HOME EXAMINATION-2017

GOVERNMENT DEHLI COLLEGE Max Marks : 85

Hussainabad, Federal “B”Area Karachi
Time (Hrs) : 03
CHEMISTRY -II
SECTION A
QUESTION # 1 MULTIPLE CHOICE QUESTIONS 17 Marks

i. Element having Atomic number 29 belongs to:

3rd period, IB group 3rd period, IIA group 4th period, IB group 4th period, IIA group
ii. Which is not correct for the formation of Atomic hydrogen from molecular hydrogen:
Absorbs 104kCal energy Required 5k oC Releases 104 kCal energy Electrical discharge at 1mm Hg
iii. Among them most stable form of hydrogen is
Proton (H+) Hydride ion (H-) Hydronium ion (H3O+) Nascent hydrogen [H]
iv. Among them one which has highest ionization enthalpy is:
Beryllium Magnesium Calcium Strontium
v. One which does not contain Magnesium is:
Magnesite Dolomite Barytes Carnalite
vi. The transition temperature for conversion of Rhombic Sulphur to Monoclinic Sulphur is:
92.5 oC 95.5 oC 112.5 oC 119.25 oC
vii. Caustic soda is used as fusing material when Bauxite ore contains impurity:
Iron oxide Silica Iron oxide & silica Dust particles
viii. Sulphuric acid is not used in the preparation of:
Plastic Fiber Fertilizers Glass
ix. Blacks spots were produced when cellulose or skin come in contact with:
Suhaga Rochelle salt Chile salt peter Lunar caustic
X The example of heterocyclic compound is:
Napthalene α-napthol Pyridine Paraffins
xi. Pyrogallol is used as developer used in photography is tri substituted benzene with hydroxyl group is:
2,4,6 tri hydric benzene 1,2,3 tri hydric benzene 1,3,5 tri hydric benzene 1,2,6 tri hydric benzene
xii. C4H6 is cyclic hydrocarbon, it is:
Butyne Cyclo butane Cyclo butene Cyclo butyne
xiii. Action of sodium metal on 2-chloro butane yields:
Octane Decane Hexane 3,4 di methyl hexane
xiv. Dehydration of ethanol is not possible in the presence of:
H2SO4 (concentrated) Al2O3 Zn/HCl Al2O3/H3PO4
xv. Sec. butyl alcohol in polar medium, treated with aqueous NaOH, undergoes mechanism:
Uni-molecular Uni-molecular Elimination Bi-molecular Substitution Bi-molecular Elimination
Substitution
xvi. Menadione is Anti-hemorrhagic compound found in:
Vitamin A Vitamin K Vitamin B12 Vitamin C
xvii. Alcohol dehydrogenase are the enzymes that are responsible for conversion of:
Lactate to Pyruvate Amylose to Glucose Alcohol to Aldehyde Carbondioxide to Carbonic acid

SECTION B
QUESTION # 2 SHORT ANSWER QUESTIONS 40 Marks
Attempt 10 questions in all. 5 each from inorganic & organic part, Each question carries equal marks.

INORGANIC CHEMISTRY
i. With the reference to following compounds: answer following:
Compound A B C D
Name Hypo Chromite Sandhur Sapphire

(a) chemical formula of “B” & “C” (b) color of “C” & “D”
(c) which of them are ores, & belongs to which element? (d) main use of “A” show by chemical equation
ii. Write down the equations for reactions in main compartment & denuder of Caster Kellner’s’ cell? Explain the purpose and
importance of “Denuder”?
iii. Give the IUPAC name of following complexes, identify which of the following complexes is/are chelates
(a) Mg[Zn(OH)4] (b) [Ni(DMG)2] (c) H[AuCl4] (d) [Cr(en)3]Cl3
iv. Explain the following behavior of transition metals (any 2):
(a) Catalytic ability (b) formation of Colored compounds (c) persistence of variable oxidation states
v. Write down the statements for arrangements of elements in systematic way in ascending order of their atomic masses?
vi. Give balanced chemical equation for following reactions:
(a) Hydrolysis of sodium aluminum hydride
(b) Fusion of sodium carbonate with sand
(c) passing mixture of carbondioxide & vapours of acetic acid over corroded lead
(d) action of hydrogen per oxide on potassium per manganate in neutral medium
vii. Explain the reason behind followings facts:
(a) Be & Mg forms polymeric hydrides on contrary with other members of group.
(b) Every period starts with alkali metals & ends at nobel gases.
(c) Boric acid & graphite are greasy in feel.
(d) Sulphur di oxide in purified cautiously before sending to contact tower.
 viii. By chemical equations give the use of following:
(a) Sulphuric acid as dehydrating agent (b) Nitric acid as oxidizing agent for SiO2
(c) CaOCl2 as bleaching powder (d) [Ag(NH3)2]OH as constituent in silvering of mirror
ORGANIC CHEMISTRY
ix. Draw the possible isomers of same type in following and define the type of isomerism involve in each?
(a) C6H12 (b) C4H10O (c) C3H7Br (d) C5H8
x. How Grignard reagent is prepared from methyl iodide? How would you prepare following using it?
(a) Ethanoic acid (b) Ethanol (c) isopropyl alcohol (d) propane
xi. Write chemical equation to show:
(a) Phenol is acidic in nature (b) Ethers are basic in nature (c) Amino acid are amphoteric (d) aldehyde as reducing agent
xii. (a) Starting from 1,2 dichloro ethane, How would you prepare Ethene & Ethyne, give equation & name the process
(b) What products are formed when water reacts with Ethene & Ethyne in the presence of acidic medium also name the products
xiii. What would be the major mono chloro product formed when each of the following compound reacts with Chlorine in the
presence of lewis acid ferric chloride? Explain why
(a) Ethyl benzne (b) Trifluoro methyl benzene (c) Methyl benzoate
xiv. Write down the equation for following naming reactions:
(a) Cannizarros’ reactions (b) Williamson synthesis (c) Dows’ process (d) Wurtz reaction
xv. Which products are obtained on condensation of following compounds, give reaction:
(a) Hexamethylene diamine & Hexan dioic acid (b) Fromaldehyde & Phenol
(c) α-glucose & β-fructose (d) Glycine & Alanine
xvi. Give IUPAC name for following compounds:
(a) (C6H5)3-C-CHO (b) (CH3)2HCOCH(CH3)2 (c) (CH3)2HCCOC(CH3)3 (d) HOOC-CH(Cl)-CH(CH3)-COOH

SECTION C:
DETAILED ANSWER QUESTIONS MAX. MARKS = 28
Attempt 1 question from each inorganic & organic part.

INORGANIC CHEMISTRY
Question NO.3
a. Flow chart for the extraction of Aluminum from Bauxite ore is given: 6
iron 0xide/silica  S T
Bauxite  Alumina  Aluminum 99% 

C
Aluminum 99.9% Answer following: (i) Name the
A B

method used in “A” and fusing material for separation of impurities along with equations, (ii) Name the process “B” & “C” what
are “S & T” & what is the purpose of their addition, (iii) Draw diagram of cell used for process “C” & give equations
b. What are the anomalies in placement of “Hydrogen” with halogens? 3
c. Complete & balanced the equations: 5
(i) KMnO4 (heat)  ____________________ (ii) K2Cr2O7 + H2SO4  ____________________
(iii) NaBH4 + H2O  ____________________ (iv) Cu2O + Cu2S  ____________________ (v) NH3 + CO2  ____________________

Question NO.4
a. How Sodium is extracted form Sodium chloride using Downs’ Cell? What is the purpose of addition of CaCl 2 to NaCl? Mention 5
Why water is avoided during extraction of sodium? OR How Nitric acid is manufactured using ammonia? Discuss the variable
oxidizing ability of HNO3?
b. Write short note on (any 2) (i) Lunar Caustic, (ii) Effect of heat on boric acid (iii) Oxides of alkali metals 4
c. Give methods for preparation of water gas? How Hydrogen is seperated from it? 3
d. How following compounds are prepared on labotary scale? (i) Hydrogen sulphide (ii) Potash alum 2

ORGANIC CHEMISTRY
Question NO.5
a. Write down balanced chemical equation for following chemical reactions: 7
(i) Benzene oxidized in the presence of O2 (ii) Sodium ethoxide reacts with ethanoyl chloride.
(iii) Ethyl chloride heated with silver oxide (iv) Methanal reacts with Ethanol
(v) Pyrolysis of acetic acid is carried out (vi) Ethene reacts with S2Cl2
(vii) Ethanol reacts with thionyl chloride in the presence of pyridine
b. Compute the structural difference between soap & detergents, Why Detergents are better cleansing agent than soap? 3
c. What are “Directing groups” make list of different directing groups, Discuss the effect of heat on “orientation reactions”, Explain 4
with reference to the sulphonation of phenols?

Question NO.6
a. Out line the mechanism of following: 6
(i) Acetylation in Benzene (ii) SN2 reactions in Terbutyl chloride & NaOH (iii) Reaction between phenyl hydrazine & HCHO
b. Draw the structure of following organic compounds:
(i) Thiamine (ii) nicotinic acid (iii) ,  di methyl valeric acid
(iv) Isobutyl ter butyl ether (v) divinyl acetylide (vi) Tri Nitro Toulene 3
c. Differentiate (any 2) from the following:
(i) Thermosetting plastic & Thermoplastic (ii) Reducing & Non-reducing sugar 2
(iii) Monosaccharide & Disaccharide (iv) Acyclic & Alicyclic compounds
d. Discuss Molecular Orbital Treatment in Benzene? OR Draw & explain the hybrid orbital structure of Ethyne? 3

Best of luck
 HOME EXAMINATION-2017
GOVERNMENT DEHLI COLLEGE
Hussainabad, Federal “B”Area Karachi
CHEMISTRY –II (SOLUTION to SELECTIVE QUESTIONS)
available @ gdcevents.wordpress.com
SECTION A (MULTIPLE CHOICE QUESTIONS)
i 4th period, IB group vii Iron oxide & silica xiii3,4 di methyl hexane
ii Releases 104 kCal energy viii Glass xiv Zn/HCl
iii Hydronium ion (H3O+) ix Lunar caustic xv Uni-molecular Substitution
iv Beryllium x Pyridine xvi Vitamin K
v Barytes xi 1,2,3 tri hydric benzene xvii Alcohol to Aldehyde
vi 95.5 oC xii Cyclo butene
SECTION B SHORT ANSWER QUESTIONS
Question NO.2
(i)
(a) FeO.Cr2O3 & Pb3O4 (c) Chromite (ore of Cr) & Sapphire (ore of Al)
(b) Red & Blue (d) AgBr  2 Na 2 S 2 O3 
 Na 3 [ Ag (S 2 O3 ) 2 ]  NaBr

(iii)
(a) Magnessium tetra hydroxo zincate(II) (c) Hydrogen tetra chloro aurrate (III)
(b) Nickel dimethylglyoximate(II) (d) Tris ethylenediamine chromium (III) chloride

(vi)
(a) NaAlH 4  4H 2 O  Al (OH ) 3  NaOH  4H 2 (b) SiO 2  Na 2 CO3 
 NaSiO3  CO2
(c) [ Pb(CH 3COO) 2 .Pb(OH ) 2 ]  2H 2O  2CO2 
 2PbCO3 .[ Pb(OH ) 2 ]  6CH 3COOH
(d) 2MnO4   3H 2 O2 neutral
 2MnO2  3O2  2OH   2H 2 O

(viii)
(d) [Ag (NH3)2]OH  Ag2O + H2O + 4NH3
(a) C12 H 22O11 12C  11H 2O
H 2 SO4

CHO COOH
(b) Si  4HNO3   SiO2  4 NO2  2H 2O
(c) CaOCl2  H 2O 
Ca(OH )2  Cl2
(CHOH) 4 + Ag2O (CHOH) 4 + Ag
CH2OH CH2OH

(x)
(a) (c)

O
  
H OH O H HOH OH
     
CH3 MgI + C
O

H3C
C + Mg(OH)I CH3 MgI + H3C C O
H3C
CH
CH3
+ Mg(OH)I
OH
(b) (d)
     
H H OH OH
 
CH3 MgI + H C O

CH2 + Mg(OH)I
CH3 MgI + C2 H5 I C3 H8 + MgI2
H3C

(xi)
(a)
OH NaO (c)

+ NaOH + H2 O H2O -
R CH COOH R CH COO
(b) +
NH2 NH3
+ - + -
H5C2 O C2H5 + H I H5C2 O C2H5 + I
(d)
H H
O
C
H O + Cu(OH) 2 + NaOH H C + Cu 2O + 3 H2O
Feh. A Feh. B
ONa

(xii)
(a) alcoholic
H2C CH2 + Zn H2C CH2 + ZnCl 2
H2C CH2 + 2 K OH HC CH + 2 KCl + 2 H2O
Cl Cl
Cl Cl
De halogenation reaction
Dehydrohalogenation reaction

1
 rearrangement O
(b) HC CH + H OH H2C CH H3C C
H
OH
H2SO4
H2C CH2 + H2O H2C CH2
H OH Ethanal
Ethanol
(xiii)
(a)
C2 H5 C2 H5 (c)
Cl
FeCl3
+ Cl 2 + HCl OCOCH3 OCOCH3

FeCl3
(b) + Cl 2 + HCl
CF3 CF 3
Cl
FeCl3
+ Cl 2 + HCl

Cl

(xiv)
(a) Cl NaO
H H O 300 °C
C
O + C + NaOH CH 3OH + H C + NaOH + HCl
200 atm
H H O
ONa (c)
(b)
- + ONa HO
2 H5C2 OH + 2 Na 2 C2H5O Na + H2

+ HCl + NaCl

- + + -
C2H5O Na + C2H5 Br C2H5OC2H5 + NaBr
(d) 2CH 3 I  2 Na 
Pd
C2 H 6  2 NaI

(xv)
anidelinkage amidelinkage
 H 2O
(a) NH (CH ) NH  HOOC  (CH )  COOH 
2 2 6 2 2 4  [ NH  (CH 2 ) 6  NH  CO (CH 2 ) 4  CO  NH ]
Hexa  methylene dia min e Adipic acid Nylon

(b) (c)
OH
OH OH
OH OH OH
CH 2 H
O -H2O H
OH HO OH H
+ H
C
H
+ H OH O OH -H O
2
HO O
H + H HO H OH
OH H HO
H O
HO OH OH
OH H H HO
H OH
H
OH
OH H
O O -H2O O O
H2N CH2 C-OH + H2N CH C-OH NH CH2 C NH CH C
n
(d) CH3 CH3

(xvi)
(a) 2,2,2 Triphenyl Ethanal (c) Ter butyl isopropyl ketone
(b) Di-isopropyl ether (d) 2 chloro 3 methyl butandioic acid

SECTION C: (DETAILED ANSWER QUESTIONS)

Question No.3(c)
(iii) NaBH 4  4H 2 O  H 3 BO3  NaOH  4H 2
(i) 2KMnO4 heating
 K 2 MnO4  MnO2  O2
(ii) (iv) Cu2 S  2Cu2O 
 6Cu  SO2
K 2 Cr2 O7  2H 2 SO4 
 2KHSO4  2CrO3  H 2 O (v) 2 NH 3  CO2  H 2 O 
( NH 4 ) 2 CO3

Question No. 5(a)

(i) (ii)
O O O
V2O 5
+ 9 O2
HC C
O + 4 H2O + 4 CO2
2 H3C C + C2H5ONa H3C C + NaCl
400 °C HC C OCl OC2H5
O

2
(iii) (v)
O O
2 H5C2 Cl + Ag2O C2H5OC2H5 + 2 AgCl MnO2
CO 2
(iv)
2 H3C C H3C C + + H2 O
OH 500 °C CH3
H OH
C
H O + C2H5OH
H5 C2 O
CH2
hemiacetal (vi)
acid
CH2 CH2 Cl
H2C CH2 + S2Cl 2
S + S
CH2 CH2 Cl
(vii)
C2 H 5 OH + SOCl2 3 C2H5Cl + SO2 + HCl

Question No. 6(b) (v)

(iii)
(i)
CH2=CH-CC-CH=CH2

(vi)
CH3
(iv) O 2N NO 2
(ii)

NO 2

Best of Luck for BIEK Examinations

available @ gdcevents.wordpress.com
prepared by:
Zain Ul Abdeen (lecturer) in Coordination with Prof Shoaib Ahmed (HOD-Chemistry) Govt. Dehli College.