BITSAT Birla Institute of Science and Technology, Pilani Solved Paper 2012 Instructions 1, There ate 150 questions in all. The number of questions in each partis as follows Subjets No. of Questions Part (Physics) 1-40 Parc Il (Chemistry) 41-80 Pare (a) English Proficiency 81.95 (b) Logical Reasoning 96-108 Part IV (Mathematies) 106-150 2, All questions are multiple choice questions with four options, only one being correct. ‘3, Each correct answer fetches 3 marks while incorrect answer fetches 1 matk. Part | Physics 1. A straight wire of mass 200 g and length 1.5 m carries a current of 2A. It is suspended in mid-air by a uniform horizontal magnetic field 8, The magnitude of B (in tesla) is (assume g = 9.8 ms~*) (a) 2 (b) 1.5 {c) 0.55 (d) 0.65 2 In the circuit shown the value of I in” ampere Bl fm 1a | [a 1 fal (b) 0.60 (ce) 0.4 (d) 15 3. When light of wavelength 300 nm falls on a photoelectric emitter, photoelectrons are liberated. For another emitter, light of wavelength 600 nm is sufficient for liberating photoelectrons. The ratio of the work function of the two emitters is (@) 1:2 ) 2:1 4:1 @ 1:4 4, A monatomic gas is suddenly compressed to (1/8)th of its initial volume adiabatically. The ratio of its final pressure to the initial pressure is (Given, the ratio Of the specific heats of the given gas to be 5/3) (a) 32 © 24/5 (b) 40/3 @s2| BiTSAT - soived Paper 2012 5. The intensity of the magnetic induction field at the centre of a single turn circular coil of radius 5 cm carrying current of 0.9 A is (a) 36nx 107 T — (b) On x 107 T (©) 36nx10°T — (d) On x 10° T 6. A capacitor of capacity 0.1 uF connected in series to a resistor of 10 M Qs charged toa certain potential and then made to discharge through resistor. The time in which the potential will take to fall to half its original value is (Given, logo 2 = 0.3010) (a) 28 (b) 0.6935 © 05s (@) 10s 7. If the force is given by F = at + be? witht as time, The dimensions ofa and b are (a) (MLT*), [MLT] (b) (MELT), [ML] (© (MET), (ML?T™) (a) (MPT), [MIT] 8. A ray of light is incident on the interface between water and glass at an angle i and refracted parallel to the water surface, then value of x, will be wear eas es Giess 7 (a) (4/3) sini (b) ae 4 O33 @i 8. Abody is moved in straight line by constant power of machine. What will be the relation between the travelling distance and time? (a) s? ) T or (a) T* 40. Two equal charges q are kept fixed ata and +a along the xaxis. A particle of mass Chemistry 41, The ionic conductance of Ba** and Cl- are respectively 127 and 769° cm? at infinite dilution. The equivalent conductance (in Q~! cm?) of BaCl, at infinite dilution will be (a) 330 (b) 203 (0) 139.5 Oa 42. If the clevation in boiling point of a solution of 10 g of solute (mol. wt. = 100) in 100 g of water is AT, the ebullioscopic constant of water is @ ah a7, (oioary (@) 100 aT, 48. Given that; H,0(!) —> H* (aq) + OH" (aq); aH = 57.32k H,(g) + 5 O2(g) —> H,000; ~~ 286,02k) Then calculate the eee of formation of OH™ at 25°C. hs. (a) ~ 228.8kI (b) ~ 343.52 kJ (c) + 228.8 kJ (4) + 343,52 I 44, Calculate the amount of heat evolved when '500.cm* of 0.1 MHClis mixed with 200.em? of 0.2 M NaOH. (@) 97.30 (b) 2.865 kd (©) 2.292 bd (d) 0.573 45. Which of the following will be the most effective in the coagulation of Fe(OH); sol? mand charge 9 is brought to the origin and given a small displacement along the axis, then (a) the particle executes oscillatory motion (b) the particle remains stationary (c) the particle executes, SHM along x-axis (4) the particle executes SHM along y-axis (a) Mg(PO.)2 (6) BaCl, (6) NaCl (@) KCN Identify ©” in the following reaction; NOs O Sach 4 NeNOs, y NaN, \ (a) benzamide —__(b) benzoic acid 0. (©) chlorobenzene —(d) aniline ona 4 J A ,COONA CY WY OH coon 10,7 mp (a) Friedel-Craft reaction (b) Kolbe reaction (¢) Reimer-Tiemann reaction (@) Wittig reaction Which of the following is isoelectronic of carbon? (a) Nat @)AI* (© 0 @) NT In which of the following species only one type of hybridisation is present? (a) CHly—CH, —CH=CH, (b) cH, —CH=CH—CH, (0) CHy=-CH—CH—=CH, (qd) CH; —CH=CH—CH80. 2Mn0; + 5H,0, + 6H” — 22+50, +81 ‘dentify Z in the above reaction (a) Mn* &) Mn* (Ma (@) MnO, Bi, In the titration of NaOH and HCl, which of the following indicator will be used? (@) Methyl orange (b) Methyl red (©) Both (a) and (b) (@) None of (a) and (b) 82. Which of the following is correct IUPAC name for K,(Cr(CN),0,(0).NH,]? (@) Potassium amminecyanoperoxodioxo- chromatic (1V) (b) Potassium amminecysnoperoxodioxo- chromium (V) (© Potassium amminecyanoperoxodioxo: chromium (Vi) (4) Potassium = amminedicyanodioxoper -oxochromate (VI) 53, Which of the following is process used for the preperation of acetone? (a) Waber process (b) Wacker process (©) WolfKishner reduction (4) Gattermann-Koch synthesis 54, Lindane can be obtained by the reaction of benzene with (a) CH,CVanhydrous AlCl, (b)C,HsVanhydrous AlCl, (€) CH,COCVanhydrous AIC, (@) Cl, in sunlight 55, The structure of cis-bis (propeny!) ethene is H a), oo G ABN ea Oy o> H a 56. 5 moles of Ba(OH), are treated with excess ‘0f00,. How much BaCO, will be formed? (394g (b) 197 g (seg (4) 985g 58, a. 1 The decomposition A diatomic molecule has a dipole moment of 1.2 D, Ifits bond distance is 1.0 A, what fraction of an electronic charge, e exist on ‘each atom? (a) 25% of e (b) 50% of e (© 60% of e (d) 75% of e ‘A gos is heated through 1°C in a closed vessel and so the pressure increases by 0.4%. The initial temperature of the gas (a) - 23°C (b) + 23°C (o) 250°C (d) 523°C For 2NOBr(g) — 2NO(g) + Br3(g) 2 and pis the total q will be at equilibrium, Ps, x pressure, the ratio = 1 1 5 1 5, Oo temperature is 1 at OF ‘maximum for (a) MgcO, (b) CaCO, (©) BaCO, @srco, When some amount of zinc is treated separately with excess of sulphuric aci and excess of sodium hyéroxide solution, the ratio of volumes of hydrogen evolved is () 1:1 (1:2 (| 2:1 @)2:3 ‘A compound (A) when treated with PC, and then ammonia gave (B). (B) when treated with bromine and caustic potash produced (C). (C) on treatment with NaNO, and HCI at 0°C and then boiling produce ortho-cresol. Compound (A) is, (a) ochlorotoluene (b) o-toluie acid (€) metoluie acid (4) obromoroluene Alizarin is an example of {a) triaryl dye (b) azo dye (c) vat dye (@) anthraquinone dye4. What will be the main product when acetylene reacts with hypochlorous acid? {a) Trichloro acetaldehyde (b) Aceraldehye {) Dichloro acetaldehyile (@) Chloro acetaldehyde 6. Barium titanate has the periovskite structure, ie.,a cubic lartice with Ba fons ar the corners of the unit cell, oxide fons at the face centres and titanium ions at the body centre. The molecular formula of barium titanate is (a) BaTiO, (b) BaTiO, (c) BaTiO, (@) BaTiO 66 Which of the following hormone, is responsible for the growth of animals? (@) Avxin (b) Insulin (© Adrenaline (@) Somatotropin 67, Which of the following have the largest ionic size? (a) F )O™ (Nat) Mg (88. Ifthe radius of H is 0.53 A then what will be the radius of ,Li?*? @oi7z a (b) 0.36A (053A (6) 0594 68, Which of the following will have highest value of pK? (@) FCH,CH,COOH (b) CH,CH.F COOH (¢) CH,CH. Br-COOH (gd) CH,CH,COOH GastA) + NaOH 9 B24 9D and D decolourises acidified KMn0, Idenuify C and D. (a) Na,COy, NaOH (b) (COOH), (COON): {) (COONA),, (COOH); (@) None of the above Ti. The polymer polyurethanes are formed by treating diisocyanate with (a) butadiene (0) isoprene (©) geo! (a) acrylonitrile n. 1 ‘What will be the volume of Oz t NTP liberated by § A current flowing for 193s through acidulated water? (a) 56 mL. (b) 112 mL (c) 158 mL (@) 965 ml. COs goes to alr, causes green house effect ‘and gets dissolved in water. What will be the effect on soil fertility and pH of the water? - (a) Increase ~ ~(b) Decrease {@ Remain same (4) None of these 2N,05 —* 4NO, +O; If rate and rare constant for above reaction are -240x10° mols’ and 3x10 57 respectively, then calculate the concentration of NOs, (14 12 (00.04 (A) 0.8 ‘The molecule BF, and NF, both ace covalent compounds, but BF, is non-polar and NF; is polar. The reason is that (a) boron is a metal and nitrogen is @ gas in ‘uncombined state. (b) BF, bonds have no dipole moment whereas NF, bond have dipole ‘mome {€) atomicsize of boron is smaller than that of nitrogen. (@) BF, is symmetrical molecule whereas INF, is unsymmetrical 1.2% NaCl solution is isotonic with 7.2% glucose solution. What wil be the van' Hoff factor, i? @os 2 Green vitriol is (@) ferrous sulphate (b) tin oxide (0) zine oxide (@) fesrous carbonate ‘2-bromopentane with alcoholic KOH yields fa mixture of three alkenes. Which of the following alkene is predominant? (a) L-pentene 1 we(b) Cis-2-pentene (©) Trans-2-pentene (@) Cis-1-pentene 78, In which of the following compounds, the bond length between hybridised carbon ‘atom and other carbon atom is minimum ? (a) Butane (b) Propyne (©) Propene (@) Bucene 80. Which of the following is IUPAC name of compound? English Proficiency Directions (Q.Nos. 81 to 83) Out of the four alternatives, choose the one which expresses the right meaning of the given word. 81. Dubious (@)Doubeful (© Duplicate 2, Flabbergasted (@)Scared (b) Embarrassed (© Dumbfounded (@) Humiliated 83, Eternal (a)Innumerable (b)Unmeasurable (©) Prolonged. (4) Perpetual (b) Disputable (@) Dangerous Directions (Q.Nos. 84 t0 86) Choose the word opposite in meaning to the given word. 84, Despair (a) Belier (b) Trust (©) Hope (d) Faith 85. In toro (@) Bluntly () Partially (©) Entirely (d) Strongly 86. Protean (a) Amateur (b) Catholic (©) Unchanging (4) Rapid one coo oe ‘0 (@) 1, 4-dichloro-2, 6-dioxo-4-carbony!: Loie acid (b) 2,4-dioxo-1, 4-dichlorohexane-1 carboxylic acid (6) 1,4-dichloro-2, 4, 6-dioxocyclohexane I+ carboxylic acid @ 1, 4-dichloro-4-formyl-2, cyclohexane -1-carboxylic acid. 6-dioxy Directions (Q.Nos. 87 to 89) 4 part of the sentence is underlined. Below are given alternatives te the underlined part at a, b and ¢ which may improve the sentence, Choose tie correct alternative. in case no improvement is needed, your answer is 87. He declined all the allegations against him. (@)spurned (b) refused (0) refuted (@) No improvement 88. Ics time we leave, {adleft (b) have to leave (©) would leave (4) No improvement 89, We spent an hour discussing about his character. (a) on his character (b) of his character (© his character (4) No improvement Directions (Q.Nos. 90 10 92) Sentences are siven with blanks to be filled in with an ‘appropriate and suitable word, Four alternatives are suggested for each question, Choose the correct alternative out of the four. . Are your really desirous visiting Japan? (aot (b) in © (@) about$1. When Indians from the South move North, they find certain aspecs of life quite from their own. (a) strange (b) separate (0) different (@) divergent ‘The sky is overcast, we ...... the storm will ssoon burst. (a)expect (b) hope fo) trust (¢) suspect Directions (Q. Nos. 93 t0 95) The first and the last parts ofthe sentence are numbered 1 to 6 The res of te sentence is spel nto four parts and named P, Q, R and S. These four parts are not given in their proper order. Read the parts and fird ‘out which of the four combinacions is correc. Then {ind the correct answer. 83. 1. Early ro bed, early torise, makes a men healthy, wealthy and wise But for the morning tea, | had to wait for someone to get up before me. ©. This saying inspired me co rise early R. That day I was the first ro getup. SS. One day | got up early in the morning 6. Then 1 realised that it was a waste of time to get up carly and wait for the ‘morning tea. Logical Reasoning 96, In a certain code MONKEY is XDJMNL. How is ‘TIGER’ written as? (a)QDFHS (0) SDFHS (© SHFDQ (a) WEES 47. Find the missing number from the given responses Ry Rw ep VY V 1 zm? 31 (0) 229 (©) 234 (ay 312 (a) QSRP (b) QPRS: (© PORS (a) SPOR 1. A wood-cutter was cutting a tree on a river bank. P, He knelt down and prayed, @. His axe slipped and fell into the water. R. God Mercury appeared before him and asked about the matter, S. He could not get it back asthe river was very deep, 6. He dived into the water and came up with an axe of good, (a) RPQS (b) RPSQ. (© QSRP (6) QSPR 1, Adog stole a piece of meat from a butcher's shop. P, He barked in anger. Q. He ran to the jungle with the piece of meat, R. He saw his reflection. 8. He crossed a river on the way. 6. He lost his piece of meat. (a) QPSR (b) SRP. (©) QPRS (a) SRPQ If the day before yesterday was Thursday, when will Sunday be? (a)tomorrow (b}day after tomorrow () today (@) two days after today 99, In a row of children Ravi is fourth from right and Shyam is second from left. When they interchange positions Ravi is ninth from right. What will be Shyam position from left? (@) Filth (©) Seventh (b) Sixth (¢) Eighth103. Which number is wrong in the given series? 41,9, 25, 50, 81 @1 25 (50 er 108, In the following question and A stands for any of the Mathematical signs at different places, which ae given as choices under each question, Select the choice with the correct e ch % i) ‘makes the question as correct equation? at 105. Which answer figure is the exact mirror ® ® © @ Image of th> given figure when the mirror is 102 “All the members ofthe Tennis cub are MA (pmievahrarFO members of the badminton club tao", No er E| (a) Some women play Tennis a (>) No member of the Tennis club plays Q badminton Answer Figures (© Some women are members of the 1 as S22] (@) No woman is « member of Tennis club fa) (b) to @ Mathematics 106. The equation of the base BC of an 108. The length ofthe tangent rom (5,1) tothe equilateral AABC is x+y and A is circle x* + y? + 6x ~ 4y ~ Ghat) The lengh of he ade cf eo ‘nal a oe wa »(3) ©) 6 ol on att 2? 109. Ifthe length of the major axis of the ellipse (3) (3) (2)-(B- someone 107, The equation of the circle circumscribing the triangle formed by the lines x + y = 6 ‘of minor axis, its eccentricity is 2x + ye dand x» 2y. ss titi eae @x? ty? + 17x + I9y ~ 5¢ @5 (b)x? + y? -17x = 19y - 50 2 (ox? +y? + 17x ~ Wy —5 of (ax? + y? — 17x —19y +5“MNS and 7 ave (S)(5) ‘minor axis, If STB is an equilateral triangle, then eccentricity ofthe ellipse is 1 1 1 m+ «©! o> of @ the foci of the ellipse = Land B is an end of the a) OG V The dlitfrence ofthe focal distance of any point onthe Byperbola sequal tts (a)laruscectum (eccentricity (€ length ofthe transverse axis (half the length ofthe transverse axis HA4B4C = 180°, then Cota = cord + cote A= DY CO iy caual corA cot Bore Saual to i (0) cota cosBeorc @-1 @o 118. The angles ofa triangle are in AP andthe lease angle i 30". The greatest anpe ve radians i Te le ans be a) 7 yt fa) 12 (b) 3 e if ean20 B 2 m. 1m. x ms equal 10 pi A=ES ofS) MS. IF4sin“* + cos"! x= m,then xis equal to 1 as 2 1 1 @} 3 MB In a aaBC,a=2.b=3 and sina Then, e0sC is equal to 1 2 wo; oF 1 @h vB © 7. 118. 19, 129, 8 m2. 123, 124, ‘The vector equation r=1-2j-k+e(6j-k) Fepresents a stright line passing through the points (@@.6,~1)and (1, 2, -1) (b)C0, 6-1) and (-1, 4 2) (OG, ~2 - 1)and (1, 4,- 2) (@(L- 2 - Iand (@,- 6 1) The work done by the force 4i ~ 3j + 2k in ‘moving a particle along a straight line from the point (3, 2-1) 10 (2 =1, 4)is (a) 0 units (b) 4 units (©) 15 unies (@) 19 units tn 2 sana +» 2 ay a] ¥ 0 (sin 2 Weos2 1 (@) 2c0s2 + sin2 1 peg SP ona ee X= O.then /(0)is equal to 3 ®2 "O4 wo d 'f-xis measured in degree, chen 2. (cos.) is ismeasured in degre, then 4 (cos) equal 10 (@)-sinx 0) 29 sin x ©-Bainx sine (2) ester tenes (a)~secx (©secx (b) seex + tan x @) seex ~ tan x Ifx= cos? Band y = sin’ then 1 (2) is equal to (a)tan?@ (b) co?@ (sec? (4) cosec? 8 ay Warm at?, y = 2ar,then 2 i equal to * ae 1 @-t w-@t © aac? OF @-4 2dS if the cate of change inthe circumference of a circle of 0.3 cm/s, then the rate of change in the area of the circle when the radius is Sem, is (a)1.5 sq cm/s (b)0.5 sq ems (05 sq cms (@)3 sq cm/s 126. fy = x" — ax* + 48x +7 is an increasing function for all real values of x, then a lies (a)(-14, 14) (b) (12, 12) (O(-16 16) @ai, 2) 127, Rolle's theorem is not applicable for the function f(x) =|] in the interval [-1, 1] ecause (a) (1) does not exist (D)£’(-1) does not exist (c) f(x) is discontinuous at x = 0 (@ F © does not exist 1/2 __sin*@ 1am, (0? 0" __ ois equal x LY are eatet heal wu (0 : = oz ws tm cas! recs equal to x 1 wr on ‘01 (5) @o 11 um t+ 2 + 4] nenlae] n42 én. (a)log 2 (b) log (1 + V5) log @o 192, By climinating the arbitrary constant A and Bicomy = Ax? + Bx,we get the differential equation Waa IF foxy = OE * a) — TORO ba) GQ, x Oand f(0) = kand (x) is continuous at x= G then kis equal to @a+b @e-b @a (ab 134. 14 — Sis a root of the quadratic equation 2? + ar+b=0,then (a, bis equal to (ae 41) C8 4D in, 8) @-41, 8) 195. Ifo and are the roots of the quadratic equation 4x? + 3x +7 = 0, then the value 11 24) ods hs 3 3 @-$ 3 3 4 3 ws 136. Ifa, are the roots ofax* + bx + ¢ = Oand a+kBrk are the roots of pe? + gx + r= Othen? ~ 82 is equal to z 2 © (:) @o P pr @* wi 137, Area of the triangle in the argand diagram formed by the complex numbers. = ie, 2+ia,wherez = s+ iyis (a)/z) ()lzf (o) 2}? dap all @ 32h138, 139, 12, aa. | ‘The sum of_n terms of the series oe 24°86 (@n-1+2" (n-1 @i+2" 0.2 + 0.22 + 0.222 +... ton terms is equal to (2)-(Z)a-10 (n- ce ay «(2)p-@)o-1>] of 2 ‘The number of ways in which a team of 11 players can be selected from 22 players including 2 of them and excluding 4 of them is @) Cy, )"%, cy @ *c, The number of ways four boys can be seated around a round table in four chairs of different colours is (ay24 (by 12 (23 (d) 64 If the coefficient of second, third and fourth terms in the expansion of (1 +x)" are in AP, then m is equal to @7 4 ©@s Ws if laa? A= 1 bb? =Ka-b)(b-e)(e-a), tee then k is equal to (a)-2 1 (2 (@ abe a+b ab a ate ¢ |isequalto be bte 145, 14. 148. 149, (adobe (abe (oarbic® (4% xa b| asi Wa,= 6 x gland, =| lore the Ja b x| la given determinants, then G@a; = 3(a,)* 1 wo(f)tan-as, @(Z)en-%00" (A, = AQ)? The system xtdy-2=3,3e+y450=7 and 2x + ay +2 = Shas {a) infinite number of solutions (© trivial solution (@)no solution If the three points (k, 26), (2k, 3K), (3, 1) are collinear, then k is equal to (a)-2 1 ©; oa @-; ‘The foot of the perpendicular from the point (3, 4) on the line 3x ~ 4y +5 = Ois 81 92 92°81 oes) (333) 46 54 8192 ea) Cas) ‘Avkite is flying at an inclination of 60° with the horizontal. If the length ofthe thread is 120 m, then the height ofthe kite is (a) 60/3 m. (b) 60m 60. ao (@)120m omm If the focus of parabola is at (0, - 3) and its directrix is y = 3, then its equation is (@)xt=-1ay — (b)x* = 12y (@y?s-12y @y?=12ePhysics L® 26 Le 12 a 31) 22, (by 31.0) 82 (a) Chemistry a0 a SL an @) 8. @) 82, ne mw 81 9g a) 101 () 102. 4 Mathematies 108. (97, «a U8) 1 @) 126. (0) 137, 186. 6197 (a) M6. Wd) 147, (a) 28 38, 8. (a) 19.) 29. (0) 38. 1) 8. 10) 0. «ay 0. (a) 7. (b) 2 ua ww 12 16, 144. (a) 10, 20, 30, 50, 70. 50. 10, us, 125, 136, 145,Hints & Solutions Physics 1. Magnetic force on straight wire F = Bil sin@ = Bil sin 90° = Bil For equilibrium of wire in mid-air, F=mg Bil = mg 3 B= TE. 200K IE X98 So cer 2x15 2. We can simplify the network as shown 40 149 ———_ [ae | 2 f 6a (@) () H-—__| a ee ay te ay 18a u 240 © wd av ee So, net resistance, R=24+16=409 Therefore, current from the battery YA aa, R 4 Now, from the cirewit (b), aI’ = 61 Sr = eft Buti=l+l'=14 1=3; 2 =» Jetson 5 3. Work function is given by = we = Paso Py 5. The intensity of magnetic induction field = tol Bo 4nx107 x0.9 2x5x10 B=36nx107T 6. By equation of charging, = qo(l — eR) According to question, qg_1 21.050 % 2 % 0.50=1-—78 eV 21 0.50= 0.50 eVR an or or 2.3026 log, 2Gr € = CR x 2.3026 logy 2 1 10 x 10 10° x 2.3026 log; 2 ort = 2.3026 x 0.3010 or 1 = 0.6935 Dimension of at = Dimension of F (ar) =F) wf ‘MLT™ war (a) =(MLT*) Dimension of bt? {be} =F] wf “} jension of F (b) =[MLT“] sini hat tt whe Snr sin she Fin 90 sini 8, Power = (MIT) = constant (Witty or Sta 10. Work done, W = MB(1 - cos®) = 90° 11. Given, V = 50sin(502) V Maximum voltage, Vp = 50V i insin( so +3) ma ‘Maximum current, iy = 50 mA = 50x 10° A. iy Mo ja” Ja 50x 50x 107 = eae x10 2 12. y = S(sin 4nt + V3 cos4nt) y = S(sin ant + 5/3 cos4xt) Power dissipated, P ~ =1.25W a= {Alw ad A= G+ 5? = (35378 = 00 = 10 13, By the principle of continuity Ay, = Ava ‘According to question, Ay = v= 2a 14, Given circuit é av 2v £j¢—-—— gO R® In loop (1) 12 500 - Ri = 12=4,(500+R) +)From Eas (i and (i, 12x 4(500+R) i = 12x50=500+R = 002 15, EMF induced in an electrical circuit Le (numerically) 16, To convert a galvanometer into voltmeter, the necessary value of resistance to be ‘connected in series with the galvanometer is me txtgeR 18, The work done = area of p-V graph = area of triangle ABC 1 = xapx2Vv=3pv 3°? P| 18, Given in, = 10 Apparent frequency n’ = 1 ( where, n = real frequeney of source v= velocity of sound locity of source 10 9 20, Orbital velocity (v,) at a height A above the earths surface is given by Given, 21. ‘Tension in the string T = mg =30%10 300N Tha m= 10 kg T Mg T Mg = Ma From the figure 300 - 10 10 = 10a a= 20ms* ‘Thus, the maximum acceleration with which the stone can be raised is 20 ms Given, s=10m and ) ts = at 1o= 5 200¢2. Now, s=ut+ a, da? 2 s=0+4x2x10x10 2 $=100m Hence, work done WeFxs Wsmaxs W =50x 2100 (0000 = 10" J ‘Threshold energy of A is Exh, 6.6% 10 x 1.8% 10! = 11.88» 10” 5 _ 1.88 x “16x10 O74ev Similarly, Ey = 0.91 eV Since, the incident photons have energy greater than £,, but less than By So, photoelectrons will be emitted from metal 4 only, Let @ be the angle between vectors P and Q Whose resultant is R, Hence, P= Q and R? 3PQ = 3P* As RP =P? +Q? + 2PQ.c0sd 3P? =P? + p24 272 cos or 3P? - 27? = 2P cose or P* = 27? cos or 1 cos cos =} thus, cos® = cos 60" 2 or In stable equilibrium, the centre of gravity of Object, lies at minimum height from ground. As the object is given a slight push, its centre Of gravity rises because it comes in unstable equilibrium. 2a. |. Fringe displacement xy = Range, = R=“ R Given, Hg = $ wbainto _ one. = sin = 2cos6 = tand=2 @= tan (2) otal mass of the shell = 20 kg Ratlo of the masses of the fragments = 2:3 Masses of the fragments are 8 kg and 12 kg Now, eccording to the conservation of momentum vy 8x6=12%0 v (velocity of the larger fragment) = 4 mvs Kinetic energy = 1 inv? ny = > 1 eaxlax(@te : (4)? = 964 Acceleration |a| = 2x o= ie Vx [2 Vooooa =o rads Kepler's second law. or 2m de constant de L= constant 1. Momentum is conserved is non-clasticity collision but kinetic energy is not conserved. Duneae ‘The produced rays in sonography are ultrasound. 1 tx aela a Minimum force required to move a body up @ rough inclined plane A, = mg (sin @ +H c0s®) Minimum force required to prevent the body form sliding down the rough inclined plane. F =u mg cos According to question, R=3%, c+ mg(sin@ +p. cos®) = 3 (4 mg cosé) sin® + cos8 = 3p cos sin@ = 2p cosd tan@= 2u weeded wi V3 = tan 30° =30° The effective spring constant k, of this arrangement is, re eee kk” 2k go tne kk nace 3 ‘The effective spring constant k, of this arrangement is 31, Electric power 1 or Pat R a mR LR PR 2x P Ras 38, An object is said to be moving with a uniform acceleration, if its velocity change by equal amount in equal intervals of time The velocity-time graph of uniformly accelerated motion is a straight line inclined to time axis. Acceleration of an object in a uniformly accelerated motion in one dimension is equal to the slope of the velocity-time graph with time axis, 39. From Stefan’s law the rate of emission of energy per unit surface area of a black body is inversely proportional to the fourth power of absolute temperature (1) of the body £ =oT4(6 = Stefan’s constant) 40, From Coulomb's law = ie 4ney or q__ @ 4 (a0) =*=(+0.9) = Feox Hence, SHM along x-axis.cnemistry 41 a6 for Bal = nz Ba + 2 1 1% for Bact An Ba? + a= cy 2 1 = 5% 127 +76 x lar = 139.52"! om? 1000 x w era MW an 1000 x w = 100%100% a, 1000 x 10 =an 43. Consider the formation of Hj ork, #£6)+ 106) — Hot, Ait = ~ 2862014 AH, = AH, (H,00) — att, (H4,(g)) ~ 54H, (4) ~ 28620= aH, (14400) 0-9 4H, (H,0() = ~ 286.20 Now consider the ionisation of 0 HOW) — H'(aq) + OH" (aq); (AH = 57.32) Atle = aH, (H"(0q) + Ay, (OH-(ag)) ~ alt, 4,000) $7.32 = 0+ alt/(OH;,) - (— 266 20) or, AH (OW"aq) = 57.32 ~ 286.20 =~ 228881 HCL + NaOH —s Nact + 14,0 Ate=o, Number of moles = 5000.1 200%0.2 © 1000-1990 =0.05 04 During neutralisation of 1 mole of NaOH by 1 mole of HCI, heat evolved = 57.41) Fe aeuttalised 0.04 moles of NAOH by 0.04 ‘mole of NaOH, heat evolved “According io Hardy. Schulze rule, coagulation Baer of tons is directly proportional va charge on ion Fe(OH), is positively charged colloid, twill be coagulated by anion. (2) Mg 5(PO4) == 3Mg? 4 2POy (©) Bac, — Ba + 2¢1- (©) NaCl — Na’ +.¢ @ KCN — K+ ¥en POS has highest charge among the given anions Mas{PO,), is the most effective in coagulation of Fe(OH), sol 4, No. Ni OSes OU" Chae NACI NH) Ay son, 0 7. At 120-140 temperature and 1.5 am Pressure, Sodium: phenoxide searts with OO, 1 ield sodium salicylate which on further |hydrolysis gives salicylic acid 48. Number of electrons in C= 6 Number of electrons in Na =11-1= 19 ~3=10 Number of electrons in 0 = 84 2 10 Number of electrons in N* = 7-126 “N° is is0-eleetionie with ¢, Number of elections in al‘49. (c) (a) CH; CH, — CH= CH, we o a ca (b) CH, —CH=CH—CH,” want (¢) CH,»=CH—CH=CH, ral ee al (@ CH,—CH=CH—CH3 oe 80, 2MnO; + 5H,0, + 6H” — 2Mn** + 80, + 8H,O 51. In the titration of strong base with strong acid, we can use methyl orange, methyl red, phenolphthalein as indicator. 52, The IUPAC name of K,{Cr(CN);0,(0),NHs] is potassium amminedicyanodioxoperoxo- chromate (V1). 53, In Wacker process, when mixture of propene and air is passed through mixture of Pd and CuCl, at high pressure, acetone is formed. Pd + CuCl, — PdCl, + 2Cucl 4CuCl + HCl +0, —> 4CuCl, + 2H,0 CH,CH=CH, + PdCl, + HO —> =e CH,COCH, + Pd + 2HCI 4, Lindane is y-benzene hexachloride, It can be prepared by creating benzene with Cl, in sunlight. 30 ow 4 ba | H 4 a a a i + a- and Buisomers a Va H a “penzene hexachloride orLindane 55. The two propenyl groups attached to 1, 2 position of earbon in cis-form. /Cl= CH CH;—CH=CH CH=CH-—CH, 56, Ba(OH), + CO, —> BaCO, + H,0 5 moles of Ba(OFi), = 5 moles of BaCO, 4 Mass of BaCO, = moles of BaCO, x molecular mass of BaCO, 5x 197 9858 moment d 12D 10x 10* cm = 1.210" esu ‘The fraction of electronic charge, ¢ is 12x10 esu ~gax10 Mesure =0.25¢ =25%0fe 58, (a) Let = 7,=(0 +1) o4p , 1004 nd y= =p+ is P= PomnaTR 100 100 1007 +100 = 100.47" 0.4T =100 100 r 04 = (250 - 273)°C =- 23°C 59. 2NOBr(g) = 2NO(g) + Br,(g) ‘2p |p) 2p BQ mad |S f ott 9x (oy and ky = 280" * (Pag) (Pa)? @)-(3) 60. Barium salts are quite stable because of great electropositive nature of Ba. Hence, Ba compounds possess high decomposition 61. 2 + HS0, 2nSO, +H. tT Zn + 2NaOH+— Na2ZnO, + H, 7 a a 2 of. (oy meio (oy se CH, CH; aa Oe as 63. Alizarin is an anthraquinone dye. It gives a bright red colour with aluminium anda blue colour vith barium, __ Fibre == Q 9 ‘a es 60 OH ef 64, CH==cH + HO" —cr pea) ue mee, ia 1 Ze ‘OH Cl 2 ‘table 2, 2dichloroacetaldehyde 65. Number of Ba** ions at the corner of unit cell 1 mB had Number of 1 a6xta3 Number of Ti" jons at the boxy centre * Molecular formula of baritim titanate ai, 66. Somatotropin is the harmone, secreted by anterior lobe of pituitary gland. It is also called growth harmone as it stimulates protein synthesis, glycogensis and some other biological activities. It deficiency causes midgets or dwarfism. 67. Number of electrons in F'= 9+ 1=10 0? =8+2=10 M-1=10 10 Number of electron: Number of electrons in Na* Number of electrons in Mg? « 12 ~ Since, F,0? , Na* the size of isoelectric species decreases with increase in nuclear charge (i.e., number of Protons). Hence, correct order of size is OF > F > Na’ > Mg 88. The radius of hydrogen atom = 0.53. gLi2* jon also has only one electron but it has 3 protons in nucleus, hence, its electron feels three times more attraction from nuceus in comparison of hydrogen atom. Thus, the radius of 3Li?* will be 0.53 Mg* ave isoelectric and oz A1 68 OK, = Stronger the acid, higher the K values and lower the pK, value. ‘The order of acidity of given acids is as follows CH, CH CH Br COOH > FCH,CH,COOH > CH,CH,COOH Since, CH,CH,COOH is the weakest acid among the given, therefore its pk value will be highest. 5 70. CO + NaOl —> HCQONa o> X fot (COONa}, — + (COOH), eisogyanace +HO—R'—OH —> alscol ° ° I 4 —NH—R—NH—C—O pyuretnanes 96500 +: ACNTP, volume of =56mL TR. CO, + HO + H,C0, —> H” + HCO} Here(H" increases hence, pH] decreases due to which sol fertility will also decrease, 7A, The reaction is of first order and for a first order reaction, rate, R=KINOs) 2.410 = 3x10 X(N Ds] Inyog) = 24210: 3x10 = 08 mol 75. BR, is symmetrical planar, although it has polar bonds but resultant dipole moment is zero. In NFy, lone pair cause distortion, hence, polarity arises. 16, For NaCl pV = nST x! 5, 100 12 7000 58.5 ucose, pl’ = nSt 100 ton Bm % 0.0821 xT xi (0) For g NaCl and glucose solutions are isotonic Piz Pa On dividing Eq, (i) by (i), we have 22 585.1. 9502 180" 12 T1, FeSO, .7H,0 is known as green vitriol. go 8. CHCH,CH,GHCH, > Br CH,CH,CH,CH—=CH, +CH,CH,CH=CHCH, By Saytzeff’s rule, substituted alkenes are more stable, Hence, out of cis and trans forms, rans product is more stable. 79, We know C—C bond length = 1.54 that C=C bond length = 1.344, Cas bond length = 1.204 Since, propyne has triple bond, therefore, it has minimum bond length 80. Hence, IUPAC name is 1, #-dichloro-4-formyl 2, 6-dioxy-cyelohexane-1- carboxylic acid 0 coor clLogical Reasoning 98. MONKEY XDIMNL Similarly, TIGER QDFH Lay 97. 19x17 = 221 12x 19= 228 Similarly, 13 x 18 = 234 88. If the day before yesterday was ‘Thursday. Then, today will be Saturday and the Sunday will be tomorrow. 99. When Ravi and Shyam interchange their position than Ravi’s new position (ninth from right) is the same as Shyam’s initial position (second from left) + Total number of students in the row +141 =10 So, Shyam’s new position is same as Ravi's initial position (fourth from right) third from left. So, Shyam’s new position from left =10-3=7th Mathematics 106. Length of perpendicular from A (2, ~ 1) to the line x+y ~2=0is (2-1) 100. Answer figure (d) will appear when a piece of paper folded and cut as shown in the question. figure. tH. Food om ‘Badminton ‘cup 103. The pattern of series is 1 9 2% 1 miedo Hence, 50 is the wrong number. 108. Given equation, 24.4 445.44 From option (d), 2424454 24= 4420 24224 105. Answer figure (c) is correct mirror image of question figure.407. Lines, x+y = 6,2x+y =4 and x+2y =5 intersect at points (-2, 8), (7, ~ Vand (2, 2) Now, all these points lie on xt y?=17x- 19y +50=0 108, Required length of tangent is (S;, where $,=25+41430- 4-349 We 309. Length of minor axis = 2b and according 0 the given condition length of major axis = 3(2b) = 60 110. (cannot be negative) 111. The difference of the focal distance at any point on the hyperbola is same as length of the transverse axis. i. ¢., 2 112, Since, A + B+C = 180° = co(A+B+C) Loot A cot GLA corBeotc-EcotA 0 = cot A cot Beate - EcotA= 0 cot A + corB + corG = got ore ‘cot A cot B cote 113, Now, 30° = 30° x 2. rad = — 180" 6 Let angle be a, a+ d, a+ 2d area in AP Now, ga4dd=n (VAB4C=™) = 3xtesder 6 . )_* - 2)" 6 «Greatest angle = a+ 2 a%42.Eek 6 6 2 414. Given that, tan 20° = P tan 160° - tan 110° 7+ tan 160° tan 110" __ tan (180?-20") - tan (90° + 20°) T+ tan (160° — 20° ) ran (90° + 20°) an 20° + cot 20° = T+ tan 20° cot 20° ape pice Tel 3p 118, Given, 4sin™! x + cost x= SoBe = 4sin e+ S— sin 2 = asin! x= 5 16. a=By sin rule, 8-4 5 Sin 6 2, 1_sinB = ; = sin B=1=B = 90° ‘ a2 In ABC, cose = P= 5 117. Equation of the line passing through a and b isa+e(b—a). Here, b-a=6j-k =b=6j-k+i-2j)-k =i+4j-2hk Given, line passes through (1, ~ 2,1) and (1, 4,~ 2) 118. Work done = (Force displacement) = ai ~ 34+ 2k) {(2i- j + ake) ~ (31+ 2j-K)) 41-3) + 2k)-(-1- 3) + 5k) 449410) = 15 units 118, tm 2+ 2)8802 + 1) ~ Bein (term) tin INRA +24 Dems 1D ey T ‘in 2 + 2eos 2 2 120, Now, tim, £0) = tim 35488 @ form) = lim 3+ 2tan xsec? x ya Since, f(x) is continuous at x = 0 F(O=3 ® sin x 180 rar. (cosa) 122, 4 Hlogtseex ~ tan x9) as [see x tan x ~ sec? x] secx tan x sec x[tan ‘sec x — tan x 123. Given, x = cos?@, y = sin? On differentiating w.r.t.O respectively, we get ae * 8 ~~ scostosind to and 2 3sin*0coso 2 Now, & =~ 3810-0080 _ _ tang ae Seostosind a) 1+ (2) =1+tan?9= sec? dx, 124, x= ar’, y = 2ar On differentiating w.r.t. ¢, respectively # oat, © = 20 at at dy md dy att 125. Circumference of circle, C = 2nr dC _ oy ar ue 03_ar (dc = S824 40 03 cm/s given Qn dt ( de sie ) Now, A=a? [$]_.-8x0a-1senoms dy 3,2 126, & = 3x? ~ 20x + 48>0 dx (ey is an increasing function) + Diseriminant, D< 0 = 4a? 4x 3x 4860 = 14420 = ag (-12,12)421, Rolle’s theorem is not applicable for the function f(x) =|x{in(-2, 11 sf” (O) does not exist. - ¥C ret 1 ev * sete ered e+e” wut = [0 et a) sin''0-+ cos? -[? sint@/2-0) go ‘Sin'(n/2— @) + c0s"(/% 2(? Lotta cos" + sin” (on adding Eas. (2) and (id, we get a(t sin" 0+ 608" gg 0) cos" + sin" ® aff? de=Eaie% 0 2 490. Let 1 = {5 cos xd = Ta fi teoste— 0 de one tal Jong =in[t Fo staal 1 geetlog 4018 = eile ois = log 6 - log 1 = log 6 432. Given,y = ax? + Bx oe) On differentiating, we get ® oac+B 2 fy 2a ae 2d? a at 5 pee - a det “e Jog( + ax) - log 133, Given, {00 = {fox iscontinvous at x= kand (0) =k 2 lim fOO = vim 128% 2a aa wrin( cake 194, 1F4~ Si is root of x? +ax + B= 0, then 4+ Si is also the root. :.Sum of roots =~ a= 8 = a=-8 and product of roots =16 +25 a (,d)= 8.40) 435. Given equation can be reveiten as aw 3x+Ze0 ang= aspe-3apnZ 197, Since, iz = ze'*/? 7 e This implies that isis the vector obtained by Now, 14 mee rotating vector = in anti-clockwise direction ap ¥ through 90°, 136, Since, a, are the roots of the equation z ax? tbr+c=0. i ‘Az) 0 2a e and & + k,B + k are the roots of the equation “04 1 AB prt + ge +r a0, So, area of AOAB ~ 7.04 x08 n= 1 Then, e+ k = Yura 2 138, Let, be the sum of first n terms of the series. 20-172) and = ea aay 139, 0.2 + 0,22 + 0.222 + ...n terms op * 2a = 0.1 + 0.11 + 0.111 +... terms) =2(2 ewe nvems) 10" 100" 1000 2(9 99 999 jf =5( a+, 9, —— tom Ba. on slot terns) = ae a1 a 1 2a =5(2~ sot? Goat ggg t= terms apr, Vb aac 2p 2a 4ale eo etic Ag gant | 140. Number of required ways =H IG, = My M1. «. Required number of ways =4t=24 142, Since, T, ="C) "Cyx,Ty = "Cae Also, Tp, Ty) Ty are in AP. a ete, - 2n! 21(n=2)! ee gtd @-Da-d (n-D(n-2) = 1 GDB aa-Y - 6+n?—-3n+2=6n-6 = ntagn-6n+8+6=0 = n?-9n+14=0 = (=7)(n=2)=0 = neTor2 ne7 (:ne2) l1aa@| lt a a | va a=|1 bb? Ii b-a ba?) 2} lo c-a cai} jac ¢ (using Ry > Ry ~ R, and Ry > Ry ~ Ry) ra a | =(b-a)(c~a)|0 1 b+a) jo 1 c+a =(b-a)(c-a)(c+a-b-a) = (b-a)(c~a)(e~b) = K(a—b) (b- 6) (c~ a) = kel (given) c bee (by R, > Ry ~ Ra) [> 9 | (by R, > Ry +R) deel o| a ate c-a| (by 6s 96, ~C)) = 2b(ac + c* — c? #ac) = 4abe |x a b 16, Given, A, =/b x a) A= ja b x be 4 Ja x d olan) [ise =|b x aslo jab x| jab x a x 0] |x a bl a5 oj+|b x @ 001) _|x “\b aE b \x ol aay as alte at a o£) = 36, qe 3a 146, Given system of equations are x+ay-22=3 Ox+y+S2=7 and ax+3y 43-5 jl 4 2] A=|3.1 5/ 23 | 4 = 15) - 4(3- 10) - 209-2) ~14+28-14=0 5)=140 1| 2. No solution will exist.