Class - 11th

Chemical Equilibrium

1. Write the relation between Kp and Kc for the given reaction.

H2(g) + I2(g) —→ 2HI(g)

2. An acid having pH = 6 is diluted 100 times. What will be the pH of the final solution ? [Ans. pH
= 6.98]

3. Write the expression of Kc for the following reaction-

CH3COOC2H5(l) + H2O(l) -—> CH3COOH(aq) + C2H5OH(aq).

4.What is meant by the conjugate acid-base pair ? Find the conjugate acid/base for the
following species :
HNO2, CN–, HClO4, F–, OH–, H3O+, and S2–.

5. Define solubility product. Calculate the solubility product of Ca(OH)2 if its solubility is 3 moles
L–1. [Ans. Ksp = 108]

6. Write the expression of Kp for the following reaction:

Cu(NO3)2(s) ——> 2 CuO(s) + 4NO2(g) + O2(g)

7.One mole of H2O and one mole of CO are taken in 10 L vessel and heated to 725 K. At
equilibrium 40% of water (by mass) reacts with CO according to the equation,
H2O(g) + CO(g) H2 (g) + CO2(g), Calculate the equilibrium constant for the reaction. [Ans.
0.444]

8.Four moles of PCl5 are heated in a closed 4 dm3 container to reach equilibrium at 400 K. At
equilibrium 50% of PCl5 is dissociated. What is the value of Kc for the dissociation of PCl5 into
PCl3 and Cl2 at 400 K. [Ans. 0.50]

9. Dihydrogen gas is obtained from natural gas by partial oxidation with steam as per following
endothermic reaction : CH4 (g) + H2O (g) CO (g) + 3H2 (g)
(a) Write as expression for Kp for the above reaction.
(b) How will the values of Kp and composition of equilibrium mixture be affected by :
(i) increasing the pressure
(ii) increasing the temperature
(iii) using a catalyst ?

10.The ionization constant of aniline is 3.69 × 10-10 :

(i) Calculate pH of 0.01 M solution of aniline.
(ii) Calculate the degree of dissociation of aniline in the solution.
(iii) Calculate the ionization constant of conjugate acid of the aniline.