reviews
the same time, has increased the number of problems and devices
twhelp students and has incorporated new material
In the preface two axioms are emphasized: Dont Get Bebind
and Work Lots of Problems. These truths are then supported by
{very large number of good problems of varying degrees of di
cally: Some of the more dificult problems are designated by an
Ssterisk: Reinforeement of concepts also supports the above axi-
fms, After concepts are defined, the definitions often are reiter
Sted on subsequent use, and roferenes is made to the earlier
Presentation, Problems are then used to reenforee the concept
"This edition of Wade's bock retaine the functional group ap-
proach: however, there are several significant changes from the
Fist edition. Stereochemistry is treated earlier (Chapter rather
than Chapter 8), prior to the chemistry of alkenes and alk! hal-
des. Spectroscopy aloo receives a more prominent treatment in
this editon it and MS are treated Chapter Ils ah this fo
lowed by a chapter that is devoted to both carbon and hydrogen
NMR. UV'is not ineluded with the ether spectroscopic tools but is
addressed later when conjugated systems are discussed. Afar th
‘introduction of spectroscopic techniques, problems dealing with
spectra are incorporated into the treatment of subsequent func-
tonal groupe. One of the outstanding fertures of Wade's books i
{he exellent spectroscopic tables found inthe appendix.
"The formal chapter on heterocyelic chemistry has buen removed
and this material dispersed throughout the tex. The chapters on
fromatic chomist+y include the typical benzanoid aromaties and
also polynuclear aid hetero aromatic compounds, The approach to
aromatic chemistry does an excellent job inthe reinforcement of
evonance and MO theory that were introduced much earlier. This
all encompassing approach to aromatic chemistry dove, however,
load toa very bref treatment of benzyne chemistry and als of the
addition elimination mechaniom (the Mebeenbeimer complex is
‘ot mentioned by name)
"The final three chapters of this text deal with special topics.
Bioorganic molecules and polymers are treated, The parallels be-
‘ewoen these systems and the simpler organic molecules treated
‘earlier are stressed. These chapters reenforee once mare such im-
portant concepts as hydrogen bonding, acid-base chemistry, stere-
‘chemistry, ote
‘The study of organic chemistry requires the mastery of a new
language. This book introduces & large numberof definitions and
sow terms in the Srst part of the book, While formal definitions
fare given and used, Wade has managed to treat these ideas and
terms in the everyday language of organie chemistry, making for a
‘are personable treatment of the subject.
"The numerous devices ta help the student contribute tothe user
friendliness ofthis volume include fourealor printing, marginal
hhints to aid in problem saving, key definitions printed in blue and
key reactions highlighted hy hive check marks, and end-f-chapter
reaction summaries, Essential problem-solving skills for each
chapter also are summarized before the problem atthe end ofthe
chapter. Nucleophiles are printed in blue and electrophiles in
green. Finally.curved red arrows are used for “electron pushing”
that is stressed Uiroughout this book.
Tn summary, [feel that Wade has improved and updated an al-
ready good organie text, He has not lost sight of his primary
reader-the first-year organi student, This book should be consid-
ered seriously by anyone teaching a general one-year organic
‘course to chemistry majors nd preprofesional students
\W. Preston Reeves
‘Texas Lutheran Colege
1000 W. Court Street
‘Seguin, TX 78155
Organic Chemistry Experiments: Microscale and
‘Semi-Microscale
‘Bruce N. Campbell,Jr. and Monica McCarthy Al. Brooks/Cole:
Pacific Grove, CA, 1994. xxxi + 553 pp. Figs. and tables. 19.2 x
24.0.m. $58.26
Campbell and Ali have written a comprehensive laboratory text
for organic chemistry. There are 76 numbered experiments, many
of which provide soveral choices of syntheses or reactions. Proce-
‘14 Journal of Chemical Education
dures are provided for both micro and semimicro seales, Detailed
directions are provided for early experiments; those for later parts
of the course are more general. There are more than enough op-
tions to offer a full-year laboratory sequence and provide adequate
experimental skills for tho students. This text presents an admi-
rable balance of techniques, syntheses, reactions, analyses, and
kinetic studios, Thore aro two organie quantitative analyst
periments and a full 42-page chapter on organie qualitative a
is. The text als
sR
to prepare forthe laboratory and on writing laboratory reports
Following are a few specific comments about some of the fea-
tures in the tex, and some suggestions for improvement in future
editions
‘There is an introductory section of about five pages on labora
tory safety and eautions within the text about the use of toxic,
flammable, and carcinogenic chemicals, For the most part,
meets the admirable goal of teaching students how to work safely
with materials that ean be dangerous. However, other than a gen-
‘eral sort of warning in the intraduetory section, they do not exe
on the student about the hazards of corrosive acids and bases. 12
my experience, students are more likely to he injured by concen-
trated solutions of sulfurse aed, nitrie acid, and sodium hydroxide
‘than they are to be harmed by hazardous organie chemicals. I roe
‘ommend that warnings about these hazards be inserted where ap-
propriate throughout the text
"The references and cross references at the beginning of the ex:
periments should be quite helpful to students and instructors who
‘want more information. Many of the references are to experiments
published in this Journal
‘The authors have interspersed questions in the text that chal-
lenge the students to think about what they are doing and to try
‘to get them to understand the procedure before they earry it out.
‘This is an excellent feature; these would be even better if they
were set off by shading or a different typeface or in some other way
‘than a simple flag in the margin.
‘The authors use many common names-vanilly] aleohol, hydro-
cinnamie ac, and (amylbenzene, for example-that will mean lit-
tle to the students, I think systematic names also should be
provided.
‘The book has a chapter on infrared and nuclear magnetic reso-
nance spectroscopy that appears to be adequate. Many organic
laboratory instructors, however, will want to make a much more
‘extensive use of these techniques than is provided.
Tnsummary find thisbook intriguing, Its certainly worthy ofeare
fal consideration by all eganie chemistry laboratory instructors,
John W. Hill
University of Wisconsin-River Falls
River Falls, Wi 54022
Basic Inorganic Chemistry, Third Edition
Albert Cotton, Geoftrey Wikinson, and Pau! L. Gaus. Wiley
[New York, NY, 1995. xi + 838 pp. Figs, and tables. 18.1 x 25.9
om. $81.85.
‘The now edition of Basie Inorganic Chemistry is a signifieant
improvement over an already excellent book. The underlying phi-
Tosophy remains: that students learn inorgunie chemistry best if
there is primary emphasis on faets a8 a bass for understanding
important principles The third edition should be the text of choice
{ora sophomore-junior level inorganic chemistry course for those
instructors who want an essontially doseriptive approach to the
subject with an emphasis on periodicity, reactivity, and structure
‘There i a wealth of information inthe text, certainly too much for
complete coverage in one semester, To insure optimum student
learning in a one-semester course, the instructor has to select only
‘small number of chapters from the Main Group and Transition
Elomonts and from Special Topics while thoroughly emphasizing
the First Principles of part I. The level of sophistication of the
principles presented, however, is too high for the average student
who has had a typical general chemistry course. Thus, many in-
Sstructors will have to provide supplementary material to help the
students bridge the gap and take full advantage of the consider-—_—
able merits ofthe text. Alco, the third edition has some value as a
mid-level reference work in inorganic chemistry for professional
Scientists who haven’ completed a course in physical chemistry
Dut who have a basie background in chemistry.
“The format of the third edition remains the same with respect
to major parts and chapters, except for the addition ofthe chapter
titled “The Inorganic Solid State" and the appendices: “Aspects of
‘Symanetry and Point Groups”, “Table of Hydrogen like Atomie Or-
bital Wave Functions”, “Ionization Enthalpies of the Slements"
“Tonie Radi, “Electron Attachment Enthalpica of Selected Ele.
ments" and
Unita) from Various Sources”, There are 830 pages in|
tion (as opposed to 708 in the previous edition). Tho new chapter
land appendices account for hal of the inerease while expanded
average in most of the remaining chapters accounts forthe res.
Few changes have been made in the chapters: Group VIB, The
Halogens, The Noble Gases, The Transition Elements and Special
‘Topics. One example of the new material added to this edition is
the discussion of the chemistry of important new elasses of com-
pounds like the fullerenes. Other noteworthy improvements in-
clude new approaches to the depiction of ionie structures,
‘Quantitative approaches to acid-base chemistry, expanded and
‘unified treatment of periodicity in structure and reactivity among
‘the main group elements, Wades rules for boranes and carberanes
and reaction summaries for many elements. Several new figures
‘and many exercises have been added along with new post-1990
supplementary readings at the end of each chapter. Many of the
‘changes enhance the value of the third edition as a tex.
Tn summary, the third edition is sufficiently different from the
second edition to warrant addition toa professional library as well
suse as a now text
Laurence J. Boucher
“Towson State University
“Towson, MD 21204
‘Chemische Kabinettstiicke: Spektakulére Experimente
und geistreiche zitete
H.W. Roesky and K. Mickel. VCH: New York, NY, 1994. 314
1p. Figs. and ilus, 16.7 x 24.0 em, $40.00.
“Chemische Kabinettaticke,” the experimental leetures that
Roesky has presented throughout Germany have enchanted and
enlightened experienced industrial chemists, seience teachers,
‘students, and laypersons interested in science, Now 124 of these
spectacular demonstrations are presented successfully in book
format. Each experiment features sections of safety precautions,
apparatus, chemicals, detailed procedure, explanation (including
fequations when appropriate), disposal, and references (many to
larticles in the J. Chem, Educ., some us recent as 1993)
Diagrams, structural formulas, tables, and black-and-white
photographs as well’as 37 beautiful and striking full-color plates
‘on 28 pages are provided. The entire book is printed on heavy, aes-
‘heticlly pleasing paper
"The unique feature of the book, however, which differentiates it
from almost all other collections, isthe liberal use of hundreds of
fascinating historical, literary, philosophical, and snecdotal facts,
lengthy quotations, and aphorisms that the authors have ingen-
ously integrated with the experiments in accordance with their
deeply humanistic approach to science, which stresses the impot-
tant role of chomistey in our culture and civilization, In this re-
spect, its a successful amalgam of literature, art, and seience.
‘Besides quotations from scientists and natural philosophers
such as Aristotle, Avicenna, Berzelius, Edmund Davy, Einstein,
Emil Fischer, Geber, Thomas H. Husley, Keplor, Licbig, Luerotivs,
Lichtenberg, Oppenheimer, Paracelsus, Sagan, and Wohler, the
‘book contains prose or poetry by Woody Allen, Francis Bacon, Yogi
Berra, Cicero, Dali, Dante, Freud, Goethe, van Gogh, E.T.A. Holt
‘mann, Klee, Lessing, Manin, Mareus Aurelius, Michelangelo, Mon-
taigne, Nietzsche, Petronins, Picasso, Schiller, Schinberg, Mark
‘Twain, and Walt Whitman as well as passages from the Bible and
‘Talmud. This collection of masterpieces of the demonstrator’s art
ga balanced blend of theater and chemistry and a real bargain.
George B. Kauttman
Caltornia State University Fresno
Fresno, CA 83740
Titles Of Interest
Clean Technology and the Environment
A.C. Kirkwood and A.J, Longley Ealtors. Chapman & Hall
[Now York, NY, 1995. xiv + 350 pp. Figs. and tables. 165 x 26.1
com. $129.35.
Environmental Organic Chemistry: tlustrative
Examples, Problems, and Case Studies
Fond P. Schwarzenbach, Philp M. Gschwend, and Dieter M.im-
Boden. Wiley: New York, NY. 1995. 400 pp. Figs. and tabies.
19.3 23.5 em, $29.95 PB.
Making Sense: Simulation-of-Research in Organic
Chemistry Education
‘Hanno van Keulen. CD-8 Press: Princetonplein 5, 3584 CC
Utrecht, The Netherlands, 1995. 213 pp. Figs. and tables. 17.2
x2390m,
‘This is a study of organic synthesis from an educational
point of view. More specifically, the relations between
teaching and learning organic synthesis in a university
chemistry curriculum are investigated. The focus is on the
Iaboratory course for first-year chemistry students (at
‘Utrecht University). Specifically, laboratory-based instruc-
tion in organic synthesis is investigated to determine sci-
entific organie synthesis. The author's thesis is that chem-
istry students have to make sense of organic synthesis to
be able to contribute to it. Consequently, much attention is
devoted to what exactly “making sense” is in the context of
organic synthesis.
Quality Assurance in Analytical Chemistry
Wemer Funk. Vera Dammann, and Gerhild Donnevert. VCH:
Now York, NY, 1995. xl + 298 pp. Figs. and tables. 17.8 24.6
cm. $80.00.
‘The quality assurance of analytical methods from their
development to their application in routine analysis is sys-
‘tematically described. The book will be of special interest
with regard to the compuslory introduetion of quality as-
surance systems in laboratories for food examination.
Monographs
The Logic of Chemical Synthesis :
E. J. Corey and Xue-Min Cheng. Wiey: New York, NY, 1989.
496 pp. 18.1 x 25.3 om. $49.95 HB/S24.95 PB.
‘The ttle ofthis three-part volume derives from a key theme of
‘the book the logic underlying the rational analysis of complex syn-
thetic problems. Although the book deals almost exclusively with
‘molecules of biclogical origin, the approach taken is fully applica-
ble to other types of carbon-based structures. Part One outlines
the basie concepts of retrosynthetic analysis, and the general
strategies for generating possible synthetic pathways by logical
reduction of melecalar complexity. Part Two, a collection of mul-
tistep syntheses, provides much integrated information on syn-
thetie methods and pathways for the construction of interesting
‘target molecules, Part Three is intended to balance the coverage
of Parts One and Two and to serve as a convenient guide to the
now enormous literature of multistep synthesis.
Volume 73 Number 1 January 1996 AIS,