Professional Documents
Culture Documents
Studies in The Right-First-Time Dyeing of Cellulose With Reactive Dyes: Role of Material-To-Liquor Ratio
Studies in The Right-First-Time Dyeing of Cellulose With Reactive Dyes: Role of Material-To-Liquor Ratio
If 1"1,1, ;I f
III' Ii III 'Ii J Ii I,JW~
",l ,. j J,J~ 1111
il", j" l"l,dl I ill'I'fl" IIU __ •
.•
The effect of variation in the material-to-liquor ratio on 37 commercially available reactive dyes (25
Procion and 12 Remazol) has been studied. It is observed that the extent of variation in the KlS value due to
the variation in material-to-liquor ratio is different for different dyes. Based on the effect of variation in
material-to-liquor ratio, the dyes have been classified into following three different groups : dyes which are
marginally affected ; dyes which are moderately affected ; and dyes which are significantly affected. The ...-
reproducibility of dyes which are marginally affected by the variation in material-to--liquor ratio is better
than that of the dyes of other two groups.
I[<,j I-
A
'/--
112 Black 1l0.67
121.12
150.22
Bril.Red116.94
134.36
107.98
107.93
Bri1.Yellow
YellowHE4R
Bril.RedM8B
259.95
432.61
211.03
II9
151.68
146.38
114.08
113.96
107.37
118.06
123.33
117.28
146.5
115.44
100
120.01
128.51
104.68
Bril.Red
BlueM4GD
100
100113.13
100.46
102.52
107.51
123.61
111.5
108.45
117.81
104.02
107.76
100.66
YellowMGR
GreenHE4BD
Bri1.Red
Bri1.Red 299.34
146.38
106.53
106.68
101.63
113.36
149.12
Bri1.Yellow
Gold. 102.61
II3.45
155.99
II7.71
2108.75
276.29
283.69
241.31
347.01
171.85
164.65
120.98
133.36
II6.35
182.8
125.6
182.29
172.92
127.35
104.66
134.13
179.26
268.15
307.99
198.19
178.91
105.52
130.32
136.31
II3.76399.47
100.26
121.58
Yellow
IIO.75
120.39
II4.19
EB
121.3
129.62
106.46
106.08
103.19
124.71
118.13
145.67
154.31
117.41
IIO.68
103.57
II7.14
119.33
116.76
152.61
122.41
126.07
104.99
121.03
128.59
II7.81
123.3
142.04
107.25
108.09
101.81
124.6
162.48
183.28
396.52
II HGR
102.12
110.75
122.9
138.67
104.01
101.06
101.23
107.49
146.68
134.98
100
283.27
131.57
166.76
II
112.39
208.6
Bril.Blue
Navy
Navy
Dye
Turq. 145.23
142.13
187.677.52
8.97
H8B
M5B
8.26H4G
Cone.
104.16
126.25
145.59
112.18
113.89
179.89
147.92
149.54
205.6101.88
II5.12
171.71
170.67
133.24
Blue
Bril.Orange
Bri1.0range
Blue
HEG
Category
SR1S
SRzoSRs
SRIO 1.09
HE3B
HE7B
4.89
108.39
1I5.33 H4BN
H5GHE6G
HER
H3R
M3RHR
H2R
M2R
HER ¥ Shade
2
0.2 %
INDIAN LEIBRETEXT. ofRES.,
dye JUNE 1998
(Group) Yellow 86
(Conte/)
YellowFG
RedRB 302.16
308.24
154.19
199.09
192.06
180.65
132.13
118.28
193.96
164.36
128.26
173.53
120.43
132.58
112.24
103:36
117.59
104.4
124.08
114.31
120.17
111.36
107.61
Bril.Blue
Brl.Red
Blue3R
Gold.100
Yellow 3218.89
135.08
135.14
],41.62
202.65
158.52
117.09
122.03
101.02
175.49
176.95
338.46
133.5
184.83
100142.47
297.83
286.66
361.72
219.73
160.38
123.93
173.75
112.37
Bril.Violet
Dye 154.22
158.61
130.06
145.81
145.66
Yellow
125.33
117.05
105.62
108.1
129.75
116.77
121.82
143.83
148.72
133.11
146.24
111.9
183.35
163.82
208.93
142.68
109.65
127.25
BlackRL-1D
BlackB-1D
106.59
Turq.BlueG
Bril.Orange
Category
100SRs
SR20
SRIO
SRIS GR-ID
5B-1D
BB-ID
151.94
119.535RRNL-ID
3R-1D 0.2
22
Shade
Table I-Strength % of reactive dyesof atdyevarious M:L ratios--Contd
ratios
(Group)
Sl
%
01:10-
Rl.94
I1:7
0.68
0.5
0.46
0.87
0.49
.98
0.2
.56
1:13
0.65
0.33
Table 2-CIE-DE %
. 0.2
.480.33
.54 Bl
0.5 CIE-DE
1.0 of Group value
1 dyes at M:L M:L ratios
at different the individual dyes. But, the structures of most of
Yl
0.2 Recipe the reactive dyes taken for the study are not yet
disclosed by the manufacturers. Once the dye
structures are known, the reason for this change in
the dye behaviour can be interpreted better.
4 Conclusion
Better shade control can be achieved if the
reactive dyes less sensitive to the M:L ratio
YI-Procion Yellow HE4R; BI-Procion Navy Blue HER; changes are used for dyeing. This is a small step
and RI-Procion Bril.Red HE3B towards RFT dyeing.
• M:L = 1: 10 is kept as reference
Table 3--CIE-DE of Group 3 dyes at different M:L ratios Acknowledgement
This work is a part of the research funded by the
Recipe CIE-DE value at M:L
YI BI RI 1:7 1:10- 1:13 Ministry of Textiles, Government of India. The
% % % .author is grateful to the Ministry for the financial
0.2 0.5 1.0 2.57 o 4.59 support.
0.5 1.0 0.2 5.6 o 4.47
1.0 0.2 0.5 6.26 o 3.67 References
0.5 0.5 0.5 4.91 o 4.26 J
1 Collishaw P S, Glover B & Bradbury M J, Soc Dyers
0.33 0.33 0.33 5.73 o 2.9 Colour, 108 (1992) 13.
2 Bradbury M J, Collishaw P S & Moorhouse S, Text Chern
YI-Procion Bril.Yellow H4G; BI-Procion Bril.Blue H5G; Color, 27 (1995) 19.
and RI-Procion Bril.Red H4BN
3 Bradbury M J, Collishaw P S & Moorhouse S, Book of
• M:L = I: 10 is kept as reference Papers (American Association of Textile Chemists &
I
1,)/ ,~ II i ,,,I
I, ,,1 I II I 1/, " J. 11,111lI1 •• lill 111111111
I'NII "I aH JH.' 11 I 111'1 '11'1
"'
;.
f-
l-