TARGET CH EMISTRY

DAILY PRACTICE PROBLEMS

JEE (ADVANCED) : 2014 DPP

COURSE NAME : URJAA (UR) DATE : 08.07.2013 to 13.07.2013 DPP NO. 07 TO 08

* Marked Questions are having more than one correct option.

DPP No. # 07
1. Calculate ratio of de-Broglie wavelength for an proton and -particle, if they are accelerated through
same potential difference V.

2. Calculate ratio of de-Broglie wavelength for a proton and -particle, if their kinetic energies are same.

3. Calculate the uncertainty in the velocity of a cricket ball having a mass 150 g, if the uncertainty in
its position is the order of 1 Å :
(A) 3.50 × 10–24 ms–1 (B) 7.20 × 10–24 ms–1
(C) 9.30 × 10 –22 ms –1 (D) None of these

4. The uncertainties in measurement of position and momentum of an electron are equal. Choose the

h
correct statement : (Given  7.2  10 18 )
4
(A) The uncertainty in measurement of speed = 8 × 1013 m/sec.
(B) The uncertainty in measurement of kinetic energy = h / 8m.
(C) The uncertainty in measurement of speed = 8 × 1016 m/sec
(D) Increasing the wavelength of light used in the experiment will decrease uncertainty in position and
increase the uncertainty in momentum.

5. If the light of wavelength 3 × 10–10 cm is used in used to detect an electron, then the uncertainty in
velocity will be : (h = 6.6 × 10–34 Js, m e = 9.1 × 10–31 kg).
(A) 106 m/s (B) 2 × 106 m/s (C) 2 × 107 m/s (D) 107 m/s

6. If numerical value of mass and velocity are equal for a particle, then its de-Broglie wavelength in
terms of K.E. is :
mh h
(A) (B) (C) both are correct (D) none is correct
2K.E. 2m2K.E.

7. The orbital angular momentum corresponding to n = 4 and m = – 3 is :

h 6h 3h
(A) 0 (B) (C) (D)
2 2 

8. Spin magnetic moment of xn+ (Z = 26) is 24 B.M. Hence number of unpaired electrons and value
of n respectively are :
(A) 4, 2 (B) 2, 4 (C) 3, 1 (D) 0, 2

9. Spin magnetic moments of V (Z = 23), Cr (Z = 24), Mn (Z = 25) are x, y, z respectively. Hence :

(A) x = y = z (B) x < y < z (C) x < z < y (D) z < y < x

10. Calculate :
(a) the value of spin only magnetic moment of Co3+ ion (in BM).
(b) the number of radial nodes in 3p-orbital
(c) the number of electrons with (m = 0) in Mn2+ ion.
(d) the orbital angular momentum for the unpaired electron in V4+.

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 DPP No. # 08
1. A d-block element has total spin value of + 3 or – 3. Then, the spin only magnetic moment of the element
is approximately :
(A) 2.83 B.M. (B) 3.87 B.M. (C) 5.9 B.M. (D) 6.93 B.M.

x+
2. Spin only magnetic moment of 25Mn ion is 15 B.M. . Then, the value of x is :
(A) 1 (B) 2 (C) 3 (D) 4

3. Spin only magnetic moment of 26Fe2+ ion is same as :

(A) 26Fe (B) 24Cr2+ (C) 28Ni4+ (D) All of these

h
4. Orbital angular momentum of an electron is 3 . Then, the number of orientations of this orbital

in space are :
(A) 3 (B) 5 (C) 7 (D) 9
5. The correct order of the magnetic moment of [25 24 24 is : Mn4+, Cr3+, Fe3+]
(A) Fe3+ > Cr3+ = Mn4+ (B) Fe3+ > Cr3+ > Mn4+
(C) Cr3+ = Mn4+ > Fe3+ (D) Fe3+ > Mn4+ > Cr3+
6. What is the maximum possible number of electrons in an atom with (n + l = 7) ?
7. Predict total spin for each configuration :
(a) 1s2 (b) 1s2 2s2 2p6 (c) 1s2 2s2 2p5
2 2
(d) 1s 2s 2p 3 (e) 1s 2s 2p 3s 3p 3d 4s2
2 2 6 2 6 5

8. In the following electronic configuration, some rules have been violated :

4
4p
1
4s
5
3d
I : Hund II : Pauli's exclusion III. Aufbau
(A) I and II (B) I and III (C) II and III (D) I, II and III
9. What is the potential difference through which an electron, with a de Broglie wavelength of 1.5 Å,
should be accelerated, if its de Broglie wavelength has to be reduced to 1 Å :
(A) 110 volts (B) 70 volts (C) 83 volts (D) 55 volts
10. A neutral atom of an element has 2 K, 8L, 9M and 2N electrons. Find out the following :
(a) Atomic number of element (b) Total number of s electrons
(c) Total number of p electrons (d) Total number of d electrons
(e) Valency of element (f) Number of unpaired electrons in element

ANSWER KEY
DPP No. # 07
p 2 2 p 2
1.  2.  3. (A) 4. (B) 5. (C) 6. (A)
 1  1
7. (D) 8. (A) 9. (C)

6h
10. (a) 24 or 4.9 BM (b) 1 (c) 11 (d)
2
DPP No. # 08
1. (D) 2. (D) 3. (D) 4. (C) 5. (A) 6. 32
7. (a) 0 × (± 1/2) = 0 (b) 0 × (± 1/2) = 0 (c) 1 × (± 1/2)
(d) 3 × (± 1/2) = ± 3/2 (e) 5 × (± 1/2) = ± 5/2
8. (C) 9. (C)
10. (a) 21 (b) 8 (c) 12 (d) 1 (e) + 2, + 3 (f) 1

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