emai syaubari@unsyiah.ac.

id

T 75 Celcius

ln P1 sat/kPa 4.42133
P1 83.20686 kPa

ln P2 sat/kPa 3.737258
P2 41.9827 kPa

a x1 y1 P/kPa
0 0 41.9827
0.2 0.33132 50.22754
0.4 0.569205 58.47237
0.6 0.748295 66.7172
0.8 0.887989 74.96203
1 1 83.20686
90

80

70

60

50

40

30

20

10

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
 Assumsing that carbonated water contains only CO2 (1) and H2O(2), determine the compositions of the vapor and
liquid phases in a sealed can of "soda" and the pressure exerted on the can at 10C. Henry's constant for CO2 in
water at 10 C is about 990 bar

Henry's Raoult's
Law Law

y1.P=x1.H y2.P=x2.P
1 2 sat

P = x1.H1+x2.P2sat

Dik : H1 990 bar

P2 sat 0.01227 bar at steam table
x1 0.01 permisalan
x2 0.99 permisalan

Dit : Hitung komposisi vapor dan liquid fasa

Jawab :
Menggunakan rumus persamaan gabungan henry

P 9.912147 bar

Menggunakan persamaan raoult untuk mencari y2

y2 = x2.P2sat/P

y2 0.001225 fasa cair

Dari hasil ini kita dapat mencari y1 dimana :

y1+y2=1 maka y1=1-y2

y1 0.998775 fasa uap

ons of the vapor and
constant for CO2 in
For the system methanol(1)/methyl acetate(2), the following equations provide a reasonable correlation
for the activity coefficients :

Rumus

Dit : a. P and (yi), for T = 318,15 K and x1 = 0,25

T 318.15 Kelvin
x1 0.25
x2 0.75

P1 sat 44.5109 kPa

p2 sat 65.64146 kPa

A 1.107076
gamma1 1.86401
gamma2 1.071642

P 73.50031 kpa Persamaan 10.6

y1 0.282205 Persamaan 10.5

y2 0.717795

b. P and (xi), for T = 318,15 K and y1 = 0,60

T 318.15 Kelvin Asumsi gamma

y1 0.6 gamma1 1
y2 0.4 gamma2 1

P1 sat 44.5109 kPa

p2 sat 65.64146 kPa

A 1.107076

P 51.08934 Anggap gamma1=gamma2=1 gamma1 gamma2

1 1
hitung x1 dengan persamaan 10.5 1.690558 1.113269
1.475856 1.20133
x1 0.688676 1.580321 1.151593
x2 0.311324 1.524479 1.176179
1.552955 1.163127
Karena x1 dan x2 sementara sudah dapat maka balik ke persamaan 10.7 1.538068 1.169809
Mencari gamma1 dan gamma2 sesungguhnya 1.545752 1.166323
 1.54176 1.168124
gamma1 1.690558 1.543827 1.167188
gamma2 1.113269 1.542754 1.167673
1.54331 1.167422
P 74.36427 1.543022 1.167552
1.543171 1.167484
1.543094 1.167519
1.543134 1.167501
1.543113 1.167511
1.543124 1.167506
1.543118 1.167508
1.543121 1.167507
1.54312 1.167508
1.543121 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
1.54312 1.167507
x1 x2 P
0.688676 0.311324 51.08934
0.592952 0.407048 74.36427
0.642936 0.357064 70.39258
0.617147 0.382853 72.35177
0.630545 0.369455 71.31039
0.623608 0.376392 71.8432
0.627207 0.372793 71.56512
0.625342 0.374658 71.70877
0.626309 0.373691 71.63417
0.625807 0.374193 71.6728
0.626067 0.373933 71.65276
0.625933 0.374067 71.66315
0.626002 0.373998 71.65776
0.625966 0.374034 71.66056
0.625985 0.374015 71.65911
0.625975 0.374025 71.65986
0.62598 0.37402 71.65947
0.625978 0.374022 71.65967
0.625979 0.374021 71.65957
0.625978 0.374022 71.65962
0.625979 0.374021 71.65959
0.625978 0.374022 71.65961
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
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0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
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0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596
0.625979 0.374021 71.6596