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Module Examination 2015 Exploring Science: Monday, 8 June 2015 2:30 PM - 5:30 PM Time Allowed: 3 Hours
Module Examination 2015 Exploring Science: Monday, 8 June 2015 2:30 PM - 5:30 PM Time Allowed: 3 Hours
Module Examination 2015 Exploring Science: Monday, 8 June 2015 2:30 PM - 5:30 PM Time Allowed: 3 Hours
S1041506F1
S104/K
S104/
EXPLORING SCIENCE
This examination consists of THREE Parts (A, B and C) all of which should
be attempted. Parts A and B address the ‘Core material’ studied by all
students. You should answer all the questions in Parts A and B. Part C
concerns the ‘Option material’ at the end of the module. There are three
questions in Part C, one on each option. You should attempt one question
from Part C. For each Part, the following table indicates the type of
question, the choice of question (if any), the recommended allocation of
your time and the proportion of marks awarded.
You are provided with a computer marked assessment (CME) form for Part
A, graph paper and an answer book. Answer the Part B questions and your
chosen Part C question in the answer book, using the graph paper where
required. Additional answer books and graph paper are available from the
invigilator if needed. A list of standard equations and constants is attached
to this examination paper as a separate insert.
At the end of the examination
Make sure that you have completed Part 1 of the CME form and that you
have written your personal identifier and examination number on all of the
answer books you have used and on the graph paper you used for Part B.
Failure to do so will mean that your work cannot be identified.
Attach the graph paper you used for Part B to the answer book you used for
Part B. Put all your used answer books and graph paper together with your
signed desk record on top. Fasten them together in the top left-hand corner
with the paper fastener provided. Attach the CME form and this question
paper to the back of the answer books with the flat paper clip.
(1) One CME form is provided with this paper. The invigilator has a
supply of spare forms if you should need any.
(2) You should use an HB pencil to make entries on the CME form. If
you make any smudges or other spurious marks on the form which
you cannot cancel out clearly, you should ask the invigilator for a
new form, and transfer your entries to it.
(3) If you do not wish to answer a question, pencil across the ‘don’t
know’ cell (‘?’).
(4) If you think that the question is unsound in any way, pencil across
the ‘unsound’ cell (‘U’), in addition to pencilling across either an
answer cell or the ‘don’t know’ cell.
(5) For each question you must pencil across either a single answer
cell or the ‘don’t know’ cell.
(6) We suggest that in the first instance, you answer by pencilling
across the facsimile CME rows reproduced below. Check your
answers before transferring them to your CME form.
(7) You should note that NO ADDITIONAL TIME will be allowed at the
end of the three-hour period for transferring your marks to the CME
form. Time for this is included in the 1 hour 20 minutes for Part A.
(8) On Part 1 of the CME form you must write in your personal identifier
(NOT the examination number) and the ‘assignment number’ for
this examination (S104 81). You should also pencil across the cells
in the two blocks in Part 1 of the CME form corresponding to your
personal identifier and assignment number given above. We
suggest that you check that Part 1 of the CME form has been
completed correctly before moving on to Part B of the examination
paper.
(9) Failure to follow the above instructions may mean that we shall not
be able to award you a mark for this Part of the examination.
Note: You may use a page at the back of any of your answer books for
any rough work required in Part A. Please note that this rough work will
not be considered by the examiners.
PART A Computer-marked questions on Core material
Attempt ALL of the questions in Part A.
Part A carries 45% of the total marks.
Questions 1–5 carry 1 mark each.
Questions 6–25 carry 2 marks each.
You are advised to spend about 1 hour and 20 minutes on Part A.
Pencil your answers on the CME form provided.
Each question requires ONE answer for which you should pencil across ONE cell
in the corresponding row on the CME form.
No marks will be given for questions where more than one of the answers has
been selected from the key.
There are no penalty marks for incorrect answers.
Question 1 Figure 1 shows the anthropogenic sources of atmospheric methane. Which one
of the following statements about these sources is incorrect?
7% biomass
burning
8% waste
treatment
36% energy
production
14% landfill
38% livestock
Question 3 Which one of the following is an incorrect definition of the sort of uncertainties
and errors that may arise in any scientific experiment?
KEY for Q3
A Random uncertainty is defined by measurements scattered about a mean
value.
B A systematic error is one that results in the measurement of a quantity being
consistently different from the quantity's true value.
C Systematic uncertainties are uncertainties due to random errors.
D Experimental uncertainties may arise from the equipment or method being
used to make measurements.
E Random uncertainty can be estimated by repeating the measurement a
number of times.
Question 4
In the equation a =
(b - c ) , the units of quantity b and c are m s−1 and the units of
d
quantity d are s. What are the units of quantity a?
KEY for Q4
A m s−1
B m2 s−2
C m s−2
D m2
E ms
D b=
(ad )
c
E b =2
(ad )
c
75° W 15° E
10 km 10 km
Pacific South America South Atlantic Ocean
Ocean Andes B
5 km 5 km
C
E
A D
0 km 0 km
5 km 5 km
0 1000 2000 km
10 km 10 km
Question 9 Which one of the following is an area where volcanoes do not occur?
KEY for Q9
A the Himalayan mountain chain
B the Andes mountain chain
C ocean ridges
D East Africa
E Japan
Question 11 Which one of the following statements, describing the energy changes involved
when electricity generated by a wind turbine is used to light a bulb, is correct?
KEY for Q11
A The kinetic energy of the wind is directly converted into electrical energy by
the turbine in a single step.
B All the kinetic energy of the wind is converted into electrical energy by the
turbine.
C Electrical energy is converted into both light and internal energy in the bulb.
D There are no energy conversions involved in the transmission of electricity
from the turbine through cables to the bulb.
E No stage of this process involves the conversion of kinetic energy to sound
energy.
Question 12 How much energy is transferred when a 1500 W heater is switched on for
5 minutes?
KEY for Q12
A 1500 J
B 7500 J
C 90 kJ
D 450 kJ
E 1.5 MJ
Question 13 A vase is knocked off a shelf and falls 0.8 m to the floor. Assuming it was initially
at rest, which value is closest to the speed of the vase when it hits the floor?
KEY for Q13
A 1 m s−1
B 2 m s−1
C 3 m s−1
D 4 m s−1
E 5 m s−1
Question 15 Which photon from the list below carries the most energy?
KEY for Q15
A A photon of X-ray radiation.
B A photon of gamma-ray radiation.
C A photon of radio radiation.
D A photon of microwave radiation.
E A photon of infrared radiation.
Question 16 Aqueous nitric acid (HNO3) will react with solid magnesium hydroxide (Mg(OH)2)
to form an aqueous product. Which one of the following reaction schemes best
represents this reaction?
KEY for Q16
A HNO3 (aq) + Mg(OH)2 (s) = Mg(NO3)2 (aq) + H2O (l)
B 2HNO3 + Mg(OH)2 = Mg(NO3)2 + 2H2O
C 2HNO3 (aq) + Mg(OH)2 (s) = Mg(NO3)2 (aq) + 2H2O (l)
D 2HNO3 (aq) + Mg(OH)2 = Mg(NO3)2 (aq) + 2H2 (g) + O2 (g)
E HNO3 (aq) + Mg(OH)2 (s) = MgNO3 (aq) + H2O (l)
Question 17 Which one of the following represents the electronic configuration for the
aluminium ion (Al3+)?
KEY for Q17
A 1s22s22p63s23p64s2
B 1s22s22p63s23p1
C 1s22s22p63s2
D 1s22s22p6
E 1s22s22p63s1
Question 19 Which one of the following statements related to the equilibrium reaction below is
incorrect? Assume the equilibrium is at 25 °C and at a pressure of 1 atmosphere
in a sealed reactor.
Question 20 Which one of the following statements related to covalent compounds and
bonding is incorrect?
KEY for Q20
A Covalent compounds are discrete entities.
B Covalent bonds can be single, double or triple.
C In covalent bonding, electrons are transferred from one atom to another.
D A covalent bond between atoms of different sizes will exhibit a dipole.
E Molecular formulae are used to describe covalent compounds.
Question 21 Which one of the following statements about the eukaryotic cell cycle and
reproduction is incorrect?
KEY for Q21
A A male spermatozoon fertilises a female ovum to produce a zygote.
B During mitosis, DNA molecules become coiled but the overall length of each
molecule remains the same.
C Clones contain DNA identical to that of the parent cell that divided to produce
them.
D The cell cycle can take anything from a few hours to many weeks to complete.
E In a haploid cell, each autosome is one of a pair.
(a) Plot these data on a graph, plotting Quantity A on the horizontal axis. You
should label the axes of your graph and give your graph an appropriate title.
(4 marks)
(b) Draw a best-fit straight line through your plotted data. (You should judge the
line by eye, but use a ruler to draw it.)
(1 mark)
(c) From your completed graph, determine the values for
(i) the gradient and
(ii) the intercept of your best-fit straight line.
Include the units for both and give your answers to two significant figures, using
scientific notation where appropriate. Indicate on your graph those features used
to determine the gradient and intercept values but give any calculations in the
exam answer book.
(5 marks)
H H H H H
H C C C N C C
H H H H H Cl
Compound 1 Compound 2
(i) Name the two functional groups that are present in Compound 2. Note:
For this part of the question you should not consider the benzene ring
in Compound 2 to be a functional group.
(ii) Which of these two compounds exhibits chirality? Briefly explain your
answer.
(iii) Compounds 1 and 2 will react together to form a single compound.
Sketch the full structural formula of the resultant molecule, and name
the other product of this reaction.
(iv) Name the type of reaction, and the new functional group that is formed
in the reaction described in (a)(iii).
(8 marks)
(b) Methane gas (CH4) reacts with oxygen gas (O2) to produce carbon dioxide
gas (CO2) and steam (H2O). This is shown in Reaction Scheme 1. The
associated molar bond enthalpies in kJ mol−1 for these molecules are given
in Table 2.
CH4 (g) + 2O2 (g) = CO2 (g) + 2H2O (g) Reaction Scheme 1
Question 28 (a) In a particular woodland ecosystem, of the 1.0 × 1010 kJ ha−1 y−1 of energy
entering the system from the Sun, 1.6 × 103 kJ ha−1 y−1 ends up as biomass
in the highest carnivore, a secondary consumer.
(i) Express this biomass as a percentage of the incident solar energy.
(ii) Explain why there are progressively fewer organisms as you move from
herbivore level to highest carnivore level within such an ecosystem.
(iii) Using Figure 4 as your guide, describe the role of hydrogen ions
(protons) in the capture of energy from light by chlorophyll resulting in
the production of ATP (photophosphorylation).
(8 marks)
chloroplast chloroplast
outer membrane inner membrane
STROMA light
movement of
electrons
chlorophyll H+ thylakoid
membrane
H+ THYLAKOID
LUMEN
H+
H+
H+
+
H
H+
+
H high concentration H +
+ of protons H+ H+ ATP synthase
H H+
low concentration
of H+ protons
H+ ADP + Pi ADP + Pi
+
H
H+ ATP ATP
H+ H+ + +
H H
Location 1
F
A
J
X E Y
10 m
1 km
Useful constants
magnitude of the acceleration due to g = 9.8 m s−2
gravity on Earth
Newton’s universal gravitational G = 6.7 × 10−11 N m2 kg−2
constant
Coulomb’s law, constant of ke = 9.0 × 109 N m2 C−2
proportionality
Avogadro constant = 6.02 × 1023 mol−1
Hubble constant = 70 km s−1 Mpc−1
Planck’s constant h = 6.63 × 10−34 J s
speed of light c = 3.0 × 108 m s-1
charge of proton +e = 1.6 × 10−19 C
charge of electron −e = −1.6 × 10−19 C
mass of proton = 1.7 × 10−27 kg
mass of neutron = 1.7 × 10−27 kg
mass of electron = 9.3 × 10−31 kg
astronomical unit AU = 1.5 × 1011 m
y = mx + c
4 3
volume of a sphere V = ʌr
3
area of a circle = ʌr 2
1
Ek = mv 2
2
continued overleaf
m
ρ=
V
F = ma
q = mcΔT
q = Lv m
q = Lf m
ǻV = RI
P = IǻV
v = fλ
Δλ
z=
λ0
v = z×c
v = H0 × r
§ [H + (aq)] ·
pH = −1og ¨ −3 ¸
© mol dm ¹
E = mc 2
separation distance
speed of separation =
elapsed time
rstar m
= planet
rplanet mstar
rise
gradient =
run
−13.60
En = Z 2 × eV
n2
Eph = hf
L
F=
4ʌr 2
Q1Q2
Fe = − ke
r2
m1m2
Fg = G
r2
mass of substance
number of moles of a substance =
molar mass of substance
GPP = NPP + R
2
Periodic Table of the Elements
1.01
23.0
6.94
85.5
39.1
223
133
Na
Rb
Fr
Cs
19
87
55
11
37
Li
H
K
1
francium caesium rubidium potassium sodium lithium hydrogen
87.6
24.3
40.1
9.01
137
226
Mg
Ra
Ba
Be
Ca
Sr
88
56
38
12
20
4
227
139
Ac
La
89
57
radium barium strontium calcium magnesium beryllium
actinium lanthanum
88.9
45.0
Ce
232
140
262
103
175
Th
Sc
Lu
Lr
90
58
71
39
21
Y
thorium cerium lawrencium lutetium yttrium scandium
91.2
47.9
231
141
Pa
104
178
Pr
Hf
91
59
Zr
72
40
22
Ti
protactinium praseodymium hafnium zirconium titanium
92.9
50.9
Nd
Nb
238
144
105
181
Ta
92
60
73
41
23
U
V
uranium neodymium tantalum niobium vanadium
Pm
52.0
Np
237
145
95.9
106
184
Mo
Cr
W
93
61
74
24
42
neptunium promethium tungsten molybdenum chromium
Sm
244
150
98.9
54.9
Mn
Pu
Re
107
186
94
62
Tc
75
43
25
plutonium samarium rhenium technetium manganese
55.8
Am
152
108
190
101
Os
Ru
243
Eu
Fe
95
63
76
44
26
americium europium osmium ruthenium iron
Cm
58.9
Gd
Rh
Co
247
157
109
192
103
96
64
77
45
27
Ir
106
Pd
159
247
Tb
Bk
Pt
78
46
65
Ni
97
28
108
Au
Ag
251
163
Dy
Cu
Cf
79
47
98
66
29
165
Ho
Cd
112
Es
Zn
Hg
201
99
67
30
48
80
27.0
Fm
204
Ga
167
115
257
100
Er
81
49
Al
68
Tl
In
31
13
B
5
72.6
28.1
169
207
119
258
101
Ge
Pb
Sn
82
50
Si
69
32
14
C
6
31.0
173
122
No
209
Yb
Sb
259
102
As
70
51
Bi
83
33
15
N
P
16.0
32.1
128
209
Po
Se
Te
84
52
34
16
O
S
35.5
127
210
53
Br
At
Cl
85
35
17
F
I
39.9
20.2
222
131
Rn
He
Xe
Ne
Kr
Ar
86
54
36
18
10