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Algaeprocessdescription v1.0
Algaeprocessdescription v1.0
Algaeprocessdescription v1.0
Model Inputs
Tool Inputs
Matrix
List
Error
v0.0
v0.1
v0.1-CO2Fix
v0.3
v0.9
v1.0
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Remaining Paste
Dewatering
Metabolites
Extraction
Fuel
Metabolite
Conversion
Transport
<From all>
Recovery
Waste &
Co-product
<To all>
Ed Frank, Jeongwoo Han, Michael Johnson, Ignasi Palou-Rivera, Michael Wang, Zhichao Wang
Center for Transportation Research and Process Technology Research Section
Energy Systems Division
Argonne National Laboratory
9700 S. Cass Avenue
Argonne, IL 60439 USA
Phone: 630/252-2819
E-mail: efrank@anl.gov, mqwang@anl.gov
Release Notes
10/14/11. First release. Experimental/alpha
12/20/11. Fix data validation for several drop-down menus that kept "custom" and "none" from being selected.
1/12/12. Fix computation of "CO2 produced, g CO2/dry-g digested" in Recovery tab. 0.2058 becomes 0.288 because of correct computation
2/3/12. Change CO2 demand per g algae in Growth & 1st dewater to 1.83, the stoichiometric value when algae are 50 wt% carbon. Adjust de
to the average of the 75% and 90% scenarios in Lundquist 2010. This produces almost the same result as the first release but is a clearer se
adjust to their own assumption. .
5/30/12. Harmonization version. See, "Renewable Diesel from Algal Lipids: An Integrated Baseline for Cost, Emissions, and Resource Poten
D, Frank ED, Wigmosta MS" Changes include:
CO2 tab has two separate computations for CO2 recycle and CO2 transfer since recycle involves lower CO2 concentrations and potent
Growth & First Dewater: Algae retention efficiency is used to increase the harvest pumping load, but algae are treated as 100% harvest
treatment is applied to DAF in remaining dewatering. Also, pumping energy was adjusted per Harmonization report.
Remaining dewatering: DAF output reduced to 6 wt%, default (disc-stack) centrifuge energy reduced, per Harmonization report. The DA
so this version returns it to the pond with any algae lost by the DAF. We neglect questions about coagulant returning to the pond.
Extraction: NREL wet extraction Aspen model added.
Recovery: C wt% of feed, AD heat demand, and AD electricity changed per harmonization model. Also, repair formula for CO2 produced
The net GHG results are about 5% lower than in the Harmonization report because of other changes in GREET upstream, e.g., reduced
(higher NGCC share).
Avoid division by zero errors on the nutrients page when there is no AD residue or no mass sent to AD
Fix drop-down on Growth and 1st Dewater page
Set water use (g/L-algae) to the annual average, averaged over all sites in the Harmonization report
Set productivity to the annual average, averaged over all sites in the Harmonization report
Add comments explaining how to obtain the HTL results.
12/13/12. Add infrastructure tab. Misc. non-functional edits.
y input assumptions for the pathways.
The default setup is for the Harmonization study scenario. To reproduce the HTL study, change the values on the Nutrien
& 1st Dewatering, Extraction, and Recovery tabs according to the instructions on those sheets. Then, in GREET, set the ye
in the "Set with APD" column to match those in the "HTL" column at the top of the page (Key inputs assumptions table."
The Harmonization study and HTL study reports are available at http://greet.es.anl.gov/publications
e the values on the Nutrients, Growth
s. Then, in GREET, set the yellow boxes
inputs assumptions table."
cations
CO2
None 0.000E+00
None 0.000E+00
None 0.000E+00
None 0.000E+00
None 0.000E+00
None 0.000E+00
None 0.000E+00
None 0.000E+00
None 0.000E+00
None 0.000E+00
None 0.000E+00
None 0.000E+00
None 0.000E+00
None 0.000E+00
None 0.000E+00
None 0.000E+00
Energy consumed: KWh/g-
output except as noted
Residual oil 0.000E+00
Diesel fuel 0.000E+00
Gasoline 0.000E+00
Natural gas 0.000E+00
Coal 0.000E+00
Liquefied petroleum gas 0.000E+00
Electricity 1.159E-05 1.159E-05
Site thermal 0.000E+00
Site Electricity 3.041E-05 1.990E-04 3.041E-05
2.160E+04
122,920
101,325
302
2.1
80.0%
1.000E+00
1.213E-02
1.516E-02
95.0%
1.99E-04
s in APD to facilitate
rchers to develop the simulation
2 capture. GREET must be
work is in progress and is not
y selecting CO2 capture in APM
s in APD to facilitate
rchers to develop the simulation
2.12E-06
1.99E-04
Algae Biomass Model C:N:P composition of macr
Fraction of dry weight
from carbon 0.55
Relative Relative Relative
abundances abundances abundance in
in biomass, in biomass, protein,
molar basis mass basis molar basis
Molecular wt.,
g/mol
C 12.01 175 55.00% 4.43
N 14.01 21 7.70% 1.16
P 30.97 1 0.81% 0
molar mass, g/mol
3821.3636364 100.1
g/g-algae
AD Solid Residue g/g-LEA
N P
Share of LEA 20% 50%
Utilization 40% 100% AD Liquid Residue
g lost/g-algae 0.0092 0.0000
g displaced/g-alga 0.0062 0.0041 g/g-algae
Share to Algae
Share to Soil
To reproduce the HTL results, set "Share of LEA" for N,P to Share blowdo
0%, 0% above and set utilization for P to 90%, below.
N, g/g-algae P, g/g-algae
Input 0.0195 0.0041
Volitilized 0.0010 0
Sludge 0.0154 0.0041
AD blowdown 0.0000 0.0000
Loss in return 0.0031 0.0000
Liquid to soil 0.0000 0.0000
Balance 0.0000 0.0000
C N P P2O5
Total Nutrients added, g/g-algae 0.0195 0.0041
g nutrient displaced by residue/g-residue 0.0153 0.0100 0.0230
Total nutrient in residue, g/g-residue 0.2423 0.0382 0.0100 0.0230
180 634
mass LHV Model from Lardon Biogas model from Sialve 2009 Protein: C4.43 H7 O1.44
molar mass, LHV, MJ/kg LHV, BTU/ton N1.16
g/mol m3 CH4/g-VS Carb: C6 H12 O6
100.1 15.5 13,356,312 8.51E-04 Lipid: C40 H74 O5
180 13 11,202,068 4.15E-04
634 38.3 33,003,016 1.01E-03
C6 H12 O6
C40 H74 O5
Net-Process Summary
Summary: Algal
growth and 1st
Level Dewatering
Input per unit output 2.46E+00
Recoverable CO2, g/g prod
Mass to recovery, dry-g/g p
Materials consumed, g
per unit output except
as noted
Media water 4.79E+01
Fresh water 0.00E+00
NH3 1.91E-02
(NH4)2HPO4 1.72E-02
None 0.00E+00
None 0.00E+00
None 0.00E+00
None 0.00E+00
None 0.00E+00
None 0.00E+00
None 0.00E+00
None 0.00E+00
None 0.00E+00
None
None 0.00E+00
None 0.00E+00
Energy consumed:
KWh/g-output except as
noted
Residual oil 0.00E+00
Diesel fuel 0.00E+00
Gasoline 0.00E+00
Natural gas 0.00E+00
Coal 0.00E+00
Liquefied petroleum gas 0.00E+00
Electricity 0.00E+00
Site thermal 0.00E+00
Site Electricity 4.86E-04
Recovered Nutrients
Recovered water
Nutrients
Facility Parameters
Algal oil fraction 25.0%
Productive days/yr 330
Reactor Parameters
Specific productivity,
g/L-culture/d 2
Circulation power
intensity, KWh/L-
culture/d 0
CO2 loss, as fraction 5.00E-02
Media loss overhead, L-
culture/g-algae 0.00E+00
Evaporative Loss (Non-
spray), L/g-algae 0.00E+00
Spray-Evaporation
cooling demand, L/L-
culture/d 0.00E+00
Circulation energy for
spray evaporative The PBR Block has not been
cooling, KWh/L-cooling
tested. Cross-check all results
water 0 and use with caution.
Spray evaporative
cooling water loss rate,
percent of circulated
volume 5%
Output concentration
(w/v), dry g/L 4.00E+00
Volume of cooling water
circulated, L-cooling
water/g-algae 0.00E+00
PBR Circulation power
for reactor KWh/g-algae
0
Computations
Water flows per net gram algae after 1st level dewatering
Evaporative loss
L/net g algae 4.23E-02
Media loss overhead
per g algae, L/net g
algae
0.00E+00
Growth media, L/net
g algae 2.00E+00
Total water, L/net g
algae 2.04E+00
Water passed
downstream from 1st
dewatering, L/net g
algae 1.00E-01
Water separated in
1st dewater, L/net g
algae 2.12E+00
Water sent to waste,
L/net g algae 0.00E+00
Water returned for
media make up, L/net
g algae 2.12E+00
Water returned from
other operations,
L/net g algae 9.44E-02
New water introduced
for media make-up,
L/net g algae
4.79E-02
New water introduced
for cooling, L/net g
algae
0.00E+00
Water Consumption
Water consumption,
L/net g algae 4.79E-02
Algae
Media Farming Water for 1st Level
Circulation Nutrient Use, media Cooling dewatering
Input per unit output
Recoverable CO2, g/g
product 0 0 0 0 0
Mass to recovery, dry-g/g
product 0 0 0 0 0
Materials consumed, g
per unit output except
as noted
Media water 4.79E+01
Fresh water 0.00E+00
NH3 1.91E-02
(NH4)2HPO4 1.72E-02
None
None
None
None
None
None
None
None
None
None
None
None
Energy consumed:
KWh/g-output except as
noted
Residual oil
Diesel fuel
Gasoline
Natural gas
Coal
Liquefied petroleum gas
Electricity
Site thermal
Site Electricity 3.64E-04 6.72E-05 1.00E-12 5.56E-05
ae passed downstream
Culture Culture
Circulation concentratio
power n (w/v), dry
KWh/g-algae g/L
3.64E-04 5.00E-01
0.000E+00 4.00E+00
3.64E-04 5.00E-01
veraged over all sites in the Harmonization study was 13.2 g/m2/d while the annual average
eraged over all sites, was 0.0423 L/g-algae. If you use 25 g/m2/d and 0.229 L/g for productivity
ues comparable to figure 3.1a in the Harmonization report.
(67,400 gCO2e/MMBTU-RD), you must study each of the resource assessment sites
n. This cannot be done by setting a single value here; however, you can use the annual
full study.
5.72E-01 4.330E-01
Custom Summary:
Summary of Growth and Algal growth
water 1st and 1st Level
movement Dewatering Dewatering
2.46E+00
0.00E+00
0.00E+00
4.79E+01 4.79E+01
0.00E+00 0.00E+00
0.00E+00 1.91E-02
0.00E+00 1.72E-02
0.00E+00 0.00E+00
0.00E+00 0.00E+00
0.00E+00 0.00E+00
0.00E+00 0.00E+00
0.00E+00 0.00E+00
0.00E+00 0.00E+00
0.00E+00 0.00E+00
0.00E+00 0.00E+00
0.00E+00 0.00E+00
0.00E+00
0.00E+00 0.00E+00
0.00E+00 0.00E+00
0.00E+00 0.00E+00
0.00E+00 0.00E+00
0.00E+00 0.00E+00
0.00E+00 0.00E+00
0.00E+00 0.00E+00
0.00E+00 0.00E+00
0.00E+00 0.00E+00
0.00E+00 0.00E+00
4.86E-04 4.86E-04
Remaining Dewatering
This worksheet computes all additional operations, after 1st stage dewatering, required to dewater
and, if needed, dry the algae. The result should match the requirements for extraction.
Notes:
1. Select up to 4 individual steps via the drop-down menus in the Net-Process Summary table. The
steps are assumed to be applied in order and the net result is computed in the summary column.
2. The various unit operations have parameters that can be set. See the various sections in the
page. The energy consumption for each is computed for each step in the summary table at the
bottom of the page. These are used for selection into the Net-Process Summary at the top.
3. "Efficiencies" for the dewatering describe algae retention. A 90% efficient process loses 10% of
the dry mass. It is assumed to go to anaerobic digestion (AD).
2. Water removed in dewatering subsequent to 1st stage is treated as lost since it is a small
fraction of the 1st state water movement.
Dissolved Air
Flotation
Retention efficiency 90%
Return lost algae to yes
culture (as live)?
Initial solids, g/L 10
Output solids, g/L 60
Power consumption,
KWh/g-algae 1.33E-04
Coagulant used,
g/dry-g-input 0.004
Water returned to
culture, L/g-algae out
0.0944
Algae returned to
culture, g/g-out 0.11
ce it is a small
ncy not reported.
t as noted
Thermal Centrifu Flocculate Custom Custom None
drying ge & Settle Remaining Remaining
(to be Dewaterin Dewaterin
done) g1 g2
1.00E+00 1.05E+00 1.39E+00 1
3.846E-03
1.930E-05
0
Extraction
6% Feedstock
P, wt% of feed lost to
solids and oil, gP/afdw g Solid content,
algae on ash free
15% basis 15%
Solid content,
Nitrogen loss, g/dafg-algae 0.0215 including ash 17%
Density
(kg/m3) 1000
cp. Specific
heat for
slurry, const.
P, kJ/kg/K
4.12
cp. Specific
heat of
aqueous
product,
const. P,
kJ/kg/K 4.12
cp. Specific
heat of water
at 320C.
kJ/kg/K
5.89
cp. Specific
heat of water
at T exiting
HTL HX,
kJ/kg/K 4.91223173
Efficiency
Bead milling
Sonication
Hexane extraction 95%
Ethanol extraction
Supercritical CO2 extraction
Hexane Extraction
Location on-site
Hexane consumption,
g/g-oil produced 5.20E-03
Net heat required,
KWh/g-oil produced 1.38E-03
Heat source CHP
Boiler efficiency 80%
Electricity required,
KWh/g-oil produced 5.400E-04
1.00E+00
0.000E+00
0.000E+00
Pumping
Low High
pressur pressure
e pump pump
In reactor
Efficiency,
combined
Temperat pump and
ure (oC) 300 Efficiency 67% motor 50%
Pressure
needed
(meter Pumping
Pressure water energy cost
(Pa) 10,639,454 25 head) 0 J/ kg slurry 2.13E+04
Pumping
energy Pumping
cost J/ kg energy, J/g
feestock 0.00E+00 biocrude 3.73E+02
Pumping
energy,
J/g
biocrude 0.00E+00
Custom None
Extracti
on 2
1 1
0 0
0 0
Products Heat exchanger Energy input
Pumping
total
energy,
J/g
Product Effectivene 85% 94% biocrude 3.73E+02
HTL heat
HTL oil Temperat demand,
g/dafg- ure of hot kJ/kg
algae 0.38 stream 300 slurry) 206.3137
Mass into
HX,
treated as
water 1.00
Carbon balance model from paper to estimate organic C in aqueous
C in algae, g/dafg-algae 55%
% of C in algae recovered in gas 8%
% of C in algae recovered in soli 2%
C wt % of oil 73%
% of C in algae recovered in oil 50.4%
CHG Integrated with HTL
Biogas
yield on
organic
C basis
99%
CH4
fraction
60%
Electrici
ty
demand
,
kwh/g-
CH4 3.100E-04
g
organic
C/g
biocrud
e 0.57263158
Methan
e yield,
gCH4/g
-HTL oil
4.535E-01
CO2
yield,
gCO2/g
-HTL oil
8.315E-01
Electrici
ty
demand
,
kwh/g-
HTL oil 1.41E-04
Phosph
orus
recover
ed, g/g-
HTL
1.066E-02
Conversion
Design Selections
Pond Liner Yes
Pond Liner Thickness (mil) 40
Settling Tank Design Concrete WWTP Capdet Design
Anaerobic Digestion Design Harmonization Report
Extraction Column Packing Material Stainless Steel
Makeup Water System Pond Liner No
Algae Productivity (g/m2·day) 13.2
Material Lifetimes
Pond Concrete 30 year
HDPE Liners 30 year
LDPE Covers 30 year
Paddlewheel Steel 30 year
Settling Tank Concrete 30 year
DAF Concrete 30 year
Centrifuge Steel 30 year
Centrifuge Concrete 30 year
Homogenizer Steel 30 year
Homogenizer Concrete 30 year
Column Steel 30 year
Column Concrete 30 year
Column Packing Lifetime 30 year
AD Concrete 30 year
AD Steel 30 year
Makeup Water PVC 30 year
Makeup Water Concrete 30 year
Cast Iron Pump 30 year
CO2 Distribution Concrete 30 year
CO2 Blowers 30 year
Operating Days Per Year 365 days
Inoculum Ponds
Value Unit
LDPE Cover Thickness 6 mil
Liner Surface Area for Reference Facility 1235000 m2
Surface Area Plastic Cover Per Pond 10157 m2
HDPE Liner for All Innoculum Ponds 138 m3
Geotextile Liner 27578 kg
LDPE Liner 1% Innoculum Ponds 1.55 m3
Volume of Excavated Material 100553 m3
Concrete 146 m3
Scaling Factor for Facility Area 40.52
Settling Tanks
Value Unit
Number of Tanks 13
Volume of Each Tank 300781 ft3
Volume of Excavated Material for CAPDET Design 15100 m3
Volume of Slab Concrete 991 m3
Volume of Concrete Walls 152 m3
Volume of Excavated Material for Plastic Lined Walls 9508 m3
Surface Area of Walls 1613 m2
Liner Volume 1.64 m3
Dewatering Centrifuge
Value Unit
Weight of Each Centrifuge 13500 kg
Number of Centrifuges 4
Total Centrifuge Power 254.8 hp
Building Surface Area 136 m2
Concrete Slab Thickness 0.30 m
Concrete Slab Volume 41.5 m3
Homogenization
Value Unit
Number of Homogenizers 28
Weight of Each Homogenizer 5443 kg
Extraction Centrifuge
Value Unit
Number of Centrifuges 5
Weight of Each Centrifuge 3200 kg
Total Centrifuge Power 61.7 hp
Building Surface Area 70 m2
Concrete Slab Thickenss 0.3048 m
Concrete Slab Volume 21.4 m3
Stripping Column
Value Unit
Stripping Column Height 40 ft
Stripping Column Diameter 13 ft
Stripping Column Volume 5309 ft3
Reference Column Volume 308 ft3
Reference Column Weight 5443 kg
Scaling Factor for Volume 17.2
Mass of Stripping Column 93857 kg
Anaerobic Digestion
Value Unit
Length of 12" Pipes for AD Facility 3000 m
Total Number of Centrifuges 8
Weight of Each Centrifuge 2850 kg
Volume of Slab Concrete for AD Facility 6360 m3
Volume of Wall Concrete for AD Facility 17800 m3
Concrete Slab Thickness 0.30 m
Building Surface Area 650 m2
Volume of Concrete Per Tank 65.0 m3
Volume of Excavated Material for AD Facility 223000 m3
Volume Each Digester 4300 m3
Number of Digesters 126
Liner Surface Area Per Tank 4300 m2
Liner Thickness 30 mil
Liner Volume Per Tank 3.28 m3
3) Calculations of Energy Consumption and Material Usage, KWh/g-algae and g-material/g-algae except as noted
Infrastructure Custom
materials
Input per unit output
Recoverable CO2, g/g product
Mass to recovery, dry-g/g product
Materials consumed, g per g algae except as noted
Concrete 5.000E-02
Steel 1.656E-04
Plastic 1.124E-02
Excavation, m3 7.022E-06
Cast Iron 3.998E-06
None
None
None
None
None
None
None
None
None
None
None
Energy consumed: KWh/g-produced except as
noted
Residual oil
Diesel fuel
Gasoline
Natural gas
Coal
Liquefied petroleum gas
Electricity
Site thermal
Site Electricity
Results for Large Growth Pond Construction
Value Unit
Concrete 1.13E+08 kg
HDPE 4.93E+07 kg
Polypropelyne 1.02E+07 kg
Excavation Volume 3.70E+07 m3
Results of AD Construction
Value Unit
Concrete 5.12E+07 kg
HDPE 0.00E+00 kg
Excavation Volume 2.23E+05 m3
Steel 2.62E+05 kg
5.78E-04
CO2
Stripping AD Makeup Water Distribution
Column Construction Piping System
1.14E-04 2.14E-05 1.53E-04
0.00E+00 0.00E+00
0.00E+00
4.95E-07 4.58E-07
2.08E-07 5.82E-07 6.62E-07
1.69E-06
5.28E-08
ried Design Specifications
1
0
Capdet Design 1
and Concrete Floor 0
None
Media water
Fresh water
AD Residue
Hexane
Ethanol
Supercritical CO2
Methanol
Sodium hydroxide
Sulfuric acid
Hydrogen
Methane 1.39E-02
Chitosan
Concrete 2100 kg/m3
Steel 7800 kg/m3
Plastic
Cast Iron
Excavation, m3
Custom1
Custom2
Custom3
Custom4
Transport
Backhaul
NH3
NH4Cl
NaNO3
KNO3
Ca(NO3)2
Ca(NO3)2.4H2O
(NH2)2CO
(NH4)2HPO4
K2HPO4.3H2O
K2HPO4
KH2PO4
K2SO4
Ca(H2PO4)2 + 2 CaSO4
Ca(H2PO4)2
Ca(H2PO4)2.H2O
Misc. values used in computations that are not available from the materials dropdown yet.