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Soal Elsus 1 PDF
Soal Elsus 1 PDF
IR Spectrum
(liquid film) 1718
100 43
Mass Spectrum
0.5 CIl
o
80 .>t:. co
'"
CIl
0-
€'"
0
60 CIl
til
til
..c UV Spectrum
M+"
40 '5
'"
..c 29 72 1.0 '"
33.3 mg/10 ml
20 * 1.0 cm cell
Y C4H aO
1.5
solvent: ethanol
II II
LlLillL
solvent I
--J -- --'~'__
proton coupled
proton decoupled
I III
I I I I I I I I I I I I
1H NMR Spectrum
(200 MHz, CDCI 3 solution)
TMS
1.
90
Problem 2
IR Spectrum
(liquid film) 1715
I I I I I I I I I I I I
I
DEPT CH2~ CH 3t CHt
proton decoupled
200
I I I
160
I I
120
I
solvent
80
I
•
I I
40
U I I
0 o(ppm)
1H NMR Spectrum
(200 MHz. COCI 3 solution)
exchanges
with 0 20
~
~
A
r---
12 11 ~
TMS
--1
I
I I I I I I I I I I I
10 9 8 7 6 5 4 3 2 1 0
o(ppm)
9
r Problem 3
IR Spectrum
(liquid film) 2984
1741 1243
60 Q)
(/) UV spectrum
40
'"
.a
'0 29 1.0 solvent: ethanol
Q'!. M+"= 88 15.4 mg /10 mls
20 path length: 1.00 cm
~ ,I I C4Ha02
1.5
40 80 120 160 200 240 280 200 250 300 350
m/e A. (nm)
1H NMR Spectrum
(200 MHz, CDCI3 solution)
TMS
10 9 8 7 6 5 4 3 2 1 o
s (ppm)
92
Problem 4
,
c,
IR Spectrum 1744
(CCI4 solution)
100 57
Mass Spectrum
29
80 .><
Ctl
Q)
Co
60 Q)
en
No significant UV
Ctl
J::J
M+" = 88 absorption above 220 nm
40 '0
*'
20
I
40 80 120 160 200 240 280
m/e
I I I I I I I I I I I I
13C NMR Spectrum
(100,0 MHz, COCl a solution)
1H NMR Spectrum
(200 MHz, COCl a solution)
expansion
2.0
,
10 ppm
I TMS
10 9 8 7 6 5 4 3 2 1 o
o(ppm)
93
Problem 5
IR Spectrum
(liquid film)
proton coupled
solvent
I ~
proton decoupled
• I o(ppm)
200 160 120 80 40 0
1H NMR Spectrum
(200 MHz, CDCI 3 solution)
TMS
l'
I I I I I I I I I I I
10 9 8 7 6 5 4 3 2 1 0
s (ppm)
94
Problem 6
IR Spectrum
(liquid film)
1716
60 CIlQl
40 '0
'"
.0 solvent: methanol
0~
M+' =86
20
I
I I I I I I I I I I I I
proton decoupled
,
solvent
1H NMR Spectrum
(200 MHz, CDCI3 solution)
TMS
I
I I I I I I I I I I I
10 9 8 7 6 5 4 3 2 1 o
() (ppm)
95
Problem 7
IR Spectrum 2249
(KBr disc)
80 "'" 53
'"
Q)
o,
60 Q)
Ul
No significant UV
40
40 '0
'"
.I:l
M+" = 80 absorption above 220 nm
'#.
20
~ 1
40 80 120 160 200 240 280
m/e
I
(100.0 MHz, CDCI 3 solution)
proton decoupled
- - - ' - - -
solvent L
200 160 120 80 40 o 0 (ppm)
1H NMR Spectrum
(400 MHz, CDCI3 solution)
TMS .
I I I I I I I I I 1
10 9 8 7 6 5 4 3 2 1 o
o(ppm)"
96
Problem 8
IR Spectrum
(liquid film)
80 .,., 57
'"a.
<J)
60 <J)
Ul
No significant UV
'"
.."
absorption above 220 nm
40 '0 M+" =114 « 1%)
*-
20 99
II I
I I I I I I I I I I I I
13C NMR Spectrum
(50.0 MHz, CDC'3 solution)
1H NMR Spectrum
(200 MHz, CDC'3 solution)
TMS
I
I I I I I , I I I I I
10 9 8 7 6 5 4 3 2 1 0
o (ppm)
97
Problem 9
3458
IR Spectrum
(CCI4 solution)
I I I I I I I I I I I I
proton decoupled
sOIV~.1
I I I I I I I I I I I I
1H NMR Spectrum
(200 MHz, CDCI 3 solution) .. :
:<
~
,;,',
;:>
Exchanges with ..
s,"
°2° t~
"'
S- TMS
I 1
I I I I I I I I I -.1._
10 9 8 7 6 5 4 3 2 1 0
s (ppm)
;
98
Problem 10
IR Spectrum
(KBrdisc) 1693
20
," I,
proton decoupled
solvent
1H NMR Spectrum
(400 MHz, CDCI 3 solution)
TMS
I I I I I I I I I I I
10 9 8 7 6 5 4 3 2 1 0
o(ppm)
99