Biweekly Test - 3 (Advanced) : DATE: 23/06/2018 TIME: 60 Min. AS: (PCM)

Biweekly Test – 3 (Advanced)
DATE : 23/06/2018 TIME : 60 Min.

AS : (PCM)
SECTION I : MATHEMATICS
Integer type
1.  
Number of values of x  R which satisfy the equation cos  x  4 cos  x  1 is  
 
2. For x, y, z   0,  , let x, y, z be first three consecutive terms of an arithmetic progression such that
 2
1
cos x + cos y + cos z = 1 and sin x + sin y + sin z = , then 2 cot y is
2
If the Sum of all the values of x in  ,2  , which satisfy the equation 81|cos x| cos
2
x |cos x|3  
3.  43,
is K , then K is
4. The value of tan 6° tan 42° tan 66° tan 78° is K, then [K] is(where  is greatest integer function)
5. The number of integral values of  less than 51, such that tan2   sec    holds for some  is
sin  sin3 sin9 A
6. If A  tan 27  tan  and B    then equals.
cos 3 cos 9 cos 27 B
1
7. The number of solutions of the equation cot x  cot x   0  x  2  is
sin x
8. If 2 cos x + sin x = 1, then sum of all possible values of 7 cos x + 6 sin x is
One or more than choice type


9. If A  0, B  0, A  B  and y = tan A  tanB , then
3
(A) the maximum value of y is 3 (B) the minimum value of y is 1/3
(C) the maximum value of y is 1/3 (D) the minimum value of y is 0
10. If in ABC, sinC  cos C  sin  2B  C   cos  2B  C   2 2 , then ABC is
(A) equilateral (B) isosceles (C) right angled (D) obtuse angled
11. If cos5  a cos   b cos   c cos   d then
3 5
(A) a  5 (B) b  20 (C) c  18 (D) a  c  d  21

12. Number of real solutions of the equation  tan x  1 tan x  3  tan x  5  tan x  7   33
       
(A) will be 2 in  ,  (B) will be 4 in  , 
 2 2  2 2
     
(C) will be 4 in  ,  (D) will be 3 in  , 
 2   2 
13. Let [x] = the greatest integer less than or equal to x and let f (x) = sin x + cos x. Then the most
   
general solutions of f  x    f    are
  10  
 
(A) 2n  , nZ (B) n, n  Z (C) 2n, n  Z (D) n  ,n  Z
2 4
3 3
14. If sin    ,     then
5 2
 1  3  3
(A) cos  (B) sin  (C) tan 3 (D) tan   
2 10 2 10 2 4
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Passage – I
If  and  both lie in the interval  0,5  such that sin   sin   2 then
15. Minimum value of    will be
(A)  (B) 2 (C) 3  (D) 6 
16. The value of cos2  sin2 will be
(A) 0 (B) 1 (C)  1 (D) 2
Passage – II
, ,  are the values of  satisfying a tan3    2a  x  tan   y  0
17. If tan   tan   h, then
(A) ah3 + (2a – x)h = y (B) ah3 + (2a – x)h + y = 0
(C) ah3 + (x – 2a) h + y = 0 (D) ah3 + (x – 2a) = 0
18. tan   tan   k then
(A) y2 + (2a – x) ak2 + a3k2 = 0 (B) y2 + (2a – x)ak2 + a2k3 = 0
(C) y2 + (2a – x) ak + a3k2 = 0 (D) y2 + (2a – x) ak2 – a2k3 = 0
SECTION II : PHYSICS
Integer type
19. A steel ball is dropped from the roof of a building. An observer standing in front of a window of
1
height 1.5m high notes that the ball takes s to fall from the top to the bottom of the window. The
10
ball reappears at the bottom of the window 2s after passing it on the way down. If the collision
between the ball and the ground is perfectly elastic, If the height of the building is H, find 2H.
Take g = 10 m/s2.
20. A body when projected vertically up, covers a total distance D during its time of flight. If there were
no gravity, the distance covered by it during the same time is equal to nD, find n?

21. If velocity of a particle moving along a straight line changes with time as V(m/s) = 4 sin   t, its
2
x
average velocity over time interval t = 0 to t = 2(2n–1) sec, (n being any +ve integer) is
(2n  1)
m/s, find x ?
22. A particle is projected from point P with velocity 52 ms-1 perpendicular to y
the surface of a hollow right angle cone whose axis is vertical. It collides at
Q normally. The time of the flight of the particle is
P Q
900 x
23. If the ratio of radius of curvature at the highest point of projectile to that just after its projection is
3 x
found to be , then find the value of x. (The angle of projection is 300)
8
100
24. A particle is moving on a circular path of radius m in such a way that magnitude of its velocity
19
varies with time as v  2t 2  t , where v is velocity in m/s and t is time in s. The acceleration of the
particle at t = 2 s is
25. A particle A is projected from the ground with an initial velocity of 10 B
5 m/s
m/s at an angle at 60° with horizontal. From what height h should
another particle B be projected horizontally with velocity 5 m/s so that
both the particles collide on ground at point C if both are projected h 10 m/s
simultaneously (g = 10 m/s2)
60°
A C
26. Two particles A and B are projected simultaneously in the directions shown vB=10 3 m/s
in figure with velocities v A  25 m/s and vB  10 3 m/s. If they collide in air vA=25m/s
after 2s, the angle  is
 60°
x

27. Two swimmers A and B start swimming from different positions on y
30m P
the same bank as shown in figure. The swimmer A swims at angle
x
900 with respect to the river to reach point P. He takes 120
10m
seconds to cross the river of width 10 m. The swimmer B also
takes the same time to reach the point P
(A) velocity of A with respect to river is 1/6 m/s A B
5m
(B) river flow velocity is 1/4 m/s
(C) velocity of B along y-axis with respect to earth is 1/3 m/s
(D) velocity of B along x-axis with respect to earth is 5/24 m/s
28. A man who can swim at a speed v relative to the water wants to cross a river of width d, flowing with
a speed u. The point opposite him across the river is P.
d
(A) the minimum time in which he can cross the river is
v
d
(B) He can reach the point P in time
v
d
(C) He can reach the point P in time
v  u2
2
(D) He cannot reach P if u > v

29. A board is moving with a velocity v with respect to earth. Man A is
running with a velocity 2v with respect to earth and the man B is running A  B v
with a velocity –2v with respect to earth. Both men start running from the
opposite ends of the board at the same time, as shown. Length of the
board is L. If they meet after time T.
(A) value of T is L /4v
(B) value of T is L/2v
(C) Displacement of man B with respect to board in time T is 3L/4
(D) Displacement of man A with respect to board in time T is L/4
30. Two particles are projected from the same point with same speed u at angles of projection  and 
from horizontal strike the horizontal ground. The maximum heights attained by projectiles is h 1 and
h2 respectively, R is the range for both and t1 and t2 are their time of flights respectively then
 t
(A)     (B) R  4 h1h2 (C) 1  tan  (D) tan   h1 / h2
2 t2
31. A train starts from rest at S = 0 and is subjected to acceleration as a(m/s)2
shown 6
(A) Change in velocity at the end of 10 m displacement is 50 m/s
(B) Velocity of the train for S = 10 m is 10 m/s
(C) The maximum velocity attained by train is not greater than 14 m/s S(m)
30
(D) The maximum velocity of the train is between 15 m/s and 16 m/s
32. Two projectile are thrown at the same time from two different points. The projectile thrown from the
origin has initial velocity 3iˆ  3ˆj with respect to earth. The projectile has initial velocity aiˆ  bjˆ with
respect to earth thrown from the point (10, 5). ( î is a unit vector along horizontal, ĵ along vertical).
If the projectile collides after two second, then the
1 1
(A) value of a is –2 (B) value of a is (C) value of b is (D) value of b is –2
2 2
Passage – I
A person walks up a stationary escalator in t1 s. If he is standing on elevator, then elevator carries
him up in t2 s. The length of elevator is l.
33. If man starts to walk on moving escalator in the direction of motion of escalator, then time taken by
the man to move up is
t1t 2 t1 t 2
(A) (B) (C) t1 + t2 (D) t1 – t2
t1  t 2 t1  t 2
34. If man starts to move opposite to moving escalator, then time taken by the man to move up is
t1 t 2 t1 t 2
(A) (B) (C) t1 + t2 (D) t1 – t2
t1  t 2 t1  t 2
Passage – II
A projectile is thrown from the origin in x-y plane, Vy(m/s) Vx(m/s)

where x-axis is along the ground and y-axis is
vertically upwards. The vertical velocity and the 10
horizontal velocity vary with respect to time
according to the graphs shown. Accelerating due
10
to gravity is g. t1 2t1 t(s)
2t1
k
35. What is the value of t1?

(A) 10/g (B) 20/g (C) 30/g (D) none of these
36. What is the initial angle of projection?
(A) 450 (B) 750 (C) 600 (D) none of these
SECTION III : CHEMISTRY

Integer type
37. A mixture of N2 and H2 is caused to react in a closed container to form NH3. The reaction ceases
before either reactant has been totally consumed. At this stage, 2.0 moles each of N2, H2 and NH3
are present. The sum of moles of N2 and H2 present originally were respectively.
38. Magnetic moment of Xn+ (Z = 26) is 24 B.M. Therefore the sum of the number of upaired
electrons and value of n is
39. An electron in hydrogen atom (ground state) jumps to higher energy level x, such that the potential
energy of electron becomes half of its total energy at ground state. What is the value of x ?
40. In an atom the last electron is present in f-orbital and for its outermost shell the graph of  2 has 6
maximas. What is the sum of group and period of that element ?
41. An electron jumps to higher excited state of a orbital which is non directional and have 4 radial
node then shell with which electron belong ?
42. The maximum number of elections that can have principal quantum number, n = 3, and spin
1
quantum number, ms   , is
2
43. Number of hydrogen atoms in 36 ml of H2O at 277 K are xNA. x is ______
44. Number of lone pairs in 18 ml H2O at 273 K is xNA. Then value of x will be
45. In a certain electronic transition in hydrogen atom from an initial state to a final state, the difference
of orbit radius is 8 times the first Bohr radius. Which transition does not satisfy the given condition?
(A) 7  1 (B) 6  1 (C) 5  1 (D) 3  1
46. The work function for Ag metal is 7.5  1019 J. Ag metal is being exposed to the light of frequency
1220 Å. Which is/are correct statements ?
(A) Threshold frequency of metal is 1.135  1015 s1
(B) Threshold frequency of metal is 8.33  1015 s1
(C) Stopping potential is 5.46 volt
(D) If light of wavelength 3600 Å is used then photoelectric effect take place
47. Which statement is/are correct about hydrogen spectrum?
(A) Energy of 2nd orbit is different for 1H1, 1H2 and 1H3
(B) Visible spectrum can be obtained in Lyman series and Balmer series
(C) Infrared spectrum is obtained in Paschen, Brackett and Pfund series
(D) Total number of emission lines obtained in Balmer series is n – 2, where n is principal quantum
number and n > 2.
48. An electron is moving in 3rd orbit of hydrogen atom and radius of first orbit is x then
(A) de-Broglie wavelength is 6x (B) de-Broglie wavelength is 2x
h h
(C) Velocity of electron is (D) Velocity of electron is
6 xm 2xm
nd
49. Velocity of an electron in the II stationary orbit of hydrogen atom is
(A) Equal to velocity of light
1
(B) Equal to times velocity of light
137
(C) Equal to velocity of an electron in sixth stationary orbit of Li+2
1
(D) Equal to times of the velocity of light
274
50. In which of the following orbital/orbitals radial node and angular nodes are same?
(A) 4p (B) 3p (C) 5d (D) 6f
Passage – I
Large quantities of Hydrogen are required these days in industry for various purposes. Water is
found to be the cheapest raw material from which hydrogen can be obtained. One of the important
methods for the commercial production of hydrogen is ‘Lane’s process’ in which steam is passed
over hot iron. Iron decomposes steam with formation of magnetic oxide (Fe3O4) and hydrogen.
i 3Fe  4H2O  Fe3O4  4H2
steam magnetic oxide
Iron is regenerated by reducing magnetic oxide with water gas (it is a mixture of CO & H 2 in 1:1
mole ratio)
ii Fe3O4  4CO  3Fe  4CO2 
iii Fe3O4  4H2  3Fe  4H2O
 steam recovered
[Equal amounts of magnetic oxide react in steps (ii) and (iii)] Steam so produced is again used in
the previous step in which magnetic oxide is produced : [At. wt.  Fe = 56]
51. How many grams of iron are needed in order to produce 11.2 liter of H2 gas at S.T.P
(A) 56 gm (B) 21 gm (C) 42 gm (D) none of these
52. How many gram water gas is needed in order to recover all the iron in previous problem
(A) 14 gm (B) 7.5 gm (C) 15 gm (D) none of these
Passage – II
The approximate size of the nucleus can be calculated by using energy conservation theorem in
Rutherford’s  -scattering experiment. If an  -particle is projected from infinity with speed v,
towards the nucleus having z protons then the  -particle which is reflected back or which is
deflected by 1800 must have approach closest to the nucleus. It can be approximated that a-particle
collides with the nucleus and gets back. Now if we apply the energy conservation initial and collision
point then :
(Total Energy)initial = (Total Energy)final
(K.E.)i + (P.E.)i = (K.E.)f + (P.E.)f
(P.E.)i = 0, since P.E. of two charge system separated by infinite distance is zero, finally the particle
stops and then starts coming back.
1 kq q
m v 2  0  0  1 2
2 R
1 2e  ze 4kze2
 m v 2  k R 
2 R m v 2
Thus the radius of nucleus can be calculated using above equation. The nucleus is so small a
particle that we can’t define a sharp boundary for it.
53. If  -particle with speed v0 is projected from infinity and it approches upto r0 distance from the
nuclei. Then the speed of  -particle which approches upto 2r0 distance from the nucleus is
v0 v0
(A) 2v 0 (B) (C) 2v0 (D)
2 2
54. Radius of a particular nucleus is calculated by the projection of  -particle from infinity at a particular
speed let this radius is the true radius. If the radius calculation for the same nucleus is made by,
 -particle with half of the earlier speed then the percentage error involved in the radius calculation
is
(A) 75% (B) 100% (C) 300% (D) 400%
Keys & Hints
SECTION I : MATHEMATICS
1. (1)
cos (  x  4 ) cos( x )  1
 {cos( x  4  1 and cos  x = 1}  
or {cos(  x  4 )  1 and cos (  x )  1}
( If one of the factors is numerically less than 1, then the other is numerically greater than 1; which
is not possible as cos   1 for all  )
 either both x  4 and x are even integers or both x  4 and x are odd integers.
 x = 4 is the only solution.
2. (2)
We have y  d , y , y  z in A.P.
x z
Now,  cos x  1
 cos (y – d) + cos y + cos(y + d) = 1  cos y (2 cos d + 1) = 1 …(1)
1
Also,  sin x 
2
1 1
 sin(y – d) + sin y + sin (y + d) =  sin y (2 cos d + 1) = …(2)
2 2
Equation (1)
  cot y  2
Equation (2)
3. (3)
The index of the power of 8 on L.H.S. is an infinite geometric series
1 + |cosx| + |cosx|2 + |cosx|3 + ........ to  since |cosx|2 = cos2x etc.
1
whose sum 
1 | cos x |
1
3 1|cos x| 1 1 1 1
 (2 )  (22 )3  2  1 | cos x |  | cos x |  cos x  
1 | cos x | 2 2 2
1  1 2
When cosx = + , the solution is 2n  and when x = – , the solution is 2n ± .
2 3 2 3
   2 2 4 5 
In the interval  ,2  , the solution set =  , ,  , , , .
 3 3 3 3 3 3 
4. (1)
We have, tan 6° tan 42° tan 66° tan 78°
= tan 6° tan(60° – 18°) tan(60° + 6°) tan(60° + 18°)
tan 6 tan  60  6  tan18 tan  60  18 tan  60  18
=
tan18
tan 6 tan  60  6  tan  3  18  tan 6  tan 60   6   tan 60   6  tan18
= = = =1
tan18 tan18  tan18
5. (52)
sec 2  + sec  – (  + 1) = 0
1  1  4    1 1  4  5
 sec  = =
2 2
5
For real sec  , 4  + 5  0, i.e.   
4
Also sec   1 or sec   1
1  4  5 1  4  5
  1 or  1
2 2
 –1 + 4  5  2 or –1 – 4  5  – 2
 4  + 5  9 or 4  + 5  1    1 or   –1
5 5
   and   1 or    and   1
4 4
  1 or   1
   [1,  )
6. (2)
sin  2 sin  cos  sin  3    1
    tan 3  tan 
cos 3 2cos3 cos  2 cos 3.cos  2
sin3 1
Similarly   tan9  tan3
cos 9 2
sin9 1
And;   tan 27  tan9
cos 27 2
1 A A
So; B   tan 27  tan     2
2 2 B
7. (1)
1
If cot x > 0, then = 0 (impossible)
sin x
1
Now if cot x < 0, then –cot x = cot x +
sin x
2 cos x  1
 0
sin x
1
 cos x  
2
2
 x  2n  , nz
3
As 0  x  2
2 4 4 2
 x , . (But at x = , cot x > 0),  x =
3 3 3 3
8. (8)
If 2 cos x + sin x = 1, then value …
2 cos x = 1 – sin x
3
On squaring 4cos2 x  1  2sin x  sin2 x  5sin2 x  2sin x  3  0  sin x  1, 
5
When sin x = 1, then cos x = 0 and so 7 cos x + 6 sin x = 6
3 4
When sin x =  , then cos x =
5 5
 7 cos x + 6 sin x = 2
Hence 7 cos x + 6 sin x = 6 or 2
9. (CD)
 
y = tan A. tan   A   tan2A + 3 (y – 1)tan A + y = 0
3 
As tanA is real, D  0  3(y –1)2 – 4y  0
1
 3y2 – 10y + 3  0  y  or y  3
3
But each of tan A, tanB is less than 3 or one is 0 and the other is 3.
1
 y  3 is not possible. So y  . Also, tanA . tanB  0
3
10. (B,C)
We have sinC  cos C  sin  2B  C   cos  2B  C   2 2
 sin  2B  C  sinC  cosC  cos  2B  C  2 2
 sin 180  A  cosB  sin 180  A  sinB  2
 sin A  cosB  sinB   2
 1 1 
 sin A  cosB  sinB   1
 2 2 
  
 sin A sin   B   1, it is possible only when
 4 
 
sin A  1& sin   B   1
4 
 A  90 & B  45 then C  45
11. (A,B, D)
cos 5  cos  4   
cos 4.cos   sin 4.sin 
  2cos2 2  1 .cos   2sin2.cos2.sin 

  
  
2
 2 2 cos2   1  1 cos   4 cos  1  cos2  2 cos 2   1
 
 8cos5   8cos3   cos   8cos3   4cos   8cos5   4cos3 
 16cos5   20cos3   5cos 
a  5 , b  20, c  16 ,d  0
12. (A, D)
  
tan2 x  8 tan x  15 tan2 x  8 tan x  7  33
Let tan2 x  8 tan x  
Then 2  22  72  0
  18, 4
  18 (rejected)
tan2 x  8 tan x  4  0
 tan x  4  12
13. (AC)
  
f   = sin 18° + cos 18° = 2 sin (45° + 18°) = 2 sin 63°.
 10 
1   
As sin 63° > sin 45° = and sin 63° < 1, we get 1 < f   < 2
2  10 
   
  f     1. So, the equation is sin x + cos x = 1.
  10  
  1  
 cos  x    or x – = 2n 
 4  2 4 4
14. (AB)
3 4  4  1
sin    ; cos    ; 2cos2  1    2cos2 
5 5 2 5 2 5
 1    3  
cos     
2 10  2 2 4 
 1 3
sin  1  
2 10 10
 3
tan  3 But tan  
2 4
15. (C)
16. (C)
Hints 15 & 16
 5 9
sin   1 and sin   1. So,   , ,
2 2 2
3 7
 , .
2 2
3 9
Minimum value of       3
2 2
cos2  sin2  1
17. (A)
tan   tan   tan   0
h + tan  = 0  tan  = –h
hence put value of tan  in given equation.
18. (D)
y
tan   tan   tan   
a
y y
k  tan     tan   
a ka
put tan  in given equation.
SECTION II : PHYSICS
19. (65)
Since collision is perfectly elastic, the speed of the ball just before collision is
equal to the speed of the ball just after collision. Hence time of descent is equal to
the time of ascent. Therefore time taken by the ball to reach the ground from the
1.5 m
bottom of the window is 1 sec. H
Let u be the speed of the ball when it is at the top of the window
1 1 1 1
 1.5 = u +  10 x . ( s  ut  at2 )
10 2 100 2
 u = 14.5 m/s
ball is dropped hence its initial speed is 0
If t be the time taken by the ball to acquire the speed of 14.5 m/s, then
14.5 = 0 + 10  t ,  v  u  at 
 t = 1.45 sec
Hence total time of descent is given by
1
T = 1.45 + + 1 = 2.55 s
10
1 2 1
 10   2.55  = 32.5 m
2
If H be the height of the building, then H = 0 + gt  H=
2 2
20. 2
The displacement of the body during the time t as it reaches the point of projection
1 2 2v 0
 S = 0  v0t  gt = 0  t
2 g
During the same time t, the body moves in absence of gravity through a distance
D = v.t, because in absence of gravity g = 0
 2v  2v 2
 D   D  v 0  0   0 …(1)
 g  g
In presence of gravity the total distance covered is
v2 v2
= D = 2H = 2 0  0 …(2)
2g g
(1)  (2)  D  2D.
21. (8)
Displacement over the interval t = 0 to t = 2(2n – 1) seconds.
2( 2n 1) 2( 2n 1)
  8   8
=   cos (2n  1)  cos 0 
16
= 4  sin t dt    cos t 
2   2 0  
m
0
16 8
 average velocity = = m/s.,
22n  1 2n  1
22. (1)
u 5 2 2
t=  = 1 sec.
g sin  10
23. (3)
If v 0 is the initial velocity y
vp = v0 cos 
Normal acceleration at 0 = g cos  
P
Normal acceleration at P = g v0 vP
Hence if r0 and rp be radii of curvature at O & P (an)p
respectively. 
O x
v02
v cos 
2 2
r0 = & rp = 0 (an)0
g cos  g
Hence the required ratio
r 3 3
= p =cos3  = .
r0 8
24. (10)
dv v 2 100 19
at   4t  1 = 9 m/s2, ar    19 m/s2
dt r 100
 
2
anet  92  19  100 = 10 m/s2
25. (15)
Horizontal component of velocity of A is 10 cos 60° or 5 m/s which is equal to the velocity of B in
horizontal direction. They will collide at C if time of flight of both the particles are equal i.e.
tA = tB
2u sin  2h  1 
  h  gtB2 
g g  2 
2u2 sin2 
or h =
g
2
 3
2(10)  2

 2  = 15 m
10
26. (37)
For collision, vB=10 3 m/s
vA sin  = vB sin 60°
vA=25m/s
3
25 sin  = 10 3   60°
2
x
3
sin  =
5
or  = 37°
27. (BD)
10 1
Velocity of A with respect to river  m/s = m/s
120 12
30 1
Flow velocity   m/s
120 4
10 1
Velocity of B along y-axis with respect to earth  m/s  m/s
120 12
30  5 5
Velocity of B along x-axis with respect to earth  m/s  m/s
120 24
28. (A,C,D)
29. (ACD)
Velocity of A relative to B is 4v
L
So time, T 
4v
Velocity of A, relative to board is = v
L L
Displacement A, relative to board  v
4v 4
Velocity of B, relative to board = 3v
3L
 Displacement of B, relative to board 
4
30. (ABCD)
u2 u2
h1  sin2  and h2  cos2 
2g 2g
u2
R 2sin  cos 
g
u2 2gh1 2gh2
R 2 , R  4 h1h2
g 4 4
t1 2u sin  / g
  tan 
t 2 2u sin  90    / g
31. (BC) a(m/s)2
1 v2
Area   10   6  4   6
2 2 4
v = 10 m/s
1 v2
Area upto 30 m   30  6  30
S(m)
2 2 10
v 2  180
v max  180  14
32. (AC)
v AB  3  a ˆi  3  b ˆj (10,5)
B
aAB  o vAB
 3  a   2  10 and  3  b   2  5
A
1 (0,0)
a = –2 and b =
2
33. (A)
t1t 2
When both moves in same direction, t  
 t1  t 2
t1 t2
34. (B)
t1t 2
When both moves in opposite direction, t = 
 t1  t 2
t2 t1
35. (A)
Slope of Vy graph is –g
10
 g
t1
36. (A)
uy
tan   1
ux
SECTION III : CHEMISTRY
37. (8)
38. (6)
39. (2)
Total energy in ground state = – E
2E
Potential energy at excited state  
x2
2E E
 2
 , x2 = 4, x = 2
x 2
40. (9)
As the last electron enter ‘f’ orbital hence group = 3
As there are 6 maximas therefore largest principal quantum number (n) = 6
 period = 6
Group + period = 9
41. (5)
Electron is in 5s orbital
42. (9)
Out of 18 electrons present in 3rd shells.

1
Will have s  
2
43. (4)
36 ml H2O = 36 g H2O = 2 mole
 1 mole H2O contains 2  NA H atoms
 2 mole H2O contains 4  NA H atoms
44. (2)
No. of moles = 1
No. of molecules = NA
No. of lone pair = 2 NA
45. (ABC)
n2
rn  a0 
z
72 12
r7  r1  a0   a0 
1 1
 a0  49  1  a0  48
62 12
r6  r1  a0   a0 
1 1
 a0  35
52 11
r5  r1  a0   a0 
1 1
 a0  24
46. (AC)
w  7.5  1019 J
  1220Å
w  hv 0
w 7.5  1019 J
 v0  
h 6.67  1034 Js
v 0  1.135  1015 s1
hc hc 1 1  hc hc
  mv 2  2 mv  ev 
2
   ev
 0 2    0
hc hv0 6.6  1034  3  108 6.6  1034  1.135  1015
v     34.375  4.68
e e 1.6  1019  360  1010 1.6  1019
hv 0  1.6  10 19  5.46
7.49  1019  8.736  1019
6.6  10 34  3  1010
1.6226  10 8 

  1.220  10    1220  107 m
7
  1220Å
c 3  108
v 
 1220  107
v  2.45  1012
47. (ACD)
Since masses are different, hence, 2nd orbit of 1H1, 1H2, 1H3 will have different energies.
Lyman – UV
Balmer – Visible
Paschen 
Brackett  Infrared
Pfund 
48. (AC)
2r3  n
n2
2a0   n
Z
32
2a0   3
1
  6a0
  6x a0  x
h

mv
h h
v 
m 6xm
49. (CD)
2r  n
h
2r2  n
mv
n2 h
2a0  n
Z mv
n h
2a0  
Z mv
hZ
v
2a0  nm
h 1
v
2a0  2  m
h
v
4a0m
a0 = Bohr’s radius
For sixth orbit of Li+2
h3
v  for Li, Z = 3
2a0  6m
h h
 
2a0  2m 4a0m
h 6.6  1034
v 
4a0m 4  3.14  0.529  1019  9.1 10 31
v = 1.09 × 10–6 m/s
c
 1.09  106 m/s
274
50. (BC)
n – l –1 = no. of radial nodes;
= no. of angular nodes.
n – 1 = Total no. of nodes
n – l – 1 = l  n – 1 = 2l
51. (B)
11.2 1
Moles of H2 produced  
22.4 4
3 1
mole of Fe needed  
4 2
3 1
mass of Fe needed    56  21 gm
4 2
52. (B)
3
Total iron recovered  moles
8
3
it is equally recovered in (ii) and (ii) hence mole of Fe is produced in both the reaction.
16
4 3 1
 moles of CO needed   
3 16 4
4 3 1
moles of H2 needed   
3 16 4
1
 mass of water gas needed   28  2 7.5 gm
4
53. (B)
4KZe2
r0 
M0K 02
4KZe2
 2r0 
M0 v 2
 r0 v 02  2r0 v 2
v0
 v 
2
54. (C)
4KZe2
Given R 
M0 v 02
4KZe2
 R  2
 4R
v 
M0  0 
 2 
4R  R
 % error   100  300%
R

Biweekly Test - 3 (Advanced) : DATE: 23/06/2018 TIME: 60 Min. AS: (PCM)

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Biweekly Test - 3 (Advanced) : DATE: 23/06/2018 TIME: 60 Min. AS: (PCM)

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Biweekly Test – 3 (Advanced)

DATE : 23/06/2018 TIME : 60 Min.

One or more than choice type

(A) a  5 (B) b  20 (C) c  18 (D) a  c  d  21

One or more than choice type

(D) He cannot reach P if u > v

A projectile is thrown from the origin in x-y plane, Vy(m/s) Vx(m/s)

35. What is the value of t1?

SECTION III : CHEMISTRY

Out of 18 electrons present in 3rd shells.

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