TECHNOLOGICAL INSTITUTE OF THE PHILIPPINES ChE REFRESHER COURSE DAY 1 - CHEMICAL AND PHYSICAL PRINCIPLES gehbe 4 1 e ae 1. Ithas been found by mass spectrometric analysis that in nature, the relative abundances of the various isotopic atoms of silicon are 92.23% "Si, 4.67% ®Si and 3.1% ™Si. Calculate the atomic weight of silicon from this information and from the nuclidic masses. Nuclidic masses: “Si 27.97693 u; Si 28.97649 u; “Si 29.97377 u. A__28.085u B. 28.850u C_28.580u D. 28.058 u 2. Only two isotopes of copper are present in naturally occurring copper: “Cu (62.9298 u) and “Cu (64.9278 u). Calculate the percent composition of naturally occurring “Cu using the atomic mass of 63.546 u. A__69.17% B._ 30.83% C._ 46.65% D._ 53.35% 3._What is the mass of an electron? ‘A. 1226-24 kg B. i22E22kg CIE kg D. Sai E-3ikg 4. Calculate the number of molecules in a tablespoon of sugar, C:2Ha01., weighing 10.5 grams. ‘A__6.02 £23 B._6.29 £24 C._ 1.85622 D. 1.13623 '5,_The percent composition of an unknown element X in CHX is 32%. Which of the following is element X? AH 8. F at Du 6._What is the empirical formula of a compound that is 51.9% carbon, 4.86% hydrogen, and 43.2% bromine? A. GHSBr B._ CeHaBrs C_GHsBr D. Cale 7. Hexamethylenediamine is one of the materials used to produce a type of nylon. Elemental analysis gives 62.1% C, 13.8% H and 24.1% N. Its molecular weight is 116 g/mol. What is the molecular formul la? ‘A. CoHisNa B._CethsNa CCoHeN D._CoHioNa Page 1 of 217 8. A volumetric analysis of a gaseous mixture is as follows: 12% CO;, 4% Oz, 82% Nz and 2% CO. What is the percentage of CO on mass basis? A 1% BL 12% C_1.5% D._1.9% 9. The density of a solution that is 20.0% by weight HCIO, is 1.138 g/mL. Calculate the molarity of HCIO,. ‘A._0.442 BL 199 C345 D._2.26 110. A solution is prepared by mixing 8 grams of ethanol and 50 grams of water. Calculate the molality of the solution? A. 3.0m B. 3.5m c_4m D. 4.5m 111. What is the normality of a solution of H,SOa if it has a specific gravity of 1.84 and contains 95% H,SO. by weight? ‘A. 3.56N B._5.63N C_653N D._35.6N, 12. Convert a 0.25 M solution of H,SO.to normality. AL 2N BIN Lc 05N D. O.1N 13. How many milliliters of water must be added to 5 mL of 12M HCI solution to make a 3M HCI solution? A. 10m B.1SmL LC. 20mi D. 25mL 14. A solution is made by mixing 30.0 mL of 8M HCI, 100 mL of 2M HCI, and enough water to make 200 mL of solution. What is the molarity of HCI in the final solution? A. 0.455M. B. 100M. Lc 120M D._2.20M. Page 2 of 2115. Express the concentration of a 3% by weight CaSO, solution in water in terms of ppm. ‘A._20,000 B. 25,000 C._30,000 D._35,000 16. A polluted pond contains 25 ppb of lead ions. What is the concentration of lead ions in molarity units? ‘A._1.2E8M 8. 1.26-7M C 25E-8M. D. 0.121M 17. Calculate the boiling point of a solution containing 4.27 g of sucrose in 50 g water. ‘A. 101.71°C B._101.12°C C._ 100.87 °C D,_ 100.13 °C 18. When 5.50 g biphenyl (C,H) is dissolved in 100 g benzene, the boiling point increases by 0.903 °C. What is the Kb of benzene in K/molal? A. 2.42 B_2.53 c._2.80 D._3.06 19. Calculate the freezing point of a solution containing 4.27 g of sucrose in 50 g water. A -0.46°C B._-0.65°C C-0.76°C D. -0.82°C 20. If 4.35 g of ethylene glycol is dissolved in 100 g of water, the resulting solution has a freezing point of -1.31 °C. Calculate the molecular weight of ethylene glycol. A. 61 B62 om) D. 64 Page 3 of 21,21. ‘Asolvent storage tank 19.0 m high contains liquid styrene (sg 0.929). a pressure gage, which gives kPa reading, is fixed at the base of the tank to be used to determine the level of styrene. Determine the gage pressure when the tank is full of styrene. AL 173 B._ 172000 C2004 D477 22. A Fahrenheit and a centigrade thermometer are both immersed in a fluid and indicates a Fahrenheit reading that is numerically twice that of the centigrade reading. What is the temperature of the fluid expressed as degrees Kelvin? A._233 [8.780 C433 D. 420 23. A fixed quantity of gas at a constant temperature exhibits a pressure of 737 torr and occupies a volume of 20.5 L. Use Boyle's law to calculate the volume the gas will occupy if the pressure is increased to 1.80 atm. A 83941 B. 1101 C381 D._205L 24. A child’s balloon filled at 27 °C has @ radius of 10 cm. if the balloon is taken outside on a very hot day when the ‘temperature is 50°C, what is the new radius of the balloon? ‘A__10.15 em B._10.25 cm c_1040em D. 1055em 25. A balloon filled with helium has a volume of 10,000 liters at atmospheric pressure and 30 °C. it rises to a height where the pressure has dropped to 0.60 atm and the temperature is -20 °C. What is the volume of the balloon then? ‘A. 10,000L 8B. 11,0001. [© 13,0001 D._14,000L 26. A'5,000 cm® container holds 4.90 grams of gas when the pressure is 75 cm Hg and temperature is 50 °C. What will be the pressure if 6.0 grams of this gas is confined in a 2,000 cm* container at 0°C? ‘A. 104.em Hg B. 139 emHg C_194em Hg D._308 em Hg Page 4 of 2127. Two gases occupy two containers, A and B. the gas in A, of volume 0.11 m® exerts a pressure of 1.38 MPa. The gas in B, of volume 0.16 m’, exerts a pressure of 0.69 MPa. The two containers are united by a tube of negligible volume and the gases are allowed to intermingle. What is the final pressure in the container if the temperature remains constant? ‘A. 0.78 MPa B._0.83 MPa C092 MPa [__b.0.97 MPa 28. Calculate the density of H,S gas at 0.122 atm and 25 °C. ‘A 4996-3 g/L B. 0.119 g/t C0170 gt D. 2.03 g/t 29. AtSTP a 5.0 L flask filled with air has a mass of 543.251 grams. The ait in the flask is re ;placed with another gas, and the mass of the flask is then determined to be 566.107 grams. The density of air is 1.29 g/L. What is the gas that replaced the air? ‘A._Neon B._Oxygen| C_Nitrogen D._ Xenon) 30. A gas mixture contains twice as many moles of O2 as Nz. Addition of 0.20 mole of argon to this mixture increases the pressure from 0.80 to 1.10 atm. How many moles of O, are in the mixture? ‘A. 0.355 8. 0.178 C0533, D. 0.200 31. A100 mL sample of air exhaled from the lungs is analyzed and found to contain 0.083 g Nz, 0.0194 g 0,, 0.0064 g CO; and 0.00441 g water vapor at 35 °C. What is the total pressure of the sample? A__0.95 atm 8. latm C_12atm D142 atm 32, From the data in #31, what is the partial pressure of water? ‘A._0.749 atm B._ 0.153 atm C_0.0368 atm D._ 0.0619 atm Page 5 of 21,33. ‘At the same temperature and pressure, which gas will diffuse through air at the fastest rate? ‘A__Hydrogen B._Oxygen C. Carbon monoxide | _D. Carbon dioxide 34. It takes 16.6 min for a 10 ml sample of unknown ga: ‘required 5.0 min. What is the molecular weight of the ut 5 to effuse through a pinhole. A 10 mL sample of helium inknown gas? A._13.3 g/mol B._44.1.g/mol C_177 g/mol D._7.3¢/mol 35. The rms speed of the molecules in an ideal gas translational kinetic energy of the gas in joule? molecular mass of 32 is 400 m/s. What is the average ‘A. SE-21 B._5.25E-21 C_4.256-21 D._4.5E-21 36. ‘A solution is prepared at 20 °C containing 7.8% wt. benzene at 20°°C is 75 mm Hg. What is the equilibrium AL 343 BL 415 benzene in non-volatile olf (MW 422). Vapor pressure of sressure of benzene vapor inmm Hg above the solution. C. 7.56 TD. 23.54 37. Solvents A and B form an ideal solution. Solvent A has the same temperature, solvent B has a vapor pressure which the mole fraction of A is 0.285? ' vapor pressure of 345 mm Hg at room temperature. At of 213 mm Hg. What is the vapor pressure of a mixture in AL 213 B_345 C568 D251 38. ‘At 30°C a sample of hydrogen is collected over water in @ 500 ml flask. The total pressure in the collection flask is 745 mm Hg. What will be the percent error in the am pressure of water is not made? the correction for the vapor A. 0.0%. 3 +4.5% D._ 44.3% |. What is the molar mass dissolved in 400 mL of water at 4 °C? The density of mer of biomolecule that produces an osmotic pressure of 12 mm H;0 when 20 grams is ercury is 13.5 g/cm*. ‘A._1.6764 g/mol B._3.6265 g/mol C._ 9.765 g/mol D._8:72g/mol Page 6 of 21,440. At 20°C and one atmosphere, one liter of water will absorb 0.043 g of oxygen or 0.19 g of nitrogen. Atmospheric air is 20.9% oxygen by volume, and the remainder is assumed to be nitrogen. What mass of oxygen will be absorbed by one liter of water exposed to 20 °C air at one atmosphere? ‘A. 0.009g B._0.1508 C_ 023g D._0.043g 41. A by-product of the reaction that inflates automotive airbags is very reactive sodium, which can ignite in ai ‘Sodium produced during inflation process reacts with another compound added to the airbag contents, KNOs, via the reaction: Na + KNO, -> KO + Na;O + Nz How many grams of KNOs are required to remove 5.00 gram of sodium? A. 110g B. 2.208 C4408 D. 1.008. 442. For the reaction NO + H,0 > HNO, + NO, How many grams of HNO, can be formed when 1.00 gram of NO, and 2.25 gram of water are allowed to react? A. 0.913g |B. 0.667g 15.78 D. 1378 43, Urea, CH.NO, is used as @ nitrogen fertilizer. It is manufactured from ammonia and carbon dioxide at high pressure and temperature. NH, + CO; -> CH,N;O + H,0. In a laboratory test, 10 g ammonia and 10 g CO, were added to a reaction vessel. What is the maximum quantity of urea that can be obtained? A 102g B. 121g C1368 D. 15.68 ‘44, From the date in #43, how many grams of the excess reactant are left at the end of the reaction? ‘A. 2.3g00, B._1.2COr C_L2gNHy D. 2.3gNH, Page 7 of 21,45. From the date in #43, if 11.2 g of urea is obtained in the laboratory preparation, what is the percentage yield of urea? A. 65.4% B._ 75.9% C_ 82.4% D. 91.2% ‘46. The gas acetylene is produced according to the following reaction by treating calcium carbide with water: CaC, + H,0 > GH + Ca(OH),, Calculate the number of hours of service that can be derived from 1.0 Ib of carbide in an acetylene lamp burning 2 ft® gas per hour at a temperature of 75 °F and a pressure of 743 mmHg. ‘A. 3.11hr B._3.45 hr C287 hr D._1.86 hr 47. Carbon dioxide decomposes at elevated temperature to carbon monoxide and oxygen. At 3000 K, 2 mole of CO, is placed in a 1 L container and allowed to attain equilibrium. At equilibrium, 0.90 mole CO remains. What is the value for Kc at this temperature? A. 0.82 8. 1.88 C244 D. 3:12 448. The equilibrium constant, Kc, for the dissociation of HI into hydrogen gas and iodine vapor is 21 at a cer temperature. What will be the molar concentration of hydrogen gas if 15 grams of HI gas is introduced into a 12.0 L flask and allowed to come to equilibrium? ‘A._4.58 mol/L B._0.00687 mol/L C._4.46-5 mol/L D._0.117 mol/L 449. Consider the reaction: H+ I; €> HI Ke, = 25. Determine the number of moles of H, remaining when 1 mole of both Hand l, are equilibrated in a 1 liter container. A._1/6 mole B._2/7 mole C_5/7 mole D._ 5/6 mole 50. The reaction of Br: q and Cl; q to form BrCl q has an equilibrium constant of 15 at a certain temperature. If 10 Bgrams of BrCl is present in a 25 Lreaction vessel, initially, what will the concentration of BrCl be at equilibrium? A. 3.8E-3 mol/L. B._5.77E-3 mol/L. C._1.97E-3 mol/L D._9.9E-4 mol/L. Page 8 of 21,51. Given the reaction A + B > 2C; K = 50. Determine the final concentration of C when 1 mole of both A and B are added to a 1 liter container containing 0.1 mole C. ‘A. 0.78 mole B. 0.88 mole C166 mole D._1.85 mole 52. A2 L flask is filled with 0.2 mole Hi. It is allowed to reach equilibrium at high temperature. If at equilibrium the flask was found to contain 0.078 M HI, calculate Kp. A. 4.266 B.4.2E5 C1267 D._0.0199 '53. Ammonia is formed from a mixture of 3 moles hydrogen and 1 mole of nitrogen. At lower temperature the yield is higher, but the time require for equilibrium to be reached be too great to be practical, except for the addition of a catalyst. The pressure is kept high and the temperature low as practical. Under equilibrium conditions at 400 °C and 10 atm pressure, 3.85 mole percent of ammonia is obtained. Calculate Kp for the reaction. The ratio of 3 volumes of hydrogen to 1 volume of nitrogen is maintained, regardless of the amount of ammonia formed. Of the 96.15 percent by volume which is not ammonia, one-fourth is nitrogen and the remaining is hydrogen. ‘A. 0.000139 B. 0.000145 C_0.000157 D. 0.000164 54, The reaction CO, + Ha €> CO + H20 was investigated by passing mixtures of CO; and H, over a catalyst at 900 °C at 1 atm pressure. The resulting gas was chilled quickly to room temperature by passage through a capillary and was analyzed. In one experiment the partial pressure were as follows: CO, = 0.2142; Hy = 0.2549; CO = 0.2654; H.0 = 0.2654 atm. Calculate the number of moles of hydrogen present in another equilibrium mixture containing 22.72 moles of CO, 22.72 moles HO and 48.50 moles CO>. ‘A. 76.45 moles L__8. 8.25 moles C._9.48 moles [__D. 10.1 moles 55. When NO; is cooled to room temperature, some of it reacts to form a dimmer, N,O,, through the reaction NO; > NOx. Suppose 15.28 of NOz is placed in a 10 L flask at high temperature and the flask is cooled to 25 °C. The total pressure is measured to be 0.500 atm. What is the partial pressure of NO; in the flask after the reaction come to equilibrium? A. 0.19 atm LB. 0.25 atm C._0.28atm [_D. 032atm Page 9 of 2156. Ethanol is manufactured by the hydrogenation of acetaldehyde. The feed gas to the reactor contains 30 mole% acetaldehyde 40 mole% hydrogen, 20 mole% nitrogen and 10 mole% water. if the recation comes to equilibrium at 650k and 2 bar, and if no other reaction occurs, what is the mole fraction of acetaldehyde to the product gas from the reactor? Assume ideal gases and, for the given reaction, AG? = .027 KI/mole at 650 K (P° = 1 bar). ‘A. 0.120 B._0.163 C239 D._0.283 '57. For the reaction NaHSOs yy <> Na5.07 ») + H:0 jp, AH = 19,800 cal and AG = 9,000 cal at 25 °C. Assuming AH to be constant, calculate the dissociation pressure of NaHSO. at 700 K. A. 1B atm B._27 atm c_S4atm D._105 atm ‘58. Potassium hydroxide ionizes completely in water. What is the pH of 0.05 M KOH? AL 13 B 115 ae ae D. 12.7, 59. ‘The pH of acid rain may be A 16 e as low as 2.80. What is the B. 1.663 jronium ion concentration of such acid C_ 6.3612 [b. 9.762 ). Glycolic acid, a constituent of sugar-cane juice, is used in the processing of textiles and leather. A 0.10 M solution ‘of glycolic acid, HOCH,COOH, has a pH of 2.41. What is the K, for the acid? ‘A. 1663 B 16E-4 C16ES D. 16E6 61. From the date from #60, what is the degree of ionization in the 0.10 M solution? A. 3.9% BL 8.9% Cc 12.1% D._ 17.7% Page 10 of 21,62. Calculate the OH in 0.1 molar ammonium hydroxide solution Ky = 1.8E-5. AL 1362 B._13E3 C4264 D. 4.262 63. A student is titrating 50 mL of 0.2 N HCI solution with a solution of 0.2N KOH. He accidentally adds one mL too much titrant. What is the pH of the resulting solution? A. 103 BL aaa Soo Dd. 73 (64, Calculate the pH of a 0.01 M NH.NO, solution given ky = 1.6E-5 for NH. A 24 B. 3.6 Cc 42 Dd. 56 65, Calculate the percent ionization of 0.10 M butanoic acid (K, = 1.5E-5) in a solution containing 0.05 M sodium butanoate. ‘A 3.065 BL 3.0E-4 3.062 D452 66. In a titration, 2.7 cm’ of 0.100 mol dm’ sodium hydroxide, NaOH, solution is added to 25.0 cm’ of 0.125 mol dm? benzoic acid, CsH COOH solution. Calculate the pH of the resulting solution given that the pk, of benzoic acid is 4.19. AL 313 B. 412 C745 D_ 9.42 Page 11 of 21,67. The solubility product of Pbi is 7.9E-9. What is the molar solubility of Pbl, in distilled water? A._2.0E-3 B. 1256-3 C_5.06-4 D._8.9ES 68. The solubility of gold (Il) nitrate is 1.0E-4 g/L. what is the solubility product of Au(NO,).? A. 106-16 B. 2.7615 C._1.26-26 D. 32-25 69. What is the equivalent weight of a weak acid that requires 26.3 ml of 0.122 M KOH to neutralize 0.682 gram of the acid? ‘A212 g/equiv B._ 4.70 g/equiv C147 g/equiv D682 g/equiv 70. What volume of 0.125 M H,SO, is required to neutralize 2.50 g of Ca(OH)? AL S4mb B__270mL C135 mL Ld. 0.170me 71. In standardizing a solution of HCI itis found that 47.26 mL of the acid are equivalent to 1.216 g of pure Na;CO;. What is the normality of the acid? ‘A._0.4855N 8B. 0.3540N C_05020N D._0.3902N 72. Vinegar is an aqueous solution of acetic acid. A 5 mL sample of a particular vinegar requires 26.90 ml of a 0.175 M NaOH for its titration. What is the molarity of acetic acid in the vinegar? A. 0.52 B. 1.04 [Lc 094 [__b. 047 Page 12 of 2173. A mixture of Na;CO; and BaCO; weighing 0.2000 g requires 30.00 mL of 0.1000 N acid for complete neutralization. ‘What is the percentage of Na,COs in the sample? A. 55.7% B. 44.3% C_ 34.4% D._42.1% 74. A 1-gram sample impure K;COs is taken for analysis. The solution of dissolved sample required 58.10 ml of 0.14 HCI. However, 0.65 ml of NaOH was used for back titration (1 mL HCI is equivalent to 2.60 mL NaOH). Calculate the purity of the sample expressed as percent K,O. ‘A. 38.14% B._ 40.23% 34.8% D. 42.1% 75. A mixture contains Na;COs, NaOH and inert matter. A sample weighing 1.500 g requires 28.85 mL of 0.500 N HCI to reach a phenolthalein end point. And an additional 23.85 ml to reach a methyl orange end point. What is the percentage of NaOH in the sample? A. 84.27% B. 50.68% L_© 2057% D._ 6.67% 76. What is the mass of precipitate formed when 12.0 ml of 0.150 M NaCl is added to 25.0 ml of a 0.0500 M AgNO; solution? A. 258g B. 0179 C3608 D._0258— Page 13 of 2177. A 2.35-gram sample was dissolved in water and the chloride ions were precipitated by adding silver nitrate. If 0.435 g precipitate was obtained, what is the percentage of chlorine in the sample? ‘A. 10.8% BL 4.6% C._ 43.5% D._ 18% 78. A super phosphate fertilizer was analyzed for phosphorus. A 0.5414-gram sample produce a 0.1277 gram of ‘Mg,P,0; residue upon ignition of the magnesium ammonium phosphate precipitate. The percentage of P.O; present in the sample is A. 20.5% B._ 18.20% C_ 15.04% D. 14.02% 79. 0.3991 gram of an unknown sample containing chloride is dissolved and precipitated with 4398 mL excess 0.1056 M AgNO;. A sintered glass crucible weighing 23.4101 g is used to filter out the resulting AgCl. The new weight of the dried crucible is 23.9622 g. Compute the percent of chlorine in the sample. ‘A. 37.56% B._47.82% C34.22% D._27.33% ‘80. What is the molar specific volume of a gas in m'/kmol at 1.722 MPa and 99 °C if the compressibility of the gas at these conditions is 0.87? A 51 LB. 21 Cc 16 Dd. 35 81. Using the Van der Waal’s equation, calculate the pressure exerted b 1 mole of carbon dioxide at 0 °C in a volume of 1L ‘A._2.45 atm B._11.6 atm C_19.8.atm D._27.9 atm Page 14 of 21'82. A mass of 500 g gaseous ammonia contained in a 30,000 cm steel bomb immersed in a constant temperature bath at 65 °C. Calculate the pressure of the gas using the Redlich-Kwong equation. ‘A._27.51 bars B._23.86 bars C._25.40 bars D._30.70 bars ‘83. A 20-V potential difference is applied across a parallel combination of a 10-ohm resistor and 2 30-ohm resistor. ‘The currentin the 10-ohm resistor is A OSA B. 067A © 4A D. 2A ‘84. How many calories are developed in 2 min in an electric heater which draws 3.0 ampere when connected to a 220 volt line? ‘A._14,800 cal B._ 18,920 cal C._ 16,500 cal D._17,170 cal ‘85. How many grams of iron can be plated out at the cathode if a solution of Fe™ is electrolyzed by a current of 1 ampere for 30 minutes? A. 052 BL 1.04 C838 D. 16.6 ‘86. An aqueous solution of gold (Ill) nitrate is electrolyzed with a current of 0.555 ampere until 1.32 g au has been deposited on the cathode. If the atomic weight of Au is 197, determine the duration of the electrolysis. ‘A__ 65.43 min. B._23.67 min. C._58.28 min. D._60.00 Page 15 of 21,87. In the electrolysis of aqueous NaCl how many liters of Cl: at STP are generated by a current of 7.50 A for period of 50 min? ‘A. 45,000 L B. 2.611 £ Smt LD. 104L . What current is required to produce two grams of metallic copper from copper sulfate solution in 1.5 hours? ‘A. 087A B. 112A C1524 D. 1.85, ‘89. One faraday of current was passed through the electrolytic cells placed in series containing solutions of Ag’, Ni” and Cr” respectively. The amount of Ag (AW 108), Ni (AW 59) and Cr (AW 52) deposited will be: ‘A. 108g Ag, 29.5gNi, | 8B. 108gAg, 108gNi, C 108g Ag, 59g Ni, D. 108g Ag, 117.5@ 17.5 gCr 108 gCr s2gcr Ni, 166 g Cr 90. From the following heats of reaction: 2C+H2y > GHaw OH =227 ki/mol 6C-+3H24q) > CeHey AH = 49 Kd/mol Calculate the heat for the reaction CHa > CsHew A._ 26.7 ki/mol B._ -26.7 kj/mol C._-178 ki/mol D._-632 i/mol ‘91. Consider the following reaction: 2Na y) + Cy > 2NaCl jy AH =-821.8 KI, what is the amount of heat transferred when 5.6 grams of Na reacts at constant pressure? A. 821.84) B. 4,600 KI C2062) D._L0Ez Page 16 of 21,92. The AH for the formation of NOCl, from the gaseous elements is 51.71 Ki/mol at 25 °C. if the gases are ideal, calculate the AU. ‘A._52.95 ki/mol B. 56.44 ki/mol C5851 ki/mol D._60.27 i/mol ‘93. The heat of combustion of a n-heptane at constant volume and 20 °C is 1148.93 kcal/mole. What is the value of the heat of reaction at constant pressure? ‘A._-115.13 cal/mole B._-1151.3 kcal/mole C_-1151.3 cal/mole D._1151.3 kcal/mole ‘94, Calculate the heat of reaction for the following at 25 °C and 1 atm; CaCz + 2H,0,)-> CalOH)a,a + CHa ig. ‘A._-20715 cal B._-24800 cal. C_-29972 cal. D._-35420 cal ‘95. A special purpose piece of laboratory glassware, called a pycnometer, is used to measure liquid densities. it has @ ‘volume of 25 cc and a mass of 17.24 g when itis full of air. When filled with a liquid of unknown density, its mass = 45. G. what is the density of this liquid? ‘A__1.11 g/ml B._1.25 g/mL C142 g/mb D._155 g/mL ‘96. Using the Antoine equation, the vapor pressure of tetrahydrofuran at 80 °C is estimated to be torr. ‘A. 200 B. 1518 C1173 D._ 2562 Page 17 of 21,97. The coefficient of viscosity for water vapor at 150 °C and 1.01 bar is 1.445E-5 Pa-s. Calculate the molecular diameter of the water molecule under these conditions. A. 4220m [L8.3.75nm C._2.42nm D._0.40nm ‘98. A gas whose viscosity is 200 uP flows through a capillary tube 2 mm in diameter an d 2 meters long. If 5 liters of gas pass through the tube every 10 seconds, what must be the pressure head in dynes/cm?? ‘A__5.09E5 B._7.S6ES C_8.3265 D._ 9.0465 99. A certain liquid has a viscosity of 14 poise and a density of 3.2 g/mL. How long will it take for platinum ball with a 2.5 mm radius to fall 1 cm through the liquid? Density of platinum is 21.4 g/cm’. ‘A._4055 B. 28.45 C3345 D. 489s 100. A light machinery oll has viscosity of SE-2 Pa-s and density of 970 kg/m? at 25 °C, how long will it take for @ sample to pass through a viscometer if water under the same conditions takes 1 minute? ‘A._59.9 min B._ 45.8 min C_38.8 min D._27.9 min Page 18 of 23101. A liquid of density 850 ke/m* having a surface tension of 0.055 N/m, will rise how far in a glass capillary of 1.4 mm inside diameter? A._19 mm. B_ 14mm i © 5mm D._0.45mm 1102. Which of these 0.1 M solution will give the highest boi at atm? ‘A. Table salt solution B._Barium chloride C_Sugar solution D._ Potassium chloride 103. LaCP is a salt, and like virtually all salts it is complet ely dissociated into ions in aqueous solution. Suppose we dissolve 0.2453 g of LaCl? in 10 g of HO. What will be the boiling point of the solution at atmospheric pressure, assuming ideal solution behavior? ‘A._100.205 °C. B._100.051°C C._100.410°C D._ 100.103 °C 104. Find the K, for tartaric acid if a 0.10 m aqueous solution freezes at -0.205 °C. Assume that only the first ionization is of importance and that 0.10 m = 0.10 M. A. 246-6 B. 5.5E5) C_ 87E4 D._4iE3 105. The osmotic pressure at STP of a solution made from 1 L of NaCl wy containing 117 g of NaCl is? ‘A. 44,77 atm B._48.87 atm C._89.54 atm D._ 117 atm 106. How many KI of heat be removed from 1000 g of water (heat capacity of 4.184 J/g-K) to lower the temperature from 18 °Cto 12°C? A. 25E-2K [8.14 C426) D. 25K Page 19 of 21,107. Freon-11, which has the chemical formula CCL, has a normal boiling point of 23.8 °C. The specific heats of CLF and CCLF iy are 0.87 and 0.59 J/g-K respectively. The heat of vaporization is 24.75 ki/mol. Calculate the heat required to convert 10.0 g of Freon-11 from a liquid at -50 °C to a gas at 50°C. A. 015K B__0.64K) C 18K Dd. 26K 108. In an experiment, 0.02 kg of a substance is heated in a bath of boiling water until its temperature is approximately 100 °C. the substance is then placed in an insulated container that is holding 0.10 kg of water at 25°C. the final temperature of the mixture is 32 °C. The specific heat of substance, in kJ per kg per °C, is? A216 8.257 419 [Lo 10 109. A 25 g ice cube at 0 °C is placed in a glass with 2.5E2 g of tea at 25 °C. What temperature will the tea cool to? Cp of tea = 4.184 I/g-°C. ‘A. 24.3°C B. 208°C C_ 155°C D._10.5 °C 110. Calculate the enthalpy change upon converting 1 mol of ice at -25 °C to water vapor at 125 °C under a constant pressure of 1 atm. The specific heats of ice, water, and steam are 2.09 J/g-K, 4.18 J/g-K and 1.84 J/g-K, respectively. For water the heat of fusion is 6.01 ki/mole, and the heat of vaporization is 40.67 ki/mol. A. 40k) B. 48K) C_ 56K) D. 60K) Page 20 of 21111. Ten kilograms of ice -10 water? Assume an insulated container. ‘added to 100 kg of water at 20 °C. What is the resulting temperature in °C of the A. 12.65 B_ 9.28 C1183 0. 10.46 112. Polonium crystallizes in a simple cubic pattern with a unit cell length of 3.63 angstrom. Estimate the density of Po in g/cm’. A 5.48 B. 6.12 C784 D920 Page 21 of 21