Value Acetonitrite (1) Nitromethane (2)

A 14.2724 14.2043
SOAL
B 2945.47 2972.64
C 224 209

T= 75 P=
BUBL P P1 sat P2 sat BUBL T
Ex A Ex B
83.2069 41.9827
P=P2sat+(P1sat-P2sat)*x1 ti sat = (B/
66.7172 x1 = P-P2sat/P1sat-P2sa
y1=x1*P1sat/P Misal t=
0.7483 78
Table BUBL P Table T
x1 y1 P x1
A B
0 0.0000 41.9827 0.0000
0.2 0.3313 50.2275 0.1424
0.4 0.5692 58.4724 0.3184
0.6 0.7483 66.7172 0.5156
0.8 0.8880 74.9620 0.7378
1 1.0000 83.2069 1.0000

T= y1 y2 y1 =
DEW P 75 0.6 0.4 DEW T
1 96.5318
P=
y1/P1sat + y2/P2sat
P= 59.7419
A
x1 = 0.4308 1.9476
B
x2 = 0.5692 t=
x1 =
x2 =
 70 x1 = 0.6
t1 sat t2 sat P2sat = P/x1a+x2
69.8446 89.5836 44.2307
ti sat = (B/(A-ln P)) - C Iterasi a
x1 = P-P2sat/P1sat-P2sat y1 = x1*P1sat/P a = P1sat/P2sat
P1 sat = 91.7611 x1 = 0.5156 1.9710
P2 sat = 46.8368 y1 = 0.6759 t= 76.4224
Table T Equation P1 sat = 87.1796
y1 t P1sat P2sat y1 = 0.7473
0.0000 89.5836 131.5604 70.0000 y2 = 0.2527
0.2401 86.0000 118.0235 62.0260
0.4742 82.0000 104.2384 54.0031
0.6759 78.0000 91.7611 46.8368
0.8484 74.0000 80.5012 40.4583
1.0000 69.8446 70.0001 34.5960

0.6 y2 = 0.4 Manual Iterasi

P1sat = P*y1+y2a 1.9476 a awal
96.5318 96.5328 P1sat
Iterasi a 79.5779 t
a = P1sat/P2sat 1.9476 a
1.9476
t= 79.5776
x1 = 0.4351
x2 = 0.5649
 P vs x1,y1
100

90 t = 75 oC
Manual Iterasi
80
1.9710 a awal
44.2307 P2sat 70
Supercooled
76.4224 t Liquid

P /kPa
60
1.9710 a
50

T oC 40
P kPa Superheated
30
Vapor
20
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x1, y1

t vs x1,y1
95

90 t2 sat = 89.58 P = 70 kPa

85 Superheated
Vapor
t /o C

80

75

70

65
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x1, y1
Subcooled
Liquid

t1 sat = 69.84
0.6 0.7 0.8 0.9 1

0 kPa
Superheated
Vapor

6 0.7 0.8 0.9 1

t1 sat = 69.84
 Value Benzene (1) Toluene (2)
A 13.7819 13.932
SOAL
B 2726.81 3056.96
C 217.572 217.625

T= 100 P=
BUBL P P1 sat P2 sat BUBL T
1a Ex B
180.4528 74.2597
P=P2sat+(P1sat-P2sat)*x1 ti sat = (B/(A
127.3563 x1 = P-P2sat/P1sat-P2sat
y1=x1*P1sat/P Misal t=
0.7085 100
Table BUBL P Table T E
x1 y1 P x1
1A 1C
0 0.0000 74.2597 0.0000
0.25 0.4475 100.8080 0.1511
0.33 0.5448 109.3034 0.4307
0.5 0.7085 127.3563 0.6017
0.77 0.8905 156.0284 0.7993
1 1.0000 180.4528 1.0000

T= y1 y2 y1 =
DEW P 100 0.33 0.67 DEW T
1 229.3956
P=
y1/P1sat + y2/P2sat
P= 92.1564
1B
x1 = 0.1685 2.3606
1D
x2 = 0.8315 t=
x1 =
x2 =

T= 105 P= 120
P = P2 sat + (P1sat - P2sat)*x1
1F
P1 sat P2 sat
1E 1e
206.1414 86.2049
x1 = 0.2818
y1 = 0.4840

Karena dalam Hukum Raoult merupakan suatu model yang sederhana dari VLE dimana
kedua perhitungannya hanya membutuhkan asumsi dimana fase vapor adalah gas ideal
1G dan fase liquid adalah larutan ideal. Dan dalam hukum Raoult bisa digunakan untuk
spesi yang hadir dalam mol fraksi
 120 x1 = 0.33
t1 sat t2 sat P2sat = P/x1a+x2
85.5952 116.6696 82.0015
ti sat = (B/(A-ln P)) - C Iterasi a
x1 = P-P2sat/P1sat-P2sat y1 = x1*P1sat/P a = P1sat/P2sat
P1 sat = 180.4528 x1 = 0.4307 2.4042
1C
P2 sat = 74.2597 y1 = 0.6477 t= 103.3068
Table T Equation P1 sat = 197.1485
y1 t P1sat P2sat y1 = 0.5422
0.0000 116.6696 276.9117 119.9998 y2 = 0.4578
0.2953 110.0000 234.5321 99.6169
0.6477 100.0000 180.4528 74.2597
0.7887 95.0000 157.2942 63.6653
0.9092 90.0000 136.4968 54.3099
1.0000 85.5952 119.9999 47.0095

0.33 y2 = 0.67 Manual Iterasi

P1sat = P*y1+y2a 2.3607 a awal
229.3956 229.4003 P1sat
Iterasi a 109.1317 t
a = P1sat/P2sat 2.3606 a
2.3606 1D
t= 109.1309
x1 = 0.1726
x2 = 0.8274

z1 = 0.33
z1 = x1(1-V)+y1(V)
V= 0.23841812
L= 0.76158188
 Manual Iterasi
2.4042 a awal
82.0016 P2sat
103.3069 t
2.4042 a

T oC
P kPa
 Value Benzene (1) Ethylbenzene (2)
A 13.7819 13.9726
SOAL
B 2726.81 3259.93
C 217.572 212.3

T= 90 P=
BUBL P P1 sat P2 sat BUBL T
1a Ex B
136.4968 24.2603
P=P2sat+(P1sat-P2sat)*x1 ti sat = (B/
80.3786 x1 = P-P2sat/P1sat-P2sa
y1=x1*P1sat/P Misal t=
0.8491 100
Table x1,y1 vs P Table x1
x1 y1 P x1
0 0.0000 24.2603 0.0000
0.1 0.3847 35.4840 0.1649
0.3 0.7069 57.9313 0.2993
0.5 0.8491 80.3786 0.4758
0.8 0.9575 114.0495 0.7144
1 1.0000 136.4968 1.0000

T= y1 y2 y1 =
DEW P 90 0.5 0.5 DEW T
1 262.0636
P=
y1/P1sat + y2/P2sat
P= 41.1983
x1 = 0.1509 4.8236
x2 = 0.8491 t=
x1 =
x2 =
 90 x1 = 0.5
t1 sat t2 sat P2sat = P/x1a+x2
76.1991 131.8362 27.7670
ti sat = (B/(A-ln P)) - C Iterasi a
x1 = P-P2sat/P1sat-P2sat y1 = x1*P1sat/P a = P1sat/P2sat
P1 sat = 180.4528 x1 = 0.3813 5.4825
P2 sat = 34.2656 y1 = 0.7644 t= 93.8325
Table x1,y1 vs T P1 sat = 152.2330
y1 t P1sat P2sat y1 = 0.8457
0.0000 131.8362 394.5785 89.9999 y2 = 0.1543
0.4870 115.0000 265.7997 55.2867
0.6855 105.0000 206.1414 40.3920
0.8316 95.0000 157.2942 28.9133
0.9358 85.0000 117.8953 20.2364
1.0000 76.1991 90.0000 14.4831

0.5 y2 = 0.5 Manual Iterasi

P1sat = P*y1+y2a 4.8230 a awal
262.0636 262.0350 P1sat
Iterasi a 114.4224 t
a = P1sat/P2sat 4.8238 a
4.8236
t= 114.4268
x1 = 0.1717
x2 = 0.8283
 P vs x1,y1
160.0000
Manual Iterasi 140.0000
5.4825 a awal 120.0000
27.7671 P2sat 100.0000 Px1
93.8327 t Linear

P (kPa)
80.0000
Py1
5.4825 a 60.0000
Linear
40.0000
20.0000
T oC 0.0000
P kPa 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

x1,y1

T vs x1,y1
135.0000
125.0000
115.0000 Tx1
105.0000 Linear
T (oC)

Ty1
95.0000 Linear
85.0000
75.0000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000

x1,y1
1,y1

Px1
Linear (Px1)
Py1
Linear (Py1)

6 0.7 0.8 0.9 1

1,y1

Tx1
Linear (Tx1)
Ty1
Linear (Ty1)

0 0.8000 1.0000
 Value 1-Chlorobutan (1) Chlorobenzen(2)
A 13.7965 13.8635
SOAL
B 2723.73 3174.78
C 218.265 211.7

T= 90 P=
BUBL P P1 sat P2 sat BUBL T
1a Ex B
142.7112 28.2341
P=P2sat+(P1sat-P2sat)*x1 ti sat
85.4726 x1 = P-P2sat/P1sa
y1=x1*P1sat/P Misal t=
0.8348 100
Table x1,y1 vs P Ta
x1 y1 P x1
0 0.0000 28.2341 0
0.1 0.3596 39.6818 0.1255
0.3 0.6842 62.5772 0.2582
0.5 0.8348 85.4726 0.4318
0.8 0.9529 119.8158 0.6654
1 1.0000 142.7112 1.0000

T= y1 y2 y1 =
DEW P 90 0.5 0.5 DEW T
1 247
P=
y1/P1sat + y2/P2sat
P= 47.1416
x1 = 0.1652 4.4
x2 = 0.8348 t=
x1 =
x2 =
 90 x1 = 0.5
t1 sat t2 sat P2sat = P/x1a+x2
74.7135 127.3522 29.9986
ti sat = (B/(A-ln P)) - C Iterasi a
x1 = P-P2sat/P1sat-P2sat y1 = x1*P1sat/P a = P1sat/P2sat
P1 sat = 188.3766 x1 = 0.3389 5.0003
P2 sat = 39.5723 y1 = 0.7093 t= 91.7481
Table x1,y1 vs T P1 sat = 150.0014
y1 t P1sat P2sat y1 = 0.8333
0 127.3522 370.82472 90 y2 = 0.1667
0.3863 115.0000 276.8939 63.1667
0.6169 105.0000 215.0374 46.4759
0.7884 95.0000 164.3254 33.5180
0.9121 85.0000 123.3650 23.6461
1.0000 74.7135 90.0000 16.1012

0.5 y2 = 0.5 Manual Iterasi

P1sat = P*y1+y2a 4.4912 a awal
247.1059 247.1040 P1sat
Iterasi a 110.4223 t
a = P1sat/P2sat 4.4913 a
4.4912
t= 110.4226
x1 = 0.1821
x2 = 0.8179
 P vs x1,y1
160.0000
Manual Iterasi 140.0000
5.0000 a awal 120.0000
30.0000 P2sat 100.0000

P (kPa)
91.7495 t 80.0000
5.0002 60.0000
a
40.0000
20.0000
0.0000
T oC
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
P kPa
x1,y1

T vs x1,y1
135.0000
125.0000
115.0000
105.0000
T (oC)

95.0000
85.0000
75.0000
65.0000
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

x1,y1
P vs x1,y1

Px1
Linear (Px1)
Py1
Linear (Py1)

.4 0.5 0.6 0.7 0.8 0.9 1

1,y1

T vs x1,y1

Tx1
Linear (Tx1)
Ty1
Linear (Ty1)

0.4 0.5 0.6 0.7 0.8 0.9 1

x1,y1