DELTA JUNIOR COLLEGE

II YEAR CHEMISTRY EAMCET PAPER

Named Reaction & Identification of Functional Group
Date: 14-08-2019 Time : 1 Hr.
Max. Marks : 40 M

1.
OH
OH OCH 3

(p - ethyl phenol) (p - methyl anisole) (p - ethyl benzyl alcohol)

Above compound can be differentiated by using the reagent:
(a) NaOH, Tollen’s reagent, FeCl3
(b) CrO3, Tollen’s reagent, FeCl3
(c) Tollen’s reagent, CrO3, FeCl3
(d) Na, Tollen’s reagent, FeCl3
2.
-
NH 3Cl NO 2
Cl
and

(P) (Q)
Above compounds (P) & (Q) can be differentiated by:
(a) amm.AgNO3 (b) NaOH
(c) FeCl3 (d) Both (a) & (b)
3. Which of the following give positive Tollen’s reagent test.
CO 2H CO 2H
(H 2C) 2 H2C
CO 2H CO 2H
(a) (b)
CO 2H

(c) CO 2H (d) HCO2H

4. Give a simple test to differentiate cyclohexane and cyclohexene
(a) Br2 / H 2O (b) Bayer’s reagent
(c) Tollen’s reagent (d) Both (a) and (b)
5. Give test to differentiate (Bromobenzene) Ph – Br and benzyl
bromide (PhCH2Br)
(a) (i) aq.KOH (ii) Na (b) AgNO3
(c) KMnO4 (d) All these
6. Test to differentiate between (CH 3OH ) and ( Ph − OH ) is/are:
methanol Phenol
(a) Litmus test (b) FeCl3
(c) Br2/H2O (d) All of these
7. Ethylamine and diethylamine cannot be differentiated by:
(a) Hinsberg test (b) Carbylamine test
(c) Iodoform test (d) both (a) and (b)
8. Lassaigne’s test for the detection of nitrogen will fail in the case
of:
(a) NH 2CONH 2 (b) NH 2CONHNH 2 .HC l
(c) NH 2NH 2 . HC l (d) C 6 H 5 NHNH 2 .2HC l
9. A compound which does not give a positive test in Lassaigne’s test for nitrogen
is:
(a) urea (b) hydrazine
(c) azobenzene (d) phenyl hydrazine
10. Which of the following reagent is used for the separation of
acetaldehyde from acetophenone?
(a) NH 2OH (b) NaOI
(c) Tollen’s reagent (d) C 6 H 5 NHNH 2
11.

(a) (b)

(c) (d)
12. What product would you expect ct to obtain from Grignard
reaction when an excess of phenylmagnesium bromide reacts
with dimethyl carbonate CH3OCOOCH3?

(a) (b)

(c) (d)
13.
OH
Ph C CH3
H2C CH3
Which of the following combinations can not be used to prepare alcohol given
above?
(a) PhMgBr + 2 − bu tanone 
NH C l
→ 4

O
||
(b) EtMgBr + Ph − C − CH 3 
NH C l
→ 4

O
||
(c) CH 3 MgBr + Ph − C − Et 
NH C l
→ 4

O
||
(d) EtMgBr + Ph − C − CH 2 − CH 3 
NH C l
→ 4

14.
RMgBr
 → Product; The product of the reaction is:

S
O O
(a) HSO2 − CH 2 − CH 2 − CH 2 − CH 2 − R
(b) H − SO2 (CH 2 )3 − R

(c)
MgBr
SO2
(d) H − SO2 (CH )3 − R
15. The reaction of elemental sulphur with Grignard reagent followed
by acidification leads to the formation of
(a) mercaptan (b) sulphoxide
(c) thioether (d) sulphonic acid
16.
Mg
Br 
Et2O → Predict major product of the reaction:

2 moles

(a) (b)

(c) (d)
17. An organic compound (A) on reduction gives compound (B). (B)
on treatment with CHCl3 and alcoholic KOH gives (C). (C) on
catalytic reduction gives N-methylaniline. The compound (A) is
(a) methyl amine (b) nitromethane
 (c) aniline (d) nitrobenzene
18. Phenyl
enyl isocyanide is prepared by which of the following
reactions?
(a) Rosenmund’s reduction (b) Carbylamine rection
(c) Reimer – Tiemann rection (d) Wurtz reaction
19. Na2S gives purple colour with sodium nitroprusside. Purple
colour has the formula
(a) Na2 Fe (CN )6 S  (b) Na2 Fe (CN )5 NOS 
(c) Na 4 Fe (CN )5 NOS  (d) KFe Fe (CN )5 COS 

20.

(a) H 3 PO 2 and H 2O (b) H + / H 2O (c) HgSO 4 / H 2SO 4 (d) Cu2C l 2

21. An organic compound (C3H9N) (A), when treated with nitrous
acid, gave an alcohol and N2 gas was evolved. (A) on warming
with CHCl3 and caustic potash gave (C) which on reduction gave
isopropylmethylamine. Predict the structure
struct of (A).

(a) (b) CH3CH2 – NH – CH3

(c) (d) CH3CH2CH2 – NH2

22. In a reaction of aniline a coloured product C was obtained

The structure of C would be

(a) (b)

(c) (d)
23. butyl bromide on treatment with sodium methoxide yeilds
Tert-butyl
(a) sodium tertiary butoxide (b) methyl tertiary butyl ether
(c) tert-butyl alcohol (d) iso--butylene

Mild oxid (i )CH 3 MgBr

24. (CH 3 )2 CHOH  → X 
 (ii ) HOH
→Y . Here Y is
(a) iso-butyl alcohol (b) tert--butyl alcohol
(c) iso-butylene (d) sec--butyl alcohol

25. What is the e products obtained when chlorine reacts with ethyl
alcohol in the presence of NaOH?
(a) CH3Cl (b) C2H5Cl (c) CCl3, CHO (d) CHCl3
26. An organic compound A reacts with methyl magnesium iodide to
form an addition product which on hydrolysis forms the
compound B. Compound B gives blue colour salt in Victor
Meyer’s test. The compounds A and B respectively are
(a) acetaldehyde, t-butyl alcohol (b) acetaldehyde, ethyl alcohol
(c) acetaldehyde, iso-propyl alcohol (d) acetone, iso-propyl alcohol
27. Benzenediazonium chloride on reaction with phenol in weakly
basic medium gives
(a) diphenyl ether hydroxyazobenzene
(b) p-hydroxy
(c) chlorobenzene (d) benzene
28. 0.24 mole of phenol was treated with excess of bromine in
presence
ence of water. All the phenol got quantitatively converted to
bromophenol. The number of moles of Br2 reacted were
(a) 0.24 (b) 0.36 (c) 0.72 (d) 0.48
29. Which product is obtained by Kolbe-Schmidt
Schmidt reaction?
(a) Salicylaldehyde (b) Cinnamic acid
(c) Salicylic acid (d) Phenetole
30. Which one of the following can differentiate between C2H5OHand
CH3OH?
(a) H2O (b) HCl (c) I2 + KOH (d) NH3

31. Which of the following reactions will not result in the formation
of carbon-carbon bonds?
(a) Reimer-Tremann reaction (b) Cannizzaro reaction
(c) Wurtz reaction (d) Friedel-Crafts
Friedel acylation

32. Acetamide is treated with the following reagents separately.

Which one of these would yield methyl amine?
(a) NaOH-Br2 (b) Sodalime (c) Hot con. H2SO4 (d) PCl5

33. Consider the following reaction

The product A is
(a) C6H5CHO (b) C6H5OH (c) C6H5COCH3 (d) C6H5Cl
34. How many aldols are formed when acetaldehyde and
propanaldehyde undergo aldol condensation?
(a) 2 (b) 4 (c) 3 (d) 8
CH 3COONa
35. ( X ) 
(CH 3CO )2 O
→ Cinnamic acid. Then ( X ) is

(a) (b) (c) (d)

36. The end product (C) in the following reaction sequence is
−
Br2 ,red P OH (aq ) ∆
CH 3CH 2COOH  ∆
→ A  → B → C

(a) CH2 = CH - COOH (b)

(c) (d)
37. What is the end product (Z) ?

(a) Phenolphthalein (b) Methyl orange

(c) Methyl red (d) Para red
38. The products A, B and C in the following sequence of reactions
respectively are

(a) cyclohexanone, benzoic acid, benzyl alcohol

(b) cyclohexanone, benzaldehyde, 2-benzylidene
benzylidene cyclohexanone
(c) cyclohexanecarboxaldehyde, benzaldehyde, benzyl alcohol
(d) cylcohexanone, benzaldehyde, 2-benzylethene
benzylethene cyclohexanone

39. Which reaction is suitable for preparing α − chloroacetic acid?

(a) Hell-Volhard Zelinksky reaction
(b) Stephen’s reaction (c) Perkin’s reaction (d) None of these

40. Which of the following will not be soluble in sodium hydrogen

carbonate?
(a) 2, 4, 6-Trinitrophenol (b) Benzoic acid
(c) o-Nitrophenol (d) Benzenesulplhonic acid
 DELTA JUNIOR COLLEGE
II YEAR CHEMISTRY EAMCET PAPER
Named and Identification of Functional & Group
Date: 14-08-2019 Time : 1 Hr.

KEY

Sl.No. Key Sl.No. Key

1. B 24 B
2. D 25 D
3. D 26 C
4. D 27 B
5. D 28 C
6. D 29 C
7. C 30 C
8. C 31 B
9. B 32 A
10. C 33 A
11. D 34 B
12. C 35 C
13. D 36 C
14. C 37 B
15. A 38 B
16. B 39 A
17. D 40 C
18. B
19. C
20. A
21. A
22. B
23. D