Appendix C

Antoine Constants

Compiled From
R.C. Reid, J.M. Prausnitz and T.K. Sherwood, The Properties of Gases and
Liquids, 3rd Ed., McGraw-Hill, New York, 1977.
The vapor pressure is expressed as a function of temperature in the form
B
ln P vap = A − ,
T +C
where P vap is in bar and T is in K.

The Thermodynamics of Phase and Reaction Equilibria. DOI: http://dx.doi.org/10.1016/B978-0-44-4594976.00017-7

© 2013 Elsevier B.V. All rights reserved. 667
668 Tosun

Name A B C Tmax Tmin

Elements
Argon 8.6128 700.51 −5.84 94 81
Bromine 9.2239 2582.32 −51.16 354 259
Chlorine 9.3408 1978.32 −27.01 264 172
Hydrogen 7.0131 164.90 3.19 25 14
Nitrogen 8.3340 588.72 −6.60 90 54
Oxygen 8.7873 734.55 −6.45 100 63
Hydrocarbons
Acetylene 9.7279 1637.14 −19.77 202 194
Benzene 9.2806 2788.51 −52.36 377 280
n-Butane 9.0580 2154.90 −34.42 290 195
Cumene 9.3520 3363.60 −63.37 454 311
Cyclohexane 9.1325 2766.63 −50.50 380 280
Cyclopentane 9.2372 2588.48 −41.79 345 230
n-Decane 9.3912 3456.80 −78.67 476 330
Ethane 9.0435 1511.42 −17.16 199 130
Ethylbenzene 9.3993 3279.47 −59.95 450 300
Ethylene 8.9166 1347.01 −18.15 182 120
n-Heptane 9.2535 2911.32 −56.51 400 270
1-Heptene 9.2692 2895.51 −53.97 400 265
n-Hexane 9.2164 2697.55 −48.78 370 245
Isobutane 8.9179 2032.73 −33.15 280 187
Isopentane 9.0136 2348.67 −40.05 322 216
Methane 8.6041 597.84 −7.16 120 93
Naphthalene 9.5224 3992.01 −71.29 525 360
n-Octane 9.3224 3120.29 −63.63 425 292
1-Octene 9.3428 3116.52 −60.39 420 288
n-Pentane 9.2131 2477.07 −39.94 330 220
Propane 9.1058 1872.46 −25.16 249 164
Propylene 9.0825 1807.53 −26.15 240 160
Styrene 9.3991 3328.57 −63.72 460 305
Toluene 9.3935 3096.52 −53.67 410 280
m-Xylene 9.5188 3366.99 −58.04 440 300
o-Xylene 9.4954 3395.57 −59.46 445 305
p-Xylene 9.4761 3346.65 −57.84 440 300
Antoine Constants 669

Name A B C Tmax Tmin

Inorganic compounds
Ammonia 10.3729 2132.50 −32.98 261 179
Carbon dioxide 15.9696 3103.39 −0.16 204 154
Carbon disulfide 9.3642 2690.85 −31.62 342 228
Carbon monoxide 7.7484 530.22 −13.15 108 63
Carbon tetrachloride 9.2540 2808.19 −45.99 374 253
Chloroform 8.3530 2696.79 −46.16 370 260
Hydrogen chloride 9.8838 1714.25 −14.45 200 137
Hydrogen sulfide 9.4838 1768.69 −26.06 230 190
Nitric oxide 13.5112 1572.52 −4.88 140 95
Nitrous oxide 9.5069 1506.49 −25.99 200 144
Sulfur dioxide 10.1478 2302.35 −35.97 280 195
Sulfur trioxide 14.2201 3995.70 −36.66 332 290
Water 11.6834 3816.44 −46.13 441 284
Organic compounds
Acetaldehyde 9.6729 2465.15 −37.15 320 210
Acetic acid 10.1878 3405.57 −56.34 430 290
Acetone 10.0311 2940.46 −35.93 350 241
Acetonitrile 9.6672 2945.47 −49.15 390 260
Aniline 10.0546 3857.52 −73.15 500 340
n-Butanol 10.5958 3137.02 −94.43 404 288
Chlorobenzene 9.4474 3295.12 −55.60 420 320
Diethyl ether 9.4626 2511.29 −41.95 340 225
Dimethyl ether 10.2265 2361.44 −17.10 265 179
Ethanol 12.2917 3803.98 −41.68 369 270
Ethyl acetate 9.5314 2790.50 −57.15 385 260
Ethylene oxide 10.1198 2567.61 −29.01 310 200
Formaldehyde 9.8573 2204.13 −30.15 271 185
n-Heptanol 8.6866 2626.42 −146.6 449 333
Isobutanol 10.2510 2874.73 −100.3 388 293
Isopropanol 12.0727 3640.20 −53.54 374 273
Methanol 11.9673 3626.55 −34.29 364 257
Methyl acetate 9.5093 2601.92 −56.15 360 245
Methyl ethyl ketone 9.9784 3150.42 −36.65 376 257
Phenol 9.8077 3490.89 −98.59 481 345
n-Propanol 10.9237 3166.28 −80.15 400 285