Production of lead Total PM 10
Production of aluminium Total PM 10
Secondary aluminium Total PM 10
Oil & gas industries Total PM 40
Catalytic cracking ½ h average
refineries (all sizes) SO2 1.2 g/m3
Calcination Total PM 40
NO2 800
Cement kilns (all sizes)
Total PM 50
SO2 800
Non-metallic
Glass furnaces ≥ 1 t product/day NO2 800 ½ h average
industry
Total PM 50
SO2 800
Ceramic furnaces > 10 t product/day NO2 800
Total PM 50
Total PM 10
NMVOC as total C 10
HCl 10
Waste incinerators HF 1 ½ h average
SO2 50
NO2 200
CO 50
Palm oil mills Total PM 50
Minute average
(all sizes) Opacity (smoke) 20 %

Emission Control Guidelines driven by UNFCCC 33


© Siemens AG 2016

Emission monitoring guidelines in the Philippines and in Singapore

Emission monitoring guidelines in the Philippines Emission monitoring guidelines in Singapore

Philippine Clean Air Act of 1999 Air quality guidelines


The Philippines Clean Air Act of 1999 was declared to pro- The National Environment Agency NEA implemented a
tect and advance the right of the people to a balanced and suite of measures to achieve higher national air quality
healthy ecology with the rhythm and harmony of nature. standards by 2020.
The state under this act promotes and protects the global
environment to attain sustainable development while Following the acceptance of the implementation, the Min-
recognizing the primary responsibility of local government istry of the Environment and Water Resources (MEWR)
units to deal with environmental problems. adopted the World Health Organisation (WHO) Air Quality
Guidelines (AQG) in 2012 for particulate matter 10
Guidelines (PM10), nitrogen dioxide, carbon monoxide and ozone,
The following document can be used for detailed informa- and the WHO AQG’s interim targets for PM2.5 and sulphur
tion: Guidelines on the requirements for continuous emis- dioxide.
sion monitoring systems (CEMS) and other acceptable pro-
tocols thereby modifying and clarifying certain provisions The reporting frequency by NEA on the Pollutant Standards
of section 5, rule X of DAO (DENR Administrative Order) Index (PSI) which measures five key pollutants namely par-
2000-81 and other related provisions. ticulate matter PM10, ozone, nitrogen dioxide, carbon
monoxide and sulphur dioxide in the ambient air is three
The document states i. a. "Continuous Emission Monitoring times daily. The daily reports will include PM2.5 as well.
System" (CEMS) refers to the equipment stipulated in the
DAO 2000-81 used to sample, analyze, measure, and pro-
vide, by any means of readings recorded at least once
every 15 minutes (using an automated data acquisition
and handling system), a permanent record of relevant reg-
ulated pollutant emissions or stack gas volumetric flow
rate.

Another two excerpts from this document make clear that


regulations and procedures correlate quite well with US
EPA regulations:
◾ When CEMS is required, quality assurance and quality
control procedures shall comply with 40 CFR Part 60
Appendix F (Quality Assurance Procedures).
◾ Each CEMS shall be audited and conducted in
accordance to 40 CFR Part 60 Appendix F.6. Relative
Accuracy Test Audit (RATA) must be performed annually
by industries.

34 Emission Control Guidelines driven by UNFCCC


© Siemens AG 2016

Emission monitoring guidelines in Australia

There are no national wide air emissions standards in South Australia


Australia. Environment protection authorities in individual The Environment Protection Authority (EPA) is South Aus-
states and territories set such standards. tralia’s primary environmental regulator. Environment Pro-
tection (Air Quality) Policy 1994 (in force from May 1,
Australian Capital Territory 1995) set the emission standards for air pollutants from
The Air Environment Protection Policy (Nov 3, 1999) pre- power plants and industrial processes. The Policy was
pared in accordance with the Environment Protection Act amended in 2005 and the amended Policy became effec-
1997 contains information and policies relating to the tive from Nov 3, 2005.
management of ambient air quality and pollutant emis-
sions to the atmosphere in the ACT. Emission standards for Tasmania
air pollutants from industrial processes outlined in The Environment Protection Authority (EPA) in Tasmania,
National Guidelines for Control of Emission of Air Pollut- commenced operation on July 1, 2008, is responsible for
ants from New Stationary Sources 1985 are adopted in environmental management and pollution control matters
ACT. The guidelines are intended for new plants, and ret- based on the Environmental Management and Pollution
rospective application to plant and installations or those Control Act 1994. In Tasmania, emissions from industries
are already approved and under construction is not are regulated under the general provisions of the Environ-
intended. mental Management and Pollution Control Act 1994 and
the Land Use Planning and Approvals Act 1993. The
Victoria permissible concentrations and/or loads of pollutants
The Environment Protection Act 1970 is Victoria’s primary present in discharges to the atmosphere from power
environment protection legislation. State environment plants and industrial processes are set in Environment Pro-
protection policies (SEPPs) are subordinate legislation tection Policy (Air Quality) 2004 (in force from May 1,
made under the provisions of the Act to provide more 2005).
detailed requirements and guidance for the application of
the Act. The air quality management SEPP establishes the Western Australia/Northern Territory
framework for managing emissions of air pollutants into There is no state wide specific emission standards set by
the air from all sources in Victoria. The specific air pollu- both Western Australia and North Territory.
tant emission standards are set in Victoria Government
Gazette NO.S240, December of 2001.

New South Wales


The Department of Environment and Climate Change
(DECC) is the NSW government agency responsible for
developing, coordinating and delivering policy and pro-
grams to deal with environmental, climate change, sus-
tainability, natural resource and cultural heritage issues in
NSW.

The Protection of the Environmental Operations Act 1997


(the POEO Act) provides the legal basis of environment
protection regulation across NSW. The Protection of the
Environment (Clean Air) Regulation 2002, set emission
standards for air pollutants emissions from power plants
and industrial processes. This regulation was replaced
again by the Clean Air Regulation 2010, which is in force
from September 1, 2010.

Emission Control Guidelines driven by UNFCCC 35


© Siemens AG 2016

Emission monitoring guidelines in South Korea and Thailand

Emission monitoring guidelines in South Korea Emission monitoring guidelines in Thailand

In South Korea, allowable emission standard for air pollut- Thailand is mostly following the EPA guidelines.
ants emitted from the discharging facility regulates the
gaseous substances and the particles separately starting Continuous emission monitoring is mandatory for the fol-
from January 1, 2015. lowing production plants:
◾ Electricity generating > 29 MW
Allowable emission standard for air pollutants to be ◾ Boilers or heat source size 30 tons of steam per hour,
applied from the year 2015 will be separately applied by or > 100 million u/BT per hour
using common applying standard or enforced standard ◾ Cement, lime, plaster in kiln and clinker cooler
that is to be used in case single emission amount of speci- ◾ Pulp and paper (recovery furnace, lime kiln digeste,
fied harmful substance exceeds tons per year. brown stock washer, evaporator and condensate strip-
per system)
Atmosphere Environmental Standard (Environmental ◾ Petroleum
Policy Law Act 2): – fluid catalytic cracking unit (FCCU)
– fuel oil combustion unit
Emission limit values in South Korea – sulfur recovery unit (SRU)
Recommended ◾ Steel factories > 100 tons per day
Pollutant Limits
measuring method ◾ Copper and zinc factories
Yearly average 0.02 ppm ◾ Lead compounds factories
Pulse UV fluorescence
SO2 24 hrs average 0.05 ppm ◾ Incinerators
method
1 hr average 0.15 ppm ◾ Sulfur producing factories
8 hrs average 9 ppm Non dispersive infrared
CO
1 hr average 25 ppm method
Yearly average 0.03 ppm
Chemoluminescent
NO2 24 hrs average 0.06 ppm
method
1 hr average 0.10 ppm
Yearly average 50 µg/m3
PM-10 ß-ray absorption method
24 hrs average 100 µg/m3
Yearly average 25 µg/m3 Since Jan 1, 2015,
PM-25 manual method or not
24 hrs average 50 µg/m 3
specified yet
8 hrs average 0.06 ppm
O2 UV photometric method
1 hr average 0.1 ppm
Atomic absorption
Pb Yearly average 0.5 µg/m3
spectrophotometry
Benzene Yearly average 5 µg/m3 Gas chromatography

220

36 Emission Control Guidelines driven by UNFCCC


© Siemens AG 2016

Emission monitoring guidelines in Vietnam and other regions

Emission monitoring guidelines in Vietnam Emission monitoring guidelines in other regions

The country’s strategy to manage environmental (inclu- With increasing urbanization and industrialization, air pol-
ding air) pollution from industry and energy sector is lution is an increasing concern also in other parts of the
imbedded in the Decision No. 1855/QD-TTg issued by the world. Sulfur dioxides, nitrogen oxides and particulate
Prime Minister on December 27, 2007 (Approving Viet- matter emissions have been rising steadily over past
nam’s National Energy Development Strategy up to 2020, decades. "Air Quality Standards" exist in many countries
with 2050 Vision). Some of its objectives are (1) to formu- and are categorizes for industrial or commercial and
late long-term environmental objectives and standards in sensitive areas or for vehicular emissions. However, there
conformity with regional and global environmental stan- are different states of implementation to be seen or
dards and the country’s economic conditions; (2) to con- planned for the near future.
trol and mitigate environmental pollution in energy-
related activities and (3) by 2015, all energy facilities will
reach environmental standards.

National technical regulations of ambient air and emission


are compiled in 2009/BTNMT according to Circular
No. 16/2009/TT-BTNMT October 7, 2009 of Ministry of Nat-
ural Resources and Environment.

Applied scopes are prescribed respectively:


◾ QCVN 05 Ambient air quality
◾ QCVN 06 Hazardous substances in ambient
environment
◾ QCVN 19 Industrial emission of inorganic substances
and dusts
◾ QCVN 20 Industrial emissions of organic substances
◾ QCVN 21 Emission of chemical fertilizer manufacturing
industry
◾ QCVN 22 Emission of thermal power industry
◾ QCVN 23 Emission of cement manufacturing industry

Emission Control Guidelines driven by UNFCCC 37


© Siemens AG 2016

Appendices
List of analyzer conformities with regulations

Measuring Measuring Typical CGA Technique QAL 1 according US EPA Siemens portfolio
component range technology to EN 15267-3 compli- CEM system Measuring
Cold- Hot- TÜV/ MCERTS/ ant device
In-situ
extr. extr. UBA SIRA
0 ... 50 mg/m3 NDIR ● ● ● see QAL 1 ULTRAMAT 6
0 ... 75 mg/m3 NDIR ● ● ● see QAL 1 ULTRAMAT 6
0 ... 100 mg/m3 NDIR ● SET CEM CERT ULTRAMAT 23
CO 0 ... 150 mg/m3 NDIR ● ● see QAL 1 ULTRAMAT 23
0 ... 200 mg/m3 NDIR ● ● SET CEM CERT ULTRAMAT 23
0 ... 250 mg/m3 NDIR ● ● ● TÜV: SET CEM CERT, MCERTS: see QAL 1 ULTRAMAT 23
0 ... 1250 mg/m3 NDIR ● ● SET CEM CERT ULTRAMAT 23
0 ... 15 mg/m3 NDUV ● SET CEM CERT SIPROCESS UV600
0 ... 50 mg/m3 NDUV ● ● ● TÜV: SET CEM CERT, MCERTS: see QAL 1 SIPROCESS UV600
0 ... 100 mg/m3 NDIR ● ● see QAL 1 ULTRAMAT 6/23
0 ... 150 mg/m3 NDIR ● ● SET CEM CERT ULTRAMAT 23
0 ... 200 mg/m3 NDIR ● ● see QAL 1 ULTRAMAT 6
NO
0 ... 400 mg/m3 NDIR ● ● ● TÜV: SET CEM CERT, MCERTS: see QAL 1 ULTRAMAT 23
0 … 750 mg/m3 NDIR ● ● ● TÜV: SET CEM CERT, MCERTS: see QAL 1 ULTRAMAT 23
0 ... 1000 mg/m3 NDUV ● ● ● TÜV: SET CEM CERT, MCERTS: see QAL 1 SIPROCESS UV600
0 ... 2000 mg/m3 NDUV ● ● ● TÜV: SET CEM CERT, MCERTS: see QAL 1 SIPROCESS UV600
0 ... 2000 mg/m3 NDIR ● ● SET CEM CERT ULTRAMAT 23
0 ... 20 mg/m3 NDUV ● SET CEM CERT SIPROCESS UV600
NO2 0 ... 50 mg/m3 NDUV ● ● ● TÜV: SET CEM CERT, MCERTS: see QAL 1 SIPROCESS UV600
0 ... 500 mg/m3 NDUV ● ● ● TÜV: SET CEM CERT, MCERTS: see QAL 1 SIPROCESS UV600
NOx 0 ... 10 mg/m3 CLD ● ● US CEMS version
N 2O 0 ... 50 mg/m3 NDIR ● SET CEM 1 ULTRAMAT 6
0 ... 25 mg/m3 NDUV ● SET CEM CERT SIPROCESS UV600
0 ... 75 mg/m3 NDUV ● ● ● TÜV: SET CEM CERT, MCERTS: see QAL 1 SIPROCESS UV600
0 ... 75 mg/m3 NDIR ● ● see QAL 1 ULTRAMAT 6
0 ... 287 mg/m3 NDUV ● ● ● TÜV: SET CEM CERT, MCERTS: see QAL 1 SIPROCESS UV600
SO2
0 ... 400 mg/m3 NDIR ● ● ● TÜV: SET CEM CERT, MCERTS: see QAL 1 ULTRAMAT 23
0 ... 2000 mg/m3 NDIR ● ● SET CEM CERT ULTRAMAT 23
0 ... 2000 mg/m3 NDUV ● ● ● TÜV: SET CEM CERT, MCERTS: see QAL 1 SIPROCESS UV600
0 ... 7000 mg/m3 NDIR ● ● SET CEM CERT ULTRAMAT 23
0 ... 15 mg/m3 TDLS ● ● ● LDS 6
HCl
0 ... 90 mg/m3 TDLS ● ● ● LDS 6
HF 0 ... 3 mg/m3 TDLS ● LDS 6
0 ... 15 mg/m3 TDLS ● LDS 6
NH3 0 ... 20 mg/m3 TDLS ● ● ● LDS 6
0 ... 380 mg/m3 TDLS ● ● ● LDS 6
CH4 0 ... 20 mg/m3 NDIR ● SET CEM 1 ULTRAMAT 6
TOC 0 ... 15 mgC/m3 FID ● FIDAMAT 6
0 ... 45 µg/m3 UV ● ● ● ● HM-1400 TRX
Hg
0 ... 75 µg/m3 UV ● ● ● ● HM-1400 TRX
Dust/opacity 0 ... 15 mg/m3 Various ● ● ● ● D-R 290/320/800, D-RX 250
Reference values
Paramag. or OXYMAT 6,
● ● ● ● TÜV: SET CEM CERT, MCERTS: see QAL 1
O2 0 ... 21 Vol% electroch. ULTRAMAT 23
(TDLS) ● LDS 6
0 ... 30 Vol% TDLS ● ● ● LDS 6
H 2O
0 ... 40 Vol% TDLS ● ● ● LDS 6
0 ... 25 Vol% (TDLS) ● LDS 6
CO2
0 ... 25 Vol% NDIR ● SET CEM 1 ULTRAMAT 6/23
Velocity/vol. flow 3 ... 30 m/s ● ● ● ● D-FL 100/220, D-RX 250
T ● SITRANS T
P ● SITRANS P
Emission data management systems
Emission data ● ● ● D-EMS 2000
management ● Siemens UK solution (CMS)
systems ●1) Siemens Austria solution (Emidate)
1)
QAL 1 approval according to Austrian Standards, by TÜV Austria

38 Appendices
© Siemens AG 2016

Application questionnaires for CEM applications and other services for


gas analysis from Siemens Process Analytics

Application questionnaires for CEM applications Syngas calorific value


Optimize your produced gas quality, yield and financial
Siemens Process Analytics has extensive experience in return by monitoring the energy value by use of micro pro-
planning, engineering and manufacturing of analytical sys- cess chromatography.
tems including CEMS. From single standard analyzer to
customized systems, we can provide a solution that will Biogas production monitoring
meet your specific requirements. Our "Set BGA" standard analysis package is an ideal tool to
optimize biogas yield and quality from anaerobic digestion
To enable us to offer appropriate solutions according to or land fill process.
your specific requirements, we need comprehensive infor-
mation about your application, process conditions and Maritime emissions monitoring
especially the gas matrix regarding all present gas compo- Use of ULTRAMAT 23 and ULTRAMAT 6 on ships for emis-
nents – measuring components as well as perhaps interfer- sion monitoring according to IMO (International Maritime
ing components. To make this communication as conve- Organization) environmental standards.
nient and efficient as possible, we have prepared a series
of questionnaires for our products and different applica- Securing the success of your business with Siemens
tion sets. Please answer the questions as completely as industry services
possible. We will review your answers, requirements and Increasing demands make it ever more important that
comments and will contact you for further actions. industrial plants operate at highest productivity and effi-
ciency levels. The Siemens industry service portfolio helps
Application questionnaires may be found for download on companies secure the decisive advantage over the
our process analytics website: competition.
www.siemens.com/processanalytics
Whether it’s production or process industry - in view of ris-
ing cost pressure, growing energy costs, and increasingly
stringent environmental regulations, services for industry
Other services for gas analysis from Siemens Process are a crucial competitive factor in manufacturing as well as
Analytics in process industries. All over the world Siemens supports
its customers with product, system, and application-
Siemens Process Analytics offers a comprehensive range of related services throughout the entire life cycle of a plant.
innovative and proven products, systems, and services for Right from the earliest stages of planning, engineering,
process and quality optimization in diverse applications. and building all the way to operation and modernization,
these services enable customers to benefit from the
Some examples Siemens experts’ unique technological and product know-
ledge and industry expertise. Thus downtimes are reduced
Process efficiency and the utilization of resources is optimized. The bottom
Use of in-situ laser gas analyzer can improve your environ- line: increased plant productivity, flexibility, and efficiency,
mental performance and reduce operating costs by careful plus reduced overall costs.
dosing control of consumable media such as lime or urea/
ammonium hydroxide on acid gas scrubbing or SCR/SNCR ◾ Online support
DeNOx process. ◾ Technical support
◾ Spare parts
Combustion control ◾ Repair services
Use of laser for oxygen and/or CO trim on combustion ◾ Field services
plant can improve fuel use efficiency by tighter control of ◾ Training
air demand. ◾ Service contracts

Appendices 39
© Siemens AG 2016

Get more information Security information


www.siemens.com/processanalytics Siemens provides products and solutions with industrial
security functions that support the secure operation of
Service and Support:
plants, systems, machines and networks.
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In order to protect plants, systems, machines and networks
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against cyber threats, it is necessary to implement – and
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continuously maintain – a holistic, state-of-the-art indus-
trial security concept. Siemens’ products and solutions only
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Process Industries and Drives
Customer is responsible to prevent unauthorized access to
Process Analytics
76181 KARLSRUHE
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GERMANY machines and components should only be connected to the
enterprise network or the internet if and to the extent
necessary and with appropriate security measures (e.g. use
© Siemens AG 2016
of firewalls and network segmentation) in place.
Subject to change without prior notice
Article No. E86060-A3501-A101-A5-7600 Additionally, Siemens’ guidance on appropriate security
W-FPN6Z-PD-PA285 / Dispo 27902
measures should be taken into account. For more informa-
BR 0916 1.0 GUT 40 En
Printed in Germany
tion about industrial security, please visit
http://www.siemens.com/industrialsecurity.

The information provided in this brochure contains merely general


Siemens’ products and solutions undergo continuous
descriptions or characteristics of performance which in case of actual development to make them more secure. Siemens strongly
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