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ParallRxn PDF
ParallRxn PDF
[A]
k1 [B]
[B] [A]
A -> B - d[A]
dt = k1 [A] + k2[A]
k2 [C]
-> C [C]
k = k1 + k2
t ->
- d[A]
dt = k [A] [A] = [A]o e-kt = [A]o e-(k1 +k 2 ) t
d[B] -(k +k ) t
dt = k1 [A] = k1 [A]o e 1 2
d[C] -(k +k ) t
dt = k2 [A] = k2 [A]o e 1 2
k [A]o -(k +k ) t
[B] = - 1
(k1 + k2) e 1 2 + c
k [A]o k [A]
0=- 1 c = (k1 + ko)
(k1 + k2) + c 1 2
k1 [A]o -(k +k ) t
(k1 + k2) ( 1 - e 1 2 )
[B] =
k2 [A]o -(k +k ) t
(k1 + k2) ( 1 - e 1 2 )
[C] =
[B] k1
[C] = k2
Opposed Reactions
kf
->
A + B <- C + D - d[A]
dt = kf [A] [B] - kr [C] [D]
kr
- d[A]
dt = kf [A] [B] - kr [C] [D] = 0
kf [C] [D]
kr = [A] [B] eq