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Acid Base Curve Fit
Acid Base Curve Fit
pH
Cb= 0.08267 6
Va= 100 4
Veq= 56.00942 2
0
00 00 01 01 01 01 01 01 01 01 01 01 01 01 01 02 02 02 02 02 02
0 E+ 0E+ 0E+ 0E+ 0E+ 0E+ 0E+ 0E+ 0E+ 0E+ 0E+ 0E+ 0E+ 0E+ 0E+ 5E+ 2E+ 9E+ 6E+ 3E+ 0E+
Sresid =
2
#NAME? 0 0 4 1 8 5 2 9 6 3 . 0 . 7 .4 .1 .8 .0 .1 .1 .2 . 3 .4
0. 7. 1. 2. 2. 3. 4. 4. 5. 6. Vb/Va 7 7 8 9 9 1 1 1 1 1 1
Page 1
Diprotic Acid
Page 2
Diprotic Acid
Page 3
Diprotic Acid
Page 4
Diprotic Acid
4.5
4
3.5
3
pH
2.5
2
1.5
1
0.5
0
01 01 01 02 02 02 02 02 02
0
01
01
E+ 0E+ 0E+ 5E+ 2E+ 9E+ 6E+ 3E+ 0E+
+0
E+
E+
0E
1 8 0 1 1 2 3 4
00
00
9. 9. 1. 1. 1. 1. 1. 1.
0
0.
2.
4.
Residual
#NAME? 1 0.00
#NAME? 1 0.81
#NAME? 1 1.21
#NAME? 1 2.16
#NAME? 1 2.71
#NAME? 1 3.71
#NAME? 1 4.12
#NAME? 1 4.69
#NAME? 1 5.16
#NAME? 1 5.65
#NAME? 1 6.16
#NAME? 1 6.71
#NAME? 1 7.21
#NAME? 1 7.71
#NAME? 1 8.20
#NAME? 1 8.66
#NAME? 1 9.21
#NAME? 1 9.71
#NAME? 1 10.21
#NAME? 1 10.71
#NAME? 1 11.21
#NAME? 1 11.71
#NAME? 1 12.76
#NAME? 1 13.81
#NAME? 1 14.78
#NAME? 1 15.71
#NAME? 1 16.71
#NAME? 1 17.71
#NAME? 1 18.71
#NAME? 1 19.71
#NAME? 1 20.71
#NAME? 1 21.66
#NAME? 1 22.71
#NAME? 1 23.71
#NAME? 1 24.81
#NAME? 1 25.71
Page 5
Diprotic Acid
#NAME? 1 26.76
#NAME? 1 27.71
#NAME? 1 28.66
#NAME? 1 29.81
#NAME? 1 30.71
#NAME? 1 31.71
#NAME? 1 32.71
#NAME? 1 33.81
#NAME? 1 34.71
#NAME? 1 35.71
#NAME? 1 36.71
#NAME? 1 37.76
#NAME? 1 38.71
#NAME? 1 39.76
#NAME? 1 40.68
#NAME? 1 41.71
#NAME? 1 42.71
#NAME? 1 43.71
#NAME? 1 44.71
#NAME? 1 45.87
#NAME? 1 46.71
#NAME? 1 47.71
#NAME? 1 47.71
#NAME? 1 48.71
#NAME? 1 49.11
#NAME? 1 49.61
#NAME? 1 50.61
#NAME? 1 51.11
#NAME? 1 51.41
#NAME? 1 51.61
#NAME? 1 51.81
#NAME? 1 52.11
#NAME? 1 52.61
#NAME? 1 53.11
#NAME? 1 53.61
#NAME? 1 54.03
#NAME? 1 54.33
#NAME? 1 54.61
#NAME? 1 54.91
#NAME? 1 55.06
#NAME? 1 55.11
#NAME? 1 55.26
#NAME? 1 55.41
#NAME? 1 55.51
#NAME? 1 55.71
#NAME? 1 55.76
#NAME? 1 55.81
#NAME? 1 55.86
#NAME? 1 55.91
#NAME? 1 56.01
Page 6
Diprotic Acid
#NAME? 1 56.06
#NAME? 1 56.16
#NAME? 1 56.21
#NAME? 1 56.26
#NAME? 1 56.31
#NAME? 1 56.36
#NAME? 1 56.41
#NAME? 1 56.51
#NAME? 1 56.61
#NAME? 1 56.66
#NAME? 1 56.71
#NAME? 1 56.81
#NAME? 1 56.86
#NAME? 1 56.91
#NAME? 1 57.10
#NAME? 1 57.12
#NAME? 1 57.30
#NAME? 1 57.32
#NAME? 1 57.66
#NAME? 1 57.71
#NAME? 1 57.91
#NAME? 1 58.16
#NAME? 1 58.50
#NAME? 1 58.61
#NAME? 1 58.89
#NAME? 1 59.01
#NAME? 1 59.36
#NAME? 1 59.81
#NAME? 1 60.01
#NAME? 1 60.61
#NAME? 1 61.21
#NAME? 1 61.66
#NAME? 1 62.11
#NAME? 1 62.61
#NAME? 1 63.11
#NAME? 1 63.61
#NAME? 1 64.11
#NAME? 1 65.11
#NAME? 1 66.11
#NAME? 1 67.11
#NAME? 1 68.11
#NAME? 1 69.11
#NAME? 1 70.11
#NAME? 1 71.16
#NAME? 1 72.11
#NAME? 1 73.11
#NAME? 1 77.11
#NAME? 1 78.16
#NAME? 1 82.61
#NAME? 1 84.51
Page 7
Diprotic Acid
#NAME? 1 86.31
#NAME? 1 89.31
#NAME? 1 90.71
#NAME? 1 92.41
#NAME? 1 94.61
#NAME? 1 95.61
Page 8
Triprotic Acid
Sresid2= 6.386E-06
Page 9
Triprotic Acid
Page 10
Triprotic Acid
Page 11
Triprotic Acid
5
4.5 Titration C
14.00 4
3.5
pH
12.00
3
10.00 2.5
pH
2
8.00 1.5
1
6.00
0.5
g(Davies) g(Paste Special/Values) Vexp
4.00 0
Residual 4.00E+01 6.00E+01
0.00E+00 2.00E+01
0.95728 1 0.00E+00 2.00
0.955665 1 6.70E-01 0.00
0.954713 1 9.50E-01 0.00E+00 5.00E-02 Vb
1.0
0.953417 1 1.36E+00
0.952705 1 1.52E+00
0.952158 1 1.67E+00
0.951215 1 1.85E+00
0.950583 1 2.00E+00
0.94975 1 2.17
0.948565 1 2.36
0.947571 1 2.53
0.946357 1 2.74
0.945668 1 2.85
0.945043 1 2.95
0.944321 1 3.06
0.943612 1 3.17
0.942871 1 3.28
0.94205 1 3.4
0.941382 1 3.5
0.940563 1 3.62
0.939561 1 3.77
0.938753 1 3.89
0.937811 1 4.03
0.937157 1 4.13
0.936252 1 4.27
0.935408 1 4.4
0.934707 1 4.51
0.933372 1 4.72
0.932633 1 4.84
0.932219 1 4.91
0.931551 1 5.02
0.930832 1 5.14
0.930181 1 5.25
0.929537 1 5.36
0.92919 1 5.42
0.928903 1 5.47
Page 12
Triprotic Acid
0.928329 1 5.57
0.927817 1 5.66
0.927254 1 5.76
0.926697 1 5.86
0.92609 1 5.97
0.925544 1 6.07
0.925003 1 6.17
0.924415 1 6.28
0.923938 1 6.37
0.923413 1 6.47
0.922893 1 6.57
0.922173 1 6.71
0.921665 1 6.81
0.921212 1 6.9
0.920613 1 7.02
0.920169 1 7.11
0.919728 1 7.2
0.919097 1 7.33
0.918713 1 7.41
0.918141 1 7.53
0.917999 1 7.56
0.91781 1 7.6
0.917575 1 7.65
0.917434 1 7.68
0.917108 1 7.75
0.917014 1 7.77
0.91669 1 7.84
0.916551 1 7.87
0.916183 1 7.95
0.916041 1 7.98
0.915763 1 8.03
0.915438 1 8.07
0.915048 1 8.12
0.914694 1 8.16
0.913878 1 8.26
0.913495 1 8.3
0.913041 1 8.36
0.912677 1 8.4
0.912201 1 8.46
0.911868 1 8.49
0.911385 1 8.55
0.910973 1 8.6
0.910502 1 8.66
0.910138 1 8.69
0.909656 1 8.76
0.909367 1 8.78
0.908545 1 8.89
0.90756 1 9.01
0.906733 1 9.1
0.90585 1 9.22
Page 13
Triprotic Acid
0.905055 1 9.31
0.903871 1 9.46
0.902596 1 9.62
0.901716 1 9.74
0.900202 1 9.94
0.898555 1 10.16
0.896908 1 10.36
0.895581 1 10.57
0.89355 1 10.85
0.891787 1 11.1
0.88991 1 11.37
0.88774 1 11.72
0.885582 1 12.05
0.883425 1 12.36
0.881525 1 12.68
0.879437 1 13.06
0.876763 1 13.51
0.87376 1 14.07
0.870521 1 14.71
Page 14
Triprotic Acid
Titration Curve
5.00E-02 Vb/Va
1.00E-01 1.50E-01 2.00E-01
Page 15
Differentiate
DpH/ DV
2.27E+01 5 1.20E+00 3.3333E-01 2.79E-01 23.34486 0.258863
2.39E+01 5.333333 6.45E-01 3.3333E-01 5.17E-01 24.2648 0.551199 1.20E+00
2.46E+01 5.666667 4.12E-01 3.3333E-01 8.08E-01 24.79333 0.001425
1.00E+00
2.50E+01 6 4.12E-01 3.3333E-01 8.09E-01 25.20553 -0.551401
2.54E+01 6.333333 6.44E-01 3.3333E-01 5.18E-01 25.73338 -0.259673 8.00E-01
2.61E+01 6.666667 1.19E+00 3.3333E-01 2.79E-01 26.65158 -0.074896
2.72E+01 7 2.17E+00 3.3333E-01 1.53E-01 28.3341 -0.020528 6.00E-01
2.94E+01 7.333333 3.50E+00 3.3333E-01 9.52E-02 31.1705 -0.005548
4.00E-01
3.29E+01 7.666667 4.58E+00 3.3333E-01 7.28E-02 35.20975 4.362E-06
3.75E+01 8 4.58E+00 3.3333E-01 7.28E-02 39.78711 0.005576 2.00E-01
4.21E+01 8.333333 3.50E+00 3.3333E-01 9.53E-02 43.8236 0.020775
4.56E+01 8.666667 2.16E+00 3.3333E-01 1.54E-01 46.65311 0.078059 0.00E+00
4.77E+01 9 1.17E+00 3.3333E-01 2.84E-01 48.32075 0.305658 0
4.89E+01 9.333333 6.00E-01 3.3333E-01 5.55E-01 49.20716 1.057307
4.95E+01 9.666667 3.20E-01 3.3333E-01 1.04E+00 49.66732 1.785944
4.98E+01 10 2.19E-01 3.3333E-01 1.52E+00 49.93674 -0.799686
5.00E+01 10.33333 2.50E-01 3.3333E-01 1.34E+00 50.17096 -1.667688
5.03E+01 10.66667 4.37E-01 3.3333E-01 7.63E-01 50.51405 -0.589439
5.07E+01 1.10E+01 9.07E-01 3.3333E-01 3.67E-01 51.18595 -0.138166
D(DpH)/DV^2
2
5.16E+01 1.13E+01 2.01E+00 3.3333E-01 1.66E-01 52.64227 -0.028419
5.36E+01 1.17E+01 4.69E+00 3.3333E-01 7.11E-02 55.98777 -0.005187 1.5
5.83E+01 1.20E+01 1.23E+01 3.3333E-01 2.72E-02 64.46224 -0.000695
7.06E+01 1.23E+01 4.44E+01 3.3333E-01 7.51E-03 92.77989 -0.002909 1
1.15E+02 1.27E+01 -1.15E+02 -1.2667E+01 1.10E-01 57.48293 0.001917
0.5
0
0 10
Titration Curve -0.5
14 -1
12 -1.5
10 -2
pH
0
0.00E+00 1.00E+01 2.00E+01 3.00E+01 4.00E+01 5.00E+01 6.00E+01 7.00E+01 8.00E+01
Volume NaOH, mL
Page 16
4
2 Differentiate
0
0.00E+00 1.00E+01 2.00E+01 3.00E+01 4.00E+01 5.00E+01 6.00E+01 7.00E+01 8.00E+01
Volume NaOH, mL
Page 17
Differentiate
First Derivative
1.60E+00
1.40E+00
DpH/ DV
1.20E+00
1.00E+00
8.00E-01
6.00E-01
4.00E-01
2.00E-01
0.00E+00
0 10 20 30 40 50 60 70 80 90 100
Volume NaOH, mL
Second Derivative
D(DpH)/DV^2
1.5
0.5
0
0 10 20 30 40 50 60 70 80 90 100
-0.5
-1
-1.5
-2 Volume NaOH, mL
Page 18
Ka's & pKa's
Page 19