Download as pdf or txt
Download as pdf or txt
You are on page 1of 7

Energy Conversion and Management 56 (2012) 199–205

Contents lists available at SciVerse ScienceDirect

Energy Conversion and Management


journal homepage: www.elsevier.com/locate/enconman

Evaluation of some thin-layer drying models of persimmon slices (Diospyros kaki L.)
_
Ibrahim Doymaz ⇑
Department of Chemical Engineering, Yildiz Technical University, 34210 Esenler, Istanbul, Turkey

a r t i c l e i n f o a b s t r a c t

Article history: The effect of blanching and drying temperature (50, 60 and 70 °C) on drying kinetics and rehydration
Received 22 September 2010 ratio of persimmons under hot-air drying was investigated. It was observed that both the drying temper-
Received in revised form 28 November 2011 ature and blanching affected the drying time. The shortest drying times and highest rehydration ratios
Accepted 30 November 2011
were obtained from blanched samples. Six thin-layer drying models were evaluated in the kinetics
Available online 29 December 2011
research. The fit quality of the proposed models was evaluated by using the determination of coefficient
(R2), reduced chi-square (v2) and root means square error (RMSE). The Midilli et al., Page and Weibull
Keywords:
models showed a better fit to experimental drying data as compared to other models. Effective moisture
Persimmon
Air drying
diffusivity (Deff) ranged from 7.05  1011 to 2.34  1010 m2/s calculated using the Fick’s second law.
Rehydration ratio The activation energies of blanched and control samples determined from slope of the Arrhenius plot,
Effective moisture diffusivity ln(Deff) versus 1/(T + 273.15), was 30.64 and 43.26 kJ/mol, respectively.
Activation energy Ó 2011 Elsevier Ltd. All rights reserved.

1. Introduction improving existing drying systems or even for the control of the
drying process. Many mathematical models have proposed to de-
Persimmon (Diospyros kaki L.) grows in subtropical and warm scribe the drying process, of them, thin-layer drying models have
temperate climates. World-wide production of persimmon is 4.01 been widely in use. These models can be categorized as theoretical,
million tonnes in 2009 [1]. It is an important fruit in China, Japan semi-theoretical, and empirical [9]. Many studies have emphasized
and Korea and is also gaining popularity in the Mediterranean drying kinetics and thin-layer drying models for fruits and vegeta-
countries including Turkey [2]. Persimmon is relatively high con- bles – peach [6], apricot [10], apple [11–14], yam [15], berberis
tent of dietary fibers, total and major phenolics, main minerals, [16], mulberry [17], black grape [18] and carrot [19]. Some works
and trace elements make persimmon preferable for healthy [3]. It have been published concerning processing attributes of persim-
is also a good source of fiber and vitamins, mainly A and C. It is mons. Cárcel et al. [5] studied the effect of high-intensity
mainly eaten fresh, but can be frozen, canned or dried and can ultrasound on drying kinetics of persimmon slices. They reported
be stored for up to 6 month in modified or controlled atmospheres that the high-intensity ultrasound increased the drying rate at
[4]. The dried persimmon portions could be used as ingredient in the lowest air velocities. Nicoleti et al. [20] investigated the influ-
products such as muesli, snacks and breakfast cereals [5]. ence of drying conditions (temperature: 40–70 °C, air velocity:
Drying is probably the oldest and the most important method of 0.8–1.2 m/s) on ascorbic acid during convective drying of whole
food preservation practiced by humans. This process improves the persimmons. They reported that degradation rates of ascorbic acid
food stability, since it reduces considerably the water and microbi- were higher drying temperatures, independent of the necessary
ological activity of the material and minimizes physical and chem- time to attain the desired moisture content. However, study on
ical changes during its storage. Traditionally, fruits and vegetables drying kinetics and activation energy of persimmon in thin-layer
are dried in open sunlight. However, sun drying is depending on drying has not been reported yet. The objectives of this study were:
weather, affecting the homogeneity and quality of the final prod- (a) to study the effect of blanching on the drying time and rehydra-
uct. Moreover, the products are prone to microbial and other con- tion ratio, (b) to fit the experimental data to six mathematical
taminations [5]. To overcome these problems, the use of industrial models, and (c) to compute effective moisture diffusivity and
dryers (solar or convective dryers) should be used [6,7]. activation energy of persimmon slices.
Drying is a complex thermal process in which unsteady heat
and moisture transfer occur simultaneously [8]. From an engineer-
ing point of view, it is important to develop a better understanding 2. Material and methods
of the controlling parameters of this complex process. Mathemat-
ical models of the drying processes are used for designing new or 2.1. Material

⇑ Tel.: +90 212 383 47 48; fax: +90 212 383 47 25. Fresh persimmons (Diospyros kaki L.) were obtained from Isk-
E-mail address: doymaz@yildiz.edu.tr enderun (Hatay, Turkey). The selected fruits showed uniform color

0196-8904/$ - see front matter Ó 2011 Elsevier Ltd. All rights reserved.
doi:10.1016/j.enconman.2011.11.027
200 _ Doymaz / Energy Conversion and Management 56 (2012) 199–205
I.

and regular size. Samples were stored in a refrigerator at 4 °C until content of the samples were determined and used to calculate the
processing (2–3 days). The persimmons were washed with tap moisture ratio.
water, peeled and sliced manually by thickness of 5 mm and di- The drying rate (DR) of persimmon slices was calculated using
vided into two lots before use. One lot of samples was blanched Eq. (2):
in hot water at 70 °C for 2 min. The hot water treated slices were
M t  M tþDt
then immediately cooled down in tap water at room temperature DR ¼ ð2Þ
Dt
to remove excess heat, and placed on tissue paper to absorb the ex-
cess surface water prior to drying (BLANCH). The other lot was un- where Mt+Dt is moisture content at t + Dt (kg water/kg dm), t is the
blanched (CONTROL). Moreover, some persimmons were washed time (min) and Dt time difference (min).
with tap water, peeled and sliced manually by thickness of 3 and The drying data obtained were fitted to six thin-layer drying
8 mm. models that are detailed in Table 1 using the nonlinear least
squares regression analysis. Statistical analyses of the experimen-
2.2. Experimental apparatus tal data were performed by using the software package (Statistica
6.0, Statsoft Inc., Tulsa, OK). The determination of coefficient (R2) is
The drying apparatus was a pilot-scale cabinet dryer that is de- one of the primary criteria for selecting the best model to define
scribed previously by Doymaz [10]. Cabinet dryer basically consists the drying curves. In addition to R2, reduced chi-square (v2) and
of a centrifugal fan to supply the air-flow, an electric heater, an air root mean square error (RMSE) are used to determine the quality
filter and an electronic proportional controller. The air temperature of the fit. These parameters can be calculated by using the follow-
was controlled by means of a proportional controller. Air velocity ing equations:
was regulated by a centrifugal fan and fan speed control unit.
P
N
The velocity was measured with TESTO 440 Vane Probe Anemom- ðMRexp;i  MRpre;i Þ2
eter (AM-4201, Lutron, Taipei, Taiwan), and flowed horizontally 2
v ¼ i¼1
ð3Þ
through the samples. The air passed from heating unit and heated Nz
to the desired temperature and then channelled to the drying bas- " #1=2
ket. The samples were dried in the perforated square basket, which 1X N

had a flow cross-section of 30 cm  30 cm. Weight loss of samples RMSE ¼ ðMRpre;i  MRexp;i Þ2 ð4Þ
N i¼1
was recorded by using a digital balance (model BB3000, Mettler-
Toledo AG, Grefensee, Switzerland) with a sensitivity of 0.1 g. In these equations, MRexp and MRpre are the experimental and pre-
dicted dimensionless moisture ratios; N is the number of observa-
2.3. Experimental procedure tions; z is the number of constants. The best model was selected
to have the highest R2 and the lowest v2 and RMSE [11,14,17,32,33].
Drying experiments (slice thickness: 5 mm) were performed at
drying temperatures varying from 50 to 70 °C, with 10 °C incre- 2.5. Determination of effective moisture diffusivity
ment, and a constant air velocity of 2 ± 0.1 m/s for all circum-
stances. In addition to this experiments, the persimmon slices The effective moisture diffusivity is an important transport
(control; slice thickness: 3 and 8 mm) were dried at air tempera- property in food and other materials drying processes modeling,
ture of 60 °C. The dryer was started about 30 min before drying being a function of temperature and moisture content in material
experiments to achieve steady-state conditions. For each experi- [24]. Fick’s second law of diffusion equation, symbolized as a
ment, the 100 ± 2 g of persimmon slices was distributed uniformly mass-diffusion equation for drying agricultural products in a fall-
into the perforated basket as a thin-layer. Sample weight was re- ing rate period, is shown in the following equation:
corded at regular time intervals (15 min). Drying process was
stopped when the moisture content of the samples was about @M
¼ Deff r2 M ð5Þ
20 ± 0.5% (w.b.). The dried product was cooled and packed in @t
low-density polyethylene bags that were heat-sealed. All the dry- The solution of diffusion equation Eq. (5) for slab geometry is solved
ing experiments were conducted in triplicate and the average of by Crank [34], and supposed uniform initial moisture distribution,
the moisture content at each value was used for the drawing of negligible external resistance, constant diffusivity and negligible
the drying curves. shrinkage:
The average initial moisture content of persimmons was found 2
 2      3
p Deff t p2 Deff t p2 Deff t
to be 75.2 ± 0.2% (w.b.), as determined by using vacuum oven at exp  þ 1
exp 9 þ 1
exp 25 þ
8 6 4L 2 9 4L 2 25 4L 2
7
70 °C for 24 h following the Association of Official Analytical MR ¼ 2 4   5
Chemists [21].
p 1 p 2D t
exp 49 4L2   eff
49

ð6Þ
2.4. Mathematical modeling of drying curves
2
where Deff is the effective moisture diffusivity (m /s), t is the drying
The moisture content of drying sample at time t can be trans- time (s), L is the half-thickness of samples (m) and n is a positive
formed to be moisture ratio (MR):
Mt  Me Table 1
MR ¼ ð1Þ
M0  Me Thin-layer drying models applied to the persimmon slices drying curves.

where Mt, M0 and Me are the moisture content at any time of drying, Model Mathematical equation Refs.
initial moisture content and equilibrium moisture content Lewis MR = exp(kt) [22]
(kg water/kg dm), respectively. The equilibrium moisture contents Henderson and Pabis MR = a exp(kt) [23]
of samples at different temperatures used in the drying runs were Logarithmic MR ¼ a expðktÞ þ c [6,17,24]
Page MR = exp (ktn) [25–27]
obtained by the dynamic model. About three grams of samples were n
Midilli et al. MR ¼ a expðkt Þ þ bt [11,28–30]
exposed to 50, 60 and 70 °C air temperatures in the dryer until the Weibull MR ¼ expððbt Þa Þ [31]
weight loss of sample was ceased. Then, the equilibrium moisture
_ Doymaz / Energy Conversion and Management 56 (2012) 199–205
I. 201

integer. For long drying time, the Eq. (6) can be simplified as Eq. (7) 3.2
by taking the first term of series solution and expressed in a CONTROL; 50°C
logarithmic form [35]: 2.8 BLANCH; 50°C
CONTROL; 60°C
   

Moisture content (kg water/kg dm)


8 p2 Deff t 2.4
BLANCH; 60°C
ln MR ¼ ln  ð7Þ CONTROL; 70°C
p2 4L2
BLANCH; 70°C
2.0
From Eq. (7), a plot of ln MR versus drying time gave a straight line
with a slope (K) of:
1.6
p2 Deff
K¼ ð8Þ
4L2 1.2

0.8
2.6. Computation of activation energy
0.4
The dependence of the effective diffusivity on temperature is
generally described by the Arrhenius equation Eq. (9) [26,36]: 0.0
  0 100 200 300 400 500
Ea Drying time (kg water/kg dm)
Deff ¼ D0 exp  ð9Þ
RðT þ 273:15Þ
Fig. 1. Drying curves of persimmon slices at different temperatures.
Here D0 is the pre-exponential factor of Arrhenius equation in m2/s,
Ea is the activation energy in kJ/mol, R is the universal gas constant 0.032
CONTROL; 50°C
in kJ/mol K, and T is the drying air temperature in °C.
BLANCH; 50°C
0.028 CONTROL; 60°C

Drying rate (kg water/(kg dm*min)


2.7. Rehydration ratio BLANCH; 60°C
0.024 CONTROL; 70°C
BLANCH; 70°C
Rehydration of dried persimmon slices was performed in dis-
tilled water at 20 °C (±1 °C). About three grams of the dried product 0.020
was added to 300 ml distilled water, in a 400 ml beaker. Weights of
the samples were measured after 4 h. Subsequently, the samples 0.016

were drained, blotted with tissue paper, and weighed. The rehydra-
tion ratio (RR) was calculated as follows: 0.012

Wr 0.008
RR ¼ ð10Þ
Wd
0.004
where Wr is the weight rehydrated sample (kg), and Wd is the
weight of dried sample (kg). 0.000
0.0 0.4 0.8 1.2 1.6 2.0 2.4 2.8 3.2

3. Results and discussions Moisture content (kg water/kg dm)

Fig. 2. Variation of drying rate as a function of moisture content at various


3.1. Drying characteristics temperatures.

The characteristics of drying curves for control and blanched The blanching is very important parameter that affects the dry-
persimmon sliced to 5 mm thickness at 50, 60 and 70 °C are shown ing time. The blanched samples were found to have a shorter dry-
in Fig. 1. Fig. 2 shows the changes in drying rate as a function of ing time compared to the control samples. The drying time
moisture content at the same temperatures. It is clear that the required to reach final water content 20 ± 0.5% (w.b.) for blanched
moisture content and drying rate decrease continuously with dry- samples was 315, 285 and 180 min at 50, 60 and 70 °C, respec-
ing time. The drying rate was rapid during the initial period but it tively. Corresponding values for control samples were 450, 345
became very slow at the last stages during the drying process. As and 240 min at the same respective temperatures. The drying time
shown in Fig. 2, there was no constant drying rate period, and was reduced by about 21–42.8% for persimmon slices, as drying
the entire drying process occurred in the falling-rate period. This temperature was raised from 50 to 80 °C. Similar findings were re-
shows diffusion in dominant physical mechanism governing mois- ported in drying of various agricultural products [12,36,41].
ture movement in the samples. The results were generally in Fig. 3 shows the effect of slice thickness on the moisture content
agreement with some of the literature on the drying of various variations at 60 °C. As expected, the total drying time increased
food products [15,25,26,37,38]. with increasing slice thickness. For 60 °C, decreasing the slice
According to the results in Fig. 1, the drying air temperature and thickness from 8 mm to 3 mm decreased the total drying time
blanching had a significant effect on the moisture content of the about 123.5%. Thinly products dried faster due to the reduced dis-
persimmon slices as expected. The results showed that drying time tance the moisture travels. The similar observation was found by
decreased greatly when drying temperature increased. The drying Kaya et al. [19] for carrot slices and Lee and Hsieh [39] for straw-
time required to reach the final moisture content of control sam- berry leathers.
ples were 450, 345 and 240 min at the drying air temperatures of
50, 60 and 70 °C, respectively. The decrease in drying time with 3.2. Fitting of drying curves
an increase in the drying air temperature has been reported for
many agricultural products such as orange slices [26], apple [35], The moisture content data obtained at different air tempera-
strawberry [39], and carrot [40]. tures were converted to dimensionless moisture ratio Eq. (1) and
202 _ Doymaz / Energy Conversion and Management 56 (2012) 199–205
I.

3.5 Table 3
Result of statistical analysis on the mathematical models for blanched samples.
d: 3 mm
3 d: 5 mm T (°C) Model R2 v2 RMSE
Moisture content (kg water/kg dm)

d: 8 mm 50 Lewis 0.9973 0.00021 0.04894


Henderson and Pabis 0.9986 0.00011 0.03535
2.5
Logarithmic 0.9988 0.00010 0.03443
Page 0.9993 0.00006 0.02716
2 Midilli et al. 0.9997 0.00005 0.01908
Weibull 0.9993 0.00006 0.02716
60 Lewis 0.9947 0.00045 0.07805
1.5
Henderson and Pabis 0.9971 0.00025 0.05369
Logarithmic 0.9991 0.00007 0.02717
1 Page 0.9991 0.00001 0.01004
Midilli et al. 0.9992 0.00001 0.01007
Weibull 0.9991 0.00001 0.01004
0.5
70 Lewis 0.9858 0.00142 0.11471
Henderson and Pabis 0.9902 0.00106 0.09673
0 Logarithmic 0.9958 0.00050 0.06267
0 100 200 300 400 500 600 Page 0.9993 0.00007 0.02267
Drying time (min) Midilli et al. 0.9995 0.00006 0.02265
Weibull 0.9994 0.00007 0.02270
Fig. 3. Effect of slice thickness on moisture content of control samples during air
drying at 60 °C.

3.3. Effective moisture diffusivity


then fitted to six thin-layer drying models (Table 1). Non-linear
regression analysis was used to estimate the parameters of those The values of the effective moisture diffusivity were calculated
six models. The statistical results from models are summarized using Eq. (8) and are shown in Fig. 7. The Deff values were varied in
in Tables 2 and 3. The best model describing the thin-layer drying the range of 7.05  1011 m2/s to 2.34  1010 m2/s. It was noted
characteristics of persimmon slices was chosen as the one with the that Deff values increased greatly with increasing drying tempera-
highest R2 values and the lowest v2 and RMSE values. The R2 values ture. When samples were dried at higher temperature, increased
of Lewis, Henderson and Pabis, Logarithmic, Page, Midilli et al., and heating energy would increase the activity of water molecules
Weibull models were all above 0.98. The statistical parameter esti- leading to higher moisture diffusivity [36]. Furthermore, the values
mations showed that R2, v2 and RMSE values were ranged from of effective moisture diffusivity of blanched samples were higher
0.9823 to 0.9998, 0.00001 to 0.00158 and 0.01004 to 0.14242, than those of control samples at all drying temperatures. This
respectively. Of all the models tested, the Midilli et al., Page and may be due to the fact that the blanching pretreatment considered
Weibull models give the highest values of R2 and the lowest values in this study aids water movement to the persimmon surface for
of v2 and RMSE. Generally R2, v2 and RMSE values of the selected subsequent evaporation thus increasing the value of the effective
models in all experiments were varied between 0.9983–0.9998, moisture coefficients. The values of Deff obtained from this study
0.00001–0.00013 and 0.01004–0.05519, respectively. Accordingly, lie within in general range 1012–108 m2/s for drying of food
the Midilli et al., Page and Weibull models were selected as the materials [42]. The values of Deff are comparable with the reported
suitable models to represent the thin layer drying characteristics values of 2.27–4.97  1010 m2/s for the drying of apples in the
of persimmon slices. Figs. 4–6 compare experimental data with temperature range of 40–60 °C [12], 3.32 to 90.0  1010 m2/s for
those predicted with the Midilli et al., Page and Weibull models berberis fruits at 50–70 °C [16], 6.27 to 35.0  1010 m2/s for or-
for persimmon slices at 50, 60 and 70 °C. The prediction using ange slices at 40–80 °C [26], 2.40 to 12.1  109 m2/s for straw-
the models showed MR values banded along a straight line, which berry leathers at 50–80 °C [39], 1.19 to 4.27  109 m2/s for
showed the suitability of these models in describing the drying
characteristics of persimmon slices.
1.0
Table 2 50°C; CONTROL
Result of statistical analysis on the mathematical models for control samples. 50°C; BLANCH
60°C; CONTROL
T (°C) Model R2 v2 RMSE 0.8 60°C; BLANCH
50 Lewis 0.9965 0.00027 0.07643 70°C; CONTROL
Henderson and Pabis 0.9972 0.00022 0.06856 70°C; BLANCH
Logarithmic 0.9978 0.00018 0.06180
Predicted MR

0.6
Page 0.9983 0.00013 0.05519
Midilli et al. 0.9984 0.00013 0.05446
Weibull 0.9983 0.00013 0.05519
0.4
60 Lewis 0.9986 0.00010 0.03461
Henderson and Pabis 0.9993 0.00005 0.02160
Logarithmic 0.9996 0.00003 0.01927
Page 0.9997 0.00002 0.01829 0.2
Midilli et al. 0.9998 0.00002 0.01831
Weibull 0.9997 0.00002 0.01829
70 Lewis 0.9823 0.00158 0.14242
Henderson and Pabis 0.9890 0.00110 0.11317 0.0
0.0 0.2 0.4 0.6 0.8 1.0
Logarithmic 0.9960 0.00040 0.06615
Page 0.9993 0.00006 0.02641 Experimental MR
Midilli et al. 0.9994 0.00006 0.02593
Weibull 0.9993 0.00006 0.02641 Fig. 4. Comparison of experimental and predicted moisture ratio by the Midilli
et al. model.
_ Doymaz / Energy Conversion and Management 56 (2012) 199–205
I. 203

1.0 3.4. Activation energy


50°C; CONTROL
50°C; BLANCH The activation energy can be determined from the slope of
0.8
60°C; CONTROL Arrhenius plot, ln Deff versus 1/(T + 273.15) Eq. (9). The ln Deff as a
60°C; BLANCH
function of the reciprocal of absolute temperature was plotted in
70°C; CONTROL
70°C; BLANCH
Fig. 8. The slope of the line is (Ea/R) and the intercept equals to
ln (D0). The results show a linear relationship due to Arrhenius type
Predicted MR

0.6
dependence. Eqs. (11) and (12) show the effect of temperature on
Deff of samples with the following coefficients:
For control samples:
0.4
 
5203:5
Deff ¼ 6:764  104 exp  ðR2 : 0:9904Þ ð11Þ
ðT þ 273:15Þ
0.2
For blanched samples:
 
3685:9
Deff ¼ 1:042  105 exp  ðR2 : 0:9624Þ ð12Þ
0.0 ðT þ 273:15Þ
0.0 0.2 0.4 0.6 0.8 1.0
Experimental MR The values of Deff for blanched and control samples found as 30.64
and 43.26 kJ/mol, respectively. These values are similar to those
Fig. 5. Comparison of experimental and predicted moisture ratio by the Page
proposed in the literature by several authors for different fruits
model.
and vegetables such as 22.66–30.92 kJ/mol in apples [14], 25.26–
72.47 kJ/mol in yams [15], 67.29 kJ/mol in seedless grapes [36]
1.0 and 30.46–35.57 kJ/mol in strawberry [39]. The values of activation
50°C; CONTROL energy were within the general range of 12.7 to 110 kJ/mol for
50°C; BLANCH various food materials [42].
60°C; CONTROL
0.8 60°C; BLANCH
70°C; CONTROL
3.5. Effect of blanching on rehydration ratio
70°C; BLANCH
Rehydration is widely used as a parameter for dried sample
Predicted MR

0.6
quality. It indicates the physical and chemical changes during dry-
ing as influenced by processing conditions, sample pretreatment
and composition [45]. Rehydration ratio values of persimmon
0.4
slices at a constant rehydration temperature of 20 °C, calculated
from Eq. (10), are shown in Fig. 9. Rehydration ratios of the
blanched samples were higher than those of control samples at
0.2 all drying temperatures, which means that structural damage
and cell shrinkage occurred less during drying process. This factor
adversely influenced the rehydration of blanched persimmons.
0.0 The rehydration tests show that the rehydration ratios of dried
0.0 0.2 0.4 0.6 0.8 1.0
blanched and control samples at 60 °C are higher than those of
Experimental MR
dried ones at other temperatures. An increase in temperature
Fig. 6. Comparison of experimental and predicted moisture ratio by the Weibull
model.
-22
CONTROL
BLANCH
2.5E-10

2E-10 -22.4
D eff (m2 /s)

1.5E-10 2
R = 0.9624
ln (Deff )

1E-10
-22.8
5E-11
BLANCH
0
50 CONTROL 2
60 -23.2 R = 0.9904
70
Air temperature (°C)

Fig. 7. Variation of effective moisture diffusivity with air drying temperature.


-23.6
0.0029 0.0030 0.0031
pumpkin at 40–80 °C [43], and 2.60–5.40  1010 m2/s for persim- 1/(T+273.15) (1/K)
mon slices at 50–80 °C [44]. These values are consistent with the
Fig. 8. Arrhenius-type relationship between effective moisture diffusivity and
present estimated Deff values for persimmon slices. reciprocal absolute temperature.
204 _ Doymaz / Energy Conversion and Management 56 (2012) 199–205
I.

4 [8] Sahin AZ, Dincer I. Prediction of drying times for irregular shaped multi-
CONTROL dimensional moist solids. J Food Eng 2005;71:119–26.
[9] McMinn WAM. Thin-layer modeling of the convective, microwave,
BLANCH
microwave-convective and microwave-vacuum drying of lactose powder. J
Food Eng 2006;72:113–23.
3 [10] Doymaz I. Effect of pre-treatments using potassium metabisulphide and
alkaline ethyl oleate on the drying kinetics of apricots. Biosyst Eng
2004;89:281–7.
Rehydration ratio

[11] Menges HO, Ertekin C. Modeling of thin layer drying of Golden apples. J Food
Eng 2006;77:119–25.
2 [12] Sacilik K, Elicin AK. The thin layer drying characteristics of organic apple slices.
J Food Eng 2006;73:281–9.
[13] Goyal RK, Mujjeb O, Bhargava VK. Mathematical modeling of thin layer drying
kinetics of apple in tunnel dryer. Int J Food Eng 2008;4(8). Article 8.
[14] Meisami-asl E, Rafiee S, Keyhani A, Tabatabaeefar A. Drying of apple slices (var.
1 Golab) and effect on moisture diffusivity and activation energy. Plant Omics J
2010;3(3):98–102.
[15] Falade KO, Olurin TO, Ike EA, Aworh OC. Effect of pretreatment and
temperature on air-drying of Dioscorea alata and Dioscorea rotundata slices.
J Food Eng 2007;80:1002–10.
0 [16] Aghbashlo M, Kianmehr MH, Samimi-Akhijahani H. Influence of drying
50 60 70 conditions on the effective moisture diffusivity, energy of activation and
Drying temperature (°C) energy consumption during the thin-layer drying of berberis fruit
(Berberidaceae). Energy Convers. Manage. 2008;49:2865–71.
Fig. 9. Rehydration curves for persimmon slices dried at 50, 60 and 70 °C. [17] Akpinar EK. Mathematical modeling and experimental investigation on sun
and solar drying of white mulberry. J Mech Sci Technol 2008;22:1544–53.
[18] Togrul IT. Modelling of heat and moisture transport during drying black
grapes. Int J Food Sci Technol 2010;45:1146–52.
above 60 °C had an adverse effect on the final rehydration ratio va- [19] Kaya A, Aydin O, Demirtas C. Experimental and theoretical analysis of drying
lue, which decreased with increasing temperature. This may be carrots. Desalination 2009;237:285–95.
indicative of a change in the product induced by temperature [20] Nicoleti JF, Silveira Jr V, Telis-Romero J, Telis VRN. Influence of drying
conditions on ascorbic acid during convective drying of whole persimmons.
and perhaps a loss of solids during rehydration process. Similar re- Dry Technol 2007;25:891–9.
sults have been reported by Cunningham et al. [46]. [21] AOAC, Official methods of analysis, Arlington, VA: Association of Official
Analytical Chemists; 1990.
[22] Roberts JS, Kidd DR, Padilla-Zakour O. Drying kinetics of grape seeds. J Food
4. Conclusions Eng 2008;89:460–5.
[23] Henderson SM, Pabis S. Grain drying theory. II. Temperature effects on drying
coefficients. J Agric Eng Res 1961;6:169–74.
Based on the experimental results reported herein, following [24] Liu X, Qiu Z, Wang L, Cheng Y, Qu H, Chen Y. Mathematical modeling for thin
conclusions can be made: layer vacuum belt drying of Panax notoginseng extract. Energy Convers
Manage 2009;50:928–32.
[25] Singh S, Raina CS, Bawa AS, Saxena DC. Effect of pretreatments on drying and
a) Blanched samples had shorter drying times than the control
rehydration kinetics and color of sweet potato slices. Dry Technol
samples. The drying time shortened with increasing drying 2006;24:1487–94.
temperature. [26] Rafiee S, Sharifi M, Keyhani A, Omid M, Jafari A, Mohtasebi SS, et al. Modeling
effective moisture diffusivity of orange slices (Thompson Cv.). Int J Food Prop
b) Generally, the rehydration ratio of the blanched samples was
2010;13:32–40.
higher than the control samples. [27] Aghbashlo M, Kianmehr MH, Arabhosseini A. Modeling of thin-layer drying of
c) Constant drying rate period was not observed, the drying potato slices in length of continuous band dryer. Energy Convers Manage
process took place in the falling-rate period. 2009;50:1348–55.
[28] Midilli A, Kucuk H, Yapar Z. A new model for single-layer drying. Dry Technol
d) The Midilli et al., Page and Weibull models gave the best rep- 2002;20:1503–13.
resentation of drying data under all experimental [29] Meziane S. Drying kinetics of olive pomace in a fluidized bed dryer. Energy
conditions. Convers Manage 2011;52:1644–9.
[30] Arslan D, Ozcan MM. Evaluation of drying methods with respect to drying
e) The effective moisture diffusivity was computed from Fick’s kinetics, mineral content and colour characteristics of rosemary leaves. Energy
second law, the values of which varied between 7.05  1011 Convers Manage 2008;49:1258–64.
and 2.34  1010 m2/s, over the temperature range. [31] Corzo O, Bracho N, Pereira A, Vásquez A. Weibull distribution for modelling air
drying of coroba slices. LWT – Food Sci Technol 2008;41:2023–8.
f) The values of activation energy of blanched and control sam- [32] Kirmaci V, Usta H, Menlik T. An experimental study on freeze-drying
ples were found to be 30.64 kJ/mol and 43.26 kJ/mol, behaviour of strawberries. Dry Technol 2008;26:1570–6.
respectively. [33] Kaleta A, Gornicki K. Some remarks on evaluation of drying models of red beet
particles. Energy Convers Manage 2010;51:2967–78.
[34] Crank J. The Mathematics of Diffusion. second ed. Oxford: Clarendon Press;
1975.
References [35] Falade KO, Solademi JS. Modelling of air drying of fresh and blanched sweet
potato slices. Int J Food Sci Technol 2010;45:278–88.
[36] Xiao HW, Pang CL, Wang LH, Bai JW, Yang WX, Gao ZJ. Drying kinetics and
[1] FAO (2009). Fao Stat: Agriculture Data. <http://faostat.fao.org/site/567/
quality of Monukka seedless grapes dried in an air-impingement jet dryer.
DesktopDefault.aspx?PageID=567#ancor> [accessed May, 2011].
Biosyst Eng 2010;105:233–40.
[2] Akbulut M, Ercisli S, Yildirim N, Orhan E, Agar G. The comparison of persimmon
[37] Seiiedlou S, Ghasemzadeh HR, Hamdami N, Talati F, Moghaddam M.
genotypes (Diospyrus kaki Thunb.) by using RAPD and FAME data. Roumanian
Convective drying of apple: mathematical modeling and determination of
Biotechnol Lett 2008;13:3851–8.
some quality parameters. Int J Agric Biol 2010;12:171–8.
[3] Luo Z. Extending shelf-life persimmon (Diosypros kaki L.) fruit by hot air
[38] Akpinar EK. Drying of mint leaves in a solar dryer and under open sun:
treatment. Eur Food Res Technol 2006;222:149–54.
Modelling, performance analyses. Energy Convers Manage 2010;51:2407–18.
[4] Telis VRN, Gabas AL, Menegalli FC, Telis-Romero J. Water sorption
[39] Lee G, Hsieh F. Thin-layer drying kinetics of strawberry fruit leather. Trans
thermodynamic properties applied to persimmon skin and pulp.
ASABE 2008;51:1699–705.
Thermochim Acta 2000;343:49–56.
[40] Zielinska M, Markowski M. Air drying characteristics and moisture diffusivity
[5] Cárcel JA, García-Pérez JV, Riera E, Mulet A. Influence of high intensity
of carrots. Chem Eng Process 2010;49:212–8.
ultrasound on drying kinetics of persimmon. Dry Technol 2007;25:185–93.
[41] Ramesh MN, Wolf W, Tevini D, Jung G. Influence of processing parameters on
[6] Kingsly RP, Goyal RK, Manikantan MR, Ilyas SM. Effects of pretreatments and
the drying of spice paprika. J Food Eng 2001;49:63–72.
drying air temperature on drying behaviour of peach slice. Int J Food Sci
[42] Zogzas NP, Maroulis ZB, Marinos-Kouris D. Moisture diffusivity data
Technol 2007;42:65–9.
compilation in foodstuffs. Dry Technol 1996;14:2225–53.
[7] Oztop HF, Akpinar EK. Numerical and experimental analysis of moisture
[43] Tunde-Akintunde TY, Ogunlakin GO. Influence of drying conditions on the
transfer for convective drying of some products. Int Commun Heat Mass
effective moisture diffusivity and energy requirements during the drying of
Transfer 2008;35:169–77.
_ Doymaz / Energy Conversion and Management 56 (2012) 199–205
I. 205

pretreated and untreated pumpkin. Energy Convers Manage [45] Feng H, Tang J. Microwave finish drying of diced apples in a spouted bed. J
2011;52:1107–13. Food Sci 1998;63:679–83.
[44] Telis-Romero J, Gabas AL, Menegalli FC, Telis VRN. Drying of persimmon: [46] Cunningham SE, McMinn WAM, Magee TRA, Richardson PS. Experimental
mathematical model for diffusivity as a simultaneous function of moisture study of rehydration kinetics of potato cylinders. Food Bioprod Process
content and shrinkage. In: Proceedings of the Second Inter-American Drying 2008;86:15–24.
Conference, Veracruz, Mexico; 2001. p. 243–51.

You might also like