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Hand Book of Psychrometric SI
Hand Book of Psychrometric SI
Psychrometric Charts
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Handbook of
Psychrometric
Charts
Humidity diagrams for engineers
D.C. SHALLCROSS
Department of Chemical Engineering
University of Melbourne
Melbourne, Australia
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David Shallcross
Pc critical pressure
Py vapour pressure
PT total pressure
R Universal gas constant
rh relative humidity
T absolute temperature
Nomenclature Tad adiabatic saturation temperature
Tb normal boiling point
Tc critical temperature
Tdatum enthalpy datum temperature
Tr reduced temperature
B second virial coefficient Vc critical volume
c correlation coefficient Vyc liquid molar volume
C third virial coefficient x mole fraction
Cp ideal gas heat capacity Zc critical compressibility factor
f enhancement factor
functions defined in equations (3.19) and (3.20) Greek letters
real gas specific enthalpy K isothermal compressibility
ideal gas specific enthalpy A. latent heat of vaporization
. residual enthalpy ~ latent heat of vaporization at normal boiling point
enthalpy deviation v specific volume (dry mass basis)
condensed phase enthalpy o relative humidity
specific enthalpy (dry mass basis) co acentric factor
h'o enthalpy correction
Henry's law constant Subscripts
absolute humidity A air
molal humidity G non-condensing gas component
Hp percentage humidity m mixture
m mass s saturation condition
MW molecular weight V condensing vapour component
pp partial pressure W water
1 performed. The psychrometric chart is a useful way of presenting
thermodynamic data of gas mixtures which contain at least one
component which may condense to either a liquid or a solid.
While it is relatively straightforward to predict the
Fundamental Aspects of thermodynamic properties of a gas mixture of several components,
Psychrometry the situation becomes more complicated when it is possible for one
of the components to condense. All the components of a gas
mixture exert a partial pressure due to their very presence. The
partial pressure, PPi' is dependent on the component's mole fraction,
Xi' and the total pressure of the system, P T :
Psychrometry is the study of gas mixtures in which one or more By definition, the sum of all the component partial pressures must
vapour components may condense while the other components equal the total pressure,
remain gaseous. The most important example of such systems is
the water-air system in which water vapour may condense from the (1.2)
air. In nature the condensation and vaporization of moisture out of
and into air gives rise to such important meteorological phenomena
as cloud formation, rain and the wind chill factor. Such systems and the partial pressure will equal the total pressure when the gas
also have important engineering applications. Evaporative coolers consists of one component only.
cool air by vaporizing water and increasing the air's humidity, while The partial pressure may vary between zero, when the
many solids dryers operate by transferring the moisture from the component is absent, to the component's vapour pressure, when the
solid to air, again increasing the air's humidity gas is saturated with the component. Vapour pressure is the
While the water-air system is important it is not the only such pressure at which the gas co-exists with either of the other phases,
gas mixture of practical interest to engineers. Industrial gases in liquid or solid. The vapour pressure is a function of temperature,
which water vapour maybe found include nitrogen, helium, argon increasing with increasing temperature. It is also a property of the
and other inert gases, methane and natural gases, and the gases individual gas component and may vary significantly between
produced by the combustion of hydrocarbons. Equally important different components. At a given temperature, for pressures below
are systems in which the condensing vapour is not water, but some the vapour pressure the component will exist as a gas, but above the
other substance. Often a knowledge of the level of organic solvent vapour pressure a pure component will exist as either a liquid or a
vapours in air or other inert gas is vital in the safe design of solid. A vapour will condense if its partial pressure is increased to
installations and engineering processes. the vapour pressure while the temperature is held constant or if its
The physical properties of such gas mixtures must be adequately temperature is decreased sufficiently so that the vapour pressure at
characterised before engineering design calculations can be that reduced temperature equals the partial pressure of the vapour.
2 Fundamental aspects of psychrometry
PP v PP v (1.4) (1.8)
PP G
where PPi is the partial pressure of component i. Here XVs is the mole fraction of component V when the gas mixture
The absolute humidity, H, of a gas mixture is the ratio of the is saturated with the condensing vapour component at the specified
mass of the condensing vapour component, my, to the mass of the temperature.
non-condensing component, mG : The percentage humidity, Hp , is defined as the ratio of the
absolute humidity of the gas mixture at some temperature to the
Humidity definitions 3
absolute humidity if the gas was to be saturated with the condensing pass by the wick-enclosed thermometer, either by placing the
vapour component at the same temperature. This is then expressed thermometer in a flowing stream of the gas, or by moving the
as a percentage, thus: thermometer rapidly through the still gas.
A vapour will always seek to establish an equilibrium with its
_H x 100 (1.9) own liquid. Thus the liquid in the wick will seek to be in
Hs equilibrium with its own vapour in the gas passing by. If the gas
is saturated with the vapour, i.e. the vapour's partial pressure equals
where Hs is the absolute humidity at saturation. Percentage its vapour pressure at that temperature, then none of the liquid will
humidity may also be related to the partial pressure of the vapour vaporize to enter the gas stream. If however the gas is not saturated
component: then some of the liquid will vaporize in an effort to increase the
vapour's partial pressure towards the vapour pressure. The lower while pressure is kept constant. It is the adiabatic saturation
the vapour's partial pressure, i.e. the drier the gas, the higher the temperature rather than the wet bulb temperature which is plotted
rate of vaporization. However, before the liquid may vaporize heat in the psychrometric charts presented in this book.
must be supplied to overcome the liquid's latent heat of The two other properties plotted in the charts are specific
vaporization. As the liquid is in a wick surrounding a thermometer volume and specific enthalpy. The specific volume of a gas
bulb, this heat is supplied by withdrawing heat from its mixture containing a condensing vapour component, v, is defined
surroundings, the bulb itself. The temperature of the thermometer as the volume occupied by the mixture per unit mass of the non-
drops causing the wet bulb thermometer to indicate a lower condensing gas component alone:
temperature. The decrease in temperature depends on the rate at
which the liquid vaporizes. The drier the gas, the greater the wet v =
v (1.11)
bulb depression.
The dry bulb temperature is the actual temperature of the gas
mixture. The wet bulb depression is the difference in temperature Similarly the specific enthalpy of a gas mixture contammg a
between the dry bulb temperature and the wet bulb temperature. condensing vapour component, hm is defmed as the enthalpy of the
When the gas is saturated with the vapour the dry bulb and wet mixture per unit mass of the non-condensing gas component alone:
bulb temperatures are equal, and when the gas is not saturated the
wet bulb temperature is always lower than the dry bulb temperature. (1.12)
Because the wet bulb thermometer is so simple, reliable and
easy to use, it is the most popular device to indirectly measure
humidity. Unfortunately the wet bulb temperature measured is a
function of not only the dry bulb temperature and absolute 1.3 LAYOUT OF THE PSYCHROMETRIC CHARTS
humidity, but also such factors as the gas's relative velocity with
respect to the thermometer, the diameter of the thermometer and the The psychrometric charts presented in this book are constructed
extent of the radiative heat transfer between the wet bulb with the dry bulb temperature on the x-axis and absolute humidity
thermometer and its surroundings. Consequently, the wet bulb plotted on the orthogonal y-axis. As an alternative psychrometric
temperature as measured using a wet bulb thermometer is not a charts may be constructed using enthalpy and absolute humidity as
thermodynamic property of the gas mixture. Threlkeld (1975) the coordinates. The construction of such charts are described in
describes the simultaneous heat and mass transfer processes detail by Palmatier (1963) and Threlkeld (1975).
occurring about a wet bulb thermometer in detail. Figure 1.2 shows the typical layout of the psychrometric charts
The adiabatic saturation temperature, Tad' is a thermodynamic presented in this book. The charts may be used to estimate the
property of the gas mixture and is sometimes referred to as the thermodynamic properties of a humid gas once three
thermodynamic wet bulb temperature. The adiabatic saturation thermodynamic properties of state have been specified. As each
temperature is defined as the temperature at which the condensed psychrometric chart is prepared for a specific total system pressure
component (liquid or solid), by evaporating into the moist gas this property is usually one of the three state properties which is
component at a given dry bulb temperature and absolute humidity, specified by the chart user. The user is then free to specify any two
can bring air to saturation adiabatically at the same temperature, of the following properties: temperature, absolute humidity, relative
Layout of the psychrometric charts 5
Diagram title
System pressure
Enthalpy datum conditions
constant absolute
humidity line
I
I
humidity, specific volume, specific enthalpy and adiabatic saturation 1.4 EXAMPLE APPLICATIONS
temperature. Once any of these two properties have been specified
then the state of the gas mixture is fixed, and a point may be 1.4.1 Using a Single Chart for Property Estimation
located on the appropriate chart which represents the
thermodynamic state of the gas mixture. To illustrate the use of the psychrometric charts consider the
The point may lie anywhere on the chart. The saturation curve following example in which nitrogen is being used to remove
forms part of the upper boundary of the chart. Points lying above toluene vapour from a container under pressure. If the total system
and to the left of this curve are invalid as such a point would pressure is 1.5 atm we may use a psychrometric chart such as the
represent a gas mixture having a vapour component with a partial one shown in Fig. 1.3 to determine the properties of the gas. If the
pressure greater than its vapour pressure at that temperature. The gas has a temperature of 36.0°C and an adiabatic saturation
lower boundary is formed by the line H = 0, i.e. the condensing temperature of 25.6°C then the point A shown on the chart would
vapour component is absent. The left and right boundaries of the represent the condition of the mixture of toluene and nitrogen. We
chart are arbitrary and represent the lower and upper dry bulb consider toluene to be the vapour and nitrogen to be the gas.
temperatures represented on the chart respectively. The straight line The absolute humidity may be read by simply tracing a line
segment of the upper boundary is likewise arbitrarily set and is horizontally from point A back to the absolute humidity scale. This
chosen so that the appearance of the charts is consistent. is shown as a dashed line in Fig. 1.3. In this example the absolute
Once a point has been defmed by specifying the two state humidity is estimated to be 0.0660 ± 0.0005 kg toluene vapourlkg
. properties other than total pressure, the remaining state properties dry nitrogen. The error in the absolute humidity arises partly from
may be found by reading their values off the chart. Consider point the error associated with the placement of point A on the diagram,
A shown in Fig 1.2. This point represents the thermodynamic state and partly from the accuracy with which the absolute humidity scale
of a gas mixture which contains some vapour, but which is not may be read.
saturated with that vapour. By reading the appropriate scale and by The dew point of the gas mixture may be obtained by reading
interpolating between the sets of lines and curves as necessary we left from point A along the line of constant absolute humidity until
may readily determine the gas mixture's dry bulb temperature, the saturation curve is reached. The temperature at this point is
absolute humidity, dew point, relative humidity, adiabatic saturation then the dew point. The dew point of our gas mixture is 19.6 ±
temperature and specific volume. 0.2°e. This suggests that if the gas mixture were to be cooled at
The determination of the gas's specific enthalpy is a two step constant pressure then liquid toluene would begin to form at 19.6°C.
process. In the first step we read back along the line of constant Point A lies between the curves of 40.0 % and 50.0 % relative
adiabatic saturation temperature to fmd the value where this line humidity. By careful interpolation we would estimate a relative
intersects the specific enthalpy scale. This specific enthalpy value humidity of 43.9 % ± 0.5 %. The error is relatively higher than
is for a saturated gas mixture having the same adiabatic saturation might otherwise be the case because the user must interpolate
temperature, i.e. it is the specific enthalpy of point B rather than between curves rather than straight lines.
that of point A. To correct for the fact that the gas mixture is not
saturated we must add the value of the enthalpy deviation at point
A to the specific enthalpy at saturation. The resultant value is then Figure 1.3 Psychcrometric chart for the toluene-nitrogen system
the specific enthalpy of the gas mixture represented by point A. at 1.50 atm pressure
Example applications 7
150
.170
To obtain true enthalpy add enthalpy
deviation to enthalpy at saturation .160
.150
.140 cQ)
OJ
.130
~c
.1 20 ~
"0
--
Cl
.110 x
OJ
x
.100
>.
.......
.090 '6
'f
.080 :::::J
..c
Q)
.070 :;
'0
30 en
.060 .0
«
.050
.040
.030
.020
.010
.000
o 10 20 30 40 50 60
The specific volume of the gas mixture is estimated by 1.4.2 Property Estimation at Intermediate Pressures
considering the lines of constant specific volume which straddle the
point. Point A lies between the 0.60 m3/kg and 0.62 m3/kg lines of When psychrometric charts are not available for the exact pressure
constant specific volume. By interpolation we would estimate the required, the properties of the gas mixture may be estimated by
0.615 ± 0.001 m3/kg dry nitrogen. This suggests that the toluene interpolation. For most of the systems considered in this book
and nitrogen mixture occupies 0.615 m3 for every kg of nitrogen. charts are presented for at least six system pressures ranging from
Since the mixture contains 0.0660 kg of toluene vapour for every 0.80 atm to 5.00 atm. Careful interpolation of the presented data
kg of nitrogen, the true density of the gas mixture, p, would be allows the thermodynamic properties of the gas mixtures to be
calculated by: estimated for any pressure within the range of 0.80 atm to 5.00 atm.
On no account should the charts be used to extrapolate values
1 + 0.0660 (1.13) outside this range of pressures.
p 1.733 kg/m 3
0.615 As an example of how the charts may be used to estimate
properties at some intermediate pressure, consider the following
This tells us that every cubic metre of the toluene and nitrogen gas example involving the ethanol-air system. As with any system
mixture has a mass of 1.733 kg. involving air, air is considered to be the single non-condensing gas
To evaluate the mixture's specific enthalpy we first draw in the component, while the other component, ethanol, is considered to be
line of constant adiabatic saturation temperature which passes the vapour component. Suppose the total system pressure is 1.62
through point A. This line, which is shown as a dashed line in Fig atm, and the temperature is 42.0°C. The humidity of the system is
1.3, is drawn through the saturation line to intersect with the known to be 0.0900 kg ethanol vapour/kg dry air.
inclined enthalpy scale located above and to the left of the Using the appropriate charts and the following procedure the
saturation line. The point at which the extension of the adiabatic adiabatic saturation temperature, relative humidity, specific volume
saturation temperature line intersects the enthalpy scale indicates the and specific enthalpy may be determined.
specific enthalpy of the saturated gas mixture at point B. For the Psychrometric charts at 0.80 atm, 1.00 atm, 1.20 atm, 1.50 atm,
example, the specific enthalpy at point B may be estimated to be 2.00 atm and 5.00 atm are available for the ethanol-air system.
67.7 ± 0.3 kJ/kg dry nitrogen. The error in the enthalpy at These are presented on pages 208 to 213 of this book. As the
saturation value arises mainly from the error associated with the system pressure of the example is between 1.50 atm and 2.00 atm,
placement of point A on the diagram, but partly from the accuracy the charts for these two pressures are used. Table 1.1 presents the
with which the enthalpy at saturation scale may be read. Since values for the four properties found at each of the two pressures for
point A is not saturated the value for the enthalpy must be corrected a temperature of 42.0°C and an absolute humidity of 0.0900 kg/kg.
by adding the value for the enthalpy deviation at point A to the To estimate the adiabatic saturation temperature, Tad' and the
saturated enthalpy value found for point B. Point A lies between relative humidity, rh, the corresponding values at 1.50 atm and 2.00
the enthalpy deviation curves of -1.0 kJ/kg and -1.5 kJ/kg. atm may be interpolated linearly. Thus, for the adiabatic saturation
Interpolation yields a value of -1.2 kJ/kg. When this value is added temperature at 1.62 atm we find:
to the specific enthalpy value at point B, a value of 66.5 ± 0.3
kJ/kg dry nitrogen is obtained for the gas mixture's specific
enthalpy.
Example applications 9
Pressure (atm) 1.50 2.00 :::} V = 0.581 m 3/kg dry air (1.16)
= 42.7%
These values are correct to within the accuracy with which the
charts may be read.
The specific volume at 1.62 atm cannot be estimated using this
simple procedure. Over a small range of system pressures when the
compressibility factor does not vary significantly, the specific
volume for constant dry bulb temperature and absolute humidity
varies inversely with system pressure. Thus, the specific volume of
the ethanol-air mixture at 1.62 atm is given by:
2 State is chosen to characterise the non-ideal behaviour of the gas
mixtures. This method is chosen as it is relatively simple to apply
and because considerable data is available for the required
parameters for each of the systems to be studied.
Construction of the Charts For the gas mixture of components G and V the Virial Equation
of State truncated at the third term is:
(2.1)
in any way.
and,
n n n
2.1 VAPOUR PHASE BEHAVIOUR
Cm EEE
i=1 j=1 k-I
Xi Xj X k C ijk (2.4)
Many of the gas mixtures do not behave ideally under some of the
temperature and pressure conditions covered by the psychrometric For a binary system consisting of components G and V these
charts. From the many different methods, the Virial Equation of equations become:
Construction of the saturation line 11
(2.7) 6 xG2S (1 - X )2 P 2
+ Gs T B B
(R T)2 vv GV
2 232
and, 2 xGs (1 - x Gs ) (1 - 3 x Gs ) P T 2 XGs T P
--------:------BGV + ___ C
(RT)2 (RT)2 GGG
(2.8)
- (1 + 3 xGs ) ( 1
2(RTl (2.9)
where, XVs and XGs are the mole fractions of components V and G
respectively, at saturation, and P v is the vapour pressure of
12 Construction of the charts
where, 1( is the isothermal compressibility of the condensing repeated until f and XGs no longer change signifIcantly from one
component (i.e. water for the air-water system), Vvc is the molar calculation to the next.
volume of the condensed component V (either as a liquid or a The absolute humidity at saturation, H s' is the mass of vapour
solid), and kH is the Henry's Law constant to account for the component V per mass of component G. It may be written in terms
solubility of component G in the condensed phase (Hyland and of the mole fractions of the two components in the gas phase:
Wexler, 1983a).
The enhancement factor is a function of the vapour phase (2.12)
composition, temperature, pressure, molar volume and other factors.
It includes terms that take into account the effect of dissolved gases
and pressure on the properties of the condensed phase, and the where, MWi is the molecular weight of component i.
effect of intermolecular forces on the properties of the moisture The psychrometric chart is constructed with temperature plotted
itself (ASHRAE, 1989). Typically the value for the enhancement on the x-axis and absolute humidity plotted on the orthogonal y-
factor does not exceed 1.05 for any given system (Shallcross, 1996). axis. The saturation line that describes the boundary of the
Applying the enhancement factor, equations (2.7) and (2.8) thus humidity chart is drawn by plotting the absolute humidity at
become, saturation, H s' as a function of temperature for a specifIed total
pressure.
(2.10)
2.3 CONSTRUCTION OF CURVES OF CONSTANT RELATIVE
HUMIDITY
and,
The relative humidity, ~, is defmed as the ratio of the mole fraction
of the vapour component, Xv, in a given sample of the two-
(2.11) component mixture to the mole fraction, X Vs ' in a sample of the
mixture which is saturated with the vapour component. Thus,
Absolute humidity may be related to mole fractions by: 2.4 CONSTRUCTION OF CURVES OF CONSTANT SPECIFIC
VOLUME
So,
v = v = (2.18)
H (2.15)
Hs
Equation (2.15) may therefore be re-written as: where, V is the total volume of the mixture, mG is the mass of the
dry gas, n T is the total number of moles of the mixture, and, nG is
H (tJ xVs x Gs
the number of moles of the dry gas.
Hs 1 - @xVs xVs From equation (2.1), the Virial Equation of State, an implicit
expression for V may be written:
(tJ x Gs
(2.16)
1 - @xVs
V =RT
A
_ [I + _ Cm]
Bm + _ (2.19)
Substitution of equations (2.10) and (2.11) for XVs and X Gs yields P A A2
T V V
upon re-arrangement:
H = Hs (tJ (l - f PJ P T) (2.17) As noted in equations (2.5) and (2.6), Bm and Cm are both functions
1 - (tJfPvIPT of the mole fractions XG and Xv, and of temperature.
To construct constant specific volume curves, the s)'stem
In this equation f and Hs are functions of pressure and temperature pressure, PI'> is first specified. Then for a given value of v,
and are determined using equations (2.11) and (2.12) respectively, equations (2.2), (2.18) and (2.19) are solved for V, XG and Xv across
and Pv is a function of temperature alone. To construct the constant the temperature range of interest. The y-ordinate, absolute
relative humidity curves, the system pressure, PT' is first specified. humidity, is then calculated using equation (2.14), and when this
Then for a given value of (tJ, the variables J, Hs and P v are data is plotted on the psychrometric chart a curve of constant
calculated for varying values of temperature. These values used relative humidity results.
with equation (2.17) permit the absolute humidity for the specified
(tJ to be calculated as a function of temperature. When this data is
plotted on the psychrometric chart a curve of constant relative
humidity results.
14 Construction of the charts
2.5 CALCULATION OF SPECIFIC ENTHALPY The specific enthalpy of the moist gas mixture, hm' may be
calculated from equations (2.20) to (2.22) for any given
In order to calculate the positions of the remaining curves (adiabatic temperature, pressure and absolute humidity.
saturation temperature and enthalpy deviation) a method is required
to calculate the enthalpy of the gas mixture for any combination of
dry bulb temperature and absolute humidity. 2.6 CONSTRUCTION OF CURVES OF CONSTANT
The specific enthalpy of a real gas, h, is related to the ideal-gas ADIABATIC SATURATION TEMPERATURE
state enthalpy, h', by the residual enthalpy, tit':
The wet bulb temperature is usually considered as the temperature
h = hI - i1hl (2.20)
measured by a cylindrical thermometer, the outside surface of which
is kept wet with the liquid of the condensing component V. As the
The real gas specific enthalpy is thus: moist gas passes the thermometer some of the liquid evaporates
resulting in a cooling effect that causes the temperature of the wet
bulb thermometer to drop. The drier the gas, the greater the wet
bulb depression. As the wet bulb temperature is a function of not
only the dry bulb temperature and absolute humidity, but also such
factors as the gas velocity with respect to the thermometer, the
diameter of the thermometer and the extent of radiative heat
transfer, it is not possible to predict the wet bulb temperatures with
precision. Consequently curves of constant adiabatic saturation
temperature are plotted instead. It should be noted however that for
where, To is the enthalpy datum temperature, CPo' and Cpv' are the the air-water system the curves of constant adiabatic saturation
ideal gas heat capacity of the gas and vapour respectively, and, hoG temperature coincide with curves of constant wet bulb temperature.
and hoY are the enthalpy corrections for both components necessary This is because for the air-water system typically the Lewis Number
to ensure that the enthalpy, h, is in fact zero at the enthalpy datum is nearly equal to one.
condition. For the conventional air-water system, ASHRAE (1989) defines
The value calculated for h in equation (2.21) is on a molar basis the adiabatic saturation temperature, Tad' as the temperature at which
of the mixture. Since it is more useful to express the specific water (liquid or solid), by evaporating into moist air at a given dry
enthalpy of the gas mixture as energy per unit mass of the dry gas bulb temperature, T, and absolute humidity, H, can bring the air to
component a conversion is performed: saturation adiabatically at the same temperature, Tad' while the
pressure P T' is maintained constant. The adiabatic saturation
(2.22) temperature is also known as the thermodynamic wet bulb
temperature.
For a given G-V system, it may be defined as the temperature
where, hm is the specific enthalpy defined as enthalpy per unit mass at which component V, present as either a liquid or a solid, by
of the dry gas component G. evaporating into the moist gas mixture at a given dry bulb
Construction of enthalpy deviation curves 15
(2.24)
Set system pressure, Pr Curves of constant enthalpy deviation plotted on the psychrometric
chart are used in determining the specific enthalpy of a gas mixture.
Set adiabatic saturation The true specific enthalpy of a gas mixture is determined by adding
temperature to be plotted, Tad the enthalpy deviation term to the specific enthalpy of the gas
saturated at its adiabatic saturation temperature. The saturation
Calculate values for Hs2 , AI and enthalpy is read off the chart using a non-linear inclined scale.
h52 at Tad using correlations Equation (2.23) may be re-written as:
with the numeric sUb-scripts omitted. The left hand side of this
Guess value for H, equation is the definition of the enthalpy deviation, therefore:
For many of the charts presented in this book the non-condensing 3.2 MOLECULAR WEIGHTS, CRITICAL POINT DATA AND
gas component is not a pure gas but rather of mixture of gases. In THE ACENTRIC FACTOR
preparing the charts it is important that the compositions of each of
these mixtures are accurately defined. Many of the correlations used to estimate the required parameters
The composition of dry, clean air on a molar basis is assumed call for information concerning the molecular weight, critical point
to be: 78.0849 % nitrogen, 20.9479 % oxygen, 0.9340 % argon, and the acentric factor for each of the components. This
0.0314 % carbon dioxide and 0.0018 % neon (ASHRAE, 1989). information is presented in Table 3.1 for pure components.
This composition is used to generate all the air charts. For some of the charts the non-condensing gas component is a
Natural gas is a complex mixture of hydrocarbon compounds mixture. This is the case for air, the two natural gases, the two
and other non-hydrocarbon gases. Though all natural gases are mixtures of carbon dioxide and nitrogen and the Martian
predominantly methane with small amounts of the higher alkanes atmosphere. Since many of the correlations that follow require
and other components, the composition of the gas varies depending single values for Mw, Tc' Pc, Vc' Zc and co for the mixtures these
on its source. In preparing the natural gas charts two different gas must be calculated.
compositions are used: one is relatively rich in nitrogen while the
20 Physical property data
The pseudocritical volume, Vc ', is calculated from 3.3 SECOND VIRIAL COEFFICIENTS
Zlc R TIc Kehiaian (1995) suggests that for many gases the second virial
(3.6) coefficient may be related to absolute temperature by an equation
pI of the form:
c
Table 3.2 Molecular weight, critical point and the acentric factor B = T( 0.05820 - 0.012234 e 1734.29IT) (3.8)
data for the gas mixtures
where, B is expressed in cm3/mol and T is expressed in Kelvin.
pI ESDU (1973) presents a correlation for the second virial
Component MW I TIc c
VI
c
Zlc 00 1
coefficient for benzene expressed as m3Jkg. Modifying for
(K) (MPa) (m3Ikmol) consistency of units the correlation becomes:
air 28.965 132.4 3.708 0.0852 0.287 0.036
B = 201.92 - 150.07 e (720IT) (3.9)
nat. gas (A) 18.979 188.7 4.528 0.0998 0.288 0.024
nat. gas (B) 18.951 209.6 4.654 0.1077 0.287 0.028 where, B is expressed in cm3/mol and T is expressed in Kelvin.
For toluene a modified version of the correlation presented by
COiN2 : 31.373 164.5 4.310 0.0893 0.283 0.079 ESDU (1974) is used:
COiN2 : 29.614 144.0 3.839 0.0889 0.285 0.059
Martian atm. 43.235 293.6 7.187 0.0922 0.271 0.213
B = 273.31 - 158.lOe( 87o m (3.10)
Table 3.3 Second virial coefficients for equation (3.7) second virial correlation for dry air presented by Hyland and
Wexler (1983b) is used:
Component C2
B = 34.9568 _ 0.668772 x 104
nitrogen -4 -56 -12 T
(3.11)
oxygen -16 -62 -8 -3 0.210141 X 107 0.924746 X 108
----::-- +
helium 12 -1 T2 T3
neon 10.8 -7.5 0.4
where, B is expressed in cm3/mol and T is expressed in Kelvin.
carbon monoxide -9 -58 -18
carbon dioxide -127 -288 -118
argon -16 -60 -10 3.4 SECOND VIRIAL CROSS COEFFICIENTS
methane -43 -114 -19 -7 Very little empirical data is available regarding second virial cross
ethane -184 -376 -143 -54 coefficients. For the water-air system, the correlation presented by
propane -386 -844 -720 -574 Hyland and Wexler (1983b) is used:
n-pentane -1254 -3345 -2726
n-hexane -1961 -6691 -13167 -15273
BAW = 32.366097 _ 14113.8
T
n-heptane -2834 -8523 -10068 -5051 (3.12)
1.245535 x 106 2.348789 X 109
n-octane -4123 -13120 -16408 -8580 T2 T4
methanol -1752 -4694
ethanol -4475 -29719 -56716 where, B is expressed in cm3/mol and T is expressed in Kelvin.
n-propanol -2690 -12040 -16738 For the remaining systems the second virial cross coefficients
may be estimated using the empirical correlation proposed by Pitzer
n-butanol -2629 -6315 (1990):
acetone -2051 -8903 -18056 -16448
carbon tetrachloride -1600 -4059 -4653
diethyl ether -1226 -4458 -7746 -10005 (3.13)
Third virial coefficients 23
(3.14)
where, C is the third virial coefficient, Pc is the critical pressure, Tc
is the critical temperature, R is the Universal gas constant, 00 is the
and the cross critical properties T , C;j
Ve
,j
,and 00I}.. are defmed as: acentric factor, and g] and g2 are both functions of the reduced
temperature:
JT c,
Tc) (1 - k I).. ) (3.15)
0.02432 0.00313
gl 0.01407 + (3.19)
Tr2.8 Tr1O•S
(3.16)
0.01770 0.040
g2 -0.02676 + +--
Tr2.8 Tr3.O
(3.20)
0.003 0.00228
(3.17)
Tr6•O Tr1O.S
In equation (3.13), c] = 0.442259 c 5 = -0.611142 Hyland and Wexler (1983a) present a correlation for the third
C2 = 0.725650 c6 = -1.24976 virial coefficient for water vapour for the pressure series form of the
C3 = -0.980970 C7 = -0.1151562 virial equation. Rewriting the correlation in terms of the volume
C4 = 0.218714 c8 = -0.189187 . series form, it becomes:
The adjustable parameter kij in equation (3.15) is set to zero in
the absence of reliable experimental data.
Cwww = T2[ 752.82 - 2.31788 e364S.09IT
(3.21)
3.5 THIRD VIRIAL COEFFICIENTS
+ 1.49755 e 3468.S8/T - 14.2446 e 1734.29IT] 10- 4
Correlations for the third virial coefficients are only available for
water vapour and dry air. For all other gases the generalised
empirical correlation of Orbey and Vera (1983) is used: where, Cwww is expressed in cm6/mol2 and T is expressed in Kelvin.
24 Physical property data
J J .
third virial coefficient for dry air as a function of absolute
[ Z Z 13 Z Z 13 ]
temperature: P = 4 (Z , + Z ) T ( e, ej + ( e, ej (3.25)
e,j e eJ e'i P P
Cj Cj
(3.23)
where, CAAwand CAWW are expressed in cm6/moI2, T is expressed in
Kelvin, and A and W refer to air and water respectively.
where,
where, Pv and Pc are the vapour pressure and the critical pressure acetone -7.48660 1.29443 -2.66737 -2.55338
respectively and must have consistent units, and Tr is the reduced benzene -6.97961 1.32329 -2.60988 -3.38770
temperature. The values for the coefficients for the vapours of
interest are presented in Table 3.4 and have either been taken from toluene -7.25881 1.33129 -2.79827 -2.69277
ESDU (1982,1984) or have been regressed by the author from the diethyl ether -10.9553 11.50125 -23.8873 45.12717
literature.
For the prediction of the vapour pressure of carbon tetrachloride,
ESDU (1990) recommend the use of the correlation:
- 2.761 (1 - T)5 ]
where, Pv and Pc are the vapour pressure and the critical pressure
1C = [
L 5
i=O
1 +
cit i
C6 t
1
X 10- 11
(3.31)
and for 0° ~ t ~ 100°C for 100° ~ t ~ 150°C Table 3.5 Isothermal compresibility coefficients for equation (3.33)
Co = 5.088496 X 10 1 Co = 5.0884917 X 10 1
C] = 6.163813 X 10- 1 C] = 6.2590623 X 10- 1 Component C1 C3 C4 Cs
C2
C2 = 1.459187 X 10- 3 C2 = 1.3848668 X 10-3
n-pentane 7036.855 -304.676 8.42046 0 985.804
C3 = 2.008438 X 10- 5 C3 = 2.1603427 X 10-5
n-hexane
C4 = -5.847727 X 10-8 C4 = -7.2087667 X 10-8
13.03995 422.8992 5.7756 0 33.9650
Cs = 4.104110 X 10- 10 Cs = 4.6545054 X 10-10
n-heptane 11.69856 0.121788 0 0 0
C6 = 1.967348 X 10- 2 C6 = 1.9859983 X 10-2 n-octane 9.843256 0.091896 0 0 0
The isothermal compressibility of ice is given by Hyland and methanol 10.69904 1.441475 0.01136 0 0.131248
Wexler(1983a) as: ethanol 9.789885 54.39748 0.260084 0.003103 5.49329
propanol 8.43 0 0 0 0
K = (8.875 + 0.0165 T) x 10- 11 (3.32) butanol 8.10 0 0 0 0
acetone 9.6973 0.12964 0 0 0
where, K is expressed in 11Pa, and T is expressed in Kelvin.
The variation in isothermal compressibility with temperature for benzene 8.26435 0.79424 0.010554 0 0.103
the other materials of interest may be adequately represented by a toluene 7.881715 5.99166 0.042221 1.93xlO-4 0.767662
correlation of the form: carbon 8.915441 26.89171 0.175001 0.001564 2.98225
tetracloride
diethyl ether 14.61982 0.224914 0 0 0
(3.33)
Cp = C
1
+ c2 T + C
3
T2 + C4 T3 (3.34)
Reid, Prausnitz and Sherwood (1977) tabulate the ideal gas heat
capacity coefficients for a range of gases. These coefficients are
presented in Table 3.6, after they have been converted so that Cp
is expressed in JIg-mol K and T is expressed in Kelvin. The values
for helium and neon, taken from the ChemStations (1995) database
are assuI!led to be constant over the temperature range of interest.
Molar volume of condensed phase 27
Table 3.6 Ideal heat capacity coefficient data for equation (3.34) 3.10 MOLAR VOLUME OF CONDENSED PHASE
Component c] Cz c] C4 The liquid molar volumes of many of the condensed vapours may
be related to temperature according to an equation of the form:
nitrogen 31.15 -1.357xlO-2 2.680x10-5 -1.168x 10-8
4
oxygen
helium
28.11
20.79
-3.680xlO-6
0
1.746xl0-s
0
-1.065xlO-s
0
10 Vc + L ci ( 1 - Tr)i/3 (3.35)
i= 1
neon 20.79 0 0 0
carbon monoxide 30.87 -1.285xlO-2 2.789xlO-s -1.272x lO-s where Vv< is the molar volume of the condensed phase and Vc is the
carbon dioxide 19.80 7.344x10-2 -5.602xlO-s 1.715xlO-s critical volume. The values for the coefficients are presented in
argon 20.80 -3.211x10-s 5.167x10-s 0 Table 3.7 and have been taken from ESDU (1987, 1989a, 1989b).
water 32.24 1.924xlO-3 1.055xlO-s -3.596xlO-9 For water and ice the correlations of Hyland and Wexler (1983a)
are preferred. They present a correlation for the density of water as
methane 19.25 5.213x10-2 1. 197xlO-s -1.132x lO-s
a function of temperature. From this an expression may be written
ethane 5.41 1.781xlO-1 -6.938xlO-s 8.713xlO-9 for the molar volume of water:
propane -4.22 3.063xlO-1 -1.586xlO-4 3.215xlO-s
n-pentane -3.63 4.873xlO- 1 -2.580xlO-4 5.305xlO-s v = - 61692.295 + 291.8088 T
n-hexane -4.41 5.820xlO-1 -3.119x1O-4 6.494x1O-s Vc S (3.36)
n-heptane -5.15 6.762xlO- 1 -3.651xlO-4 7.658xlO-s L
i-O
ciT i
n-octane -6.10 7.712xlO- 1 -4.195x10-4 8.855xlO-s
where, Vvc is the molar volume of water is expressed in cm3/mol,
methanol 21.15 7.092x1O-2 2.587x1O-s -2.852x1O-s T is expressed in Kelvin,
ethanol 9.01 2.141x10- 1 -8.390x1O-s 1.373x1O-9 and Co = -2403.360201 c] = -2.914492351 X 10-4
n-propanol 2.47 3.325xlO-1 -1.855xlO-4 4.296xlO-s c] = -1.40758895 C4 = 3.73497936 X 10-6
n-butanol 3.27 4.180x10- 1 -2.242xlO-4 4.685xlO-s Cz = 0.1068287657 C5 = -2.1203787 X 10- 10
acetone 6.30 2.606xlO- 1 -1.253xlO-4 2.038x1O-s Over the temperature range from 173.15 K to 273.15 K the
benzene -33.92 4.744x1O-l -3.017x1O-4 7.130x1O-s molar volume of ice is:
toluene -24.35 5.125x1O-l -2.765x1O-4 4.911x1O-s
carbon 40.72 2.049x10- 1 -2.270x1O-4 8.843xlO-s 19.276404 - 4.50266 x 10- 4 T
(3.37)
tetrachloride
+ 6.69468 x 10- 6 T2
diethyl ether 21.42 3.359xlO-1 -1.035xlO-4 -9.357xlO-9
where, Vvc is the molar volume of ice is expressed in cm3/mol and
T is expressed in Kelvin.
28 Physical property data
Table 3.7 Molar volume of liquids coefficients for equation (3.35) Table 3~8 Condensed phase enthalpy coefficients for equation
(3.38)
Component c] C2 C3 C4
A = A l-=---=-Tc
- T J0.38 (3.40)
Tc - Tb
"vc
b
where, is expressed in cm3/mol and t is expressed in 0c. Values
for the coefficients are presented in Table 3.8.
where, Ab is the latent heat of vaporization at the normal boiling
point, Tb • The latent heats and the three temperatures are expressed
in consiste:q.t units. The values for Ab presented by Yaws have been
converted into kJ/kg and are presented in Table 3.9 along with
values for the normal boiling points.
Condensed phase enthalpy 29
Table 3.9 Latent heat of vaporization data for equation (3.40) For all remaining vapours the correlation proposed by ESDU
(1973, 1974) is used:
Component A. b (kJ/kg) 6
~:::Ci (1 - Tr )il3 (3.41)
acetone 329.4 501.39
i-I
n-pentane 664.736 -523.79 239.581 441.458 63.8916 -417.01 - 0.00115 + 4.21965 t + 0.198652 t 2
n-hexane 747.022 -539.02 170.964 280.819 -67.826 -123.73 - 2.93514 x 10-6 t 3 + 1.003624 xlO- 7 t 4 (3.42)
cyclohexane 1053.22 -1370.8 1433.86 -762.32 -329.47 566.020 1 + 0.0476516 t
n-heptane 171.016 971.174 -346.59 -2381.9 3676.47 -1642.0
n-octane 472.463 93.1351 -979.26 1082.30 1123.26 -1433.0 where, h! is expressed in kJ/kg, t is expressed in °C, and, the
methanol 2462.32 -4105.5 3120.83 4865.40 -2893.6 -2917.1 enthalpy datum condition is taken as liquid at O°C.
ethanol 1014.18 863.255 643.596 -780.73 -2051.7 1370.58 For the alkanes the correlation recommended by ESDU (1986)
is used:
propanol 2222.45 -8368.4 14566.8 -2870.3 -9655.7 4966.02
benzene 491.800 -337.75 419.803 3449.50 -7695.0 4452.87
toluene 705.696 -2124.4 8970.78 -18911 19431.4 -7637.1
diethyl ether 261.910 636.753 4.26865 -943.37 -208.20 986.280
30 Physical property data
1- ~) -(1 - t )]
the use of a correlation of a different form:
- cJ, {[( T
1- ~) -(1 - t )]
+C,[+ - ~)-+ - t )]
hf = - cJ, {[( T
c,l( ~ J +-t J
T
(3.43)
+3c,l(l- ~r+-t rJ
~ c,l( ~ r-( t r
T
+ 1 - T J (3.44)
J
c·l( ~ J-( t JJ}
+ 1 - 1 - T
Table 3.11 Condensed phase enthalpy coefficients for equation Table 3.12 Condensed phase enthalpy coefficients for equation
(3.43) (3.44)
Component c] C2 C3 C4
Component c] C2 C3 C4
n-pentane 3.1900 0.0130 -1.115 0.744
methanol -84.893 0.1550 -0.7130 -0.4725
n-hexane 3.3568 0.0095 -1.143 0.740
ethanol -127.809 0.1650 -0.7285 -0.4547
n-heptane 3.4542 0.0075 -1.142 0.720
n-propanol -163.419 0.1705 -0.7380 -0.4460
n-octane 3.5239 0.0063 -1.124 0.669
n-butanol -191.652 0.1740 -0.7440 -0.4417
acetone -17.005 0.1360 -0.7330 0.5220
Henry's Law constants 31
ESDU (1975) gives correlations to predict the enthalpies of Table 3.13 Condensed phase enthalpy coefficients for equation
r- r1
liquid benzene and toluene. The correlations are of the form: (3.46)
~ ~ (I ~ ~
3c.l(1 ;:
Component
r- r1
= carbon tetrachloride 0.90839 6.64730xlO-4 1.27157xlO-6
diethyl ether 2.0540 1.23873x 10-3 4.03937x 10-6
~ C,[(I ~ ;: (I ~ ~
(3.45)
+
3.13 HENRY'S LAW CONSTANTS
For the gases and liquids of interest values for C] , C2 and C3 are
presented in Table 3.14. kH is expressed in atm, and Tis expressed
(3.46) in Kelvin.
For water in carbon monoxide, Cargill (1990) recommends an
extended form of the equation to predict the Henry's Law constant:
-
E. X.J
kj - i
(3.49) C6H14 -6.3942 -55.3875 0 Battino (1982)
H J H
C7H 16 -6.0478 -166.951 0 Battino (1982)
CSHlS -5.9828 -194.827 0 Battino (1982)
where kHmiX • i is the Henry's Law constant for a gas mixture in CHpH -8.1708 -6.97967 0 Battino (1982)
liquid i, Xj is the mole fraction of component j in the dry gas C 2H sOH -7.9531 4.43802 0 Battino (1982)
mixture and kJ . i is the Henry's Law constant for gas component C3H7 OH -7.9060 25.7433 0 Battino (1982)
j in liquid i.
C4HgOH -7.6451 -11.166 0 Battino (1982)
CH3COCH3 -22.1720 377.545 2.34933 Battino (1982)
Thus, Henry's law constant for air in liquid i is:
C6H 6 -6.0554 -495.673 0 Battino (1982)
C6H SCH3 -6.2758 -371.675 0 Battino (1982)
1 0.780849 0.209479
+ CC14 -22.1869 407.891 2.3634 Battino (1982)
k Air - i k;,-i k%,-i
H
(3.50) C2HPC 2Hs 32.7008 -1382.81 -6.14581 Battino (1982)
0.009340 0.000314 0.000018 O2 HzO -179.344 8747.55 24.4526 Battino (1981)
+ + +
kAr i k~o,-i k Ne - i C 5H12 -10.4699 1276.11 0 Battino (1981)
H H
C6H14 -11.7442 1645.59 0 Battino (1981)
C 7H 16 -11.0656 1437.28 0 Battino (1981)
CSHlS -6.08479 -14.5340 0 Battino (1981)
CHpH -8.2471 137.42 0 Battino (1981)
C2HpH -7.8738 126.93 0 Battino (1981)
C 3HPH -7.59492 0 0 Battino (1981)
C4H9OH -7.6234 145.53 0 Battino (1981)
CH3COCH3 -26.2178 718.725 2.936 Battino (1981)
C 6H 6 -30.1649 874.157 3.53024 Battino (1981)
C 6H 5CH3 -6.62770 -107.597 0 Battino (1981)
CC14 -10.4321 163.87 0.5541 Battino (1981)
C 2HPC 2H5 26.1922 -953.953 -5.1785 Battino (1981)
Henry"s Law constants 33
Table 3.14 Henry's law coefficients for equation (3.47) Table 3.14 Henry's law coefficients for equation (3.47)
n- Pentane-Methane 286-291
n- Hexane-Methane 292-297
Benzene-Methane 298-303
Toluene-Methane 304-309
36 Psychrometric charts
230 45 50
0.50 atm pressure 35/ :'1/ l'-.. /: I
' • I
-
A / j- r- h .~ ."",, -"':;k
#' 170 ~
-V / rJt t-.= L
- r::-hi.X; Po
'"
,060
o~
-
/ l'-.. 7- "-.. :V
I"
30/ I-,l /
'S-'f-~
- -.:bL-
160 ~ 7'- I-- ~ :
,056
\...'f' 150 / V l,T.' --'" -d- I-- ./ ~ :
...
·o~ L f=
--A- I: . ~' ~
r-- ~
-.,., /
-:--
'iii
-
.052
- bL-
~
A I :'
" -'" r.- -
~7f 140 ·o~ / ~
~ ,
~ : ~
1;-Cj
~ ~7f
~
.0' / I.A' ~ / Lo/ fL-..; /' r.--:
.048
"0
'" -
130
-
'---- hi "X ~ r.t-- t-- / / :
co~ eo \...
--
: -~~ 0>
""
' .044
- 7 -- ""- ~
-
~~ . ~ eo,flf 25/ 7 ." -I"- ~ ~r" .::.!
o
/
7 F';: ~
""
D" : r- /
110 ~~ ~~ "'-
1""- r-- -i-- I-- ' .040 ~
-
,0 ~ ~ / I"- ~ ~ "-Q: ~ f<C- / '6
-
,is' <::
- 'E
100 ~ \~ ~ ~- i - t-- ':-', / ~ -7 ,036
,- -"" -'" K: V
.....,., k: "
-:- -
/ W-":; ""- r--,. ~ I"-
-
v/ ~: :J
'"v""-
90 rc- ""-
/ t-- -:til ~ 7- !('" I-- /: I"- r::-;
,032
~
:" -
Q)
20/ p- I-- K /.- /?:
80 "- ~ i-- P"'- ~' / b-.. .2
--, ..<:..
~ ,
- - -
/ ' 7""'- ~ V ·' T,- I-- ~ v~~ :' V l -I-- "7"- I"- 0
v .028
-
: D- r-. g., (/)
-
<"" "<;t-
-
70 ;-,. c..b / ' t-- L ~' 1":7 I-- : ~. .0
60 1
-c..... A' '7 -,.,:.
,..c:::: 17 - "/
~
- '"
--!,..c:::: ~ ---.:
:n~ .<::J
- - --
- """ - -
-
,;.c::.
...... ?
;/' '---
-:-
~ :
:"/ f--;
~
'.
1"..........,
-.. ,024 <C
-
./:
- - -
-:---
, ;-<. -:-
-
50 ? ~ /' ,~, ~ "--..... -.....l ,/" X-- -f-- / ,,:oc:;.
.020
--
~
.016
::>"' "--..... -> c: ..... -;;;: : - ~'
""--- -......:
1 / ~ ."...:::t" /' ~ ~ ~ .-' """'-' ~ ~
- --
-2 > -< .-::::: """ :>?" "--.....
- - - -- --- - - '-.-- -
::::-:............
- - --=-
30 ::>-< .,.....:: ~ ..d::
'$ ~ <- ~ ~ '<' .->"«
.0 12
c::::: >
- --
-- - .... - - - - ---:.- ---- - -
<.. ..2 <-- ::; ....::::::. -:=- c-
>""
-= .2 ~ ~
I
>- =. . ~ ~ ~ )'
<
~
::>< :::::
20
--- -
-"...
'v·
"-..... <: ?F- ~
, ~....c::: ~~ -gI.
S!'- ~, "'B :-- ~
.008
- --- --
---.;
- -, -
10 ::::-:::-r- ....... -....; '~
0
~. ~
-
""""""',
.004
5 =:::::::: 1-- ---..: .~ ::::.. ..:.:... -:' ~~ ..,..,.. ........
~ --I ;-- ~ ..:..:.....
, . "
-...;" ~ -t- ;- I-- ~ ~I-- F:::::jr--+-=::t----j~N I-- N
, . "'
r-. N 1--, "4~N ~" ~r---+- --I--I
r--: .'t":-:-:"'N I-- N
,000
o 5 10 15 20 25 30 35 40 45 50
WATER-AIR SYSTEM
0.50 atm pressure
I
I
I
/
70
...
V
,
II
I
I
"
I
- - ---
, , 80
"
: -
1 •• 1 ....
--. r--
90 100
,800
.760
- -
:
dry air O.OOT, 1.00 atm 1800 I II I ~ 4.l'ifl .720
I / I l--
I I I /
;7
1700 .680
-- -- --
Too btain true enthalpy add enthalpy
devl ation to enthalpy at saturation
I
/
/ II
/ r--,
I
- :
~
.640
/ / /
-
.~' 1500 .600
~
I I I I i:"-- r--
I I / II i--' r-'u
~
.560
I I I :1 I ....
~O; :1
..::? 1300 /
L
7
/
~ i--
I
/
I
;/ .520 '(ij
,- --
~
~ / / / 1 1-1~ '--
.480
"0
~? - --
OJ
,;§'If / ':':
:z .."'.
~
1100
/ ;!..; / .440
""-
OJ
1 0)/
C;)I§
/ / .V 'b: ' 3.5'0 ~
~
~o
~ 60
/ '/ r~: ,,' -:--
~~~1/
~'lf
~'lf .C)\ / / n\O V / .j / ~'"
.400 ~
'0
~\... l- -/.. 0/ 1--,' / 1/ "Y' 'E
<v~/
C;)'lf 0 .360
~CJ -# ./
-rr- c) '
-
:J
..c
800
:;9'lf
.~
~'lf
Q'O
/ / / / I-- ' '
.320 Q)
-
.C> :J
\>" ,'0 / / /' V' / '0
700 /
/ / / / . / / ~o.:' --: .:::... .280 (/)
.0
/ / / r,.,C) V ,/ I.'
<C
v V I / . ,/ V .240
6y ~,~.-
500/
50/ / 7" '---. /' .... 0\ / V .200
./ /' ,/ ,/ ./ ... oJ.? ;--- r-- l,,/ /'
20 0"
Y' ..< ' '''- -----
...- ,.-"
:
.080
,
, - , .040
100
'. . ...
~
~ "
.. ." .000
30 40 50 60 70 80 90 100
140
wATER-AIR SYSTEM
130 40 45
0.8 o atm p ressure ~ ., ., 50
/ . .040
f I r-- 'J l\ ~ : 1/
:V / t-:--
-- -
/ -- -/;. V: :~~ :
--
.'
Enthalpy datum: liquid water O.O I·C, 0,00603 atm 120
.t \ : .038
L I:' ~ ..... / 'v' I'--- K j .
r r-- : I
-
t-- \ :/ :
-- it:--- -----
dry air O,OO·C, 1.00 atm .J' :' \ .036
11 0 30L \
Ij: -/.!. . j r-- 1\ : :)(- ...;.
I '- : I : -- :
-
f--. ~.\ .034
To obtain true enthalpy add enthalpy L / : ~ ..J.. .' j ' \ .:-r .:
:
\ .
: W::: :\,- p-
dey iation to enthalpy a t asturation
,~,
f-.- if...: ,K -j.. . J '-:-.....: I..... :
-
~ 100 .' .032
/ 7· k .\ I :' y.. ~ -..;
\
0<:\
I : --. (.... ' ~
I .' Y :1'---
/ :
:
-,--
I : I ':'-1'-,(.
~<:>.>
~~
\..
90 / v . I... / V 7--: --, ' X
r-- ~ : :
--- ~
.030
f-.-J 1\ / : -- ~ :'\ I-.. f/ --- ~ :
-
. Q{:-
v. "-.. .' 1/ .028
/ Z '\ ../. r-.. -/..
-
~ ~ ..:.... .....
~.s 80 25 J --/- / \ .' j--.. k / \ --'p.:..... : - -..:.. \: / : ---
.026 '(ij
~'i:) I:S..: ;c:::::: -.,c\ / r-.::. / : :-;::. ";"-::: A : ~~ :
, Q{:- ~
~'- ;:,: / /: \ --:-
~
~~'\ ~ / ().~ 1/>1 -,.:-...,/ ' / \ .....,,:, 1/ - : -0
r
- --- -' - -
/ r-:::::: :z [\(~ . / ----;. --L .024
~.s 00' \,/ 16;? .\ :
--
~~ 70 ~ OJ
---
~
C:J~ \.. 0)\ '--.
~
L<'¥ "-- ."-\- /
--
<v~ <-- / .s: ~ -.....:~ : ~ ?-
~v ~ro .022 OJ
~
.r§> 0....~
~/ ~ \ /' "'- I-. ~: \ 17- 0 ~ : r.--+-. 'x ~
-
60 '?-~ f$-'? ~.
---
"
,0 20 / f-::::: l2< l,) "-;;: ~ 7 [--:<:.. / .\ --: '/ 1 ~: ~: ; 1\- 1--.' ') ~
/. - ' : \ ;:;,
"0
-
f-.- / :7 I--.. "/ ""~ / -r-.. : -.....; ../
'E
-
c.. V ~ ~ .018
-
r-:.:.. L I
-
50 '/" t--.. X~ ~ .' --;} ~ ~: ~ ,/
-
::::l
-."Q '! /
'" " ~ r-- P: IV
-
.L:
6 ./ ~ i:;>< ~~ \ --....!... :::::.;,
-
.016
><-
Q)
""-. ~ .7
-
C ./<....... r->< -L ."\- I-- l~ K \
-
...:...:. "
V: ::::l
~:
-
"" ~
-
40 "'-- <.... l/.'l . / K., : \ -...;.
-- 15 .L ./ ~ v0 ~~. (5
</
'-
.014
~
:-- /.1
-
:;.<: ./ ' ./" :->-J ~ ./ '--- . / ' ./' M-;:. >- ~ \ "-...I VJ
_.
-
--- '- .0
«
,
-
v
~ ../ --:;.<: '-f'\- .1J9\ - : --- y
-
/" '\- I _ 7 ">1......-; ,: .--/
-- --
~ /:"---j
-
"- .012
30 j'--.., Z \. >'<.,-- / ~ i<.. ~ .21 ,/' - ,i-..., ...... ....... :-- : \' ~
- -
'--: ~~ /
::- '<- / ">< "\ -.... =< \ X ~ ->:/ .-...: : \'- .-.....:
--- '\- - : r-- __
,/'
, --
;-~
10 " ~
--
.010
< :' '\'' ">: 7 : -
-
>< \.. :/' <...... ...... . /<-\j....:.. --,.. / . ~ ~
-
/~ ,/' \ ..\-
-- -
~> --- --.... --- ~
-
20 --></ ....... ,"'1 ": ...... ."-
::-.., V <...... V \:) k \'-
-.
- -_"-. -
.
X :: ">< ~ <\( ~ ~ 1:--- ~
--' --
~ ::::: ...... ......., .x <""',,>-<, ?" ~ ./" >< '\ :::::::: .......-i ? --:-. \ '''';'' - : .008
"
,- " >< -...:i
-- - - -
\" ~ ~ ><' -..:...
::!: I--- > >- ;< > <.... -:> : -> 1 '< I " Sl>< -:- 1\- ><; .
---
- -
<1 -.......J '. \" :--...
--- ---
-
"'i:,... .~~ '.
~ o.i.--
,006
-->< -.....: ' - 1....--' -< ---
-
><- ><.:>< ? <:... ..,- ¥ -.\ ,.:> ~ :..<- - ' -........~ \7 ~ --, .. -.....: "
---
-...:..
'iij
.380 ~
"0
.360 0>
..:.c:
-..
.340 0>
...:.c:
.320
.300 ~
.280 '0
'E
.260 :J
---'
.s:::
.240 Q)
......
:J
.220 (5
en
.200 .0
- r--r- :..} I «
--
/ 1: I :
I : .180
-- --
.160
:
.140
'. -
.120
:/ 1.fa
.100
.080
.060
.040
.020
.000
30 40 50 60 70 80 90 100 110 120
140
WATER- AIR SYSTEM
130 3 ~ ~% , ~
0.90 atm pressure / II \ ,Z--t"----. V -- :I :
.040
t--.. .i I! ,: I h'- ; r-:- __
Enthalpy datum: liquid water 0.01 "C, 0.00603 atm .038
120 / II ~ .\ :' / --r-\: j
dry air O.OO"C, 1.00 atm ~ .b'- /: : 1":---
'\ ; ....,~ : x. ' : ---....;, .036
/ \ I'I 1'--.1
110 b, --- -:/.. : I / • .1'-7 . j I :
.034
To obtain true enthalpy add enthalpy / J:'r\.. .f: .~ ;' 1/ : \."r:-'-- / :
deviation to enthalpy at saturation '-.... ---..,l / : ---r-;.,.( : .- -
100 .032
30/ 17"--.1:1\ --<o..j. '\ V .'-..... : 'X
f:-...: L ' :' N.,(· : -....:).,..,L : : ....... ~
.030
/ r\ 1/ : 1'---'- .' /\ ~ '\ I:'-- 1/ .\.>;,
~ .x. :' / --K' \ :--'fL : \ : / f'---r-.. !o·
.028
I :'\-K: I : ~ .. / ~ : r\;. .
J 17( : X r--, ' / : \ -:-,.z.. .\V ~ : .026
....
'co
~
'0
.024 0'1
~
.022 ---
~
C'l
60 .020 ~
:.0
.018 'E::;,
50 £
.016 Q)
"5
40 .014
'6
C/)
.0
<{
15 X .' / 1--......,. ,: ~<'~/ --..... -- /' ,~~ --- 1. . . . . \' ~ 1--
>-\. '.l::./ - ___ : \--.:..... < --- __ . --..... .012
1 /
.004
.002
N .000
o 5 10 15 20 25 30 35 40 45 50
WATER-AlR SYSTEM
0.90 atm pressure
Enthalpy datum: liquid water O.Ol °C, 0.00603 atrn
.420
dry air O.OO °C, 1.00 atm
.400
.340
.320
.300
-'co
.....
~
.280 "0
--
0>
~
.260
i---~
I, -I-- - 1. 0 ~
,240
--l-
, - r-,:..
.180
f-::... \
.160
I .140
.120
.100
.080
'. .060
100 -j.
£.
o
e {,., --
T" :n:-' .040
020
~. ," '. , I ,
50
'J
30 40
Dry bulb tem per atur e ("C)
42 Psychrometric charts
140
WATER-AIR SYSTEM
130 40 50
0.95 atm pressure
35/ V ."7 t--: rv :. J r-,:: J\ I : .040
Enthalpy datum: liquid water 0.01 ·C, 0.00603 atm 120 / / --;I... f\ :" -- -..,:.... :I . \ .038
.030
.028
....
.Cij
.026
~
""C
.024 Cl
-....
~
Cl
.022 ~
60 .020 ?:-
'5
.018 ·E
50 :::J
.c
.016 <1>
"S
40 "0
.014 CI)
.0
.012
«
30
.010
20 1 ~ /'--,< >< .. V-:o....... >r-... ~< :'---.... ::>;<l\... ~ ~ -- __ ""\-- ~ : ..........
1__
<J,;>:::";-./ -....,< >< "\::>< ---..J.' ? :o.......~1 Ofd ><- -.:...: \ N <""? ' '-.. \ --__ : , __ : >. ~ .008
.006
.004
.002
o 5 10 15 20 25 30 35 40 45
W A TE R -A IR SYSTEM
110 12 0
0.95 atm pressure .440
,120
.100
.080
.- 'Pee fie
:-- +-- ,Uh
.060
-
-I
I aTri •.;r~
c-.,.
100 -!- I
'.I
r
i:
0 I
, I
;::: .020
,
.. "
" .000
30 50 60 70 80 90 100 110 120
A.
I --~
/ :
J
7.\-
... r- \. ---~V
r--
.030
:v........ /
: /
\ -,...;
--~. 1fZ~
,028
30 \ r:-r-. / :
/ ~I'-- / . / : ........ y '7 -f-_ /' r-- '-
'co
r---../ 1\/ : ........ 1{ . r-- _ V ,: r-x : ,026
~
"C
.024
--
C>
~
.022 C>
~
.020 ~
60
U
.018 'E
/'---6.( ~I?" r-- L . /'S /~~ /[s-,; ........ \ ~ r<-r-. : '-'\- ::J
.c
50 ./" '-\ L 71:-- ./ \':><. : /':-:-. \ /' "':!t~: --,,~, "-::: :
.016 Q)
'5
'0
40 .014 en
..c
«
.012
30
.010
20 .008
.006
.004
.002
o 5 10 15 20 25 30 35 40 45
WATER-AIR SYSTEM
1.0oatm pressure
80 .. 90 100 11 0 120
'00/;/~
.400
•• f , • I, •
I : .1 f'-... r--...~80
17 I If I T---.. ......
En thalpy datum: liquid water O.Ol°C, 0.00603 atm I I r--..... I I ;-. t--... .380
7 7 F ... / / -:--.
;/
dry air O.OO°C, 1.00 atm :
.360
7 1 -----:- I-.... :
L
r /
7
I
1--- / : ......
---;. t"O .340
To obtain true enthalpy add enthalpy / : :
dey iation to enthalpy at saturation r "'F / / /:
...........
r-::-.. :
;/
!:' / : . . . r--.. : .320
/ 7 ........., j: /
.~\ .300
/ / 7 7 ........., : : r--..
o(\~ 7 l r--.. /
701 / / /. K
r- ......... :
~.Rft
.280
......... 1 ~
..:y.,*,0:> 700
f / ' 1:. I / : .V I---
~
,
'iij
~ / / CI!- i--.. 7 I: / ;.:,: r---- : :
.260
-
~
~L
~o
, / : V ~.
--- "0
L
I--- . .240
~q)- 600 I / 1/ I ' I ~ ........ 1 / :s: C)
..::.t:.
/ 7 I 7 : , 17 7 .: I 'r--. ~: I : ......... ·50
.....
-..
~o~
C)
:
~I;:)q)- o ......... 7 :- --,t.. .220 ..::.t:.
---
.200 ~
~ 50~ ~0
/ / V ;' '/f-- 1/ 1:::. / ",,':
L
'0
I;:)q)-
/ 7 : / 1 -..;; .::, . / ........
'E
..
~CJ ~ I~ / h--..
---I
«,,<:::'- .180
'$:)q)- ~q)- 1/ '07 V :/ :::J
: ..c
""-t: ;.::
---
&-q)- 9,0
60/ --.Ii / 1
/ ~ :
~ ,0~ / r ..,.Q
_, co .160 Q)
/ li f
400L
/ / /
/
;.Z..,:
I ;
~ I
.....
\"-- ..... :
:20
L
1
- ---
.140
'0/ 7 ----I... ./
r/)
/ : .0
/ / / 10/ / I /' : <X:
.. ........ :' .....
3ooLi' /.. /' / / Y'
'"
7 /" :
.120
---
~.
/ / "c
I/" / "/ "'::: 1 -..:...
L 50./1 /' ~ /' ./ I / I ..... .100
---
L ..-1 ~C'\
.060
L .u I ,/ --,., .....-: . ./ ...... 1 I ..-+-' ..:.......: ?O
, ...-
-.
-L ...... ..- --;y .-? ..- :
""
~ 0<'"
L .t:::Ir
100 :::, .040
I II",
I
I
, 'j
~"I
rte ((h'
I I
I
.020
,
. , .. , .000
30 40 50 60 70 80 90 100 110 120
140
WATER-AIR SYSTEM
130
40 , .. , ... ;-,.,.. 50 038
1.05 atm pressure / 17 :l/k J : "FQ;,7 .
0.01 ·C, 0.00603 atm 120
/ . . . r-; V r--t-- f7 : ~,
Enthalpy datum: liquid water 'i .'f-t-.. . \" 'i:'-- 7 '\ . .036
dry air O.OO·C, 1.00 atm
35A
/......,,~ : r~ II ,r,:... .
.034
110 / A:7'- V---i. II
To obtain true enthalpy add enthalpy .032
/ i7\- I: / 7r--~ : V -
deviation to enthalpy at saturation 100 / bf /' : 7-t--..:: -rr-. .030
I 1-'-'-.. V 7 --- '\ : ---,I L
A ~~/ --..... : ~~ / .028
~~ : ___ ~ yv---.. . . / I ~~
30/ V\---k· / . --)5, - t/ .026
....
f-... /:' ~. '-.. 1/ . t--t-.. \ / --- ...... - 'ro
.024 ~
"0
OJ
.022 ......
.::£
OJ
.::£
.020
60
~
.018 '6
'E
50 ::J
.016 £
Q)
.014
"5
40 (5
en
.c
.012 <{
30
.010
20 .008
.006
.004
.002
.000
o 5 10 15 20 25 30 35 40 45 50
-.-: ~o
.200 ;::.
",':
................. "i5
'E:::::J
..c
.160 Q)
-_;.:.'::V · :2o
.140 (/)
.c
I 1
<C
.120
::::-+-- I :
1:-...... .100
~
, -....:.':..
.080
,,
.060
--
-- I
--
, vOllfh~
o .--.
I .040
I· '/ .1"
I " I
~ .020
. .000
30 40 50 60 70 80 90 100 110 120
130
WATER-AIR SYSTEM
1.10 atm pressure
Enthalpy datum: liquid water 0.01 ·C, 0.00603 atm .034
dry air O.OO·C, 1.00 atm
.032
.026
, .024 .;:a
'-
~
,022 "0
C>
.:.:
.020 ---
C>
.:.:
.018 >-
.~
"0
.016
·E
:::J
-
.c
Q)
.014 :::J
0C/)
,012 .D
«
: .010
.008
.006
.004
5
.002
,000
o 5 10 15 20 25 30 35 40 45 50
WATER-AIR SYSTEM
I'
;/
!'In
o
1.1 atm pressure I I 1':--... .1 /
90
/ :'
. ,. ..
/
100
.1 .. I . .. • • 1 ..
t--.
110 12 0
.400
/ / .: ......... ' / -......."
En thaJpy datum: liquid water 0.01"C, 0.00603 atm / / 1/ : .......... :1 / : r---.. I·f 0
.380
;/
:/ .360
/ :' / :--..... ,
,
/-..:..:::.. / ./ / " / .340
To obtain true enthalpy add enthalpy I 'f-.. ,f I : ~
:- ......... -....
dey iation to enthalpy at saturation
/
/
f :/
:'1 -.......
f
I
:', r-...
.320
"/
.......... 1; ~n
J J :-.... I---
.300
o~
~ ,.... I-.i
I f II
.7 /
/
,j
.'I ...... f.-.. :'
I' --.....
~,*"~7y
7' '-L / .j / ...... --.... : :
.280
/ / -.... / V r- ....
'Cij
~ 70/ 7 / / -.... V
~
~ ............ .
1
.260
--.... --..: ' ~
,~
V
~Q<::- / / A /
"!/ V I' I l5
:
.240
"0
W~~~L ~
c' .' Ol
.:;,:.
I' ..J j.' I '/' I ,$ ' -.... --I... -....
Ol
---;... .220 .:;,:.
~Q
I
I :' V
~~~ ft;-~f[j ,,0 / / I ......... --L / c>:l: : -....
/ / ;,: -.... -/.... . / c:- : :-- ...... .200 ~
~ 50~ .u~ ~0 -.... ......:. u '6
L
",.'; 1
/ 7 / : :
<0 ~ ~ ~ / .......... / : ,'
.1 80 'E
'S)'lf ~'lf / / / I :' / / ~ :::J
&'If
~J .
7 / 1' -..:: 7 ,
jQ :/ :
,
.140 (J)
.0
,
I
300LL /' / / V ~, y
1
/ ~ /' :
I-
,--- .120
/1/ / 1
/ ~ / -;,.<l
L /' / -.:.::: /' .....()(7 ./'1 ... 1 V ./ '::-- ~Pec I;. I
.100
L
--'----
I
/.. 7' -;-..., .....{ :1
/
T
I
./
50.,"""'- / ' I : VIU~
-
. / . / /' Y fl.\) ? I ~ -,..d 1 :
---
20 --.!
....-
-
L / v .......- .....- V Y .....:::: : I 1 I
' 7. 0
.060
L ,n I
......- ....- <.>,IJ
I I I ..+-
.....-
I
..L ...... .....- 1· :;..-- "
;L 1.....- ,..- I
.L I 0
....., .040
10 0 I
...
, .< .~
I I 1
I , I ..
I 0
nu I I I '.
I .020
.. ---
I
. '. .'
I I
"
, ' , , , '
I
"
'" ' , . , ' , '"
" "
, , . .000
30 40 50 60 70 80 90 100 110 120
WATER-AIR SYSTEM
50
1.20 atm pressure .030
.022
.020 -'ro
....
C:-
"C
.018 Ol
~
.016
---
Ol
~
~
.014 '6
'E
40
-
::J
.c
.012 (])
::::J
(5
(Jl
.010 .0
«
.008
.006
.004
5
.002
.000
o 5 10 15 20 25 30 35 40 45 50
.100
.080
-r I -..:... On .060
.040
.020
, ,
.000
30 40 50 60 70 80 90 100 110 120
WATER-AIR SYSTEM
50
1.40 atm pressure .030
.022
.020 .....
'm
~
"0
.018 OJ
.......
~
OJ
~
- .016
~
, .014 "0
'E
-
:::I
.s::::.
. .012 Q)
:::I
0(/)
. .010 .0
«
.008
" .006
.000
o 5 10 15 20 25 30 35 40 45 50
WATER-AlR
SYSTEM
lA O atm pres
sure
Enthalpy d at u 0.01 ·C, 0 .006
m: liquid water 03 atm
dry air O.OO·C, 1.00 at
m
T o obtain tr ue
enthalpy add en
deviation to en thalpy
thalpy at satura
tion
.190
-
.1BO
.170 ....
'@
.160
~
-0
.150
.140 --
~
~
.130 ----
.120 ~
"0
.110
'e
-
~
.c
.100 <1>
:::l
.0 90 (5
(/)
.OBO ~
.0 70
.060
.050
.0 40
.030
\ \ 7' "F -- .020
I
""- \-- = k:::::l..",
J- ~
\?' ~
~ 0
----
.
50
['f: !{ 01 0
F=t
~ F- - -~
,
..
~
l-
11 0 12 0
.0 00
30 40 50 60 70 BO 90 10 0
WATER-AIR SYSTEM
50
1.60 atm pressure .026
.018
.....
·ro
~
.016 "0
C)
.014
--
~
C)
~
.~
"0
.012 ·E
-
::I
..c
Q)
.010 : :I
(5
(f)
.0
.008 «
.006
.004
5
.002
o
.000
o 5 10 15 20 25 30 35 40 45 50
.200
/ / I .. / / K" I .7 - '"
:...~o
.190
To obtain true enthalpy add enthalpy "'- .180
deviation to enthalpy at saturation
.170
.160
.020
+--
50 ~ .010
'. r--
.000
30 40 50 60 70 80 90 100 110 120
WATER-AIR SYSTEM
1.80 atm pressure
.019
To obtain true enthalpy add enthalpy 70 .018
deviation to enthalpy at saturation
.017
.016
.015 ....
'«;
.014 ~
"0
.013 OJ
~
.012 ---OJ
~
.011 ~
'5
.010 'E
-
:::l
~
- .009 CD
:::l
.008 (5
(J)
.0
~ .007 «
.006
.005
.004
5 .003
.002
.001
.000
o 5 10 15 20 25 30 35 40 45 50
WATER-AIR SYSTEM 6/
Z ~ ~80 90 100 110 120
1.80 atm pressure 1 ""'-J .200
1 .: I I
"'" ~
J
50
J IT
I .'
/ / ~
Enthalpy datum: liquid water
dry air
O.OI °C, 0.00603 atm
O.OO°C, 1.00 atm
/ 7 17 :' / / : "'K 17 - 1-..;,
.190
00
j
f::.W-r-/-/-
1/ .
/ ... . / '01
:r . . . .
.180
.170
To obtain true enthalpy add enthalpy .I
deviation to enthalpy at saturation / - - .160
:
.150
-;:::::"..+-
"'" -"""'::?$
:-:-
.
.140
....
/ K .130 'co
:
/ I .120
~
'0
--
OJ
.:::t!
.110 OJ
.:::t!
,
.0
',Oe.' .
. '// - -+-r----.!'-- I ~
...... ,
: ..... , I ""~..7
~
,. .
-,--_
.060
. ' -""":/"'(I>(J -
7' .050
/ . . . . . ~'Y"'/.. -
,.,. • - ""rI .040
30 40 50 60 70 80 90 100 110
WATER-AIR SYSTEM
2.00 atm pressure
.017
To obtain true enthalpy add enthalpy
deviation to enthalpy at saturation .016
.015
.014
'-
.013 .iii
~
'0
.012 Cl
.::s:.
......
- .011 Cl
.::s:.
.010 ~
'5
.009 'E
-
::::l
J::
.008 <l>
::::l
(5
.007 !/')
.0
«
.006
.005
.004
.003
.002
.001
.000
o 5 10 15 20 25 30 35 40 45 50
600
WATER- AIR SYSTEM
2.0o atm pressure
90 100 ., .. .. ,
110 .. . .
120
.200
'"
550
80/ I I Y II II ,' I I :
II .. I I ' If..-.. I :
Enthalpy datum: liquid water O.OI·C, 0.00603 atm .190
~ I il / ~ ,' I
dry air O.OO·C, 1.00 atm I I /", II : I : :
500 / I
../...
~ : ;'
:"f... I
j I : I
'-------
II
f' - .180
."'.
~
'i-.
: " .170
To obtain true enthalpy add enthalpy / I hL I : ,"",,0
Z
dey iation to enthalpy at saturation I
I
I
I : I I
-------
"-,:
"-,
II /
: II
I ..
'-" .160
I " .' I "
~ 'f,..' I
I
I V .: !
7
I
: I
:j : /
.150
~
~CS 400 / I I I I : :/ ~ /
.140
Ii'.. IT r-:.:.~ : / I :/
"'"
~~ / : .....
\.."*' j I l"-...... :1 / "-.. / :
.1 30 'cu
.~
~o 350
lL /i"-..... '/ !/ / I· /. / : ~~
2:-
/ !/ ....... : : / : K
~. ,- -0
t§~
"
: .1 20
70/ / j :/ :>: . / : : ').( 0>
.::.:.
......
f8-~~
~'?
~
300 -~~.&.-
'0<::'-
~
I.- /
/
/ /
.)(
/1
/~.
L
t§ \.. 1/
'"
/ I?:>: : : :
e
<v~
'? .100 ~
~v#_ / / /' / / .£ .-:--....... /
:
:
15
~ f...~ / V :' '/;;. ~ :' 'E
.090
-?s~ ~e_ 1"1 / . -+. V
~
/ / ~ .
-
/ :J
-
Q) ' ./
~ et$" -------: : i"""'-.. ..c
~- L "'- / / en',:
.
'"
.080 0>
/ / ~ / . ~ / : v '
0
:J
60/ /
L"':"
/
.. /
~
/
/
"-..
V .ct
'1:' : /'
/ N'...
: ..........
- .070
0
rn
..c
20
«
./
./ V / \0/ :2< /' : ........
L
"
.060
./ V / ,/. / :'
-
Q
0
~
/' / /' ' \0 ,/: .......... ... V V .050
15 ,/ X /' ~:::: ..7 v -------
: ~ :
, /"'
- --
.040
/ / / ' ,,- >< .. ' / .- / b--:
.-
/'
-
I
.030
- ---
v- I /'
"---. ..:- 1..- -<.: to
-- -- --
:
-
/"' /' i"---
L-
- I ""
I-'
.~ e :
.--
00.
L=
.'
-
. . .020
-? 2' : ........
.]
.-. r----r----
.- -;--
' 0
I-- i---- -'¥ ~,.,
50 ==--- : . r--- i---- .010
.- -
I
I -;--- "/ f.
, I
.. i----- 1--,' -. :--... ~
.000
30 40 50 60 70 80 90 100 110 120
WATER-AIR SYSTEM
50
2.50 atm pressure .0160
.0155
Enthalpy datum: liquid water 0.01 ·C, 0 .00603 atm .0150
dry air O.OO·C, 1.00 atm .0145
.0140
.0135
To obtain true enthalpy add enthalpy
deviation to enthalpy at saturation .0130
.0125
.0120
.0115
.0110
....
.0105 'iii
.0100 ~
-0
.0095 Ol
.0090 .....
..l<:
Ol
..l<:
.0085
.0080 ~
.0075 :0
'E
.0070 ::I
..c
.0065 Q)
.0060 ::;
(5
.0055 (Jl
.0
.0050 «
.0045
.0040
.0035
.0030
.0025
.0020
.0015
.0010
.0005
.0000
o 5 10 15 20 25 30 35 40 45 50
420
80/
~/
f i"-... / / :' i- f .'
"-"f:t
~ r- t=
.150
.145
7 ~ -/.... I. II K
-
To obtain true enthalpy add enthalpy / I ~
"" "
.140
dey iation to enthalpy at saturation 400 L / !I / L"l(
,*-..y.~ 340 L
:
" .120
",,7 -
1'-- If-hL ~ / / N / ~ :--
.1 15 ....
" clL
~
/ I .: / I V b., :
~L
-
~
... ~
"
-
·o~ 320 '(ij
.. -
-
.110
f.,.~ :--I- .L / ~' / :'1/ :1 ~ : /.:::;: ~
i}v 300 / 'j V ;.'/ --;
~ 6". ('lfl .V"i'-- 7- -+- .100
.1 05 '0
" -
~~
V
-"'"
OJ
·o~ r-- I- i"-... . .1 / 9· / ,:1/ t-- r- r- hL /
-
oX:
~4,~ 280 ~ .095 "-
~ .j.~ 00' 70/ / ./ I"-.. "/ ~ /-::"i'-- / : ~- :
OJ
oX:
-
~ ~ .090
-V
<v~ 260 ~ 0 Jf-- ~ -/- Ii ~ / Vc;, ~ l!' 0
~v ~,;§
.. .085
/ h( / / V / >:::
- rr
/ ~ r-;:- ~
240 ~ <- ~, Sn .~
.~ 0'~ .080 '0
2.20
~~ f$'~
.....o /
"-.. "J'; ~ L
~:;/~ 7:
V
r---, ~ ~ . -
.-&:-
/
r-- : " -."X!
~ :--- 0
~
.075 'E
::J
..c:
..-. .070
2:1:
/ L 17.V: ~ t - ~: V 9. "";;
?-.' t-- r---;:.
r-- / :1'-... tp: t--
,065
Ql
'5
- -' - - Kr.:-
/~ co"? -r- r- k
/- :--,. : / -~~ t" "'- / ...... : (5
-
~
.060
--
/ ,:V
180 (/)
60/ /
i<-
/ :-" 2S:: -r-. ~ V ~ ?" .0
r- .055 «
"--
'/ 7 ~ "7
- --- -
160 rc- YI~ ~ /'~ I-:-'- ~ ~ ~ ~ .050
-
~
-
c.... t-- r-
./ ,10 p-c... ~ ~
-
,/ /"
/" / ' /' ./ -i- ~ V .040
V ~ ;'r-:--
L V '7
- :> .r- r--
c.:::::"L .'b:-.- / '
-- --
120 1-";'.' k
-
50 Y' r--,.
.035
--
100 ~ :L V V "/ ? "'(' k::"" 1>0 ;/ k:: V ""-. rS k::: -?--- io- .Q. '/ k , .030
~ r.:- : "- C:<r'"':
"
. / .-/
~ ~ "'" ::;J> l~;., t--
,/
/ 1><,"""" V ......- ,...-
-- --
.025
:-=
-- -
...::::::
80~ 2~ "'r::::::: - -: I--=,..
..?" ' -
""1-7" ' - ...:::::: ~v :-- ~ i-- ""-. ~
~ ~
~ .020
6o~-:;;::;e: -~ -::::-~
""-- >< I ~K ~;-.
-r-- r.:- !"--... : t-- : " , "M cl--
- --.
, ..
-
.015
i- -=- k::::- r- .....:::: ~ :-r-
-- -
:-
-
~ ........-p ' '-< --=k::::' - - - : I "
':b. Lbu : t-::.... '£~
- --
. ~,
--
.010
:;:-
- ---
:--
-
-r-.
r- : - I-- t.::.... 'tJ '
-
-;- r-
--
40 t--=::: _. "
j'-O> ~ t-- ~ .005
, -!- ~~ -+- I-- r- ~ r- -f--' ::::::... ~<:' I--r-, ~ ','V
., '"
" " .000
30 40 50 60 70 80 90 100 110 120
75
--
Ol
.0075 ~
.0070 ~
.0065 Z.
ii
.0060 'E
::J
.0055 I
(!)
.0050 ......
::J
'0
.0045 en
.c
.0040 «
.0035
.0030
.0025
.0020
.0015
o .0010
.0005
.0000
o 5 10 15 20 25 30 35 40 45 50
--
C>
. .080 ~
C>
~
-
.075
.070 >.
'5
.065 ·E
-
:::J
.060 .J::
.055 <l>
:::J
.050 (5
(J)
.0
.045 «
.040
.035
.030
.025
.020
.015
.010
40 .005
.000
30 40 50 60 70 80 90 100 110 120
WATER-AIR SYSTEM
4.00 atm pressure
. .0085
To obtain true enthalpy add enthalpy
deviation to enthalpy at saturation .0080
.0075
- .0070
.0065
.iii
'-
i::'
""C
.0060 C>
.It:.
......
.0055 C>
.It:.
.0050 Z!'
iJ
.0045 ·E
::J
.c
.0040 Q)
"S
"0
.0035 (J)
..c
«
.0030
.0025
.0020
.0015
.0010
.0005
.0000
o 5 10 15 20 25 30 35 40 45 50
WATER-AIR SYSTEM
120
4.00 atm pressure .100
.085
To obtain true enthalpy add enthalpy
deviation to enthalpy at saturation .080
.075
.070
...
'iii
.065
~
-C
.060 Cl
-.
~
.055 Cl
~
.050 ~
'6
.045 'E
::l
.L:
. .040 Ql
'5
. .035 '0
en
.0
.030
«
.025
.020
.015
.010
40 .005
.000
30 40 50 60 70 80 90 100 110 120
.0060
. .0055
-·co
.....
.0050 ~
""C
OJ
.0045 -...
~
OJ
~
.0040 ~
'5
·E
.0035 :::J
-
J::
Q)
.0030 :::J
"0
(J)
.0
.0025 «
.0020
o .0015
.0010
.0005
.0000
o 5 10 15 20 25 30 35 40 45 50
WATER-AIR SYSTEM
120
5.00 atm pressure .080
.060
.055
.....
'(is
.050 ~
"0
--
OJ
.:>t!
.045 OJ
.:>t!
.040
.035
-
>.
'5
'E
:::J
.c
Q)
.030 :;
"0
(/)
.0
- .025 <t:
- .020
.015
.010
40
.005
.000
30 40 50 60 70 80 90 100 110 120
WATER-AIR SYSTEM 50
4 45 50
6.00 atm pressure .0060
45 ) :\ I \./ \ I ." X '\ :\ .0058
Enthalpy datum: liquid water O.Ol°C, 0.00603 atm j '\ 17 1\.:[7 1\ 11\ l\.-j 1\ · V 1\
dry air O.OO°C, 1.00 atm Ji\ 7 :) \1(. \ y\ \ / \
.0056
\ .0054
40
/ \ V 1\/ 1\ 1'1 f\ :' 1\
.0052
To obtain true enthalpy add enthalpy / \ II 1\ V I ) .... \ / ,l\ 1 \ 11 \ . . \ I .0050
deviation to enthalpy at saturation 11\ /' X \1/ ,1\ If\ .: 1\ II / 1\ ~ .0048
X \;,. r\ I \ V .\ )(' \ . . \V \ .0046
V \ 1J< ."\ 1/ 1\ .'" r\.
f\ 1/ : rx' V
.0044
/ D, V V\ Iv IV 1/ .\ / :' \ :V\ .:\ .0042
/ 1\ l/' I\ / .·X \ .: K ~ V ....
.0040
/i\ 1)\ IV / '\ 1\1 1\ . V \ . . \1/ ,:\ \' \ 'ro
.0038
/ 1\ ); IV f'\ IV \ 1/ \ 1\ / V:
.0036
~
-0
20 / X IV ~ .... K 1\ V :
I / :1/\ ~ \ ' A\
,' \ I\
OJ
......
~
15 .0030 ~
.0028 '5
'E
.0026 ::J
.s::
10
.0024 Ql
"5
.0022 "0
en
5 .0020 .n
~
.0018
.0016
.0014
.0012
.0010
.0008
.0006
.0004
.0002
o 5 10 15 20 25 30 35 40 45
240
WATER-AIR SYSTEM
9 100 110 12 0
6.00 atm pressure 220
,060
Enthalpy datum: liquid water 0.01 ·C, 0 .00603 atm / r::.--.j :' 1/ 1/\ ;1'--- : Y ,' V\? I'--- ,058
,056
dry air O.OO·C, 1.00 atm
200
80/ 7 ,' ;1'--- / "1\ 1/ 7----.. / .054
.052
To obtain true enthalpy add enthalpy .050
deviation to enthalpy at saturation .048
.046
.044
.042
..-.
.040 .....
~
.038 ~
"0
.036
--
C>
-
~
.034 C>
~
.032
120 .030 ~
'5
.028 ·E
-
.026 :::J
.c
100 .024 Q)
:::J
.022 "0
(f)
.020 .0
80 «
.018
.016
.014
60
.012
.010
.008
.006
.004
.002
.000
30 40 50 60 70 80 90 100 110 120
WATER-AIR SYSTEM
8.00 atm pressure
.0048
Enthalpy datum: liquid water O.Ol°C, 0.00603 atm
.0046
dry air O.OO°C, 1.00 atm
.0044
.0026
:i!'
.0024 '5
.0022
'E
::::l
-
.c
.0020 <1l
::::l
.0018 (5
(J)
.0
.0016 «
.0014
.0012
. .0010
.0008
.0006
.0004
.0002
.0000
o 5 10 15 20 25 30 35 40 45 50
220
WATER-AIR SYSTEM
8.00 atm pressure
.048
Enthalpy datum: liquid water O.OI·C, 0.00603 atm
.046
dry air O.OO·C, 1.00 atm
.044
--
Cl
.lie:
.028 Cl
.lie:
.026
~
.024 '5
·E
.022 ::J
.s::
.020 <1>
.-
::J
.018 0
en
.0
.016 «
.014
.012
.010
.008
.006
.004
.002
.000
30 40 50 60 70 80 90 100 110 120
WATER-AIR SYSTEM
10.00 atm pressure
.0034
To obtain true enthalpy add enthalpy
deviation to enthalpy at saturation .0032
.0030
· .0028
....
.(ij
.0026
~
""C
.0024
--
Ol
~
.0022 Ol
~
.0020 .?;-
'6
.0018 ·E
::I
.s::::.
.0016 Q)
"5
. .0014 "0
C/)
.0
ex:
.0012
.0010
.0008
.0006
.0004
.0002
.0000
o 5 10 15 20 25 30 35 40 45 50
WATER-AIR SYSTEM
10.00 atm pressure
.034
To obtain true enthalpy add enthalpy
deviation to enthalpy at saturation .032
.030
.028
.026
-'m
.....
~
"0
.024
--
Ol
.:>t:.
.022 Ol
.:>t:.
.020 £"0
90
.018 'E
:J
.c.
.016 .....
Q)
:J
(5
.014 en
.0
.012
«
.010
.008
.006
.004
30
.002
.000
30 40 50 60 70 80 90 100 110 120
170
WATER-NITROGEN SYSTEM
160
50
0.80 atm pressure .048
.046
Enthalpy datum: liquid water O.O°C, 0.00603 atm
O.O°C, 1.00 atm .044
dry nitrogen
.042
130
To obtain true enthalpy add enthalpy .040
deviation to enthalpy at saturation
.038
.036
.034 c
-e
Q)
.032 Cl
.030 ·c
~
.028 "0
--
Cl
.026 ..l<:
Cl
-
..l<:
.024
>.
.022
15
.020 ·E
-
:::::J
..c
.018 Q)
:::::J
.016 "0
CIl
.0
.014 «
.012
.010
.008
.006
10
.004
.002
o
.000
o 10 20 30 40 50
1800
-
.300
.280 >.
2·bo 'C
r-- .260 ·E
.240 :::::J
--
..c
.220 Q)
: -:-- ~ "5
.. .200 "0
V. I I .... 1 I .180
(/)
.0
--~ r--: ~ «
.160
/ ' r--_ , ,
--
.. .140
, .120
V .•
.100
v ..
'n
-- .
1
200 .080
L
.060
.,, .040
.020
.000
30 40 50 60 70 80 90 100 110 120
WATER-NITROGEN SYSTEM
1.00 atm pressure
10
o
o 10 20 30
1200L
WATER-NITROGEN SYSTEM
~~l l~/~:~8~0~j~jI~1==17=:~9~~=:1/:::::1:::E1~~0~~~~~~~~~~
'z t
11n
1. 00 atm press ure 1100 : t---...
Enthalpy datum: liquid water
dry nitrogen
o.ooe, 0.00603 atm
o.ooe, 1.00 atm 1000 I
, f
f-....... /
1
I
f "N :
I
~b-., :
:
;
I .: 7'-r-..... ' : I: : I
I I': f. .......... / : :--..
To obtain true enthalpy add enthalpy '/ : ~
deviation to enthalpy at saturation
~, 900 : ! -.;..... /: : '. 1 "
~ / ~ / : / :'/ 0>
g
~ ZOO --: o~ - ~/. / : :; . -.. .........
T.R" ,260
0/
'c
.j-'li~o ~•()'
.j-'li " / 7":--
' ~ :' / I'i--.. : ,240 ~
W - ,if \... / / : /"-.!..!.L ¢. /: : / '0
C:) C:) ~0 0 ........ ./.. :
~ 600 ~v ~ / / j'
1
,220 ~
'<: / (I) :
1- I--.. "
C\~ ~'li
-S)'lf
", ......... -.. .So. '0
ft;-'< / .~ . ~0 /... / / : 7 r7 ,Il'i:
,200
~
~
<v~
~~ I
~ ,!liT"-.
J
010'
.'
r -...:. -..
500, / - JI / / .k57- ........ / / ,180 'C
~
L / ":'--.. ./ :
'E
L 6/0/ / / .'/ : / r-..... : 0,
.160 E
40
L / 'J'-.-.L
: / / : ......... , ': :
:
C> " 1
--., 'v 2::J
// --- --
/: I .140
L /I
z, ........
/ ~~ : /
/ E:
./ ........
(5
CIl
L
L
50./
/ / 1/
.7 --:.<l './
/' ./
./ u :
:r . ----- .100
L ./.// '.
--
-........ .080
200vL-
.£-
./ ./ ././
// ./
./ . ODic/,
--- --:-
L ---- .060
L
;L
L
-.. ---- -..
.,...... .040
100
,020
,000
30 40 50 60 70 80 90 100 110 120
WATER-NITROGEN SYSTEM
50
1.10 atm pressure .036
.026
c
Q)
.024 OJ
~c
.022
~
"0
.020 OJ
.:>t!
---
OJ
.:>t!
.018
50 .~
.016 "0
'E
:::J
.014 .c
Q)
:;
.012 (5
C/)
..c
.010 «
20
.008
.006
.004
.002
.000
o 10 20 30 40 50
7;
120~
WATER-NITROGEN SYSTEM
1.10 atm pressure 100 f-.. aP i' /~ , 90 ; I ;
110
r-...;
110 ., ., 120
0400
7
"
I TK :/ ,) !/
O.ODC, 0.00603 atm
"
Enthalpy datum: liquid water .380
I : .... 'J :/
dry nitrogen a.oDc, 1.00 atm 000 1. ........... 1-i .' / :r---. "
r :I ........ ' / : 1. ~n
.360
1 1 :' 1 .' /-.......... ; 1 ~
r.. .340
"ZOO
To obtain true enthalpy add enthalpy 7 l: I ;-.:;...... '.
'f-.... .' I / : I :
/I :; ::j /
deviation to enthalpy at saturation .320
10<::- I :/ . . . .:::: "
.300
o<A~7
~800 f 7 1/ ," / ;~ ':. . . . I
.280 c
~O:> / -, I?"-- (l)
~ / 'II--.. I I .'
. ~' :z
oo
OJ
.260 e
~o<:- 7 cT'::::::.. 1J / / " /
:r /
70 :!::
~o ~ / . j.' ,I.' C
;;.Z..
Ii ........ -- : /
L / / 'E
!.'?l / :
c; __ · $0
t -',
~/ :\37 /7 // / ,160 ~
40~ 60/
/ /
r-...,l. Y 01. : 7
/ --- : .140
(l)
'5
L /~
/ ~ / ,' :,;; ,
(5
CJ)
--
/'
L ,/ / / / .120 ..Q
300 "n"l: /' . : : : «
·Z ./ /./ /..' / ' . / ./ >Z -:-- ......... 1·'20
.100
L
20~ ,.L
L 50/1/
/ b·<:1 /"
/"
. / .../ .../ /
........ .
/-
,
1/ :
0/
7'?
./
/ 1
-- "
--.....
"""
,080
L. / /' / ./. ' ........ 0 '1!i ...... I I ::.-
.L ..-r- .060
-
......... ,/ ...............
E __ I I
""i __
100
1 ....... :.--. •
--
-- :IT ---
--- :
- 7 ''"' .040
.020
'. .000
30 40 50 60 70 80 90 100 110 120
WATER-NITROGEN SYSTEM
50
1.20 atm pressure .030
.02.2
c
-
Q)
.020 Cl
....
0
'c
.018 ~
'0
Cl
~
.016 .......
50 Cl
~
.014 £
'0
'E
.012 :::J
.s::;,
Q)
'S
.010 '0
en
..c
«
.008
.006
.004
.002
o
.000
o 10 20 30 40 50
7
WATER- NITROGEN SYSTEM 12~
110 120
1.20 atm pressure 100 / '0 ;q:} :' i,:::f,U II I I: 100 , .
:
.400
7
O.O· C, 0.00603 atm
I 7 : II I""--... :' I I : : : : I"--- " I': .380
Enthalpy datum: liquid water I I : : /..;....[1 II : : :....... -... ·f5:0
dry nitrogen O.O· C, 1.00 atm / 1 ; / ~ --i-...-........ : : I ~
:-\7
000 I :' ; .360
I I :'1 1 I : ii- I "
'. .340
To obtain true enthalpy add enthalpy r ~ : j I I / : / : r---... : : I
deviation to enthalpy at saturation 00 / ,"fr--... I / I;' : : --.... "
"
,r-...
I
.320
0<::' Ii :7 it" I f:1 I : I : ":
Z
1
.~oC$ / I : I f: --::-... / :' / : r.--1"0 .300
~~ 800 II :> 71 I / N-. I
L
" C>
.220
~ 600 ~u ~ ;j/ /: :7 I ? -r-.' "
~
0,
ii;-~~ ,~~~~~ h;T 1 7 17 / ~:I C! : / _ " "
s=
/ : ~
.200
~ ~ Ii 1/ , : ·-e :1 I 0 ' I,",: --.... "
--
,1 80 '0
L
/ /I -~ I ;' 0:' /1 : 1
J -'
'E
L
"
/ :' 7 7 7
1
-...
E
0,
: )<.. :
.1 60
/ V / /:::-...J/
400L L 7 / 1 :'Y 7 I,
.140
2:::J
/ 60/ /......, _ 1/ /; 0 :.,---;.« (5
L / -,,7 7' 7 ,2 (J)
-
.100
L /' /" /" /' ./ .: ~ -- I i?;-: '4 I-=::::::::
L ~ /' / '/ 1 . 7" / : I ;!C I" .080
200 L /~ v , /. / ___ I ~
Y- ./' ././' /,. ", I
bU / /' /' ,
<.. :::t:i-
',..
I 7' ....... 1 I
!.--':' I ,060
I -......:[
-
LL I
,
In /'" /'....... ....... - ' --
;c.. ....... I I
1 ....... __ I ....... • ,n~ I I I -.:.... .040
100 -+- I
1· .
,020
I
.020
c
-e
Q)
Cl
.018
'c
~
,016 "0
Cl
..:.:
......
C>
..:.:
.014
~
'6
.012 'E
::J
.c
Q)
.010 '5
(5
C/)
.0
20 .008 «
.006
10
.004
.002
o
.000
o 10 20 30 40 50
-0<-7 --0<-
't-;) J I-,C :
,180
/ $ :' 7 7 I i' r---.... ; : ~
.......:..
:
'c
Z -
~ ~
70/.. "
Ir '"
~ ~ ,160
'- 7' /
c,,'l:f c,,1i 0
~ ,(, -S - I~ ~ / e>;l'," I :1 / : ,,~ 0>
~
\\ ~ 0/ / / I . I
,';;:::
I
c '
&,: / "'- ---0>
~~~ &r§> ~l- " 7 ", ;
'" "'- r-......
~
4. L : - 7 0)' I /
0 ,I .:: : . ,140
- - ,L
~ ,0~
-
<V<::'- -.......; / ,
'f: .' .....
>.
/i 7'
' cD7 1
/ ' / 'R . /. '" ':-...
,100 "5
-Z L '" ./' (3
,
/ ,'
/ I
(/)
250 ./' 1/
'"
'>< "
/ ~ / / , // ,: 1/ ~ .'
:
.080
.0
«
s: "><k
'
I
/ / / ~ ./' ........ -.........: !:IS
200~ ./' ./ "
./ / / 0/_/ ........ , r. I
50./ ./ ,/ ./ /" ~ ......
L ./ ,060
/-' ./ ...... ~
<
./ ./
/ " / 1/
150~ / 1
I ./ ,./
./
:L
./ / 1/ 1 I :./ "'- , "'.....-b.
--- --~
,./ , .~
, / 1/ I ' '. / ">< I ,
: ':---..
.040
X-
""
I
100 Z-
,./
--- :----':;1
,./
><... .....;. o/1J "0"
'"
I
--
Q
;C- ,
I
-'"'" I
'<
0
' . '" vI
71/'k '.
,020
l-
I
........ '. "1,1&
50 - , , i'/;'
, ., ,..
, , .!:!. ........ ,000
. " ,
"
30 40 50 60 70 80 90 100 110 120
WATER-NITROGEN SYSTEM
2.00 atm pressure
.017
To obtain true enthalpy add enthalpy
deviation to enthalpy at saturation .016
.015
.014 c
-
Q)
Cl
.013 ....
0
·c
.012 ~
-0
C>
.011 .:>t!
......
Cl
.:>t!
.010
~
.009 :0
·E
.008 :::J
.c
Q)
.007 "S
(5
!J)
.006 .0
«
.005
.004
.003
.002
.001
.000
o 10 20 30 40 50
650
WATER- NITROGEN SYSTEM
600 90 100 110 12 0
2.00 atm pressure
/: .200
.170
To obtain true enthalpy add enthalpy
deviation to enthalpy at saturation .1 60
.150
.140 c:::
<l>
C>
.130 g
'c
.120 ~
'0
C>
.110 .....OJ
~
~
.100
~
.090 'C
'E
.080 :::J
..c:::
.070
.....
<l>
:::J
'0
(/)
.060 .0
<:
.050
.040
.030
1--- -' -- . .
-
::::- =-- ::--;
-
..r
-
I I I
50
I
_ 0. 10
t==-
. , ., I
r--
......... u: ':.,
'. - .000
30 40 50 60 70 80 90 100 110 120
WATER-NITROGEN SYSTEM
50
3.00 atm pressure ,013
,01 1
To obtain true enthalpy add enthalpy
deviation to enthalpy at saturation
,010
,009 c
-
OJ
e
Ol
,008 'c
~
"0
Ol
.007 --.
~
Ol
.:.::
20
.006
->.
'0
'E
~
,005 .c
OJ
"5
0
,004 en
.0
~
,003
.002
,001
,000
o 10 20 30 40 50
WATER-NITROGEN SYSTEM
120
3.00 atm pressure .120
.090
c
<1l
.080 OJ
~c
~
.070 "0
OJ
-...
~
OJ
~
.060
~
:0
.050 'E
::I
..c
<1l
......
::I
.040 (5
C/)
.0
<{
.030
.020
.010
40
.000
30 40 50 60 70 80 90 100 110 120
WATER-NITROGEN SYSTEM
4.00 atm pressure
.0070 c
<ll
Cl
.~c
.0060 ~
"0
Cl
.....
~
Ol
~
.0050
~
'6
'E
.0040 :::J
J::
<ll
:5
(5
(/)
.0030 .0
«
.0020
o 10 20 30 40
340
WATER- NITROGEN SYSTEM
120
4.00 atm pressure .090
c:
<1l
.060 OJ
g
·c
~
"0
.050 OJ
.:..:
--.
OJ
.:..:
>-
..-
.040 15
·e
::I
..c:
<1l
"5
.030 "0
(/)
.0
~
.020
40
30 40 50 60 70 80 90 100 110
WATER-NITROGEN SYSTEM
5.00 atm pressure
.0060
. .0055 c::
Q)
C>
0
!:;
.0050 ·c
~
"0
.0045
--
OJ
-
.::.!
OJ
.::.!
.0040
~
.0035 "0
·E
-
::J
..c::.
.0030 Q)
::J
(5
.0025 (/)
.0
<C
.0020
.0015
.0010
.0005
.0000
o 10 20 30 40 50
WATER-NITROGEN SYSTEM
120
•...
5.00 atm pressure .080
.060
.055
c
Q)
OJ
e
.-t::
.050 c
~
-0
.045
~
---
OJ
..liI::
.040
~
.035 '5
'E
::J
.!:
.030 Q)
:l
"0
.025 en
«
.0
.020
.015
.010
40 .005
.000
30 40 50 60 70 80 90 100 110 120
.0036
cQ)
.0032 OJ
g
'c
~
.0028 '0
OJ
~
"'-
OJ
~
-
.0024
>.
'C
.0020 'E
:J
..c
Q)
'5
.0016 '0
(/)
..a
~
.0012
.0008
.0004
.0000
o 10 20 30 40 50
WATER-NITROGEN SYSTEM
120
8.00 atm pressure .050
.048
Enthalpy datum: liquid water O.O°C, 0.00603 atm
.046
dry nitrogen O.O°C, 1.00 atm
.044
WATER-NITROGEN SYSTEM
10.00 atm pressure
,0034
To obtain true enthalpy add enthalpy
deviation to enthalpy at saturation .0032
.0030
.0028 c:
Q)
OJ
.0026 g
'c
.0024 ~
"0
OJ
.0022 .:::s:
......
OJ
.:::s:
.0020
Z'
.0018 '6
'E
.0016 :::I
£.
Q)
......
.0014 :::I
(5
If)
.0012 .0
<{
.0010
.0008
.0006
.0004
,0002
,0000
o 10 20 30 40 50
200
WATER- NITROGEN SYSTEM
120
10.00 atm pressure .040
.034
To obtain true enthalpy add enthalpy
deviation to enthalpy at saturation .032
.030
.028 c
Q.l
0>
.026 ~
·c
~+r~~~~--~~~H+.~~~+-~~~~~~4--P~~-,~+-4 .024 ~
""C
--
0>
~
01
~
~
~~~~~~&7~~~~~~~-r~~~r-+-~-r~--~~4-~-+~~H-+ .018 ~
·E
rr~~~~~~++~-7r-~~~~~k-~~-r~~--~~~-+~~~+-~~-+ .016 E
Q.l
.014 "5
"0
rf)
/Y~r-~~~~~~~~~~~~~~~~~~~~~-r~~~+-~~-+~L-~~H--+ .012 ~
60
.010
.008
40 .006
.004
30 .002
.000
30 40 50 60 70 80 90 100 110 120
WATER-METHANE
0.80 atm pressure
.065
Q)
c
ell
.060 .c.
Q)
.055 E
~
"0
.050
--
01
~
01
~
.045
~
.040 'C
'E
:::J
.035 .c.
Q)
:5
.030 (5
I/)
.0
<{
.025
.020
.015
20 .010
.005
.000
o 10 20 30 40 50
WATER-METHANE
0.80 atm pressure
Enthalpy datum: liquid water O.O°C, 0.00603 atm
dry methane O.O°C, 1.00 atm
.500
I
I---
'. '. --..::
~ pu- .
, I' I .450
/1 I '. I
.400
/ : I. . " .350
.200
.150
200
"7
----- .100
.050
~,~ .000
30 40 50 60 70 80 90 100 110 120
WATER-METHANE
1.00 atm pressure
Enthalpy datum: liquid water O.O°C, 0.00603 atm
.065
dry methane O.O°C, 1.00 atm
.060
To obtain true enthalpy add enthalpy
deviation to enthalpy at saturation
.055
.050 Q)
c
ctI
..c
.045 CD
E
~
.040 "0
Cl
..:.::
......
Cl
.035 ..:.::
~
:.c
.030 ·E
::J
..c
Q)
.025
:5
(5
(J)
..c
.020 «
40
.015
.010
.005
o
.000
o 10 20 30 40 50
21
rjO:Ot·'~
t:8rO:.t:"[-~-J-:-l-t-:9ro;i~lrJ::t:"t~'l:r~Jot:1rOl=iS~~120
WATER- METHANE
1.00 atm pressure 2000I- / ,' "/ I :' / ~ I:' : : .3. '
700
.680
Enthalpy datum : liquid water O.O·C, 0.00603 atm
1900 I / ,' i/ if ~t--.. : .......... .
.660
1800 1 If if f:--- . . . . . : .640
dry methane O.O·C, 1.00 atm : / :--- .........
1700 I ,-- ::::-. ---... . . .620
.600
/ / ! /:1"--- / '7-r--... '. .,
0'
To obtain true enthalpy add enthalpy ~,
.580
deviation to enthalpy at saturation 1600 I r-. .. .L II: I-, i J::'I"---r-- :' / ,....;. -"",:,,:,,':'0 ... .
.560
't:::-~<\' ~'. L ~ / .:
r . . . ,:
rP ;' "..; 7"--- <)i : ti:
/: /
1m '
, '. .540
~w 1500 / 1=&: ' : r--.. .520
O(;\ L
400 ' 70 / :!1. . . . . I fI... ,'
/ E:' /. .500
~~ / J II 16: V : ..........
.480
III
c
')\' ! j I I : I ' /l---5~ I co
~)i:
- 1300 - .$.,/ I I II II ," 1 I 'i-. ~ .460 J::
Q)
~O~1200 f ~~~~ If II .V '-i! ;
.440
.420
E
~,§ - ~ '- / I -;r-- / .-"1/ II c:j ~
~c:>t'f'f1100 / .400 "C
.vc:>t'f'f,§0 I nl . J ...... r-:, " :S / :r--- 0')
-
700L /
L / / /Y A 0l? --v,; /'
.240
"6
60
L
L ~-..L .' I
/' / ./
J
V .
t.:%'
/
/ / ,'
/ .......... b-
""
"
.220
.200 «
(f)
..c
500
L 50/ / " . / /' ./
V
p-<....-:· f~ I ;.-- v .180
.160
400 L / /' /" ./ r--- ~ .:..--r .140
L ./ V / , / --:'" ./ i-';' Q / 1: ,.<.?1f
-.. .120
r
- --
300 L .,/ 1/ i><- .,/....- ... . , / / .......- --- : 1
.v / 1/ 'V ......- .100
,L .- .080
200 / - '
. ..- . ihl
100
o
---- .060
.040
.020
·V
.000
30 40 50 60 70 80 90 100 11 0 120
WATER- METHANE
1.20 atm pressure
.054
Enthalpy datum: liquid water O.O°C, 0.00603 atm
.052
dry methane O.O°C, 1.00 atm .050
.048
To obtain true enthalpy add enthalpy
.046
deviation to enthalpy at saturation
.044
.042
.040
Q)
.038 c
a:l
..c
.036 CD
.034
E
~
.032 "0
Cl
.030 ~
"""-
Cl
~
.028
.026 >.
."!::
"0
.024 ·E
-
::l
.022 ..c
Q)
.020
: :l
.018 0(f)
.0
.016 «
.014
.012
.010
.OOB
10 .006
.004
o .002
.000
o 10 20 30 40 50
1900
WATER-METHANE 1800
80 90 ~ 110 120
1.20 atm pressure .600
.580
Enthalpy datum: liquid water O.O°C, 0.00603 atm 1600 .560
dry methane O.O°C, 1.00 atm .540
.520
To obtain true enthalpy add enthalpy .500
deviation to enthalpy at saturation .480
.460
.440
.420 Q)
c::
.400 C\l
£
Q)
.380
E
.360 ~
1j
.340 OJ
~
.320 ........
OJ
~
.300
.280 ~
.260 '5
~
'E
-
.240
..
:J
r--. ~;.: ~b!. .c:
/ : -- ......... .220 Q)
:J
v .200 aUl
.180 .c
.160
«
I
.140
--- I
I
.120
........ . .100
-- .080
.060
.040
100 .020
.000
30 40 50 60 70 80 90 100 110 120
WATER-METHANE
1.50 atm pressure
.040
To obtain true enthalpy add enthalpy .038
deviation to enthalpy at saturation
.036
.034
Q)
.032
-
c
ctS
.I:;
.030
Q)
.028
E
~
"0
.026
~
......
.024 Ol
.::.!
.022
~
.020 '5
·E
:::l
.018 .I:;
Q)
.016 "5
"0
(/)
.014 .c
<C
.012
.010
.008
10 .006
.004
.002
.000
o 10 20 30 40 50
1400
WATER-METHANE
80 ~ 100 110 120
1.50 atm pressure .440
1300 / / :'11
Enthalpy datum: liquid water O.O·C, 0.00603 atm .420
1200
dry methane O.O·C, 1.00 atm .400
.380
To obtain true enthalpy add enthalpy
deviation to enthalpy at saturation - .360
.340
.320
<1l
-
.300 c
ctl
.c
.280 <1l
E
.260 ~
-0
--
Ol
.240 .!o::
Ol
.!o::
.220
.200 ~
'C
.180 'E
:::::l
.c
.160 <1l
:5
.140 0tJ)
.0
.120 <t:
.100
.080
.060
.040
.020
30 40 50 60 70 80 90 100 110
w ATER-METHANE 170
2.0oatm pressure
160 , 4.0 , . .. 50
.034
I I ~ Y .: ./ \ /'
Enthalpy datum: liquid water O,O' C, 0,00603 atm
150
I I N \: / IA \ .032
O,OT, 1.00 atm 140 / / V/<-\ I / i'-.. X :"
dry methane
/ ""'I / ~ I :' N ,
130 / 0 L :' I \ "'1/ ,'. I ;""- .030
To obtain true enthalpy add enthalpy ?J.<:'
e' / \ I A :/ \ ~ / "'x : .028
dey iation to enthalpy at saturation e\S' 120 1"'-.. \i : b( V V \/
o~~ / A / // /\ " J\
':>~~ 110 0/ / \1'>( :I "'"
Ii'-.. \ .; /
"'" K / \n
.026
,,/
~o~ 100 · o~ L A / \ /- V :V
-
:/ ~ c
~\)"f(): ~ y ' ""'\
c:"f(): 90 ~..;§
c:"f(): (0' / / X )< ,/ 1\ "'" 'X.,: / ""\
l\:l
..c
.022 0>
~ ~v \),,0 / / "x, :.\ / ~ V \ E
~«'\ /\ ~ / \ / ;' "'-.. /: .020 ~
~ ~
/ .~ / :"
/"'"
~~\S'f(): 80 .~ e"f():
,X I ,'.
"'" '"
~~ ~~ / :' A- /\ / ;
"'"
'0
\.13
70 / X / /' c/': \ V / \ :' / .018
OJ
-. ~
60 / Y / \X ./
,,/\ ~ ,:' 'X .IX :
\ .016 ~
/\ V
'" ""-
/ ~ ~-, '/ "?/
50 o~ ~;J<:' 7 X \/ .... / '" ~' ~/ : \
: '0
.014 'E
/~ X 010/ "- / '
.............. A A
/ \ : /' ~
":tV '"
L
. ~ "'" /' ~ \
"'- """ c}/0 . / ' ..c
~
"'"
~ V [1,: \ \ (J) /.
"'"
~
/'"
40 .............. ,: 0>
.............. ~ 7 ,~ / ' <-. /\ /' ~ :' ~ ~
.012 '5
""',
'0
30 /("" /'" >< ./' ~ ~ 7' X :' X
""" ' ,k" \ // ~
.010 .0
(J)
"'" "'"
:~ !
\'8 '"
..---
.008
"'"
~ ...........
~ ><----V> . . . . . . 1 X
---"""
--
~ -------- ;> ~
-
10
\ \ ~
'" ~ ~ "'-..
"'"
:\fa.--
--""
....--~ v.....-- ~ ~
"'-.. -- ~ .n 0/0\ ---><
.006
"K .\- \ "'-..
"'"
~
"'"
~ ,"
~ ~ ~
---:j~ ~ ~ ~ X ""'1 --/.--: ~ ------- \~
o ~
---"'"-"" ~
"'" -----
"'-.. \ "'-..
-
,
.004
~ ~ ~ <:( zo ~ ~ "'- "\
"""':
"'"
~ ~~ ~ ~ ~
o
~~ ~,--~ \"-... k - ~ '- - ~ a .n ~~ humid t~ K .: :"'" " \1; "'"
\ilI "- .002
I - \e" "- "- \~ ->00;:: "-.", ""-\0
~ "'". . ,
", : \~ ~
.""- \0. " \9"-
\cp
"-
"" :
o
\0
'- ~ ~
"- I, "-
'"
"'" "'" "'"
"'-l\~
"'" "'"
"- '-I'
"""
.000
o 10 20 30 40 50
WATER-METHANE
110 120
2.00 atm pressure .400
.340
To obtain true enthalpy add enthalpy
deviation to enthalpy at saturation .320
.300
.2BO (])
-
c
<13
.c
.260 ( ])
E
.240 ~
"0
--
.220 Ol
.!i<::
Ol
.!i<::
.200
i!!'
.1BO :a
q: 'E
.160 :J
"';" . .c
(])
.140 ..-
:J
(5
en
.120 .c
«
.100
.OBO
200 .060
.040
.020
100 _ _ _ _ __
.000
30 40 50 60 70 BO 90 100 110 120
WATER-METHANE
3.00 atm pressure
.021
To obtain true enthalpy add enthalpy .020
deviation to enthalpy at saturation
.019
.018
.017 Q)
-
c
.016 til
..r:::.
Q)
.015 E
.014 ~
'0
--
01
.013 .:.::
01
.:.::
.012
.011 .~
'0
.010 'E
-
::::I
..r:::.
.009 Q)
::::I
.008 '0
(/)
.0
.007 ~
.006
.005
.004
.003
.002
.001
.000
o 10 20 30 40 50
WATER-METHANE
3.00 atm pressure
.170
To obtain true enthalpy add enthalpy
deviation to enthalpy at saturation .160
.150
.140 (l)
c:
(Ij
.J::.
.130 (j)
E
.120 ~
"0
.110 Cl
~
""-
Cl
~
-
.100
>-
.090 ' 5
·E
.080 :::I
-
.J::.
(l)
.070 :::I
(5
(J)
.060 .0
«
.050
.040
.030
100 .020
.010
.000
30 40 50 60 70 80 90 100 110 120
130
WATER-METHANE
120
40 50
4.00 atm pressure
y'
.017
'7 'xl' / VI Y\ /
Enthalpy datum: liquid water O.O·C, 0.00603 atm 110 / / / ./\ II I\:'
.016
O.O·C, 1.00 atm
I V / 1\ 1 I 'V
dry methane 100 / \ / Y\ Y I ,'. /\ .015
I A / \ V : II \ \:' \
To obtain true enthalpy add enthalpy ~ V \1 \ / '\ 1 ;1' \ / .014
deviation to enthalpy at saturation 11\ / 1 1\ V :, 1\ / Y )(,:
/ X 1 \/ 1;\ .: \ \ V :\
o V \VL\ . / \ / ,' ~ /
.013
/ ~
/ X / \ / \r ~, y
y \ /' V
\X 0 : 1\
~
/' 1\ '\ ,008 >.
.003
.002
~r\l---'\:"\. ~ -- ~ \ --\--- ~ 2.~f..-- \ \ -\-~"\ I ~r-- \ . \
~ ~~ \ I\I--~ \ _I---- '\ Ino/\I~p.\ativ ~midtv ~ f - - "'\ \ :' \ \~ Y 1\ :' \ .001
,,;.., \ w- \ \\0_ \ r-- .~\ \ \? :1
\ \ \ != :' \ \ : \0
\:on ~ \ \ <><., \ \ ~ \ " Oi \ \ '\ U) \ \ I c~ :' \ \ : t~
.000
o 10 20 30 40 50
wATER-METHANE 550
4.0o atm pressure
80 9~ 100 110 12 0
v----- J:
"
.140
'f /\ r7 I .... ;' j \ ........... 0-- r-.- I 1
,\
Enthalpy datum : liquid water o.oce, 0.00603 atm 500 / 'Y. /
'! r--...... :'/ 1\ I ;'
b( :1\ /
...........
r-----. r--...... .130
dry methane o.oce, 1.00 atm '-......... II IV ; / .I' ........... j' ~I
' :-....
V j.
......
0~ ,,?-?S ,0~q j'-......., ~ I 0\9" '7' -.....;. f,(\ ........... N /;,"'~ V- ..........: ........ \ : ........... ........ :
-
Cl
,s : .070 .:.:
t... / /~ ~ / V; r-.- \ V r--..... ~ <lJ : '\ ~ V r----..,
~
~
250 60/ / "/ ...........V\ . 0'0- r ........... k( .... ~ ts:-..... ;' / ~ ........... 1\ V
..........
r----.., ~: '\ ........... .........
~
ii
/ 7 ')< / /~ ~ '- /......... :1'-- K \ / r----. t--..... ~: . . . K ti-. .~ : ' ...........
........ '<1" ; ~
'
/' I~ :
.060 'E:::J
/- /' / -;,. K >( ~ V
~~ J:"':-- '>< / \ I'-- t---.. :
~ .c
'> ~
r--...... <- :'
~ O'a Q)
200 .050 :;
/ "/ ~ / ........... ,/ <......
'.:~ ~ ~v
f\- ~ '/ N r-.- I\ ...........
....... kt
.'
~ "6
/ /' I/< V K I":"'" ........./ :::-ore
,//" v--. , / :\ r>: ........... V : ..........
r-..... k( ...........
r-.- .........
~ ~ . / I':-- ........... '\ CJl
..c
/'
«
:><:: f-x' ~ ;:.::.... / ...... r->
50 y .040
r--... /" : ...........
k ...... -;:..... r----... V ~ ['-...... --:-....
r-..... /k:- t--- ........ -......;.. .'
150
r-.- olj> <. ...... "
t',. .
I
V ::><-
./ ><1../ I> ~ ::><- p< r-........ ~
V .........
~P: \ ......r--..... .: .,.- V r----.., ........
:-- ........... 0
.030
/'~ >1--\V
><....
<1/ ~ vr........ ,/'...... ~ 1"--.....1...-/ r--...... ~
~ :--,: V- I'--
r-..... s ~ . [--...
'-.V ~ I'--
"' "
~ .' ~ '+
10 0
40&< ;;;
,.......",. , ~ K ~ "> < >< ;-..... ~
.......
~ ~ .......... K r-.... \-....: I'--
...........
tff! t> < .......I\. 1'--..... .......... : ................ .........'\ rt ......... ~:
/'
...........
-
p< ~
I'-- ~ k- ~ r-.... 'IN N. ~ ~ ~ ::",
~ r><><~ r\.., > k ;,---
Kr----... r-..... P>< ~ "'-..... ~ '<
aT
r.... ><: ~ ~
p. ~ ~
WATER-METHANE
50
5.00 atm pressure .014
.010 Q)
c
<tI
..c
.009 Q)
E
~
.008 ""0
01
..:.::
.......
01
.007 ..:.::
~
'5
.006 ·E
::J
..c
Q)
.005
'S
"0
(J)
..c
.004 «
.003
.002
.001
.000
o 10 20 30 40 50
WATER-METHANE
110
5.00 atm pressure
Enthalpy datum: liquid water O.O°C, 0.00603 atm
dry methane O.O°C, 1.00 atm .100
.080
Q)
c:
-
ell
.c
.070 Q)
E
~
"0
--
0>
.060 ~
0>
~
.050 ~
'5
'E
::J
-
.c
.040 Q)
::J
(5
C/)
.0
~
.030
.020
.010
.000
30 40 50 60 70 80 90 100 110 120
WATER-METHANE 90
40 5o
10.00 atm pressure .0070
80
/ j IX 71 I 1\ ,; \ I \
.0068
Enthalpy datum: liquid water o.o·e, 0.00603 atm \ / \ / \ j \ I \ .0066
o.o·e, 1.00 atm
j / \/ / V' I \
dry methane 70 / \/ ;; 7 IX ~ \ .'
.0064
,0062
~0' / /\ I \ 7 \ :' \ / \ ,\ .0060
To obtain true enthalpy add enthalpy ~f(} / / \ I \7 \ / :' \ I \ / .0058
deviation to enthalpy at saturation
~0
60 / 1\ I Y J )\ : V \ /.: .0056
o.~
~~f0
3 1/ IX 1\ I \ ;' I \ .0054
\.'+' J / \ / \I \7 1\ X : I .0052
, 0<:"- 50 " 0<:"- / r\ 1 V X X \ 1/ \ :'
:
.0050 -Q)
~~~
~ ~ ,/ V\ 1/\ / / \ :/ \ / \:' @
r::,?f. r::,~~~ (0' / / \ / \ V 1\ / \ 1/ X
.0048
~ .0046 .;:;
~~~ 40 ~c. ~..s0 L LV" X A V\ \/' \ : 1\ /
/ '\
Q)
.0044 E
~~~ &-t§> ~i"~ V \ / / \ /V \/ \ V .0042 ~
~ ,0~ /V \/
/ \/ \ /\ V\ \ :'/ \ .0040 -c
30 / IX V\ / \ / 1\ X : / \ \/ \ .0038 ~
Cl
/ / \ / \/ \/ \ \ V \ / : \ .0036 ~
/ lY V\ /\ / Y ~ ;' / 1\ \ / IV \ .0034 .......
20 / 0\0/ \ / \/ \ V 1\ / \ s'\v \ X '\ \ .0032 ~
211/ , tV V\ /\ ~ Y \ ~: \ V\ ", : \ \ -c
/ / ·\oV \/ \ V / \ Y ~; X ... . \ / ,0030 'E
.0028 ~
10 , / ft 1\ V\ / \ fr \ V\ ~: 1\ /' \ Y (n
,0026
/ IV Y X \ l -g 1\ :' V \
Q)
~ / \ A ~ :' K .0024 ~
/ ' ./' '\ / \/ ' CI~ V\ / 1\ V \ o~, V \ \ ~ W \ g
../ r\ v l-1 / V\~ n
.0022
\/ \ \ A : 1\ \ \~ ,:\ \
'\ /1 -d'.<n"...' . \
/ .0
,0018
11/ V W-- I---Y X 1-- . / rt \ A' \ ~ \ (11
~: , 1\ ~
,0016
~V ~ W ~ l...- V\ o"l/- V \ l..---Y' \ j~: ...... ~ \ I \:!."' :' \ \---
--
.0014
V\ \ A- l'e ,:
~V
1\ ______ f\ ___ K l..--\-" ~ v-1 ---' Q~ 1\
~..- W ~ J...- 1
\ H'
-- \ ft \ U---- \
---
.0012
..... ~----
11--- \ J.. ~ i§;' \ \ ~ I--
\
-
t::-'1--]\ ~ \ ).- H L-\- I- \ j.----- ,,/. \ \ 1\ :' \ -'I f-r" \ :' ,0010
---- ~ ,~
/ l.- '\ pc 'I
.0008
I.\- t\
I-- .l-- W ~ ~ --\- 1--\ 1\ __ ~j.:.=- \ \:- ~ \ .~
1\ V
f\_ H- f\ ~
\ J=: j-----\--" \ ~ I--- 1\
~
IOP/o j\ela\iVE humIC IW /\ -'I \ ,: cD,\ \ :'\
.0006
\ .0004
~
\ \ '\ \ f-l: \ 1\ 9 \ \ 1\ \
'
1\ \ 9\ \ :' \
.0002
\ \ 1\ \. \, , "
~Cn \ \ \ \ \ \:'1 10) ,
\ ' " ' .0000
o 10 20 30 40 50
360
340
WATER-METHANE
320 0 90 100 11 0 12 0
10.00 atm pressure
r .~ '" /
.060
/ '" II \1 / '~-J / : '" t '\ I I .058
Enthalpy datum: liquid water O.O·C, 0.00603 atm 300 / /" , 1/ :' ~ : )(1 1\ / "\ .: "" .056
dry methane O.O·C, 1.00 atm I
/1\:' I 'f :' V '\, IA .: "" / "' : I .054
/ '\ II .\ ~ II: ~ / 'Xl \ .: I~ i ,:", .052
To obtain true enthalpy add enthalpy / / '\ k / N' : V"l : / "' : / I~ '" .050
deviation to enthalpy at saturation I "'\ I )\V 1\ j K I I I": I I .~ j ""
.048
/ I ') ./" Xi ~ I .: /~ . . \ l!\ I~ / .046
/ 'y,' II ,\V "\:' / '" J ~ "" )l '\ .: 1')( .044
/ I y, j ",I / ,~ I A\. :"- 1\ '" Ii V I~ .042 OJ
/ '} / ,),: / '" lX " V.: "" / "{ \.: ""1/
-
c
,040 ro
.J::
.038 OJ
E
.036 ~
'0
.034
--
Cl
~
.032
Cl
~
.030
160
.028 i!'
.026 'C
140 'E
a-
.024 ::J
.J::
.022 OJ
120 ::J
.020
Ul
.018 .c
100 <C
.016
.014
80 .012
.010
.008
.006
30 40 50 60 70 80 90 100 110
950
WATER-HELIUM SYSTEM
50
1.00 atm pressure .280
.270
Enthalpy datum: liquid water O.O·C, 0.00603 atm
.260
dry helium O.O·C, 1.00 atm
.250
.240
To obtain true enthalpy addenthalpy
.230
deviation to enthalpy at saturation
.2.20
.210
.200
.190 E
:::J
.1 80 Q)
..c:::
.170 ~
"0
.160
.150
~ OJ
..:>t!.
.140
£'
.130 :g
.120 E
:::J
.11 0 ..c:::
(l)
.100 :;
<5
.090 ..0(/)
<{
.080
.070
.060
.050
.040
.030
50
.020
.010
o .000
o 10 30 40 50
.:Y.
WATER-HELIUM SYSTEM 8000
90 100 110 .. 120
07
' ., , .
1.00 atm pressure ..... 2.800
7500 I I i SO : I II r------I: :
:
:
:
Enthalpy datum: liquid water O.O'C, 0.00603 atm I I , / .' / / I; / : ...........
N :S',., )..
2.600
) 1 :........... Wci
dry helium O.O'C, 1.00 atm .' I,
/ :
..... : Olu , :: I'"
6500 tJ-I : 'II J .' / i / II :
I :
-.......:. 'If:') ri~
" ..
Too btain true enthalpy add enthalpy / / . . /r---...!;[ !/ : / ;: " ~ :-.: ilfI7' 1
"
2.400
~7
:j
devi ation to enthalpy at saturation I : / / "
: ~~
2.200
~.;:)
~
/ / : /
I ! r-....,
r------ : " "
"
'.
;;
I
/ / 1/ I! :1 ........... r:-....
b~""0,7
701
....
2.000
L ./ / .' I
.' I : -> --. '.
E
~:;
I: II
/ ,?'M . . . ....... / I: "
:--r-- 1,800 Q)
~
~ ~ / ! / I
.... -----.'. 77. On .s:::
/ :g, -;
~Q ~Q
---
4500 '. ~
~rtf .0' / ,I / / I
---§: "-- /:
-
,:§rtf '0
1.600
t]f I~ iY.;:)~0\.. J
o 'I
~ II:
,
"'-0 : / ~
Cl
L "
~CO 4000 CO Cl
~Q.~
rtf ~~
::.ortf fb~
/ / j: !/ :/ / ¥ ~: ~ 1\ .::.!
---
"
1.400
~
rI:i
3500
.rI:i
~ ~ J N ....... f : oVj I /
A; ,
":/ t?' ~ '.
'.
>-
;t::
<vI:::' / ~ ,(Q f / ,'-...:..\
<....... 7 ~ ,
:::g : '0
/ : / /~ -cs I:-.
-- 'E
t', "
---
1,200
60/ / / / o\cv
V:' -/.-. ....... / ~:
/ : '. :<5;., I--- ~ 00 ~
..c
30/,
.
,
: -:r-..
/ / / i/ C\j '
1.000
.Sl
25~
~
.2- T-- --.
-----
/ / /:
/ / ;/ 0
// (5
II)
.c
·s
/
/ I
~'j7
/- ~ / ,/
.'
Q) ,/ .800 <C
200~ / /
--- --- ".
./
./ / / -..,..( o I ~ /" I
-
./
50/1/ /' ... / / -;:.,;:; 2 :/ I
---
'7 '7 'v .600
1500L...i ./ ;/ /' /-
:;:r
/ 1/ /' 0/0/
L
-- '. ...l
./" / ;/
L 1 ./ . /, ' <......
', I
--
./ I
.400
----
n
< I
.200
500 -'!
' "
.. '.
' .. ..
"' "'"
.. " "'" .000
30 40 50 60 70 80 90 100 110 120
600
WATER-HELIUM SYSTEM
2.00 atm pressure
.100
E
.:!
.090 Ui
..c
~
"C
.080 Cl
.::.!.
......
Cl
.::.!.
.070
.~
"C
.060 'E
::J
..c
.050
.....::J
\l)
150 (5
en
.c
.040 <C
.030
.020
.010
.000
o 10 20 30 40 50
/t - J.... :
3500
/ 'f....... / " "f ) : "~
1.200
Too btain true enthalpy add enthalpy / I :"" , I I II :
1'--: II: LL :""-.....
f'-.-.
dey iation to enthalpy at saturation / j II ~ II / /'S lOe
}-... Ii};.. : :""" f'O"
~' I II ' 1
, 7 .
~~ )
1.100
"
.~
I :
I;J' 3000 I ~~
'0""<:.'
/ r-i I :' II
/ .: / I'--. /
:
: /: ""-.....
: 1/
v: V:
~ 1
1.000
"-:.." II
L ~O; / / 17'f'-.-. h i-- / ~ rZ1&6;. E
¥
/ I l' II ~V ! / ~: / I-- N ~\ 'iI it'?" .;!
L v: .900 Qi
• 0<::-\.: 2500
~
. 0<::-
- ~'b'~• c)\ - 70L I /
I/.: / :; -...:: "-,
~:
K- "- 1/ :r':: .s::::.
~
;§'b' I)( I :' II 17 Ii 1:---- r-.., I i 1/ 'j \1 "C
(§ -
2LL -.~'b'~v ~
~\... .800
17' r-,
/ ' V
C)
~Cj C:J'b' ~(lJ ~~ ""-.....
/~ ~'i
~
~ ......
/ ;;:: .
~
~'b' /
/
E ,' "').( ~
it;-~ r;b-'b' / / /
~
/ .:::J ,'
~ ~
.700
~ ~ ~q- L II olf / K ~
:/ ~ 6'0
L
Ill .
~
-/
~ ,'
<v~ ~ (0 /
- ~- 1/ I>' :/ / 1/ -,,' L p;' V ~
~: : -;.
'6
'f
;t
.600
/ 11V ' / V' '- r-J$( l'.... r-'..
""
~ I.
.500
/.
;1 /' I'-x '"k V. :
I
~fJ./
:1 / '.'- '0
/ ;; ./ v.
1/·'
./ ol~ V ./ ~k
f--,
I
I;; " , : J"-.-.- ' I--
~~
V t---....
«
CJ)
.c
-
, " ./
~ ·I
.400
v
/' /' /' /'
,L-
./ :/' . . . . r::"
":> :"
/" I : ~
,
"
.......
./ '. I
100QL
L -
-
50 /--:; l./ /" ....... V V
LOj< V
/ . V .'
I I ./' . ....... "
.300
L -- ......", :
'" "-:-
'-.,./
/'" V . / V I ::= :
-,
"":::::::1 : ~I.
- c:::::.L-"
./
Z.
I>< '
. / ./
.....- . / .....- .· 7 r-..,
./ ,V .' ---
f....:: - I '"' :
I
'- .--
l--" .......
' ----- I ~
.--
--
./'
--
./' .200
£.
-
.-- v ....... l.--"
500/
~ ~Q "
I ' -....:::::
, I
= -
I-
.t. ~ ~ -f-" I'- \'I ::::,. I'--..
I .100
,
I I
, I ....... ..::::-
-
I I .
360
WATER-HELIUM SYSTEM
340 40 50
5.00 atm pressure .060
320 ~ / / :' '\V I.... I ~
Enthalpy datum: liquid water a.o·e, 0,00603 atm I J~ / :' 1 " :1 1
.058
.056
dry helium o.o·e, 1.00 atm 300 1 II 1)( / 1 /'-V ,''J
.054
280 ~ / l /,,11 :/ " ! .052
To obtain true enthalpy add enthalpy 1 1 A I ,' /~ I "'-V' .050
deviation to enthalpy at saturation / V b( ," / "y ,' / ,:" .048
/ "" / /::\ V / .... ~ / .... ." .046
/ A / / /~ V.: y .044
.042
E
.040 ::I
Q)
.038 .s::
.036 ~
-
'C
.034 C>
.::.::
.032 C>
.::.::
140 .030
60 .018
.c
<C
,016
40
.014
20 ,012
.010
j .OOB
.006
004
002
000
o 10 20 30 40 50
1800
WATER- HELIUM SYSTEM
120
5.00 atm pressure .500
.480
Enthalpy datum: liquid water O.O°C, 0.00603 atm
.460
dry helium O.O°C, l.00 atm
.440
--
.280 Cl
~
Cl
.260 ~
.1 40
.120
.100
.080
.060
200
~RIi~~!lmi§~atm3·040
30 40 50 60 70 80 90 100 110 120
.020
.000
WATER-NEON SYSTEM
50
1.00 atm pressure .056
.054
Enthalpy datum: liquid water O.ODC, 0 .00603 atm
.052
dry neon O.ODC, 1.00 atm
.050
.048
To obtain true enthalpy add enthalpy
140 .046
deviation to enthalpy at saturation
.044
.042
.040
.038 c
0
(J)
.036 c
.034 ~
-0
--
.032 Cl
~
Cl
.030 ~
.028
~
.026 'C
.024
'E
::J
.c
.022 (J)
~
.020 "0
(f)
.018 .D
~
.016
.014
.012
.010
.008
.006
.004
.002
.000
o 10 20 30 40 50
WATER-NEON
o
1.0 atm pressure 190V
~:o 90 ., , 1)0, . 1, 10. 120
?7
....... .700
f I I I--- j I---.. .680
Enthalpy datum : liquid water O.O°C, 0.00603 atm I I, I .660
I I ,II
/ r--- r--.
?
dry neon O.O°C, 1.00 atm 1700 I I I . / .......
r:-- .640
.620
H-.. / ! ......... -.:...
.600
To obtain true e nthalpy add enthalpy I' I -- :J
.580
---/
.........
";7
1500 / / .560
I 1-- .540
I I I r:--, r--.
.520
llJo I I I I j N t-- .500
c<A<;:- 1300 f Ir---~
" ......... II I .480 c
-
/ / .:--;-- r--. ......... :2. ~o
/ 0
,,~~o,,/ ---
.460
t-- J j : Q)
c
.440
/ / I 0 1 / V r--, : -',
.420
~
-:-- t:--..
1
'0
j
~"'~ -0"
70/ / I'·j.." / ! / .400 ~
~Cj
~'lf
t};-v 1000 ~ ,-0
~ ":\
/ ---...
/ 0'1
/
I'--. .J / I e:
i c-'
/
II
:
I -r-
I--
.380
""-
C>
.:.t:.
---r-:'"
c,'lf IlJ
--
.360
ill ~wS V
'If 0L . (j
--<.... I 5 ~: ~o
~~-4, 900 .340 >.
.-
:,<::-'If ~ / / / . / I ~ / / : 'i5
--- r-.
IlJ
~&.....l"g
.320
'E
«,<::'~- 800O~
-- --r-.
/ / di .300
/ / / / / v. .280
:::l
..c.
700 / / r-----I.( ' j)" / / Q)
V
.260 '5
---r
L
/ / ,::." :: /
/ '0
600
L /
60/
/
/
,
/
/
/ 010. V /
---- -- c- -'.
--- ~
.240
.220
.200
en
.0
«
---- ----
--
soo L
--
/ / /
/' / /"
.180
/ / ' 7'
/'
/ -? : -.:::
--
/' ,./ '''11/(
Vn' .160
40yL /" . / /' /' -..;:
/' 7' /"
•,~ (m' -- .
oU/ ,./ ,./ 'un .140
---- ---
/" /' :". / 1. ~n -
:/ .120
.L / ....- ,/" /' /- n 01,
/'
---
/' ../
..--
-',
.10.0
L
-.L
.....- /' ....- ....-
200 .0.80
L -"
.060.
Y.
.040.
100
~E
.020.
.000.
30 40 50 60 70 80 90 100 110 120
WATER-NEON SYSTEM
2.00 atm pressure ,028
.020
c::
0
(1)
.018 c::
~
"C
.016 0>
.::.:.
"'-
0>
.::.:.
.014
~
"C
.012
'E
~
£
Q)
.010 '5
'0
(/)
.D
<{
.008
.006
.004
.002
o
.000
o 10 20 30 40 50
wATER-NEON 900
a
2.0 atm pressure
90 , , .100
, 110 , . ,...120
.300
I II I II I If "-1.,: I I ; 0 ,jl'>,
2
rJ II '
" I"-I /
v
En thalpy datum: liquid water O.O"C, 0.00603 atm l
dry neon O.O"C, 1.00 atm
80!'-
...L t:--../
, / / /
/
:
:
""" .280
/ / ............. ( :
1 ~ .260
/ / /.' 'I I: / -
L
To obtain true enthalpy add enthalpy r--L
/ : j V ~
dey iation to enthalpy at saturation / """" ~ .240
/' 0 II .: II I "~.Ioo '
~~L
/ / ~
/""
/ I '/.. / :' / / :
O'~ : I ~
I ~
.220
L C!- \. . -
/ / " ",: I 1 : ............. '/C~,4
/ /
I II / I I . . li- / I 'l", "
V .200
c
~ I II h( ,:11 I : "~ 0'1j. I
0
Q)
c
~1f
~o<::'-
500"
-: 0<::'-
J-~.O
-
1 '" ./
/ ~ /
/ I
lV ,1
:'1
/
/ .............
r--J
V: ~ V
/
:
'" :::J
/
!I :,.,
-...;::; ~
.180
~
"C
--
OJ
~1f ~ III 70/ / I I l1' "- V /. : ..:.::
/ /
L
~ Gj ,: A
~1f .v ,§ .160 OJ
..:.::
~ ~
/ ~r V
/ I:' " c '
I / "-
"' r.-..: / '. -
4L
fty'< 'S)'li ~'li _ /
0
~ .~ !Zi /
/l "- ~:
<v~ ,,?,,?Y,1lI~
or 1/ /1 ~
/ 'b( V v VI V I, c6 j I'--....
.140 '8
" <Y;~ f(
"
0): 1 'E
L / 1/, / '",K r-..., v / " ::J
/ / : JJ
.120 .s=
/ / / 1Y :/ V N /' I'--- Q)
'S
30z f 60/ / / 01,
/ /' I'--.... V / c;: : I
I
"""'I (5
/ : '- .100 f/)
L- / t'X /
~f.>/ ./ i'-..... /' .m , /' "~ !7
.0
«
/ / /' ><
/' ol, V /1 / / ' "-
0; : V
" r--...... v
/' V / ./
x v :/1 /'
1"- ;.."
/ 1 " /
.080
200' £
5u ../ ./
./ / ,/ /' V I
o/oj./'
/" : ['-....
I ./ ,
"- J-.... ~ /9s
~ ,,/ ;x..../,
1/
........-:
v- ' 1
: 01-
r-...,
,
/ '-.... 1 1......- I
........ .060
£- v
'-
?< / ;;...- I "'- I,
-
.......- ,
/./
, ...... I>< - I
-- ,
./
00 /
;L
.... ,...... ./ ....- ..- ........
.040
Z- 1 .--
l- .020
I --......
,000
30 40 50 60 70 80 90 100 110 120
WATER-NEON SYSTEM
50
5.00 atm pressure .010
.007
c
0
Q)
c
~
.006 "0
Ol
-..
~
Ol
~
.005
~
"0
'E
-
:J
.004 ..c
Q)
:J
(5
en
~
.003 <t:
.002
.001
.000
o 10 20 30 40 50
WATER-NEON
5.00 atm pressure
Enthalpy datum: liquid water o.o°c, 0.00603 atm
.110
dry neon O.O°C, 1.00 atm
.090
c
.080 0
Q)
c
~
"C
.070 Ol
.::t:.
.......
Ol
.::t:.
.060
~
"C
·E
-
.050 ::I
.s:::.
Q)
: :I
"0
.040 (/)
.0
«
.030
.020
50 .010
.000
30 40 50 60 70 80 90 100 110 120
WATER-ARGON SYSTEM
50
1.00 atm pressure .030
.022
c::
...
.020 0
0)
ell
.018 ~
"0
--
0)
.!i<::
.016 0)
.!i<::
~
.014 '5
'E
:::J
.012 ..c::
<1>
"5
(5
.010 en
.n
«
.008
.006
10
.004
.002
.000
o 10 20 30 40 50
1000
WATER- ARGON SYSTEM
1,00 atm pressure
- :............
"
0;/
~}~ / / / -h( ~ r-
i
1/ : / / 11 c
-.. ~
.:..~
0
f> .;?'i' 7 / 7 71 / . "
.220 El
ctl
~o , 7
50 ~o~ 70 / / =1 / 1 l L-..~ '"I .200
~
'0
~,;}flf ~flf \...Ci' L / / / '?: I
---- --
C)
--
.!II::
1;-'" ~
500 , CJ,,:>'l:f. ~0 I ~I~__ 7. r7 / &:' / '":-..
I .180
C)
.!II::
\\ ~ ~ / II I'Y ' P.: ~, 7,70
~~ 450 ~'l:f r,S-flf / / 1
-..
~ ~ ~'l:f # / / .I J'r----J!.: / I/,
1 ,: / '
"
.160 i?;-
~ 400 '?' ....10 J ~ 'l' ~: r---_ / o. '6
-
1
'E
"
-
1
--.! / a: / 1 --:. qQ.
<1l
::J
30y 60/ / I / / ols>' ;' ~;Z::: ,!9 /'
--.
--.' 70
.1 20 aen
:/ / / / / 1 .100
.0
«
25~ / // 1/ 010. I .;;:.:1 - - - __ "
L / // n ~?~
:L In ........ , ........ ........ ....- ....- ....-
lOOf ...-. I , q --.' .040
.020
50
~, .000
30 40 50 60 70 80 90 100 11 0 120
WATER-ARGON SYSTEM 55
.010
c
0
.009 .....
Ol
<1l
~
\J
--
.008 Ol
~
Ol
-
~
.007
>.
ii
.006 ·E
a-
::J
..c::
<1l
.005 ::J
en
.0
.004
«
10
.003
5
.002
.001
o :
.000
o 10 20 30 40 50
500
WATER-ARGON SYSTEM
90 100 110 12 0
2.00 atm pressure .160
450
/- 1) ~ :/ / j ............ ;; ............ ~
7
80/ f--l 1/ , j ": f-. / : N :
.1 40
/ 17 .i
/ ..........
/ f ~ II ':- I'---Q~
Too btai n true enthalpy add enthalpy / / r7 ~ ! I'-.-
deviation to enthalpy at saturation / 7 l t V; V
"- I'
f'-.- / - ,130
O~' T
/ ............
/ ,"::J.. : 1
L
~(Sj
"",,- / / ~ :
.120
/ / ~ / :' / / ~ / ........ :
o~
L
Ii
/ / t---- / / / :K P(7"
'"
..........
S:f:"0;
L / / ,/ /
/ 1
.110 c
~~
............ ~
/ .... / 0
OJ
r-L / / .. I :
L -
/ I
~
L
'?>' ~ '-
/ / / / ~I / / ~ / : N : Q.."
--
/i OJ
~Cj 250 1:oJ'lf 0 .090
701. 1I 7
~
/ .."."
~'lf ~v ~ - / ~ "-... : ~ OJ
/ I / ;g /
L
~
~~ :!J'lf ~'lf /
............
/ . ..........
~ &'If 9,0 "- .080
/0 ;7 / 'J ( 7' ;; .
<v~ ~ ......0~' -
/ / .. . 1/ ............
-/ »
.-
:c
2L
"-
- / /
-yo
V /
,
1/ 1-5;
0<
:--.....
<?: / .070 'E
7 K I :s: :1/ ~ ~e
-
/0 "- / ::::'I
L
..c
/ 1/ l<r-.,. 1/ ./ ./ , 'T: .............
-/:
1ty "-.., '" .060
Q)
/ / 1/ ..........
~ ::::'I
15~L 60/ /1 /
/
1/ 010 '" :/'
........, ,/
1/ ./ . C"2 :I '" ,,- I
/'
/"
.............
, .050
(5
en
.0
/ /' '>< '"
"
I /. /' <{
/ S: I OJZ"
~
/
/ / /"
~,
,/ ' /' --....:::: <: ............. ./'
?"-l..
I
.040
L ./ / /" ..- ./ /'
: / /7 .......... '/
1/
............. ./'
I
l o0 L
L 50/ ::
/' / ./' ./ /.. /' ',!'; ' ........ , ....... ............
.030
L /' / ...- ..- 1- - ......
-
../ -....... : ........
><. " 0/ •
'"
--
:L
-
...... ....... ........ ...... /-" ""c . v:r-,
50 L
/ '"
.......
/ .......
...... ::;p
I --' "-
-....::::
, ........ ........
.020
><" ..........
-£-
J'C. I I .~
(h.
I "n,
.010
0
, ,
~ . .
.. "
.000
30 40 50 60 70 80 90 100 11 0 120
35
.0020 ~
o
.0018 .2
.0016 «
~~~~~~4-~~~~~-~~~-+~-t~~~~--~-~~~~~~~~--l .0014
~~t)~~~~~~~~~~-t~~-~~~~t-~¥-~~~~~~-+~~-+~~~~~ .0012
.0010
o .0008
~~~~~~~tt~~~~~~~~~~TF~~~~~~~---+~~f-~~~~~~~~~~~~--~~ .0006
~~~fitS8Em~ffit:~~·0004 10 20
.0002
.0000
30 40 50
WATER-ARGON SYSTEM
5.00 atm pressure
.052
Enthalpy datum: liquid water O.O°C, 0.00603 atm
.050
dry argon O.O°C, 1.00 atm
.048
.046
To obtain true enthalpy add enthalpy
deviation to enthalpy at saturation .044
.042
.040
.038
c
.036 a
....
Ol
.034 C!I
~
.032 ""0
--
Ol
.030 ~
Ol
~
.028
.026 g
""0
.024 ·E
-
:::J
.022 ..c
Q)
.020 :::J
.018 "0
(J)
.0
.016 <t.:
.014
.012
.010
.008
.006
.004
20
.002
.000
30 40 50 60 70 80 90 100 110 120
140
WATER-N 2 /C0 2 SYSTEM
50
Gas mixture: 79.0 mol % N2 and 21.0 mol % CO2 .040
.036
Enthalpy datum: liquid water O.O·C, 0.00603 atm
dry gas mixture O.O·C, 1.00 atm .034
.032
To obtain true enthalpy add enthalpy
deviation to enthalpy at saturation. .030
.028
.026
-
~
:::::J
x
·E
en
(\j
.024 OJ
~
"0
.022
--
OJ
~
.020 OJ
~
.018 >-
.-e:
"0
.016 ·E
a-
:::::J
..c
.014 w
:::::J
30
.012 en
.0
.010
«
20
.008
.006
10
.004
.002
o
.000
o 10 20 30 40 50
1500 /: / i I : / :
.560
; / L
"
.540
Enthalpy datum: liquid water O.O°C, 0.00603 atm -----J '
7'"'!--
/ /
1400 I :' .520
dry gas mixture O.O°C, 1.00 atm r~-1 :
.500
,...,:
To obtain true enthalpy add enthalpy .
"
,
I """ ~ I ,f)',
.
~'•,
.480
.460
deviation to enthalpy at saturation. ~ -Nt---
.440
~
.420 ::I
.400 X
r, 'E
=:--......; '. .380
.360
C/)
ctI
OJ
.340 ~
'0
.320 Ol
.:lo::
-.
.300 Ol
.:lo::
,280
>-
:t::
.260 '0
.240 'E
'. I
-
::I
.220 ..c
I .200
Q)
: :I
~ "! 0C/)
.180
1
1-- _ .0
I .1 60 <t:
I ".
.1 40
: ./ I
.120
-t">-~ I I
/ 1 " .100
I
--' ,
I .080
I
...... 1 ...- o 1 tin
.060
: 1
.040
II
30 40
I 50 60 70 80 90 100 110
-0.
120
.020
.000
--
C>
.018 ..::.:::
C>
..::.:::
.016
.014
->-
'0
·E
::J
.s:::::
.012 Q)
30
:5
(5
.010 fJ)
..0
<X:
20 .008
.006
.004
.002
.000
o 10 20 30 40 50
.260
C/)
co
.240 C>
--I--. . ~
'0
.220
--
C>
~
-
.200 C>
~
/
. -- .160 'E::::l
..c
.140 Q)
/ :1--- :;
.120 aC/)
/ .0
/" 1<0 ex:
.100
-- .080
Ur,
.060
-- -- .040
.020
.000
30 40 50 60 70 80 90 100 110 120
.016 ~
"0
--
.015 OJ
..:.::
.014 OJ
..:.::
.013
.012
~
"0
.011 'E
::J
.!:
30 .010
.....
Q)
::J
.009 (5
(J)
.008 ..c
20 «
.007
.006
.005
.004
.003
.002
.001
.000
o 10 20 30 40 50
1100
W ATER-N2 /C0 2 SYSTEM
n ,
80 100 110
Gas mixture : 79.0 mol % N2 and 21.0 mol % CO 2 1000
I :" I :' I :'1 N
is
I I "I
L i~'
: / ~
1.20 atm pressure
I I : ,:1 I :11 r-
Enthalpy datum : liquid water O.O°C, 0.00603 atm
dry gas mixture O.O°C, 1.00 atm
oo
/
L
/
' r-......
,'. /
1§§31 I I(
-""""r--..
'
t i l mEr:----.Hi:
:
:: -:--
;: : /
/ I : /:' I :-......-...... ,' :/ ::
To obtain true enthalpy add enthalpy
deviation to enthalpy at saturation .
~~~--~~A/.. II ~/~~~~/~:
: /,'. ~~/~2~/~~~~~
/
I : / I
I U~~~~&~~~~~~~~1:~
/ 1
'f--..:; I"
:/
/ [:' /
/
I
-.,:,.
II "
'UII '019
~
:
9(1
~ ~i S rn "
:
"
.280
.260 ~
/ ;f I -.. . . . ....... ..1 / ----~~!J 1I.?r:·, ' ~
/ / I / rr--.
: : I " ---r--.- ' .240 'E
I 1<,> 1' II ;' Ii :it--- " / ', en
/ / V /r:; ... / I :'f... .220 ~
70/
I r--,. / .'
/ I .' / ' :; 1 ::/
I.W : In,.:
! r--:-- -L :
: / --- - - i - . ' ,
.200 -5
Cl
/ 7 1 r:-:--.l 1/ / / 2: ~ : r---...: I I ~
It 1/ . t-- V 'E: I ~: " r--- ' fT. .180 ~
/ 1/ 0\01 :' I II .' I"-r-- : / m: / ';6: ",I'--
.160 £
/ V /"---- : / ....., "0
.'.
-
/ 1/ I :"V V V :' V ,., ,' ___
',ncO'. 'E
.140
/ 1/ .-.:P/ V -f ~/
::l
.s::
60/ / -/ / ~ .120
.$
-
/ / 57'1-- / .. I'" --. I
::l
'0
/ / / V· / /'" c:J ./ '00
.100 ..c
en
/ ' / /'" V· / :V «
/ V / .''/ 1 ./ I ./
---- l' I-- ~ ,' I
<!l : Y
I
/ 1
.080
bU /' / /./ ./ ./ oo .y / / ?O- '
L ""--./ /--:,.< /" f/./ V
.060
:2- I
-
.......... 1/ / 1 / f"
-
In
....... I-- 1,-.--
~. ~
.040
.020
." .000
30 40 50 60 70 80 120
.020
Enthalpy datum: liquid water O.O°C, 0.00603 atm
.019
dry gas mixture O.O°C, 1.00 atm
.018
To obtain true enthalpy add enthalpy .017
deviation to enthalpy at saturation.
.016
~
:::l
.015 X
'E
.014 en
('(I
OJ
.013
~
'0
.012 OJ
..::.::
.......
.011 OJ
..::.::
.010
.~
'0
.009 'E
-
:::l
.008 .c
Q)
:::l
.007 (5
en
.0
.006 «
.005
10
.004
.003
.002
.001
.000
a 10 20 30 40 50
: -';-
.160
I'--- 1"--- :
1.0 . .
: """=: .....:
.140
;l:.'
.120
........
v : ~ . . . . c 80
.100
/' '.
/~r-. '.
'. .080
/' :1 ~
:I i:
.060
~
-- ......
'. --
-:::
.020
.000
30 40 50 60 70 80 90 100 110 120
--
OJ
.009 .::.t:.
OJ
.::.t:.
.008
~
'C
.007 ·E
-
::l
.c
.006 (J)
: :l
"0
.005 (/)
.0
«
.004
.003
.002
o .001
.000
o 10 20 30 40 50
/
~~I/ .jll / ,: ' II ;
:1,/ I -rt:'t-+f- : ~"'- :
II
If
j :: ,200
,160
To obtain true enthalpy add enthalpy
deviation to enthalpy at saturation. ,150
~
.140
x
::J
.130 'E
(J)
<IS
,120 C>
?!'
'0
,110
--
C>
~
,100 C>
~
,090 ;:.
'5
,080 'E
-
::J
.c
.070 <1>
r--_ _
200 ::J
(5
,060 (J)
.c
,050
«
150
,040
100 / - .030
L-
-- -
,020
~
1::::
I
I
v
o - .010
50 l- - I
I
-+-- ...1 1--.' . ~
1'.,
,000
30 40 50 60 70 80 90 100 110 120
.000
o 10 20 30 40 50
.004 --
~
OJ
~
~
:c
'f
::J
.003 ..c:
Q)
'5
(5
(/)
.0
<{
.002
.000
o 10 20 30 40 50
~
.003 '6
'e
:::J
..c
Q)
~
0
rJJ
.002 .0
~
.000
o 10 20 30 40 50
W ATER-N2/C02SYSTEM 260
90 100 110 120
Gas mixture: 79.0 mol % N2 and 21.0 mol % CO2 .068
l~ /: I I I r---..Y:· I 1\
/ II r 1r--...
5.00 atm pressure 240 / 7 If., ~~,J/ I I / :' ------- : ,: / .064
80/ I : /~ ' / / ~ --- .' /
Enthalpy datum: liquid water O.O·C, 0.00603 atm '1---[ I ,: II \ l ---1'---1 / : ---rI-- .060
220
I / I' t-W X/ /:---... / : \
dry gas mixture O.O·C, 1.00 atm
.056
.032
120 ~
'6
.028 'E
:::J
100 .c
.024 Q)
'S
0(/)
.020 .0
80
<t:
.016
60
.012
.008
.004
30 40 50 60 70
.038
Enthalpy datum: liquid water O.O°C, 0.00603 atm
.036
dry gas mixture O.O°C, 1.00 atm
.034
To obtain true enthalpy add enthalpy
.032
deviation to enthalpy at saturation.
.030 ~
x
:::l
.028
'E
(/)
.026 til
Cl
.024 ~
'0
Cl
,022 -..
~
Cl
~
.020
>-
:t::
.018 '0
'E
.016 ::l
.c
<J)
40
.014 'S
"6
(/)
30 .012 .0
<l::
.010
.008
.006
10
.004
.002
.000
o 10 20 30 40 50
'Y/~~~~t8~0rl-'-j~f'I--"I--,":
1700
L
.560
--'. .500
.480
To obtain true enthalpy add enthalpy ~ '.
-...: ' .460
deviation to enthalpy at saturation. ;---....
.440
I:
~
.420
x
::J
.400
'E
.380 en
ctS
.360 Ol
.340 ~
"0
.320 Ol
.::.:.
""-
.300 Ol
.::.:.
.280
.260
.240
->.
'C
'E
::J
.220 .!:
Q)
.200 "S
.180 "0
en
I
I ..c
.1 60 ~
v I
.140
: / / I
_I- .120
I 'U
.100
.080
.060
.040
I I In
.020
'"
.000
30 40 50 60 70 80 90 110 120
130
WATER-N2 /C02 SYSTEM
50
Gas mixture: 90.0 mol % N2 and 10.0 mol % CO 2 .034
--
Ol
.018 ..::.::
Ol
..::.::
50 016
~
'6
40
.014 'E
:::l
.J::
.012 <1l
30 :5
(5
.010 ..c
If)
<{
20 .008
.006
10
.004
.002
.000
o 10 20 30 40 50
7t
W ATER-N2 /C02 SYSTEM
Gas mixture: 90.0 mol % N2 and 10.0 mol % CO 2
L 80 90 .. , . 100 110 120
100 II " ~' I !/ ' I' : ...... r:-... I : I: : I .400
II ." r-r--... :"I . / I .380
1.00 atm pressure I / : II .1"""" ,I 1/ : I.......... :
:
.r-
To obtain true enthalpy add enthalpy I !-...!
:j : .............. I '.
C$,/
7'--
II .300
1
L -
~ / ~ I >...:: ~ ', I .260
~'+O;, 700 / 0/ I c:: ,' / ' / ----4.......: : / r--.. '.
7
~ s::- - -~ ,j '/ 1/ q : 1/ l ......... t--:j r<=:
.240
.0<::0-
~~
~o ~
~ \...V
J.
/ rr--..i :
1/ :
/
1
;; '!.1': t. :
; ....... r-...... :
:
I
" --- K
.L ~: V
/ 60/ / / .v o~ : 17 . r--- '. ~
.160
L / / / V
L
400 I ,' 7 i-..... ~:
.140
I / //~r--
L / --
1/ / 1,;' , :/
.020
=
~
.000
30 40 50 60 70 so 90 110 120
50
Gas mixture: 90.0 mol % N2 and 10.0 mol % CO 2 .028
.027
1.20 atm pressure
.026
.017 m
Ol
.016 ~
"0
--
.015 Ol
.::t!
.014 Ol
.::t!
.013
Z.
.012 '0
.011
·E
:::J
.!:
.010
$
:::J
.009 (5
(/)
.008 .0
.007
«
.006
.005
.004
.003
.002
o .001
.000
o 10 20 30 40 50
~80/
€I
.300
I I "'- <......... -7 ,r---..
:j : 'Ye/,
ty o · :
I I j .' .,...... ........ : I : j II : .....: ,m/X I" -..I
Too btain true enthalpy add enthalpy
deviation to enthalpy at saturation.
~ ~~/ I
/
jT
7
:T
:j j ......... hi.
: IL :--. f...L
:
/ :
:
:
:
:
F:.:.: ---~ :in
, .280
.260
I II II
~~2
I V : ......... : 1 ~
::J
/ / I j / / ....... r-:-.... t::';=
.240 x
.j j ---r---..;. 'E
'-.: 2'
.' : : "
~~ t-...
¥ / ~K / j r--. : : en
~ -·~o~ - 70/
V '/. rr= bS'' .:r7 I / : / : i--
.220 n3
C>
L II:' ~
~o
~'?i
~'?i.&
~ \...
I I
: : ~ t--.:. 1<'0
.200 "0
/ ~71 / 7 r7 /' :-- r---. A : : ""'"
~ . CJ":J'?i ,§~
--
: C>
0/
":Jftf
500 ~ l§ Ii ~ r--. Q: - .180
~
C>
/ / / 1/:' / : ~
"~
0\0/ .' / t: '.
r;;.~ is'/'"
)' ~r/j : CIl ;
<v~
-
-~ ,~~ /
/
/
~'l
::'"bZ. /
:
1/ "".
ra · /1 ---- IN :,
: r--- P:. '.
.160 ~
'6
Z
/ :
4 / / / 1 :/ 1°; V
,
I 'E
--- ...,.
.140
,." .
::J
/ I /
---- I--.i I ~
::;
: '. i!...U .c
L 60/ / V : V
3 zL
Q)
/ 0\0 / '.
: .120 '5
/ / /.'
/- [7
/ ~ r--
....... - "0
en
/ 7 r-.. / / : V /
./
.0
.1 00
/ 1 >' /" ~y ."" : I--- r-. I. . <x:
L ./ ./
/' /
./ .. ' / :>< :'./ ~ >, I 1
L -.. .080
V V r-- K ::
---
./
L 5u/ / ';/:'" 7 1 ,,~
--
200 ./
L ./ / 1/ / V iij -,.---
--
/' /'.' .060
- --
L 7' /' /' , I-> .......
v- C '. .-;-
L- i.--"' '.
-
~ ~
,~
/ / .;...-- "'-. '. 1
f-"
00 .L
L
, '" .040
, I ~
I
.. .020
"--:-
~ .. ,
I I
- .000
30 40 50 60 70 80 90 100 110 120
.020
Enthalpy datum: liquid water O.O·C, 0.00603 atm
.019
dry gas mixture O.O·C, 1.00 atm
.018
.010 ~
30 '6
.009 ·E
:::l
.008 .s::
Q.l
"S
.007 "0
en
..c
.006 «
.005
.004
.003
.002
.001
.000
o 10 20 30 40 50
.220
To obtain true enthaJpy add enthaJpy
deviation to enthalpy at saturation.
" :t:Fri'i:= .200 ~
-....; ~s
x::J
.180 'E
I/)
ctS
OJ
II .160 -5
--
OJ
j : ::s:
OJ
.140 ::s:
: I 1-+
~
.120 '6
V : ~I
~'f'-...- C 8<:: 'E
V t'S.
-
::J
'. .s::::
Q)
::J
1---:
-.......
I- .080
(5
I/)
.0
'. r-... '. r
<{
... r::::::::
- .060
.......
'-
.040
.....
I
--.. ""::::: 'ts..
'-- .020
.000
30 40 50 60 70 80 90 100 110 120
x
~
.012 ·E
(/)
.011 Cll
OJ
~
.010 -0
--
OJ
~
.009 OJ
~
.008 ~
-0
·E
.007
-
~
..c
Q)
.006 ~
(5
(/)
..c
.005
«
10
.004
.003
.002
.001
.000
o 10 20 30 40 50
600
-
1-1
It !- :- ,: ./
'""- :
500
/ ~
I : "'"
/
O.O·C, 0.00603 atm
l- j I- II -
Enth aipy datum: liquid water .160
H?++- I If V
450
10\
~ / l / ~ I~
:/
~ :
-f -
!--
.130
'()~
~ LhL / It I 17 r-::
/ r-~"
18) ~
r-
"'" - ~ i:- - i f
::J
~¢J.> J 6'$
x
-
h I-- f--,;.
--!Y"- Z I /. 7 I}~ -
.120
\...,¥ 'E
--
C>
'b'
.~'li
-
.:::t:.
r;z::- -
I
- ~ t7 ~
q}'li '--
~~~ '- : '" / .090 C>
~?$..$J~~ /
,---.1 -:7 ;LI--N 6 '- .:::t:.
~'li
-/ / ~....
</) .
<v~ 250 :
-
0\ 0 'I: ~
.080 ~
""-- 7L-
V ?S V :' <0' .: "--I'--.
60/~ ~ hL: ~--
~
"(
-
"0
;; -
/ / ~
~ r-~
. cl-:' r-- r-- -;. 'E
'-. ::>:: '.
N-k/
~ i'l ' .070
-
::J
"---:-
/V~ .L ~ ~ I-- . - ~. :--'x r--~ I--:-- --.:
-
~
~
.J::
- -/
.'. ~
r
200 -.., ~ Q)
-,. / I
- - - / '. -
·V .060 ::J
- --:..~ - - - -- -
:' - I -....,."1' .
/" I
:-- -"..<: II)
.0
.050
«
/'
- -=J2
,/'
~//o<.-..,~
I I '" --
~ .zo :~ ~
L<
150 £ C\ 0[0
/'
7- -i- 7"
--
50 '/ .::::::: 'x .-/ ............ .040
-, ./
/ 1/ , / "-- .,.0:::::::
~ 't:
? ~
"""-
?r-......." t\ora .7 ......-
--
./ I .c" ~
100 .....- . / "'-- -,..:::: .030
-
:.--
4V............ ? :>"' I
...... r-- ~
--
~ ::::"..
-- - -.:.,..,- - - --
..c... :>""'-. ~
V .....- :::>-" fl 01 c:: "':-
- - "-:J - -
c::::. T. ><....:: ~
---
"<..:.--
- -
~
-
.020
-- - - - - -
--..:,. _ I
- -
........ ' e ~
-::::
i--' _
""t
~-
-- -- - "" - r- - t+; -
c.
-
t-- '.
---
~
.010
.005 ~
'5
·E
::l
..r:::::
.004
Q)
"5
"0
(J)
.0
.003 «
.002
.001
.000
o 10 20 30 40 50
.004 Ol
~
>-
:t::
""C
·E
-
::J
.003 ..c.
Q)
::J
(5
Ul
.0
<t:
.002
.000
o 10 20 30 40 50
I I \/ ;' :' i\ I
5.00 atm pressure / 1
\ / '/ 1
\ I V
I \/ / \ :' X : 1/ \ \ :
O.O°C, 0.00603 atm / /\ / Y '/ \ / \
Enthalpy datum: liquid water \' I
~e' / \ '/ 1\ I r\ :' I .006
dry gas mixture O.O°C, 1.00 atm .~-v 40
/ \ I I / :V :"\
~
'lJ.? / X I \ I, !\ \ 1/
To obtaI'n true enthalpy add enthalpy ~~(J 1/ / \ 1/ /\:' I \ / \ / :5.:
')~~ / \ ;X / ....\ / \ /' \ /:' ;!1
deviati on to enthalpy at saturation.
\.'f.:
·o~
/ V / \ / 'i /: i\ :
.005 ~
·o~ ~ / / \ / X / \ / :\ / V
~~
x
30 ::J
~-v ~.j.7f 'i V
.... ' / 1\ / X \: / \ V : \ / :'\
~? ?'li-
/ X / / :\ )\ )( \ /
"E
'li- ~v ~.j.e
~~"'i
II)
.~ e'
/ \ (\ :/ 1\ 1/ 1\ : / 1\ IY ('Ij
Ol
«.-~'(;' '\I'-~ ~<::? / 1\ / /\ / \ V \/ \' / \ / \
,e .004 ~
/ V\ V r\/ fo-.. ' /\ :'/ \ :' 1/ \ '0
20 A 1\ / X / \ ,..... r\ / \ / 1\ )( \ OJ
.!i<::
""-
/ LX 17 / Y X 1\0.,: V ." .' OJ
.!i<::
/ 1\.\./ Y / "\ V \: / \ / 'if ,: V \
/ ~ V\ / V ,I)( \ 1, / §':\ \ 10:> : \ :/
.003 ii
~
/'1 \ / l"oV / 1\ V\ /" / 1\ '/I:' \ / (f) \:' \ 17 'E
10 ./ ~ ~ ,\ V V \1/ .' 1\ V \ -~ :' / [ \ 0
(1)
r\ / f'v;i ,: £
::J
/ IV A Q/ / \ / IV V \ ~v \ o· :' \ / '\
,'x
Q)
/" V A1 >( A
~I. 1\ ~\ \ 0 :,. V\ :' \ :20
/ i--P( /'V\ / W V r\ ? \ X ~ ,: r\ \ --5": \ \ II)
,002 .c
/ Y /'\ V\ / 1 ~lo/' \ . / V'\".' ...........- \ '. \ V 'E;' -ex:
~ X I~ / \ --P\ ......... .: \ ./ .........--- \ \ ~:' ~ £,'" \
/ ~ ~ ........---\ . / . / ----\ o·'~/' \ .'L..-----\ \ A. ~ \ ,,,",~\
, 0- \:
----'
....-'(..
--
~ ~ X J-...--\' ~ K X ....). \ \ ...---:'\
--
\ .'
--
.....-::::k1 \ --- -'\ J--\ \ ~ \~O;!!---'\ :' \ ~ iFf:' \ \ ~K \
.-::::--K ~ '\ ,..- ~~
~ :\ .-\- [\0'- i\ ~ \ )j[." \ --~ ..' 2. \ \
.001
280
W ATER-N2 /C02SYSTEM
260
90 100 110 120
Gas mixture: 90.0 mol % N2 and 10.0 mol % CO 2 80 / / \ 1 ... I N J I ' j :. '\' ,. . 1 ;-.... , . '\'; .068
Enthalpy datum: liquid water O.O·C, 0.00603 atm / / :71\-- .I :' I / ~ !: .060
220
dry gas mixture O.O·C, 1.00 atm
.056
60
.012
.--
40 .016
30 .014
.012
.010
.008
.006
.004
.002
.000
o 10 20 30 40 50
-
.040 (ij
....
CO 2 2.5 mol % .038 :J
ca
.036 c
To obtain true enthalpy add enthalpy ~
.034 -0
deviation to enthalpy at saturation. .032 Ol
~
Ol
.030 ~
.028
.026 £-0
.024 'E
-
:J
.022 ..c
Q)
.020 :J
"0
.018 (/)
.c
.016 «
.014
.012
.010
.008
10 .006
.004
o .002
.000
o 10 20 30 40 50
210
.038
Enthalpy datum: liquid water O.O·C, 0.00603 atm
dry natural gas O.O·C, l.00 atm .036
.034
Natural gas composition:
CH 4 80.0 mol % .032
--
Cl
.::.!
Ol
.020 ~
.018 ~
'5
.016 ·E
-
::I
.c:
.014 <1l
: :I
.012
a
(f)
.c
<C
.010
.008
.006
.004
o
.002
.000
o 10 20 30 40 50
-
.020
~
CO 2 2.5 mol % .019 ::l
<1l
.018 c::
To obtain true enthalpy add enthalpy ~
.017 -0
deviation to enthalpy at saturation.
.016 Cl
~
Cl
.015 ~
.014
.013
.012
->.
:0
'E
-
::l
.I::
.011
OJ
.010 : :l
0(f)
.009
.0
.008 «
.007
.006
.005
.004
o .003
.002
.001
.000
o 10 20 30 40 50
~
'5
.005 ·E
-
:::J
J::
<1>
.004 :::J
(5
en
.0
«
.003
.002
.001
.000
o 10 20 30 40 50
300
-
~~~ 180
30 L
/. ~ Y-- .: X : /!r---.. .: .054 0>
N2 0.4 mol % ~ \..~ 170 '\ / : 7- f..:.. ./ : /.: :
...
-
E---, (ij
CO 2 1.8 mol % ~~o 160 ' 0<::- / r-...J!f. r J '/ '-- .: : "- 1 / : ;
.052
.050
:::J
as
~e:,~.s 150
~
~.;§.1i \.. v' L L.·· #.: ~ : I '\ /: : r--..Y : ;
c
e:,1i ~ J .. ' ~:: 1/ .: r-x / .: /:' ~ ; .048
To obtain true enthalpy add enthalpy
dey iation t.o enthalpy at saturation. ~~-\
~
140 ~u .;§.0
z,: ~
/ r-.../~ : x::.
~ V: ~
:-......... . j
: : '->:
; ,\ .:7
~ .044
.046 ~
'C
/ 1
/ ." 1/,,<:' .'17«0' : A, : V 0>
<v~~~ 130 .~ 0'~ f---../ .: / .. IW : .042 .::.::
--.
"'?-~ ~~ ~ ...
o V "-
/ .
V ....... ~ : ):
.040 0>
.::.::
120 .....e / / :~ ~: X ~ :A' ~')I., ;
h<:' I,\~
/ --:;s.. ~ :/ V D(" _. : -::- :~
.038
110
A. 7- t,..:/-..; ~/" K :/ --....1 /' '\:--
1--..-' : .AX; : \ ,034
.036 ~
'5
100 /' k' .V ~ /:' '\ V- I-..: V : :'\. :/ f-..::' : C? :' .032 'E
90 / ' l~~ V /" ~ A' : / ~ : V: ~ ~'! : :::J
-
20/ .v .030 J::
~k ./ ~ ~ I '\ : ~,
80
/ ' 7 - ~"I . / .,'/ ./ .x:- ~ ~ : :/ :
.028 Cll
:::J
70 r<../ /" "'ol~:> F-..... I)( ./' .............. :. / ---- :\ ~ ? '>< : : :--.
/:
.026
a
r--.... .x .024 en
-
. / V K ·· !)'/ /. ~ / : '\, ~ r-..... : ....... --- : .c
60
/' X ><-
'/ ~ V '\1:-'--....... / ' .:
/ '
~~.~
:' > : "'!>< :'\ : ,022 «
.'>< .......-- .020
._,
50 /~ / ~ / / ' : S;::? --;-:....... ....--- : ~ 110- : -:-.......: , .018
40
10........... )J-'" ;:>
/" / ...... V ....... ~
"'-->< ~ f...-'\ : ......... v r-... ;' \ ~ : r-...... : '\t-- .016
:-.....-....
-
p<-.... ~ ,~,;/o >< ::;;? c; :1 : :'\ ..- .014
~ .,;.
-' ~ '\?~
-.. . . . .,.: 1.--- :----
30
<-- ><
--
>-S:.... L-- ~
-
~
<:"----- ~ ......... ,:.-- ~ '.
:--
.012
20 ~ ~~ ><--
.-.- ">< \ ",Q 0/o- ><:: ~ . ~.- : '\ -~ : .-:;
--- ~ ..::;.~~
>< ~ .-.-
------
.010
: ><::
-
~ ;'?< ><c : ~ .-:,. ~ ", -......... " 'V:- .008
--
~~
-
~~
10
r--------~
:----......
:::> ~
-= --- '"S:>. ~ ~ --.,
.::>-<:::: ~ "
~
-=-- zU'
"- :
"':'- m..9J~\.i ~elativE 1mQ110 IV
~:
~
---....... .
--;-
1-""":"""
-..." ---"-~/ '.
'\' ~
. .......
'.
;--.....
---......:.
.............. .006
.004
....... ..... ~ ~ -.....-.... "-~ :-- ~ "V:\ '0' .. I a-..
.............. " \. ~'"
joo....
... "
~
'
r--.. '\,.o r-:-....
~ --::--I 1--.... ~,\.o, '.-:--- '.~
.002
.000
o 10 20 30 40 50
-
.040 (ij
....
CO 2 1.8 mol % .038 :J
CIl
.036 c
To obtain true enthalpy add enthalpy ~
.034 "0
deviation to enthalpy at saturation.
--
Cl
.032 .::tI!
Cl
.030 .::tI!
.028
i?;-
.026 ii
.024 ·E
-
:J
.022 ..c
Q)
.020 :J
"0
.018 (/)
..0
.016 <
.014
.012
.010
.008
10 .006
.004
o .002
.000
o 10 20 30 40 50
.038
Enthalpy datum: liquid water O.O·C, 0.00603 atm
dry natural gas O.O·C, 1.00 atm .036
.034
Natural gas composition:
CH 4 85.0 mol % .032
.020 ---en
.!II::
.018 £
"0
.016 'E
-
:::J
.£:
.014 (J)
:::J
(5
.012 (f)
.0
<{
.010
.008
.006
.004
o
.002
.000
o 10 20 30 40 50
C 2 H6 8.8 mol %
.022
C 3 Hg 4.0 mol % II)
«S
C)
N2 0.4 mol % .020 (ij
~
.014
~
'0
.012 'E
:::J
~
Q)
.010 "5
(5
II)
..c
.008 <:
.006
o
.004
.002
.000
o 10 20 30 40 50
~
ii
.005
'E
:J
-
.s::::.
Q)
.004 :J
'0
(/)
.Q
«
.003
.002
.001
.000
o 10 20 30 40 50
-
0
02 0.18 mol % .023 E
.022 « I
CO 0.10 mol % c:
.021 «I
.020 t
To obtain true enthalpy add enthalpy «I
.019 ::2:
deviation to enthalpy at saturation.
.018 ~
"0
.017 C)
.016
.015
--
.::.!
C)
.::.!
.014
.~
.013 "0
.012 'E
-
::J
.011 ..c
Q)
.010 ::J
.009 (5
en
.008 .0
.007
«
.006
.005
.004
.003
.002
.001
.000
o 10 20 30 40 50
90
WATER-MARTIAN ATMOSPHERE SYSTEM
1.20 atm pressure
.021
Enthalpy datum: liquid water O.O°C, 0.00603 atm
.020
dry Martian atmosphere O.O°C, 1.00 atm
.019
Martian atmosphere composition: .018
CO 2 93.82 mol %
.017
N2 4.17 mol % e
Q)
.016 ..c
AI 1.73 mol % a.
(/)
.015 0
02 0.18 mol % E
Cii
CO 0.10 mol % .014
c:
«l
.013 :e
«l
To obtain true enthalpy add enthalpy
.012
:2:
deviation to enthalpy at saturation. ~
"0
.011
--
Ol
~
.010 Ol
~
30
.009
~
'C
.008 'E
:::l
20 .007 ..c
Q)
:5
.006 "0
(/)
.0
.005 <X:
10
.004
.003
.002
o .001
.000
o 10 20 30 40 50
80
WATER-MARTIAN ATMOSPHERE SYSTEM
1.50 atm pressure
.008
---C>
..l<:
.007 .~
"'0
·E
::J
.006 .L:
<1>
S
.005 (5
(/)
.0
.004 c:x:
.003
.002
.001
.000
o 10 20 30 40 50
70
WATER-MARTIAN ATMOSPHERE SYSTEM
2.00 atm pressure
-
00
0
02 0.18 mol % E
CO 0.10 mol % .009 ctl
c
ctl
t
To obtain true enthalpy add enthalpy .008 ctl
~
deviation to enthalpy at saturation.
~
"0
.007 0>
.....
.::s:.
C>
.::s:.
.006
~
ii
.005 'E
:::J
.c
<1l
.004 S
'0
00
..c
.003 <t:
.002
o
.001
.000
o 10 20 30 40 50
£
"0
'E
-
.002 :::I
..c
Q)
:::I
(5
en
.0
«
.001
o&m~t::±I:mEmHm~B.ooo 10 20
N-PENTANE-AIR SYSTEM
a
0.8 atm pressure
900 / j ·IJ
. , .,
1
20
I--- r-11
/ --- r--
7
l!..o
..
2.400
2.300
En thalpy datum : liquid water O.O°C, 0.2413 atm ~~
1'-----, 1 /7 2.200
dry air
/ ~ i / : 1-r-- tI- 7
-
O.O°C, 1.00 atm
BOO ~
I- -.!t. / ;; / /
2.100
-
To obtain true enthalpy add enthalpy
:1..: J hL 2.000
----
/ c/o", SPeci
--
dey iation to enthalpy at saturation
-
/
700
/ Af . . I -1-..: t--- /kId. 1.900
1.BOO
..:.'" (rr
\I ai~1
.~' 7 -.::::::: ~
~
/ /J . / / /
...
'to'§.
"I><I~ If-- <11 : J~
/ / /
1.700
I 1.600
" ....
r7 1,500 'ro
/ If rE; --/ / II /
~o
~~/ ~ /
- lL ,: f V- I"----;K- / /
~
.L
"0
'--
.0'
.:S~ 500 ~o )
1.400 C>
e;,~ .:S~
/ / V
/
17 ~
---
-.~
~ -~ /:' /
=:::::: 11 " 1.300
C>
L
~
iY~
~ Cj
~v ~.§
0
/
/ ~: V
/ V [7 ~
<v~ -.r§>
~ ~~ 0' O~ L! / / V /
/
1.200 ~
'5
---
/
~ ....0 1.100 'E
/ / r / : /
/ / :::::J
- -
~
.L 1,000 J::
/ /
/
:/
/ D- r--- I-- / /'
ell
-
.900 :::::J
./ / 7 ;!7 v : I-
7 (5
/ t">.<::>7 / / /' --. (J)
L / ""
./ / . / .'
/ / / /
,800 .c
«
ZL
../ "r ./""'
.700
2
-10./ /
~ '/"'"
./""' A"
../' / V /. ./
/
,., v ......
-
,500
----- -------
- - - -- -
L
--
........- ../ ~
__ I.--" ;;.<-.
-- -----
~ 01_ .........
../ ........... .......
100/..1:"
...--
-
.400
-----
.'
......... ~
...--
----
iou/,
- -- ----
1.20
----
-t:.1J............. "
- -
L. ,300
,/
---
I-""'
L
./
, r-- ~\J
,
- .200
.,L I
.. '
.'
.' ..
o .. ' .100
" ,. '
.'
"
..
, .. . , . ' .000
-30 -20 -10 o 10 20 30
N-PENTANE-AIR SYSTEM
/ - 1----
850
r- -h --- If ;: I
I
1.900
1.800
H- -I-r--
700
jr- ----tf: ----
/ 1.700
/
650
Too btain true enthalpy add enthalpy
/ V :
.~ .
/ r-- ~
'l1 '
~:
?
dey iation to enthalpy at saturation I 1.600
~/--- W ' ,: /
/ / V
-/
1'-
1.500
.~, 550
/ / / --- r--i-r ---I II
~,
~'lj 0 : / 1.400
~,,"'l>~y / / 1</):/
/ I
;:,o"Z --
7.30
--
J.
!c- ' I--r----:- ....
\..'*' 1.300 'iii
/ 7 ~
l§'; ~J I f / ~
"0
Z
vi..'lj '0<::- 1.200
V
t--- / /
f1i :
/ --
C>
~
~ c.:.'lj 400
~
~..j.'lj\..0' [£:'
~ .!o::
2'
/ / 1.100 C>
,YZ
'?-~ ~~ / 'C
/'
- ---
300 ,0 I--- /
.900 'E
- 0/ / / ,V V
I--.
V
/
:
/ ::J
..c
.800 <1l
/- ~ / V ./ v
./ V Va
~ r---:-
"S
"0
zL
.700 (J)
/, / ' / 1/r--- ~
./ : /' ..c
/ ' V ," / «
/ I ~I;)/ / :' .600
-
./ 0 1. /' ........- / 1 V V I
/ / .~ /f/ / - - -K
~
....- .'/
/y
----
.500
-10/
~
....r ~ 7..en
---
~ ....... V
// .....---- r--
---
L -" l---"""""
....--
-
100 1,..- .400
'L" ........... I.............. I........... ..... ~n~ - ..... ~ ,. ' --------
--- ----
- ---
~
..............
L - - ....-- I.--'"' ___
- --- ."-
>< , .300
L -t:..v_ _ 1- I
'Pecif.
5~
---
::><-
---.. 4u
r---
~
I-- r--
I-- ~
~
0
,~ 'It> (f1i
ILkn ...,
YI/ .
Oon
-= .200
.-
.2'.
0
o .. ." 1
." ,
..
.. ,
.100
.. .. .. '
.. .000
-30 -20 -10 o 10 20 30
650
N-PENTANE- AIR SYSTEM
20 .. , 30
1.20 atm pressure .,
It
'
600 1.500
j ~ ~ l.Ja..
-
~ I-- t:--:
Enthalpy datum: liquid water O.O°C, 0.2413 atm ......... / -:-'
L
...-
1.400
- hi
550
!
/
dry air O.O°C, 1.00 atm ~
r-- .... /~
I
1.300
1--!-
500
:f-- r-2::: tb-- r--.
Too blain true enthalpy add enthalpy
dey!.ation to enthalpy at saturation £i ............. / / 1.200
/
V- 1/ i: / F=: "!Yo-
.~,
1.100
o~~ 10-:
~
400 : -
~Q):
~~C; /~ ~S -.......:::... .....
l---i / / 7 -.::::7.- -
--
1.000 .itj
/
~'Z
:
C> : '
~o v,' : ~
~,'1> . O\;'- / 'C
L / V:~ t"-7 7
,900
--- ~ / :
~ ~ N
--
OJ
~~
~
A '1> -co'1~.§(U'
~v ~0
> -ff
~ . - - ~ /
~
OJ
~
-
/
.800
/- /I~V
:--.' W
/
-
~~ :f;)'1> ~1}_ ::---
~ 'It . I / >.
L V
250 6''1> Q0
- ~- ~ 0~
0/
/
/ /
-,,<-
/l / ~
/1
/
V
;><-.......:
~
'''V .700 ' 0
'E
-
::I
2~ /- r........./ -,L. ~ /: ./ £:
./r
7"
.... /
.600
><- ...... -.,. Q)
/
I
./ .2
~I/ / - 1'-::>< --..
1~
: 0
/ / /7' :--......... ./ 0.8s (/)
I
--...... , .500 .n
~ I/ /
./
/ 1 /
/---
t:--- 6 ./ <t:
L -10/
/ / I ~I --> '- /.' I /"1 1----= --.. '
/'
--...... .400
1~ ...<
./ / ~ . /.. ,
......r
:t><-
/ ~
~ ,
,----
50
f I.............. ...--- ..........
~
< ., btU- l~ 1
-- -
-.::v....<
-- -- -- -' --
1'1 Ilr•.
.200
-- -
L. I >< nl'\ 0 --......
L.
-
0:75
---
-l- "
L -<
..
.,'
~
'
...... ,>(i 01. .'
o _.' , .n
.. - .' .100
-,-
.' ..
-" 0
. .
'
.. --
~ ~
,,- -"
I
" " ' • I' "
.' ,., .000
o
'"
.750
.700
...
.650 '(ij
~
"0
.600
--
OJ
.::t:.
.550 OJ
.::t:.
.500 ~
:0
.450 'E:::J
..c:
.400 Q)
~
0
.350 (J)
.c
<t:
.300
.250
.200
.150
.100
.050
I _._
.000
-30 -20 -10 o 10 20 30
320
2.0oatm pressure . , 20 30
280 .700
I ;' j j .) --=::: :::".
Ent halpy datum: liquid water O.O·C, 0.2413 atm 260 r-- L / ~ j
I o " Ii---.:.. ~ !
/ "'" "'/"
.680
,660
--'" ---
n ' '
dry air O.O·C, 1.00 atm .640
240 10 f".-.
.( V /---= ~; / .620
I!- / / / ."'-. r---, ........ .600
Too btain true enthalpy add enthalpy 220 / ~ / V "'-~/ ,'.
.580
/ I V I':Z7' r-..! ; /"-- Ys.?
---
devl ation to enthalpy at saturation
.:(.., 200 ?-. /' / ./ ""-- / :-- ~ ~
,560
flY .540
o~ / I~ ,:-
rI- i§; ' r---. /
""
§( r-- -,L. ~r--.. V
.520
~~~ / /: ;
- -
180 .500
\.."*' / 1--~J / ~ l0: / ~~ /
---
~
.480
• 0<:"-
160 I I:' V-- ~ ~ / V ........... "h- .460
.....
'(ij
~ I :' I :'/
""
-....::
~,;§
• 0<:"- /.,.. ~/ R- )Z ~':So
.v r-- I----V
~ .440 ~
?'li- ~..;§.'l).(V' L ') r--..:- -/-- /. r'" ,: / ...........
:' .420
"C
~~
-""
140 ?'li-
/ L .: )< /;f ,7'-- b-L- ).' /
--
;- OJ
~u ~.s0
--
~~ .400 ~
-
;' .340
100 ~ / ~ V ~ :-- ~ ./v r--- r--.: Y "t!'t,9 '0
-
/ ,/"--- I::x ./
.320 'E
/ / ~~~ V ~
.300 :::J
..c::
80 ~h / /" I'X ~ / ~ r-- k .280 C1>
L"" ~ / ~ ~ .'
~./ 0 .' 7 r-- ~ / .- '5
60 / ' / ' ~~~ ,7 "'-'" ~ h,'L . . . v:-.. - 7" ~ .' Ii - -
.260
.240
'0
V)
r-- -;:
-10/" / /,'7 I'-- K
- -
.0
~I.....x-- . / i"--- ~ ~ «
'---
~ .220
r----: ~ .............
-
2F-7 --, V:-:'" ;/' ~ ~V .......- .. r--- ~ '''C!o;tR
/;::-< p,., ~.. - / ~ ~.-:.: ., ~
.200
,
40
/ ~
- / i"--... ~ r.o-
- - -- -., -- -
~ ..............
.180
V ... ' X r---;:- ~ .':,..... ........--
- -.
/~'..... ~ . ,I .......- ........-- 1 - I~ ~ r-- r---
......-
--::...
.160
....... .. V /"" """ I o'!y:.v
-
20 __ v.~ .----.0 '----
-
~ ~ r---,....:
-
~ ;---
"
.140
- -
-
-2~ .J..><:: .J...7""' ------" ~
~
::ct.o of ?""" . .'::':- c-- ~
~ 10
--
~ .........
--- - - --
.120
-
v I . ':.--
-
~
~.
0 ~
~ ~ "Y iM ::::::0
«
-' -
~.:
.100
- --..
;,v--: ....
I ,~ . ~ -- ""1 :-:- r- ., ~ .............. -..... ''I!<r
-- -
~
-,.- ~ :s::
-=-- .080
1-
r----::: ~ ~- ~ .::;::; .' ~ 1 '-Zi f- "'- ,~r-:- "'"<:;::;: ~" .........
r---- -=-
.:=> 0;'
-
.. "
,.'
.060
- -
..m,
-- -
-20
I--
- ., ' ~ ." ~ ~ !fu;Q' ~
I=:::-:--
- .- -
...r>.
.040
~ =-
.-=... "'-.:
~ -....:..:..:.
~
-::,.", ~
'
.'
-
::::", '
120
N-PENTANE-AIR SYSTEM
30
5.00 atm pressure .260
.250
Enthalpy datum: liquid water O.O·C, 0.2413 atm
.240
dry air O.O·C, 1.00 atm
.230
.150 ~
.140 ~
.130 ~
'6
.120 'E
-
::::l
.110 .c
OJ
.100 ::::l
(5
.090 (f)
.0
.OBO «
.070
.060
.050
.040
.030
.020
-30
.010
.000
-30 -20 -10 o 10 20 30
1400
N-HEXANE-AIR SYSTEM
1300
0.80 atm pressure
2.700
Enthalpy datum: liquid water O.O·C, 0.0597 atm 1200
2.600
dry air O.O·C, 1.00 atm 2.500
1100 ;-~ / ,' / :1 ~ .~
2.400
To obtain true enthalpy add enthalpy
2.300
deviation to enthalpy at saturation
2.200
2.100
-
2.000
1.900 "-
1.800
'co
~
1.700 "0
OJ
1.600 ..l£
"'-
OJ
~
1.500
.700
~
-
.600
t--
--- .500
- - f1:30
r------
.400
.300
.200
.100
.000
o 10 20 30 40 50 60
1000
N- HEXANE- AIRSYS TEM
1.0o atm pressure
50 " ,
60
2.000
/ I/,'
7
:/
-::rF f::- f-f r--
~
900
Enthalpy datum: liquid water O.O°C, 0.0597 atm
;':' I I
V- I-- --..::
7.S0
1.900
-
40
dry air O.O°C, 1.00 atm
hi / -r-- l7-
1.800
-....::::
/
~
800
~ 7 r--
/ l :.-;-1--I----h -- --:::::::
1.700
To obtain true enthalpy add enthalpy
/ ~ :'
-
dey iation to enthalpy at saturation / 1.600
~o~
\...'f.'S.'f.0; 600
- / /
V
~ :~/ /
/
---.:::: [l ;~
~(".?i- . 0<::-
J
/
~ $; / Ikgd,
ail;!
~
r "/ r--::
~ ~ 1.200
""C
F;Z t::---,L: V:
/ / 1/
/
- --
0>
.!o:
L
Q~ eo
-- r-7
C::) / 0>
f§. ~u ~..§ 1.100
<v~'(;' / V .. 1/
/ /
.!o:
- &t§>?i-Qe}?i-_ 30/ / r--. 1.000 ~
Z
400 ~ ,0~
- / / V :: / /
V
71- r--L(I
.900
:0
-E
/ [7 t----:;, f(...... V/ Y --.....:: r;z: :J
30~
L /' ~ ,/y V
../
--i-.
V
/"
i"":;::><.
V
/"
V
./
.800
£.
Q)
::;
(5
.700
/ ./ / 'O~ /., /'
I
V
./
-:~ r-- V
(/)
.0
<C
./
L 20~ 1 /" ./ ./"
.600
I ./ .... () ./ ,.....- ----Ii -.-.-. I--.
/ / ./
~ I 1. 10
2~ ...-
./ ./~ ~ ./'
- --- --
_500
.------
------
/' / .....-V P ......-
----
L ~ / .............- .......
..............
-> :-- f-"' V
---
~ .n 0
L .....-:.. ...- ...- I
.400
- -- - -
...-.-"
--
10
---
--
.....-
~
---
L 1....--- L.----
- --
_. AU
-- -
.300
100
-\LL - I::::::::' ..
L n ;;v ~
.;/
::::: _200
..
-_ . .' .-
-.- .100
.. ' .-
.-
-- --
o -- --
' .. , .
.. .000
o 10 20 30 40 50 60
1.100
1.000 .....
iij
~
.900
u
--
Cl
~
Cl
~
.800
~
::c
.700 ·E
-a
:::l
.c
.600 Q)
:::l
(/)
.500 ..c
«
.400
-- -- IV.8S .300
--,.. ..
- ---.
c-
.200
.100
·OL
---
o .000
o 10 20 30 40 50 60
.~,
'<Y ~I .I V
/ / ~ ::7'r --
49 (
.900
o.~ 400
LI 7" ~!l- I---lL ...........
~ 0. 80
-
q; :
V ,-::
'S-'f-~
\...'*' / ( - bL= t:---..L .~~:/ / r--;:-
.BOO ....
'co
~.§
~
. 0<:'- 350
·o~ / / V ~) r--............ Z- I--- /
- / ~
~
c;,'lf. ~
~.;§ 0O'
c;,'lf. \.
/ /
7-
-T- ~ ~ V ............... /
:-:'--
V"'- .700
'0
Ol
~~~
~'lf.
300 ~v
~ ~
::§0 /~ ~ L [;1' / /
~~ .1/ ......
~
Ol
7-............... o./'s......
~
-
I
.500 .s=
/. ~ /' /'
.::L. /'
V ./' f--.... - t--- : V <1l
: :l
L
L - L / 'O~ ......... t;.< C?'
./ /v
/
.............. .'/ V
......... .400
(5
CI)
.0
150
20/
7:'----, ~ . / 1 1C~V
~.'
----
~
,~
/
-- ---
/' ./ ./
.300
./ ~
R V V k-- I I.··· ....-
-- -
100 ./ ./ V c:; •• ' .............
-
../
~ -- ....-
.--v t--o...:.
--
10 ........... [.....--' ..-
---- K
~
-
.,.. 0/, ....- .;.--
XL .....- ........ .200
----,
<" ~
---- --
L----
-
~ .,
o _' . ....
, ,
. --- .
, - .000
o 10 20 30 40 50 60
440
I~ ~ ---/..
I
.,
50
:,:/
_ ...
~ 1/ -- 60
,800
--- I- r--- ~
En thalpy datum: liquid water O.O·C, 0.0597 atm ~ .750
/ .F
360
~ ~i
~
dry air O.O·C, 1.00 atm 4{
L1'/ V ---~~ K
340 .700
320
/
To obtain true enthalpy add enthalpy J ,650
~ k~ II- r;~
dey iation to enthalpy at saturation r-- bL-
/ t---
.~, 300
flY / ~
/ rsK ~ L t<
~.,.
o~ 280 ,600
~~ 0 bL--r-- K i9C'/~C
I--
· o~
\....'f.'S 260
r- k- b2 ~ V. V ~~ L
r--.. I--
.~ : ~~
b/. /
I--
,550
-....
/
{~ 'Cij
240 · o~ ~~.... /
~:S ~
.0' /
r--
1)'" '7 ,500 ~
~..§
~1-7V K 7
- "7
~~ 220 ~ 1"'<1. ..........
~ ~ ::::--...
"0
~~~
~'lJ'
~v ~0
\....
~ /
i'---.. r-- r-r:r-- ~S'9'
--
Ol
-
3 0 /f ' 5 I'--... t-- ~
~~~'lJ'
- g-
200 ~ ~ .450
~ ~V ,oc::- ./ ,/
V Ol
/
.~ 0''lJ' f-- ~ ~'? ~
-/-
~
~?:Y f$'~
180 ,10 / /
~ I'--::: .400 .~
-
~
160
/
/ f>< V r-- ,so
~
-;7 r£; K :x
/
/'
~~~ /"
V .350
"0
'E
~ r- b4
:::J
IY ~ r--
~ I - - t--
~ t-- ~
-........... I \..(So2 .!:
/ / ~ ~ ~ f-- tx
140 Q)
.~:.
/' ./' 'S
-K
o.~ ~
.300
V ,,'7-'
1
20~V I::X
R r-- r-- r-- I-- '0
..........
kt()~ ~ /
120 /' en
~ ~ ./ t-- .....- ..c
-
~
./' 1.....- ,250 <C
-
./
t........... V
. / l7 K L
k K f-..-. V
k? 4
ole ...........
~f'I
I/' ~
k v .....- I- ~."1'~
Y _
/ / r--../ V ....... V ./
v
-- - --
8~ .200
"
....--
........
~k
-
./ ~ ...............
~O.// ............
~ ::::..
k..c:::::: ~
--- r:::::: f-.
t---........
--- -
l..--"
4ft
..;~ 01 ..-- -<.......:
-
~ I--
--- --
/ ~ .150
---- - 10.....
f-'
- .:> ~
p-;- .". '-" ---I.-
........,
<" -;;;...- f-. t-.......
u --::- ~ .-
........
~.
i
"
190
.190 ~
"0
.180 C>
.170 ~
C>
~
.160
.150 ~
'6
.140 ·E
.130 ::J
.L:
.120 Q)
"S
.110 (5
II)
.100 .D
.090
«
.080
.070
.060
.050
.040
10
.030
.020
o .010
.000
o 10 20 30 40 50 60
-....
.500
.480
b 1/ iJ.;/ :' / ~ "Oil / :
.460 '(ij
/ / -~ L .'/ / "" ."'~ I-- : .440 ~
/ / / /~ ~'--'"- V )' <"to .420
"C
--
OJ
.400 ~
OJ
.380 ~
.360
.260 :5
(5
(/)
.240 .c
.220 ~
.200
.180
.160
.140
.120
.100
.080
- .060
- .040
- ."."\ - IV '
.000
o 10 20 30 40 50 60
300
N-HEPTANE-AlR SYSTEM
60
1.00 atm pressure .540
.280
~
.260 '5
.240
·E
::J
..c:
.220 C1l
"5
.200 "0
(f)
.180 .0
«
.1 60
.140
.120
.100
.080
20 .060
.040
.020
o
.000
o 10 20 30 40 50 60
260
N-HEPTANE-AIR SYSTEM
1.20 atm pressure .460
.400
To obtain true enthalpy add enthalpy .380
deviation to enthalpy at saturation
.360
.340
.320
....
.300 ·cu
~
.280 '0
--
Ol
~
.260 Ol
~
-
.240
>-
100 .220 i5
'E
-
.200 :J
.c
<1>
.180 :J
(5
.160 CJ)
.0
~
.140
.120
.100
.080
.060
.040
.020
o
.000
o 10 20 30 40 50 60
.260
.240 ~
'n;
~
.220 '0
--
0)
~
.200 0)
~
.1BO ~
'0
.160 'E
:J
..c
Q)
.140 'S
0
en
.120 .0
<t:
.100
.OBO
.060
.040
.020
o
.000
o 20 30 40 50 60
N-HEPTANE-AIR SYSTEM
60
2.00 atm pressure .260
.250
Enthalpy datum: liquid water O.O·C, 0 .0151 atm
.240
dry air O.O·C, 1.00 atm
.230
.220
To obtain true enthalpy add enthalpy
deviation to enthalpy at saturation .210
.200
.190
.1S0
.170
-·co....
~
.160 "C
--
0>
.150 ~
.140 ~
.130 .~
"C
.120 ·E
~
-
.110 ..c
50 Q)
.100 ~
(5
.090 (/)
..c
.OSO «
.070
.060
.050
.040
10
.030
.020
.010
.000
o 10 20 30 40 50 60
.085
To obtain true enthalpy add enthalpy
deviation to enthalpy at saturation .080
.075
.070
....
.065 'iii
~
"0
.060 C>
.....C>
~
.055 ~
.050 ~
:.c
.045 'E
::J
..J::
.040 Q)
"S
.035 "0
(f)
.0
.030
«
.025
.020
.015
o .010
.005
.000
o 10 20 30 40 50 60
N-OCTANE-AIR SYSTEM
0.80 atm pressure .250
.240
Enthalpy datum: liquid water O.O·C, 0.0039 atm
.230
dry air O.O·C, 1.00 atm
.220
--
OJ
..l<::
.140 OJ
..l<::
.130
~
.120 '0
.110
'E
-
~
.c
.100 Q)
~
.090 (5
(J)
.0
.OBO c:x:
.070
.060
20 .050
.040
.030
.020
.010
.000
o 10 20 30 40 50 60
140
N-O CTANE-AIR SYSTEM
130 50 60
1.00 atm pressure .200
/ \ II I t'---.: I \ /
'" 1'\ .......
.195
Ent halpy datum: liquid water O.O°C, 0.0039 atm 120 I I IY I',( X .190
I I ·\ / ............ I \ .185
dry air O.O°C, 1.00 atm I I 1\ ,. r--... I .: \ / I I ............ \ .180
110 40L / V r--..: 1\ / ~ .175
Ii'--. 1/\ / 1-7( / \':;',/
.170
Too btain true enthalpy add enthalpy L f r---......; \ / \:--.... ~.
.165
devi ation to enthalpy at saturation .~,
100 /\ / / "-...... / \/ ........... V :\ .160
~ \ I / / [\';-:.... / /\ '----L : \
.155
~<A / "')ol, / .\ ~ \ / .~
,'. V .150
~'f-~ 90 / / /'- 'JZ \ V :'
\..~ /
---....;..
/ X r ~ :'
: ......,
V\ / ..............
)(--..
/
.145
.140
~~
·o~
80
/ \ V i"-.. \ / :
.135
·o~ / / --y.... \ / ~ \.: .........
~-v ~ .130
~t::;, ~.,§ 00' /\ / )'\ V 1\ r--..... / .. \ 7' .125
~\l"\ 70
'C): t::;,'C): \.. / )Z / / :'7 .......
/ \ ~ : \ / .120
§:''C): ~v ~..se / / \ 7"- / C) : y ...... -,< \ / : ............... ./
.115
~~ .~ 0''C): <........ / ~.
\ / ..............\ / )('..
\>-~ ~\l .110
60 ,e 30 / / I'-L \ ./ ~ / / \'---.... . ./ \ ..........
.105
'/ [7 ').<
X '----...... / \ .. ' ............... / \ .100
/ \ /" ...... / \ :><.... / ~ .. \ / ............. \ .095
~
'5
/ 7\ /'" r-./ \:' \ -......,...: \ V ........
50 ~ V "- 'E
/ y... V ~ / ......... Y :x .......
\ ':n
.090
.085
::J
.s::
010 V /t-- ../ ./ ~ \' i"-.. ".-
r-..... )II'
.080 $
40 /<?J~
<..... \ A ." 0\0
7
....... ><:
A ...... 6<:
''"><' \
r\ I ............... /. \ >< ............... \ 1\ ~ \ .075 -8
./ /. ............. .~ . ' / ' V '-.........\ .070
. / /~ 7 ~;.' .,> ;..
(J}
~ ..-/ "-......\. '\--, /
20 / . "><:: ~ '!()~ <....... / .' \ ><...... ' / \ ............., "\~:., , / \ ..... .......... / \ ......... .......
.065 «
.0
30 .060
/ \ ,/ < /
~ /' / ' ><..::....... V
~
7. ~ ,:/\
/ '--\.. / "
><.
............ ~ .
?"--- ....... \
.......... \ .--/
>< ............... ..\~~, ............. .055
/ ;x..; ./' / ~ T"fo --;;:x. ....... /?i --....::..
.050
20 ,.#'. "'\'- ....... ~ ............ ~ -...... .045
~ ><
./'" .><.. /" J?< ....... / .. ~ / ............ \
~ ~~.....
~~ \ >< \ ............... \ } .. ' '-......",.- .040
--
.>< V ~~ 0\.0-% :::><:: ......... ....... .\ ~
10.........-:: 1.><..., ..><... \:> <' . . . >< >- ...... 6..~ .......- ..............
~
.--- .............. \
---- .-"" .035
----
10 .............. ~ \"<i..
--
"-""'--..J ....- ~
->
r-:.:.,'\ ::::> '-..... '3~ ~ .030
-, ------
.........
--
..' ~ .......... .......
\ -..., - : ' -:.:... \ -;: ...............
0
~«:: <"" ....... .....\- ~ -::...- I-- ......... ~ ~ \
>= :..:--
--=:: :-.....
.............. --\.
~
............ . . '
.............. \ ....-
.025
.020
:::> ~ ~ . .. Y ............ r-<' ~ c--
"'<
- \--... '\-"
.....-:! r-:;:. ' ............. ~ ~. ' ............... .'
.. :-, ><c .............. .015
~ ~ t::::-- ~ ::t .x .......... ~ ~ ReWiV'e--lJ! II"" '\--.. ....... ........ \ \ ............ \ 5- -...
.010
~
... ..
0 ....... .. <:-' .......... ............... ~ .......... . . ~o ............ \~ .............. ...... ~ --\c::1 ............. ~
.' ... -....
~
'
. , .,
......... ~ ~ ," " ~ 'r-- 1\ ~...... .......... "--\.:~
.' . i"-.. \ 0 --........... \ ~ ~
.005
.000
o 10 20 30 40 50 60
.095
......
~
C>
~
.090
.085
.080 ->.
'0
'E
.075 :::J
~
.070 Q)
.065 '5
(5
.060 (J)
30 ..0
.055 «
.050
.045
20
.040
.035
.030
.025
.020
.015
.010
.005
.000
o 10 20 30 40 50 60
110
N-OCTANE-AIR SYSTEM
60
1.50 atm pressure .130
.125
Enthalpy datum: liquid water O.O·C, 0.0039 atm
.120
dry air O.O·C, 1.00 atm
.115
80 .110
To obtain true enthalpy add enthalpy
deviation to enthalpy at saturation .105
.100
.095
.090 ..........
'cu
~
.085
~
.080 "0
--
Ol
.075 .::s:
Ol
.070 .::s:
.065 £
"0
.060 'E
::s
.055 .c
Q)
.050 ::s
+-'
0CI)
.045
.0
.040
<t.:
20
.035
.030
.025
.020
.015
.010
.005
.000
o 10 20 30 40 50 60
N-OCTANE-AIR SYSTEM
60
2.00 atm pressure .100
.085
To obtain true enthalpy add enthalpy
deviation to enthalpy at saturation .080
.075
.070
-....
.065 '(ij
~
"0
.060 Cl
.::,(.
"-
.055 Cl
.::,(.
.050
.045
->-
'C
'E
~
..s:::.
.040 Q)
'5
'0
.035 (/)
.0
~
.030
.025
.020
.015
.010
o
.005
.000
o 10 20 30 40 50 60
N-OCTANE-AIR SYSTEM
60
5.00 atm pressure .040
.034
To obtain true enthalpy add enthalpy
deviation to enthalpy at saturation .032
.030
.028
.026
-
..n;...
~
"0
.024 C>
~
.......
.022 C>
~
.020
.018
->.
'5
·E
:::::J
.s:::
.016 Q)
"5
(5
.014 (f)
.0
.012
«
.010
.008
.006
.004
.002
.000
o 10 20 30 40 50 60
500
"
.320
~ r---- ~:.: ';--/
dry air O.O·C, 1.00 atm 400
I '---I ; -r-;L ............
. . . 1.1n
.310
.300
3BO / / ~ : :' ! /"" .290
To obtain true enthalpy add enthalpy 360 / lL I~ :' '-I...... Ii V .2BO
dey iation to enthalpy at saturation / ~ r--., ~ I ~a : / .270
.~,
340
/' ,......,/ I Ci :' V -r- ,..~
/
o~~ 320 / j ....... bL C: :' / / : ,;---::. J:i;; . .260
.250
')~<::t> 300 r----,. V '1k.( : / ~
'f: / / / ~ .
-.:L
~ :; /
.240
.230
O~~ / / / V:- I - - / .iii
~
20£.......... ~. ...............
~ - ~ , r.. . /G .: / r:-.. V
.220
L
~,j.1i- 260 ~o ::::--....... / / .210 ~
~1i- -S 00' / / / -.....,.
;--..., k'
/ / Y ' ..~, .200
'0
OJ
~«\\~ ~~~
~0 - / / / / /
/ -......:::... ~
-§:'1i- 220
'V
~ 0/..;:) /- 1'-...../ V :'/ .......... h.( ./ .190 OJ
.:x
.1BO
<v~ 200
~ -':(-?Y.~~~0' / /'" -....L....... / V
....... ........
V '. .170
,0 / k V :' / / K ·. ./
.160
~
'0
/ V / / /' ::--....-....., V,..:>~ . 'E
~
-...., .1 50
....., /' / [><...... /' './ ~
::J
.c
L
./ .140
/ / X /' /'
/ '.
~ '~/JecJ . ,/
.130 S
C1l
L V
,/ / ............... /' ,/ "
...... / 0(J)
10/ .120
V ,/
V ,/'" ............ ,< '/ L ' ~17~ rJ
L
.0
6~
.070
-- --
'><" 60;!3 .....-- --- ...-- :::-...., .... I.---"
..--. a ............ 1",..- ,/ ,/ ............. .....
....-
~
V -...........:::
.....-- -.. ., <
---
I-:':' . 1..
...-- 4() 0/0
-- --- -- ---
.050
-
40f
j'-...... ~ -..::::
-
I--""
20
zL - .v
;-....
....... -- ,...- ~o/c
-t ..........
:--
......
.040
.030
~v .......... .020
!Y ...... ..........
a
. in 0
He""
' Vt -.... 'V, .010
.000
-10 a 10 20 30 40
380
METHANOL-AIR SYSTEM
-
360
30 40
1.00 atm pressure v .260
340 / ~ / : !
Enthalpy datum: liquid methanol o.ooe, 0.0399 atm 320 II k;. /
.250
.170 '(ij
~
.160 u
C)
.150 -...
~
C)
.140 ~
.130 ~
=0
.120 'E
:::J
.110 .s:::::
(J.l
.100 ::;
'0
.090 CJ)
.0
.080 «
.070
.060
.050
.040
.030
.020
- .010
.000
-10 o 10 20 30 40
300
METHANOL-AIR SYSTEM
40
1.20 atm pressure .200
260
Enthalpy datum: liquid methanol O.O°C, 0 .0399 atm .190
.170
To obtain true enthalpy add enthalpy
deviation to enthalpy at saturation .160
.150
.140
....
.130 '«1
~
"t:l
.120 0>
..::.::
---
0>
.110 ..::.::
>.
.100 ......
'0
.090 'E
::J
.c
.OBO <1l
'S
(5
.070 (f)
..c
.060
«
.050
.040
.030
.020
.010
.000
-10 o 10 20 30 40
280
METHANOL-AIR SYSTEM
260
30 40
1.50 atm pressure .180
.130
.120 ....
'co
~
.110 "0
0)
.:>tt.
---
.100 .:>tt.
0>
.090 .~
"0
.080
·E
-
::I
..c
(])
.070 : :I
(5
If)
.060 .0
<{
.050
.040
20 .030
.020
o .010
.000
-10 o 10 20 30 40
METHANOL-AIR SYSTEM
40
2.00 atm pressure .120
.115
Enthalpy datum: liquid methanol O.O·C, 0.0399 atm
.110
dry air O.O·C, 1.00 atm
.105
To obtain true enthalpy add enthalpy .100
deviation to enthalpy at saturation
.095
.090
.085
.080 -....
·ro
.075 ?:
"C
--
Cl
.070 ..:.::
Cl
.065 ..:.::
>.
.060 .-::
"C
.055 ·E
-
:::J
.050 ~
<D
.045 :::J
0
rn
.040 .0
<2:
.035
.030
.025
.020
.015
o .010
.005
.000
-10 o 10 20 30 40
90
METHANOL-AIR SYSTEM
40
5.00 atm pressure .044
.038
To obtain true enthalpy add enthalpy
.036
deviation to. enthalpy at saturation
.034
.032
.030
.iii
~
.028 ~
"0
.026 en
en
.024 ~ --
~
.022 Z'
is
.020 'E
-
:J
.c
.018 <1l
:J
.016 0
(J)
10 .0
.014 «
.012
.010
.008
.006
.004
-10
.002
.000
-1 0 o 10 20 30 40
/
ETHANOL-AIR SYSTEM
0.8 oatm pressure -:- 50 60
-......; (l.60 .600
650 / / ---~ / .580
liquid ethanol O.O·C, 0.0157 atm / / /. ~ if /
5Z
En thalpy datum: .560
dry air D.O·C, 1.00 atm / '-..... h( 1/ .:1 j 1'-........ ! ~ .540
"'-f.... :' / !:
I I ~ 1.St:- .520
To obtain true enthalpy add enthalpy 550
/ / I 17'- j : L
-......:::..
.500
dey iation to enthalpy at saturation /' h( I L / ~ L
~ :L
.480
#~ .~ II /
40/ il ~ .460
o~
I I / :' L "'-../
/ ~~
.440
~ l-I / / /
~ /
-
,:j
,420
j :
~'t<>Z j
If-. / 1/ ..............
.....
L
~v. .360
;--....
/ r--...
--
i!f : 1/ Cl
~'li
~
~
f§ \.. / 1/ ....... .340
~
-,
.0
.280 15
'E
zL
/ / / 'W-- / / ~ ~ "'-..... ....... / "
.260 ::::l
30/ K.V / /.1;5/ / I'-.. / ,~. :
'/ ::---.. 1.J,..
.240
.s::
-- --
. / >< ....--'" ..............
-. ----
",
.-
~ ,100
.-
--
,;::.:--: I ---
- -
L ....--'" V r><
50 L
L. IV -< !-- .- --
V ...... '
---
"'-:<
"'>< , 'l,O o. .-- ----- ...->,<::..
...........
::>K I
----- ,080
,060
£ I
- I
.--:;, . =-:-:-
vJ[.
. . . .. .. _7 ".
:v .040
f 1
'
I
:--.. ~ ~
' I
, " . . ... .. ...... .020
. ... ' , ' .
I
" , " .000
o 10 20 30 40 50 60
500
E T H A N O L -A IR
SYSTEM 50 60
L I~f!-t-t~ \
.400
1.00 atID pressure 450
/ {{JfI 7 . - .380
Enthalpy datum:
liquid ethanol
O.O°C , 0.0157 atm
O.O°C, 1.00 atID 40 ,- -,
l I] ;~M
""-..l!/
.360
dry air /' \~ [7 :7 7
400
;/ / - .340
To obtain trUe en
thalpy add enthalp .320
deviation to' enthalp y
y at saturation
.30 0
.280
.260
.240
.220
.200 ~
"0
.180 'E
::I
.c.
.160 ~
(5
.140 (f)
- ~
.120
.100
.080
.060
_
- .040
~\
...... \ -.:r~ .020
··· ··· ··· ··. T. -
t=:= .000
o -~
40 50 60
20 30
o 10
Dry bulb tempera
ture CC)
210 Psychrometric charts
460
ETHANOL-AIR SYSTEM 440
Enthalpy datum: liquid ethanol O.O°C, 0.0157 atm 400 / / / .: / / :-r-f ~ .340
I'- / L : / : /
-/
dry air O.O°C, 1.00 atm 380 :'/
~ / / / .320
360 / / ~ -i/.... :
To obtain true enthalpy add enthalpy / / if..... 7 r-- I-+t- I-- .300
dey iation to enthalpy at saturation
320
340
40/
'---,
/
I
/
/:
!
" I~
I !
: /
I
.280
.~, / I I rt:- -./.. ":I.. : /
~<:\ ~ 300 / / L I : / 7-'~ I
.260
I::::",. I / / .: / "'--i
"S-'f.~ 280
/ ...
/ 1~ '--- ~ /
- "~ .9n
-"
\...~ .240
£ /
"A / Ji---:' / /
hL. -..,c
.~
'0<::- 260
::/
-
~~ '0<::- C / ~ :' I .220 -c
~
.v' L /
- /
~:;) 240 ~
/ 0-/ /
~?f Cl
~~
?f t§ \...
0
/ / / / ~V ~ hL... / .200
......
~
Cl
L 5" r--.,.
~
~~~ 220 / /; / "'- ~ 0",_ ./ ~
- IL-.
~
~v ~
<v~
«::-?f ~ ~?f / / / / ? :' V!"c /
-
200 &?f ~0 ~ . .180 .i?:'
~ / / /
1~
- ~ 0~
...:
30/ 7 Y 7
~ .'
/ /
/
~~ - .160
i5
'E
>< :/
lZ
::J
/ ~ ~ / ~ 10'1-"".
-
0 /' £.
/ / / 7 ~ .
/"" /' : " vas: .1 40
Q)
----
--
./ /....-1 "" /'
.../ "< '
60 L
...--- --- ---
/'
.060
.z.
--- ------ ...--- ---- --- "'"
-------
-- - -
...- 0
':x-
...--- ..
,n
...,..?
---- ----
....-
-
lU ......... __ ~
--
40 .-> ..;:;- .........
~ J\ - r- ~
:::::,.
--- -'00 .040
--
I ~
20 "i +- , - .
., A
Ilf .........
.020
o l:=- I
- S -. -.
- .000
o 10 20 30 40 50 60
60
1.50 atm pressure .280
.270
Enthalpy datum: liquid ethanol O.O'C, 0.0157 atm
.260
dry air O.O'C, 1.00 atm
.250
.240
To obtain true enthalpy add enthalpy
.230
deviation to enthalpy at saturation
.220
.210
.200
.190 ....
'Cij
.180
~
.170 "C
OJ
.160 -...
~
OJ
~
.150
.140 ~
:c
.130
'E
~
.120 .!:
Q)
.110
'5
.100 '0
til
.0
.090 «
.080
.070
.060
.050
40 ..r-__
.040
.030
.020
.010
o .000
o 10 20 30 40 50 60
280
ETHANOL-AIR SYSTEM
260
60
2.00 atm pressure .200
240
Enthalpy datum: liquid ethanol O.O·C, 0.0157 atm .190
.150
.140
....
.(ij
.130
~
""C
.120 01
~
.110 01
..l<:
.100 ~
'5
.090 ·E
:::J
.s::
.080 Q>
"S
(5
.070 VI
.0
«
.060
.050
.040
.030
.020
.010
.000
o 10 20 30 40 50 60
ETHANOL-AIR SYSTEM
5.00 atm pressure
.060
.055
-·ro
.....
.050 ~
"C
OJ
.045 ......
.::.!
OJ
.::.!
.040 ~
i5
50 ·E
.035 ::J
.!:
Q)
40
.030 :;
"0
C/)
..c
30 .025 «
.020
.015
.010
.005
.000
o 10 20 30 40 50 60
.230
Enthalpy datum: liquid propanol O.O·C, 0.0276 atm
dry air O.O·C, 1.00 atm 220 .220
.210
To obtain true enthalpy add enthalpy 200 .200
deviation to enthalpy at saturation
.190
.1BO
.170
....
.160 '(ij
.150 ~
"0
--
.140 C>
~
C>
.130 ~
.120 ~
'6
.1 10 'E
:::I
.100 ..c
Q)
:;
.090 (5
(/)
.OBO .n
«
.070
.060
,050
.040
.030
.020
.010
.000
o 10 20 30 40 50 60
N-PROPANOL-AIR SYSTEM
50 60
1.00 atm pressure .200
.150
.140
....
.1 30 'co
~
'0
.120
--
Cl
~
.110 Cl
~
.100 ~
'5
.090 'E
:::I
..c
.OBO .....:::IOJ
(5
.070 (/)
.0
.060
«
.050
.040
.030
.020
.010
o
.000
o 10 20 30 40 50 60
200
N-PROPANOL-AIR SYSTEM
60
1.20 atm pressure .1 70
180
Enthalpy datum: liquid propanol O.O°C, 0.0276 atm .1 60
dry air O.O°C, 1.00 atm
160 .150
.120
-
.110 'iii
'-
~
-C
--
.100 ..:.::
OJ
OJ
..:.::
.090
~
.080 -c
'E:::::J
-
..c
.070 Q)
:::::J
60 (5
.060 CJl
.c
<X:
.050
40
.040
.030
.020
.010
o
.000
o 10 20 30 40 50 60
180
N-PROPANOL-AIR SYSTEM
60
1.50 atm pressure 160 .140
-·ro...
.100
.090
~
"0
C)
.080 .......
~
C)
~
.070 C
'i5
·E
:::J
60 .060 .c
(l)
:J
.050 "0
CJl
.0
40
<
.040
.030
.020
.010
o
.000
o 10 20 30 40 50 60
140
N-PROPANOL-AIR SYSTEM
130
60
2.00 atm pressure .100
120
Enthalpy datum: liquid propanol O.O·C, 0.0276 atm .095
.085
To obtain true enthalpy add enthalpy
deviation to enthalpy at saturation .080
.075
.070
....
.ctj
.065
~
"0
.060 0>
~
.055 ---0>
~
.050 ?:-
'5
50 .045 ·E
:::J
.L:
.040 Q)
"5
(5
.035 C/)
.0
~
.030
.025
20
.020
.015
.010
.005
.000
o 10 20 30 40 50 60
N-PROPANOL-AIR SYSTEM
60
5.00 atm pressure .040
.034
To obtain true enthalpy add enthalpy
deviation to enthalpy at saturation .032
.030
.028
~
.(ij
.026
~
"0
.024 C>
~
.......
.022 C>
~
.020 .~
"0
.018 ·E
-
::::l
..c
.016 Q)
::::l
(5
.014 (/)
.c
<t:
.012
.010
.008
.006
.004
.002
.000
o 10 20 30 40 50 60
N-BUTANOL-AIR SYSTEM
60
0.80 atm pressure 1.100
.950
To obtain true enthalpy add enthalpy
.900
deviation to enthalpy at saturation
.850
.800
.750 ~
.(ij
.700 ~
"0
.650 0)
.::.!
.......
.600 ~
.550 ~
'C
.500 ·E
:::J
..c
.450 Q.l
:5
.400 "0
(J)
..c
.350 <C
.300
20 .250
.200
.150
.100
.050
o
.000
o 10 20 30 40 50 60
N-BUTANOL-AIR SYSTEM
60
1.00 atm pressure .080
.060
.055
.....
'iii
.050 ~
-0
--
01
~
.045 01
~
.040 ~
'5
40 'E
.035
-
::J
.c
\l)
::J
.030 (5
C/)
.0
.025 «
.020
.015
.010
.005
.000
o 10 20 30 40 50 60
N-BUTANOL-AlR SYSTEM
60
1.20 atm pressure .064
.062
Enthalpy datum: liquid butanol O.O°C, 0.00122 atm .060
dry air O.O°C, 1.00 atm .058
.056
To obtain true enthalpy add enthalpy .054
deviation to enthalpy at saturation .052
.050
.048
.046
.044
'-
.042 'cu
.040 ~
-
-0
.038 Cl
.:::.!
.036
~
-
.034
.032 >.
.030 ii
.028
'E
:::J
..c
.026 Q)
.024 :l
(5
.022 (/)
.0
.020 «
.018
.016
.014
.012
.010
.008
.006
.004
.002
.000
o 10 20 30 40 50 60
N-BUTANOL-AIR SYSTEM
1.50 atm pressure
.054
Enthalpy datum: liquid butanol O.O°C, 0.00122 atm
.052
dry air O.O°C, 1.00 atm
.050
.048
To obtain true enthalpy add enthalpy
.046
deviation to enthalpy at saturation
.044
.042
.040
.038 .....
'(ij
.036
~
.034 "'C
OJ
.032 ~
OJ
.!o::
.030
.028 £'
.026 'E
"'C
.024 .E
.022 2::J
.020 "£
.c
.018 «
.016
.014
.012
.010
.008
.006
.004
.002
.000
o 10 20 30 40 50 60
N-BUTANOL-AIR SYSTEM
2.00 atm pressure .040
.034
To obtain true enthalpy add enthalpy
deviation to enthalpy at saturation .032
.030
.028
...
.026 '(ij
~
'0
.024 Cl
~
.022 ---
Cl
~
,020 .~
'0
.018 'E
::J
£
.016 Q)
'5
(5
.014 (/)
.c
.012
<
.010
.008
.006
.004
.002
.000
o 10 20 30 40 50 60
N-BUTANOL-AIR SYSTEM
5.00 atm pressure
Enthalpy datum: liquid butanol O,O°C, 0.00122 atm 50 11\ / 1 1\ / \ II
\6~O" "i./1o;-i\5"'- +0'"- "
,-;-.---'j- -!;-o--r
.// \ /' ..-.f-..............
\ /_ : ..................
Y :'
\ ...............
X'
~60 _016
.015
dry air / 'v / I X 1\ : 1\
4 I V I X I 1\ / il .014
/ V \ II \ I .. \ I \
To obtain true enthalpy add enthalpy
/ 1\ / 1 / \ I Y V \
deviation to enthalpy at saturation 40 I ;:, II j 1\ II \ / \ V .013
/f--tf-\\-/I'-l--4¥-\---+-j+-tr~----.l/L-+\4-:':-, j*-\\--l---!--'
jA-J:
\
j~
!\-IM--J\¥+-411++-\--111--+ 1\-++j------l,l--;/++----\.j- -hL----..It ,012
j 'X 1/ \ j
X v\ \ \ 1/
/ / \/ 11\ 1/ \ 1/ \ 1/: \ ;\
.011
...
'(ij
/ 1\1/ /\ 1/ \ 'll \11:' \ 7 \
J Rll>'\ V \V .x 11\ ;, :f;' :' \ r7 \
.010 ~
"'C
Ol
~O~ I 17 V / \ / \ / ~ .. ) .009 0,
.:::.::.
~f=t~lt.=--~fi\-:::~~~~\~~h\=~~\H~lE:-r~i~~\E-~-t±\ttJ\Ot~\.f-
m\' I'
" . .' , .'
t1I Cl \ ~t-j\
\1\ I
-, mP[\tj\t:C\stiP[
\Ul \ \
. .
t±~\iI?' =t\Ij,"::J
\ : [\d=\
\ V , . '.
~ .001
.000
o 10 20 30 40 50 60
--
OJ
.800 ~
OJ
~
.750
.700 ~
:0
.650 'E
::::J
.600 .s::
1.4n
"/
.550
.500
Q)
-
.2
0
rJJ
.0
./
.450 <
-I--
.... ./"
"7 -====r--
V
1.30
.400
.350
v '.
..--:--
".
'"
..... . .300
-- --- -- ---- -
.250
.200
- --
.150
:::: .100
.050
.000
o 40
20 30
o 10
-10
Dry bulb temperature CC)
psychrometric charts
227
,/
650
A C ET O N E- A lR SYSTEM
1.0oatrn pressure
30 40
1 - -; / -/
;7 7 ---- R7& .
1.000
/ / -j.[I
.850
To obtain true enthalpy add enthalpy II
- \----L
dey iation to enthalpy at saturation
: -/ - : 7 .800
I- - / f7Z- ~V
~/
~
' . ' "
0(;\ t--.
.750
~~/ / / ~~ r--.L
:j
~
7rt
/
V
.700
~• 0(:-
20 /
J
7 1/ "'---...
J ~: I--. "
....
'co
~~L / 7 / N~ --
~ .650
7 t::::::-- -
~<:j ~..§#(u
'" 1/ /
1. 15 ~
.L
~ .600 "0
~
~~~ ~u ~..§0
c,~
/- f-/ ..! V
7
/ !
/ ~ ~iflPvow:'
/ r. 3 /' .550 ~
~
""-
'$)~
?s~ Q0f.,.,~ - ~t- -.J V V =~
?/
<V<:::'- /
~'t' .l ' / / / / ~
. -r ..t· 10
-/ .500
/ ..,. ,/ V
/ 'r:==--:.~
:"'- 0;:;:: ~
'0
250 / / / . .450 'E
/ / 7 7 1/ "'-
i-- -.. /
/
-
:::J
~f- -- / 1/ ~
-
/.. ./
.400
10 ./ V
Q)
20~
/
/ /'
V
1/ ~~
/"
./ ~ 0
:::J
L
./ /"
.35 0 en
/:
/ f t'. 1/
~ /
-; /' ~
r- . V V 1/
7" --
I --::,..2
/" .c
<{
159L ./ "
v .30 0
. /F = - ~ V
/' V =...
~~ / t- -
L ./
v
I ............ ../
V '.
.. '.
1.00
.250
109 L L 0 ./
./ V J5Y' ~ \< - ~ "/
\~ f: -- j/"
[..../ I ~ nO -s; -- --I .....-- v ",
..
---
y"' --. .. v :::><....t-- - .200
L ./
l.,...---"" I \..---'"" L:::>< I- -
----
--
f,O% V --------
I
----
"........ n
L
---- .....-- -.><:
-
--~ !--' " n,
---
---- ----
l.-'-
...--
~ \ '--
.J" r:=--
"<T
.150
J.--- ..... ---- --""" r:-=-...:
----
~ I
50 L.
--
- 'V~
-~
-
~ -- I-- L..- -'"
I...-- ~O"""Tc
l.- ;.- - .100
I
-
i-
~v
F:: ::
-F --
nn
-vt 7 .050
o I · UQ
\
.000
o
"
-10 10 20 30 40
360
A CETONE-AIR SYSTEM
340 30 40
1.50 atm pressure
- I:
.560
320 / ~ V K 1/
.540
E nthalpy datum: liquid acetone O.O°C, 0.1249 atm / ,/,' ~( ;~. -~.L
:7 ~
.......::'. ,,-;
.520
dry air O.O°C, 1.00 atm 300 £; ~~.: / ~ ~i> I .500
2BO / ~~ :-j-.:--;. ~ 9:"1> .4BO
To obtain true enthalpy add enthalpy / /~ .... /~ / / ,' ~rLl'I
' ~
/
.460
de viation to enthalpy at saturation
'f..'
1l- 260 J ~ ~ :' / c : I/'---.-. "? :' c; /'
c<A / / >::~ 1/ 7f-- hiZ:: t-.. . " /
.440
.420
~~
\...'*"~
240 20/
f--. / j~.:. / ~ k{ ;:
'~ 1'--: .400
·o~ 220 / "7< ~,
~ f!.-, ,V / : ~o .
.3BO .-..
....
-§~ ·o~ / ~~ V V '-.....- tr- r-:-- .iii
e:,t§- 200
t§
;§''If
~
.0'
\... A / 1
f--
-7- / :/ ~
~.
/
.360
~
~
p:::=
~ "C
e:, 0 r-- .340
~~~ / ~ / :: V
"/ I'----. :::i>< G.R.
-
~v ~.;§
--
r- C>
l BO
. (§> ro,"lf .320 ~
<v~'(;'
/ / lL:: b< V .. ~
-
C>
~~ ~~ / -x: .300 ~
160
7~ lL :/ ........
h« : "':::
---L
- /
,0 ~
-
:l
.240 ..c
L - /
-
./
/ :V --- I'---.. V 1----' l/"--.......
/ ./ x Q)
:7 ><
.220
, 01. , /
o.\; / .JL" V / -........
./"
/' "
>< .2
~
.200 0
-
/ './
/' ..--/ ~,
/ ~. (/)
""7' '~~ V ]/" "-- "'O,R_ .0
/'
V V
-.......:
..--/ b-.-,...
;>4..
........ ../ .1BO «
>< 1 ./ ~
./
/~
"
80 ./ ;:...
"'" -
-
./
0 10
.160
o~;:...
V V 7 ~
../
L..---- ~ .. ~ ... ;:...-,..c:::. ~ .... .
k-
~
........, V .140
--- P '><
---
-
V I~ ~ '.
--- r--....
--
' "
V
----
.~
~
.120
L K L.--"
~ ....:::::- '-
t---...- ~
........
r----.. ~ .. .. .. ~. ........ U.6<
:--
-
..,...:;;;; ....
---
.. .. .100
E:<
- .- -
'"
..---"
~
-
'
40~ -............::
-- --
-lu I-- f--
- --
.OBO
-
F-- c.--
---
?i5. -""':::r--.. r---...: b:--
20 I -- --"
f--
1- I
:::,..
20 u/~ ............ - i.---
.060
-
, '-.. ....... --.......::: ~
.040
f:>......" nur ........ - -.
- r---
~"l"tiwe
o , ~
.020
I=:- I , ,
. ,
t-- -...:::::: ' ·V<j. ::-----.. U.SR t----...~r(1
.000
-10 o 10 20 30 40
30 40
2.00 atm pressure .400
.340
To obtain true enthalpy add enthalpy
deviation to enthalpy at saturation .320
.300
.2BO
-...
.260 .(ij
~
"0
.240 OJ
.....
.:>t!
OJ
.220 .:>t!
.200 ~
'6
.1BO ·e
::J
~
.160 Q.l
5
(5
.140 II)
.0
~
.120
.100
.OBO
20 .... .060
.040
o .020
.000
·10 o 10 20 30 40
ACETONE-AIR SYSTEM
30
5.00 atm pressure
.120
.110
-...
'(ij
.1 00 ~
-0
--
C>
.:.t:
.090 C>
.:.t:
.080 .....
>.
'0
.070
'E:::::l
30 ..c
.....
Q)
.060 .2
0
(j)
.0
<{
.050
.040
.030
o
.020
tar .010
-10
.. .000
-10 o 10 20 30 40
-
;
dry air O.O' C, 1.00 atm
--J
: " 7.000
.~' / l :
:
6.000
/ It
~
0<:\ . ~o
/ -....
i--'
~~
: "-- 'l Cn
5.500
.. -
'*:;)
\..
/ / 'j 'n;
:?
--, 5.000 ~
:/ '. I'. U>~ "C
~
/ 7
;-.. OJ
~
~Cj ~ 4.500 ~
/ / -
~o '. J.UU OJ
..:.::
~«4.q,:
-
:/
/
250 ~'b' .C)\
~ \.. 4.000 >-
Cj III
/ ",
~CJ ~.;§ '0
':5)q,: t..,q,:
&-q,: ~0
) /
/ 3.500
'E
-
::J
/ / 1/ V 2.50' .c:
<:f ....1lI~ - <1>
'. · ~qn
/ / / 3.000 ::J
7/ / V '0
40/
,/
/ .....
2.500 «
en
.0
./ / V / /. I" 2.00
/ ./ ,,(\ D~ V /
/'
/" ,./ 2.000
109¥ ./ ./ "C\ °/~ V ./
V V ~ ,halbt
-
./
/ .L :::-- ./" 1.500
- -
~ !.---'" "'~/~I -10
;/' V
- ---
~----
--
~ '~
V r.ov
---
-
-----
-
:/
-----
,~n Dfe ~
1.000
!;on? , ""
'" :-- "
~ ~
;y
.500
~, B ~ ~ ~ ~ .000
40 50 60 70
20 30
/ I :
2.400
En thalpy datum : liquid acetone O.O°C, 0.1249 atm
L II
I
: j i L
dry air O.O°C, 1.00 atm 1400
/ -j
I / / ;; / ",
2.300
2.200
f
:7 / : /
~" ~
2.100
To obtain true enthalpy add enthalpy
de viation to enthalpy at saturation
f I-- li :/ / /
/ "
2.000
0(;\?} / / /' t - -he : ~peciflr. "n 1.900
)~O;/ J
/ 1/:' V :
/ ~ ~~ajr
1.?n ' 1.800
/ 1/
/ / -
~
\..~ : ". -:,""
/
1.700 .....
~o<::- 1000
~.:}"-/ - / / 1/ V / ' / 1.600
'(ij
,§1f;,0<>
~
~?} • c)\
/ l7 / /
i7 ~
"
..,"
~ \.. 1.500
~"'o~
t<::-1f r§- t§",<!'
/ / [7 .. V / '. V 1.400 --
~
C>
/ ,0 / /
7
I
17
/ v-+-
I
I-- .L
1.200 '6
~
/ / V l7 V /'
r-
/'
1.00
1.100 .~
~ / 'Yo
"
n.f;)yY / V /'
/' / ~
1.000 Q)
/' ./ /
/'
V
./
/'
/ : V / .900 (5
'5
/ '7 .,/ V V
_"v~ (/)
/"" /' / ./
.800
.0
<{
L 30/ / Y 1~ ' - -
/' / ../
V.
./V ~
---
40~ v -,;:;.:::::: .700
./'" ./'" v ......-I v
I~ _" 010 ~ I
/
./' ../
.--
------
I
.600
/' ./ ./' ~ j.....'/'
.-V v- I nRn
--- ---
/L.::u
---
......
---
" . 1::
.500
r-"'\.
--
--- -----
-----
-- - -
---
;;.-
____ J..,..-- I ..-v " : :I-!( PeViat;,
- -
I
----
/ I I--
:::::.--- ·v :.tii1h .400
I--' Al
!-- -- .. _--- .' l1rv- ai;!
200 "-
-- .. .300
I '"
"
I
.200
I
.100
'. 70
.000
20 30 40 50 60
AC ET ON E-A IR SYSTEM
2.00 atm pressure
Enthalpy datum: liquid acetone O.O°C, 0.1249 atm
dry air O.O°C, 1.00 atm
1.000 -
.~
~
.900 -0
~
.BOO
~
/" .600
-
O.Rn
.500
.400
~
- -- --
- _ f--
o
-I--
- -I--
I
-.:= ..
~ .
• '<T
.200
.100
.000
20 30 40 50 60 70
360
ACETONE- AIR SYSTEM
340
0
5.00 atm pressure .4BO
320
.460
Enthalpy datum: liquid acetone O.O°C, 0.1249 atm
300 .440
dry air O.O°C, 1.00 atm
.420
2BO
To obtain true enthalpy add enthalpy .400
deviation to enthalpy at saturation .3BO
.360
-
.340
.320 ..(ij
....
.300 ~
"0
OJ
.2BO
1BO
......
.::I:.
OJ
.260 .::I:.
-
:J
.200 ..c
Q)
.1BO :J
(5
(/)
.160 .c
<t:
.140
.120
.100
.OBO
f--.
.-- =--±: --=1- -r--- _ - .... .-:::-- - .060
:;,. ____-+ _ -
I-- I-- ?r VIc -
40 r-- ......... .040
f- -1() ~ -Reo< hllmlditY ·.. - I ........ -r":":'---'~--I-__ (
.020
l-
_~
1 -+-1'- ()
'i-.
y .+-
I ... ...
I
I
1'"---- . 7 n - -
I ........ "~
i--
.. .000
20 30 40 50 60 70
800
BENZENE-AIR SYSTEM
750
~ 50 ., . A-. -:-;-,.- 70
0.80 atm pressure 1.600
700 / / --:-- -I--. :/ : / '. --~
~ 1.550
Enthalpy datum: liquid benzene 25.0·C, 0.1249 atm i " /'. f
/ 17-r-;:-,L~___I-L 1.500
dry air 25 .0·C, 1.00 atm 650 1.450
f- I :/ I : 1.400
600
/ 11---,11 / : / 1.350
To obtain true enthalpy add enthalpy
deviation to enthalpy at saturation
/ V / ~ 1.300
", / / ',' 0
:; ---I-:- 7
1.250
1.200
/: -----!/\ 1.150
', 1 / / ~ 1.70
1.100
/ / ....
1.050 '(ij
\'A-- / . 1.000 ~
::::-- ./ '0
.950 C>
/
1/
/ .900 C>
.850
--
.!o::
.!o::
/ /
.800 ~
'. / /'t::--- .750 :0
/ .... V 'E
.700 :::J
-
"1,{ ~~ 1.50 £
.650 Q)
/ .600 . 2
--:--.., ;;- ' ' . .~ 0
.550 .0
,/ ---- ......... .. ... V
rJl
.500 «
.450
.400
.350
'? "":- .300
... I.....? .. . :~ .... ... .... .. .. .. .. -.-.:.;
-- -
CIII"
.250
.100
o .050
.000
10 20 30 40 50 60 70
4250
3750
: '. .. r--~ ~
Enthalpy datum : liquid benzene 25.0·C, 0.1249 atm r-- ~ 7.600
/ /
7e1 :
3500 ~ ~ me (IT 3/ka d
+-
dry air 25.0·C, 1.00 atm : "
7.200
/ /
-
~.
--:- "--
~
r-- f-. - 6.800
- 17- r--
~
-
3250
J- / I :
To obtain true enthalpy add enthalpy r-- ~
dey iation to enthalpy at saturation --.:.:...'-- 3.50
I --
.~' 3000 '. 6.400
-
~ \-- f -
~ / / .... ',j~
. 6.000
~
:/
7
/ .- 5.600
~
-F --= 4--
.. ..~.25
-J / \ 1'-- f-
:;
/ I
'.
". '.r--
1
~o
~ \.:2500
~ I 5.200 '(ij
~
-I-
" n,
/ 1 -l
~flj ~o
• 'U
"
". '0 ~
11 /
\....
I
l\.
--
Cl
flj Cj ~0 / / ". 2.75 .::.!
~~--\2000 ~v ~ 4.400 Cl
/ 7-
~flj 'S)flj ~flj .::.!
/ /
'" ~ ~ '"
~. .rtf Q0
'.;>,
4.000
l-
~
'f .....o
I I
. ,-,:
1750 :/ 2.50 '6
J 1 / I 3.600 'E
7 7 / :
/ / ::J
/ .s=
15 / / I., .,,,
3.200 (])
60 L 7 7 / 1
:;
125~ / --v
2.800
'0
7
en
/ 1
/
/'
/ / ./
/:;
/' I "'.uu
..c
<C
1 0 // /' I /' 7' 7' .. / 2.400
'Z 50 /' ./
....... 1.600
-- -
.7
-
..........- ,./ ,./' .......... I .-- ............ t .......
-J. .""': lat/on -1fl
-.
--
500 L L """"""-1 , . / I 1.200
.-
---
- - -- -
- I ,;.0 .. .'-. -..
- -
/ In
Q/c I -'." . -.. ..
.800
!.-- 30°;' ~=
250 I-- ~ ?n °
."'.,
.400
10 Ofc Raja iva hl miditJ
I .
.. I
,~
.000
40 50 60 70 80 90 100
700
BENZENE-AIR SYSTEM
650 0
1.00 atm pressure 1.400
1.350
Enthalpy datum: liquid benzene 25.0°C, 0.1249 atm 600
1.300
dry air 25.0°C, 1.00 atm
1.250
550
1.200
To obtain true enthalpy add enthalpy
1.150
deviation to enthalpy at saturation
1.100
1.050
1.000
.950 ....
.900
·co
~
.850 ""C
OJ
.800 .::s:
""-
OJ
.750 .::s:
.700 ~
>-
""C
.650 ·E
;:,
.600 .!:
11~
.550 2
.. r-::::: .2
.500 0
(/)
.0
..,/'/
.450 «
.400
[.:.:-/. r::-:-,. .,.;!!
.350
.300
.250
.200
.150
o . . .... . . . .. .. . .-........., •.... . . ro\"
.100
I =::::
.. .... ... ~ . .... .
.050
.000
10 20 30 40 50 60 70
BENZENE-AIR SYSTEM
200£ ' 80 . ,. 90 100
1.50 atm pressure
- 2.400
2.200
f
2.000
r--:=::.
')n
'.-
1.800
1.600
1.400
··.'~?11
10n _ -
7i1\ 1.200
1.000
....:--. . IrJ~
r
.-J..- ..... ':'!f
--- --
'i~l
-
.800
'. '.
..
200
-
-- I
I
- ~ e- -
- f.--- i----
-I-""
~
_
-f.---~
. /.
I
]ID" '
.600
.400
- I ic t el ~(lve
lU V
.200
, ,
f"I ~f"I I
I I I ,000
40 50 60 70 80 90 100
420
-
.'
-j---f. :
25 .0·C, 0.1249 atm
360 / V / 1----;" / : /
En thalpy datum : liquid benzene / / ! . 7- -.;...:::::: ~ V .760
340
dry air 25.0·C, 1.00 atm L / Vi : / " 1--.- r.-,L "
.720
hL / / : / .......... . .:. / --..;
-
320 1 - .'
L 7 r.-- h( :/ V: . . . . . . .6BO
To obtain true enthalpy add enthalpy / "'::z / f.-- / :
"
-
300 ORr>
dey iation to enthalpy at saturation .~~' '-- / ~j / / r- r-:- "'")<
o~ 2BO / -nc ':::".. .' / / : r- .640
~~ / / 1/ .......... iL. /
rr- I-- ,-
-
.600
\...'f.~ 260 '-. / / :/ ,/ /
-r-
-
/ r-- / / P.'-;-
" ........ -/'. /
-
. 0<:- 240 .560
'0<:- ~/ / V / : / ". ""0 --.
-
~ ~
....
~v, ~ '- / / : / ~
V '(ij
~.j.'lf (v' ?- :::::::::; '-. :
~
.520
~~'lf 220 i ' .... / V .........
.... 7 --:..
-
~
A'lf ' v~'lf ~0 / r / 7" --...., / 1 / .............. '0
--
'8-~ 200 .4BO
V .... k
- -
~ ~v. ""-'" / V / ~ Cl
-
')<. /
-
I ~S Cl
,?-lS ~~ 7 -"L.. .440
/ / / 7 / "
~
"
/'
.....0 / 7 7- -L V
~
~ V
.v .v .400 >-
r--
- -
"
/ ""-- .L /
7'"" f::-- .t:
7- -.:.:.::.. ::z r--
-
'0
/ / ./' ~ L /' " .
.360 'E
~~ "---- -L V . . . . . .I ./
~
I
-
r:.:..
~
--
V / /' ::J
30
'L' ~ ......:;7 ./ r-- V / . "
-.:::"., -:F~ ,/
~ i--
.c
.v1'0,7 .v
--
.320 Q)
/ / / ' ; - - h.L ;>< ........ V(
'/u":'
--
~ol.,. ::J
/' /' -......../ /'
./ ~ ................. '<:! t0J.1/J ./" .2BO (5
100 ./ .v / °lg. 7' ---.. ......... ,./ ... "·0
"" n. .
en
""
--- - 1- ,
.r. ........- ~
.0
/ / ./ :;--' / -.....:::: ""- ,/"" ? -......::.,r, <t:
:0
.240
B~ / ./"
,/
'7
/
"../ r" 010 /
:..:::---
./
/
>< ,./ ""--- ......... '.
......... v
--
20./" ~ ~
-
'.
.200
~ Z T
60 ~ ./
7 1 ,"" ......
..-'
:---.......... .........
--
./
...--
...---- .......... --'
...... ;.--
........- ........- I
-
~ ~ .........
~ ---
.160
- - -
........- .....-r
-
AQ °/~ :?:<...
.........
---- ---.
-
...........
- --,
~
'--. IU - .120
:-3.\L Entha
. .. . _- Ipyde
._ -- vialic
~
20 .- .,. - - ... .. ----- .:.:.:.:.:.:
. 0 ___ -
:..:!....
.- . -- - .. 0. ' · ' -
-...:..:..'
- -.~ . . . ~ -- . -. . J. __ . -.,- . . .OBO
--
.... - .. ." .. . . - -....;:: - ..............
o - . -.-- .. j ..... Onl~
__ 0-
Ive
.. , .. . -- -- I
T
-- ' 0 __ -
- .00 . _.
.• (J.~ ...
.040
........
i-- . ...
, , ' ,
I
.... , . ... '
.."V
" ,000
10 20 30 40 50 60 70
Cl
~
1.300
>.
......
1.200 '6
1.100
'E
::J
..s::::::
1.000 Q,)
'S
,900 0(f)
..c
.BOO «
,700
I~_ 1-. __ """"""-1 , I
-
.600
I
--r ---- I -~....:::::: 1"-
.500
- I 1 -- I
..- I 1- - ' •. ut::v/. . :>-<'--. iO-Rn
.400
--
I . ...,.... I --,
I _-- .-
-- I I ~
.300
100
i_- --r-
I -- I ~
-~~"o .200
I T e .100
I 0.50
1 I .000
40 50 60 70 BO 90 100
260
BENZENE-AIR SYSTEM
70
2.00 atm pressure .500
.480
Enthalpy datum: liquid benzene 25.0°C, 0.1249 atm
.460
dry air 25.0°C, 1.00 atm
.440
.380
.360
.340 ....
'iii
.320
~
-c
.300 OJ
~
""-
.280 OJ
~
. .260
100
~
.240 '6
.220
'E::J
..c
.200 Q)
.180
:20
rfJ
.c
. . 160 ~
.140
.120
,100
20
,060
o
.040
,020
2,Q ...... .
,000
10 20 30 40 50 60 70
BENZENE-AIR SYSTEM
100
5.00 atm pressure .680
.480
~
.(ij
.440
~
"0
--
.400 ~
01
01
~
.360
Z.
.320 '0
·E
::J
..c
.280 Q)
"5
.240 0(/)
.0
<t
.200
.160
.120
60
I
.080
40
.040
20
..
.000
40 50 60 70 80 90 100
120
BENZENE-AIR SYSTEM
70
5.00 atm pressure .200
.170
To obtain true enthalpy add enthalpy
deviation to enthalpy at saturation .160
.150
.140
.....
.130 ·CO
~
"0
.120 OJ
~
.110 OJ
..l<::
40
.100 ~
'5
.090 ·E
=s
.J::.
20 .080 Q)
......
:::J
.070
a00
..c
«
.060
.050
.040
.030
-10
.020
.010
.000
10 20 30 40 50 60 70
170
TOLUENE-AIR SYSTEM
0.80 atm pressure
.270
Enthalpy datum: liquid toluene O.OT, 0.00893 atm
.260
dry air O.O°C, 1.00 atm
.250
130 .240
To obtain true enthalpy add enthalpy
. .230
deviation to enthalpy at saturation
.220
.210
:
.200
.190 '-
.iij
.180
~
.170 ""0
Ol
.160 .?!:
Ol
.150 x
.140 ~
'6
.130 ·E
:::J
.120 .J::
Q.l
.110
:5
.100 (5
en
..c
.090 «
.080
.070
.060
.050
.040
10 .030
.020
.010
.000
o 20 30 40 50
-
.850
.800 >.
.750 '6
.700
'E::J
..c
.650 Q)
.600 .20
.550 (/)
.0
.500 <
.450
-
.400
--- !..---""'"
-- .350
--
-.::::: I .300
I
'----
_ 1, .- . .
-..: .250
I
-
= I I -.. - I
.200
.150
1
I
.. .100
'"
"
.. I
'" . .. ..
.000
60 70 80 90
TOLUENE-AIR SYSTEM
50
1.00 atm pressure .220
.160
.150 ....
'(ij
.140
~
'0
. .130 Cl
-...
~
Cl
.120 ~
.110 ~
"C
.100 'E
::l
.r::.
.090
.....
Q)
::l
.OBO (5
UJ
.0
.070 <C
.060
.050
.040
10 .030
.020
.010
.000
o 10 20 30 40 50
70 80
1.00 atm pressure 650
1.150
Enthalpy datum: liquid toluene O.O°C, 0.00893 atm
600 1.100
dry air O.O°C, 1.00 atm
1.050
550
To obtain true enthalpy add enthalpy 1.000
deviation to enthalpy at saturation
.950
.900
.850
-
.800 '(5~
.750 ~
"0
--
C>
.700 .:.::
C>
.650 .:.::
.600 ;::.
'5
.550 'E::J
.500 ..c
Q)
.450 ::;
"0
(/)
.400 .0
<{
.350
.300
.1n
--::::: .250
.200
--....: ' .''''Cit; lin I
.150
<;...
.100
50
, I
-- I :
.050
"
30 40 50 60 70 80
TOLUENE-AIR SYSTEM
120
1.20 atm pressure
Enthalpy datum: liquid toluene O.O·C, 0.00893 atm
dry air O.O·C, 1.00 atm
- .130
.120 "-
'co
~
.110 "0
OJ
......
~
. 100 ~
OJ
.090 Z.
'5
.080 'E
::J
..c
Q)
.070 "5
0(f)
.060 .0
~
.050
20
.040
10 .030
.020
.010
o
.000
o 10 20 30 40 50
600
TOLUENE-AIR SYSTEM
Q 90
l. 20 atm pressure
V 11::--)
' 1.000
I I
,
/
I
'---
.....~:
r-=:::~ ~ ~
// 7 i"--
/a
~
c· - hi *,:'17 V
;. /
b---.
~
.850
.800
- v~:
. ~/
~,
r;.
o~ ,
L.
,
"
.750
~~ 400 V' V 7""-
h : .............
\...'f:-':)
/ / / r-:-
f--
V- ~ 2:S
/ ~'$.' r--
7"
.700
-
-4.-
' 0<::- ....
/
-
~ :' / ?-,'
.~,:::,....'lj '0<::- ~
.650 '(is
6 0 / ')N tT-
350
e:,'lj ~..:§'lj ,,-0'
~
k- r-·,l"~ K -:- r---.
~ ~
- Vr+-lL:
t:::.
/ ~
~ e:,'lj =::::::::. - ....
.600
'0
-
<v~,<::-'lj / / :
-
300 .~ t;}'lj ..... .550 Cl
r--
~ /' 'f-..... =2
.:>t!
~~ ~~
,0 ./ /
~~
/ ~
~,
'7 ~
--..V .: V I 7 '--
.500 .~
/ ,/
/'
/
~'
~
-- h..
'0
250 / >?: ./ ;'"
~ /' 'E
r--.....
v
*V -
.450
r-- Ii7.£::
-
..........
L / / "'-- ,;
./l// r-- ~V
~ ::::I
.r::.
-
/' -;7 ~ I-. : .400 Q)
-- l:21
:S- / /V
:
2~
50 ,/
/"
...... ~ /
~ ::::I
/" ~ (5
- : .350 (/)
./
-~ ,;.:./ / j/' -......::::::: /
L
.0
.// /" / / .......... y /. <t:
0
01. / I
.300
/ /'" /
l\l";-:
. ....><...1.........
/ :' ~ ,....---- ~
15 /'" / .....--
/
../" "' 0/0
/"" .....-- ../"" :
....- --.......
2<
...---
,250
><::
£- ....-r
40,......, .....-- ? :'"
--
/ ...---r -.........::
-- - --
.......-1 ,.:--
--I """"'::"
/,....---- / 50 ......... ...c:
.200
.. ,:---
-
oo~ .....- __ -.......-.. 1..-- :
--- - ----
-
0/0 -.......; ,..,.-- ~
- ----
,n
.. :.:--
----
~
1---- .150
" .:IV
,,-< -
----
I ...- ...- -+- ,,(fo - I : I i
:::-:-.....
--
Sn.a...
- ',."
I
~
0 7<
....... : I
'O/IJ.
~
.100
....... -.....: ..........
, I I (fro
.050
50
, , I air
,
o.
r--..
" -, '" " .000
30 40 50 60 70 80 90
110
TOLUENE- AIR SYSTEM
50
1.50 atm pressure .150
.110
.100 .....
~
~
"0
.090
--
Cl
.lie::
~
.080
~
40 '6
.070 ·E
:::J
.c
30 .060 Q)
:20
VI
.050 .0
ex:
.040
10 .030
.020
.010
.000
o 10 20 30 40 50
TOLUENE-AIR SYSTEM
80 90
1.50 atm pressure .800
.600
.550 .-..
.....
'iij
.500 ~
"0
Cl
~~~--~~--~~~~~~~~~~~~~--~~---+--~ .450 ~
~+-~~-t~~~~~~~~-~~~L+~~~~~--~~+-~~-+ .400 .~
"0
.350
'E:::J
..r:::::
.&
.300 -§
rJ)
.c
.250 «
.200
100 y - - -_
.150
50 i I .050
o
.000
30 40 50 60 70 80 90
TOLUENE-AIR SYSTEM
2.00 atm pressure
.085
To obtain true enthalpy add enthalpy
deviation to enthalpy at saturation .080
.075
.070
.065
-'co
"-
~
-0
.060 0>
~
.055 0>
..lC
.050 ~
'5
.045 'E
-
::J
.c
.040 <1l
::J
(5
.035 (J)
.0
«
.030
10
.025
.020
.015
.010
o
.005
,000
o 10 20 30 40 50
TOLUENE-AIR SYSTEM
90
2.00 atm pressure .600
.440
.400 .....
·ro
~
"C
.360 C>
~
.......
C>
~
-
.320
>.
.280 '6
160 ·E
:::J
.c
.240 Q>
"S
(5
VI
.200 .0
~
.160
.120
60 .080
.040
40
.000
30 40 50 60 70 80 90
TOLUENE-AIR SYSTEM
50
5.00 atm pressure .050
.048
Enthalpy datum: liquid toluene O.O°C, 0.00893 atm
.046
dry air O.O°C, 1.00 atm
~ .044
-
:::l
.J::.
.020 <lJ
:::l
.018 (5
en
..c
.016 «
. .014
.012
.010
.008
.006
.004
.002
.000
o 10 20 30 40 50
200
TOLUENE-AIR SYSTEM
5.00 atm pressure
.180
.170
.160 -...
'(ij
.150 ~
-c
100
.140
.130 -
~
~
Cl
Cl
.120 ~
90 '6
.110 'E
::J
.100 J::
80 <1l
.090 "S
"0
70 en
.080 ..c
<C
.070
.060
50
.050
.040
40 .030
.020
30 .010
.000
30 40 50 60 70 80 90
/
7
2.400
2.300
2.200
-....
'(0
/ 7 ~
2.100 "0
2.000 OJ
.::s:.
- 1.900
1.800
.......
OJ
.::s:.
1.700 ."0
£
1.600
1.500
'E
:::J
/ 1.400
.c
./ Q)
1.300 "5
(5
1.200 (/)
.D
1.100 <X:
.../ ~
--
1.000
...-/ .900
-
:7
~ I
--- .800
- - , .700
=:::::::: .600
------ .500
.' . '
c- -'::: I - I
I
I
.400
.300
.4·r
. '
. . . ... " "" ... .. ~ . . ... .
.200
.100
•• ~ • • I •• • ••
.000
o 10 20 30 40 50 60
600
t-lI I ' ..<" 2.400
Enthalpy datum : liquid CC1 4 O.O"C, 0.00122 atm
2.300
dry air O.O"C, 1.00 atm
550 2.200
30 40 50
. , ~ 60
II :,' j
1.20 atm pressure 2.000
/ I--
-.......... ·us
~ ~ -.:j
-V
/ K
r
dry air O.O°C, 1.00 atm / 1.800
I; l-
450
40/ I '-....... r-I
f- ~ r-- -L
1.700
I'-----
hZ
Too btain true enthalpy add enthalpy r.......
1Y
.~,
.
/ / 7'--
......... 1.500
/ T
/
c<A
/ ~17-~ / /
-+..../ / r71
~~ 350 r- 1.400
~o(:-
\.'+-'.)
i f-- bL- ' r/ i'fe Vo;.
............ 'f'I'IS./f.. . <1
/ - I -
1.300 '(0
...
""-
L1
/ . /tr!} 0,
rY - -
~
~v",,'?f. 300 ~
' 0(:-
~~ 19 -........
v." . ~
I 7'z
/ "0
";)'?~.;§-'?f.
";)'?f.
-
'(0' 1.200
/ /~ /
--
I
Ol
~ f. _ .::i!
z,:~~~ ~v ~.;§-0 ............. /
::----:---.... 1.100 Ol
/ V
.::i!
«?"S' 250 &~ ~l'?f.- / /
30/ / T ,
/ / "S z 7 ( -'
/
~ ,0<!: 1.000 ~
L /'
/ /'
!>~ /'
'5
'E
1/
-...,..: .900
/ / :-.:. I / ,
~ h<.
V ·,
-
:::I
2~ / V-....... ?' >tT ~
L
.800 Q)
/'
/
/"
~ /' /'/.... /"
/'
,;>< :::::::....- V .... /'[
./ :::I
(5
~ . / 1/ L .700 (/)
2 0 / 1/
./
/"
~
.~
::::><1 7
0)0 / '
....
,/
././ -..............
~ ;;/" - .0
«
.·r:::;7 ,600
L ""'<1 ./
/ / 1/ ..........-: rl'\°/d/
I ~
<" =-- V
, ,,,,..¢:1
/.'
"...
-..........::::
.............
I
............... ;;:.
.....-
10~
../
./ ./' .............. .500
/ ' AI .. ,
~/ 1/
>< :--.........
--- ...............
,/ ~
...,., ,...- I
---r---.:::: --
2
,/"
.....- ../
I
-
!51J. '
----
~ .....--- .-.r -..,. .
...-:-: ..
.400
-- --
1u ,........--. /...---"" ____ :--- -........
~ ....- 1. . . . . ><
~
--t
'
.....---
- - --- ----- -..;::::::: ..
Y ___ AI'\ o~
.-.-
~
-
....< 1
.....-:-:
,300
-
.-
50 L
---
1---
--- .. :::::1 I
.-
L. 30 ------..:
'
><:
-
.L.
~
u I.--- • "'.- .-
'
1-
I -..:::
..
1 .. - .7<-
.. -- -.......
t---
[ 'JR"
.200
--
I
e
~
·-1" ....... ~
.100
.-"
.. - .......
.. .--"
, .. -"
.. , ..
I
. . , . . ' I' ,000
o 10 20 30 40 50 60
400
CARBON TETRA CHLORIDE-AIR SYSTEM
1.50 atm pressure
38~. 50 60
..... 1.400
360 / ;-"-~ 7 /
Enthalpy datum: liquid CCl 4 O.O°C, 0.00122 atm
340
/ .. / K V-r-bL- :' I 1.300
dry air O.O°C, 1.00 atm 40~./ I :"/.. /
320 /
1.200
To obtain true enthalpy add enthalpy 300
deviation to enthalpy at saturation / 1 :tf--I-+-I- .:j / . . "K In
1.100
~I K
280
I V ./ F=7f--t- : /
1.000
--.
....
'(ij
.900
~
"C
.800 ~
~
.700 ~
160 '5
'E
-
:::J
140 .600 .s:::::
-
<l>
:::J
.500 '0
en
.0
V <t:
.400
- .300
.200
-
20 te=- .' .'
I
...:...,:.:
-
.. j "
l- , .....
.'
I--
-
. '
I
j-. ....
0 , ... - .. -- t- .l .000
0 10 20 30 50 60
300
CARBON TETRA CHLORIDE-AIR SYSTEM
60
2.00 atm pressure 1.000
.850
To obtain true enthalpy add enthalpy
deviation to enthalpy at saturation .800
.750
.700
....
.650 ·CO
C"-
""0
.600 0>
......
~
.550 ~
.500 ~
'6
.450 ·E
::J
.c
.400 Q)
:3
""6
.350 (J)
..c
.300
«
.250
.200
.150
20 .100
.050
o
.000
o 10 30 40 50 60
.340
To obtain true enthalpy add enthalpy
deviation to enthalpy at saturation .320
.300
.2BO
-.....
.260 '(ij
~
"0
.240 0)
-...
..l<:
0)
.220 ..l<:
.200
.1BO
->-
15
'E
-
:J
.s::::.
.160 OJ
:J
(5
.140 en
.0
-ex:
.120
2C .100
.OBO
.060
.040
o J .020
.000
o 10 20 30 40 50 60
10 20
0.80 atm pressure 1.400
500 / . . If-.;' / .. I( /: 1.350
Enthalpy datum: liquid water O.O°C, 0.2451 atm
1.300
dry air O.O°C, 1.00 atm 450 1.250
1.200
To obtain true enthalpy add enthalpy
400 1.150
deviation to enthalpy at saturation
1.100
1.050
-
1.000
.950 ....
'Cij
.900
~
.850 -0
--
Ol
.800 ~
Ol
~
.750
.700 ~
:c
.650
'E
:::I
.600 .c
.550 <1l
-S
.500 "0
(/)
.c
.450 «
.400
.350
.300
---
;'1--
.250
.200
.1 50
.1 00
.' . '
.000
-40 -30 -20 -10 o 10 20
400
DIETHYL ETHER- AIR SYSTEM
380
10 20
1.0a atm pressure , .
k itI
1.000
360 ~ II I
O.O· C, 0.2451 atm
~ J~ ./
r--
~ ~ LL
En thalpy datum: liquid water .950
fJ 7
340
dry air O.O· C, 1.00 atm 320 .900
0/
J! 1!1- r-....
1/ I:' 0 ~"'0~
I,:
300 '--- ,850
To obtain true enthalpy add enthal py
dey iation to e nthalpy at saturation 280 / ./ V::- rf ~ bt.
L2lz I :' I / 7"7
i--.
.800
7-;- ~
~
:
260 / ......... :
flY. ~'
I I / :-...... 7:- l- -i- f ~ los :
"k-. . :....... .750
r
~
-
~(:\ 240
/ r hi II I ~ '--I1~
"-
'O<:'-) L
\.: ~
.650 '(0
/'/1 :
~
- r-::-
:
,§~ ~ .600
"0
W. . K.
~ OJ
LZ
.550
Ii :
L
~O /
fi;.~~
.0' 1/ / 1/ ~
..............
~
160
~'lf /~ . ~ r-- I - -
~ t§ \.: ,500
<v~ 140 0 Cj -10/ / .. , /-- M( / ;$ L .........
Z / / ~
'6
><.... . P. -
_ ~
~v ~'lf~ 7i .iii / /
.450 'E::J
....
&'If
V.' / /
120 ~0 _
~' .
V :"
- ~ ....0~ /-:-'-. V ~
.: / :
""-R... ;' .o~ ..c
-
/'
.400
10~ ~'o 0 k
Q)
-........ ~
/ / ~ £ ~/
~ ,~/ :
-;:, . :20
~
.350
.5 / .'
(/)
/ 0\0/
./
/
/
1/ -~
z......... / j' ./ t>< 7-
../" .0
<{
-
.............. /
.300
<"~ ole/
/' V ../" : /
I
~ / V
~ / : ~u
/ . "./
- ':"""'/' "'V -..... "'"'-::
- -
. / ../ / .' -........
- - ---
...< V .' ....-r ..---- .... . ~ .200
..-:f."'""" 'f;,..
~
--
<> /
~JJec
.;>.< -........
./ ./ f-X". .'
..-
..J,./ .' :.:.-- An -''I ~ .... , ~ -.........::.: 1ft,,..
.1 50
oL
-- -- .><=
-;;lU_
.. ~
..- >
-h
..y ,noil,
Y- .......
' '
--
..- ..- <
--
.. "'" r::t, YqirJ
.......
I-
.........
~,
'
,100
L ,n
+- ......, '2C -If' .. :---:.::: 'JlS
-
-20 L .' .... -:::,
.. .. .. '
. "
. .
.. .' .. ' ~ .
.' """'" .050
'
.. '
.. ., '
.. .' o·
.' o·
"
, ....
..
'
i- '
.000
-40 -30 -20 -10 o 10 20
.600
.550 .-..
'-
'Ci;
.500 ~
-0
~
.450 ---.
~
.400 .~
-0
'E
.350 ::::l
..c::
Q)
!5
.300 (5
(J)
..c
.250 <C
.200
. ··' 1
.150
.100
.. '
ml
e I. ... . .050
. " .. ... I 1
I. · ··
.000
-40 -30 -20 -10 o 10 20
--
Cl
..:.::
.2BO Cl
..:.::
.260
.240
~
"C
.220
·E
::J
..c
.200 Q)
:;
1BO "0
(J)
..c
.160 «
.1 40
.120
.1 00
.OBO
.060
.040
.020
·40
.000
·40 ·30 ·20 ·10 o 10 20
~~ I .I I ~ V / RY .140
«
~ v""
,,> /" ~. ~ .. ~ V ~ V~
-20 /'" '-......./ / /
... K '"/ ~
--
' i\ ..-/
v----- k" / )?< .' ../' <:<: >.v "A
"
....... -:-..:.:.
~ ~
---
~ • (\ o/q ~
./>. K" .,\ ;::><. .040
-30
:: 0
/' ~ --/ ~
< ., ·';'0] P'<S. -::> ~
>< ~
......., . . '
~ ~ \ '-:&
~ r--... ~~
V
..---:: P< \ .. ><-- ..;><.,.,l.---> ~
b;c'"
, t---........
/~
-30 ~ .. ~
--
/ .030
~o ;>< .. ,:--:. l---"' X , ~~ ~ ~- ~
-
"
--......., ><- ---
-
-'~ ~~ ~ --- '--:,. ~~ \ .,>S ~- 1">.:.' . ~ .. ' \ ~~ ~
......., ....". ...
~o ~ ~ -<:.:
-.........,
~ ~ 2s: =- ><::::: . ... ~ '
'20...! ~ ~ :.:..:..-> ::::::.. ~ ,> . . . . ........... ....... .020
-:::: K .......,
><..:' \ 0 ,
,40 .. ............ ....;... ><:::::: 1\%; '
. -..
~ ~ '-'::::""1
~
,- ..::::>.::: ' ~
.~ ive\ h Jmltlll ~ . ~
~
'\ ,010
~.,
... . - ." 0 ,
.
. .. >< ........... -4"
~
"-..... >c'"
~~
~
i""""-.....
( ~ .' :--.:.........
:""".. .. .> \ --..s.~ ......., . ' r---
,.'
...... K ~ .,,- ~ t---. ..~ ~
~
r-.... .:..:.. ~ r--.........\ 6' ':":-- < ~
.000
-40 -30 -20 -10 o 10 20
1400
ACETONE- NITROGEN SYSTEM
40 50
o. 80 atm pressure 1300 20400
/ 1(""--
FF- t--- 1/-
/
-f-1
I - 2.300
Enthalpy datum: liquid acetone 2S.0·C, 0.2920 atm 1200
/ / 7 r-- ~ t 40
2.200
dry nitrogen 2S.0·C, 1.00 atm
1100
/ / / / 2.100
~ 1.700 c
o~ / / ~ ~ rvOlll, h..
V
/ a>
-e
I_
1.600
It- ~ ~/ ~n)
C>
<I) ;," / /
~v' / ~..;§ 00 I - -I-.kL
--
~Cj Cj~ \.... I 1.300 ~
~~ ~~ ~~
?s~ &.10
t<f 0
/ / V / ; / - r---
/ / 1.200
~
C>
~
<v~ ~ ,10~ /
/ / / 1/ / / ~~ 1.100 ::g>.
L / / 1/
7 /
v- l7- r-- l-L
/ / 1.000 'E
-
:::J
20/ / / / ..c
40~ / / / v / ~ 1--
I-.c .1, /
.900 a>
:5
L /' / . -.-;
.800 (5
V en
./
/ ;/ t--
300 L
/' / /' v
/'
.700
.0
«
/ I~ k
/" /- - '
V V
/ /'" /
;7 -'" .'
/' ,...-
I" n (~ ~
./
1)' , 111~1
,.,..n\ .600
L ~
-
---../ / /
-- --
., ' ~
--- ...-
10 . / .500
_I-- -- -- - - - --
~/
...- V
IU""':-
--- po --
../ ~
".......-
.-;
:/
--
0/.
---
~ ~ ~"'() ?V
,)"
1
0400
-::::-"- i----=:: .- ~ol ......-:: v-
.", ,,~
-
.L
y" " ~
.200
o ~ .100
.000
-10 o 10 20 30 40 50
- ---
650 1.250
3ot:-... I / / / I
rIr==
1.200
/ / /
-
To obtain true enthalpy add enthalpy 600 1.150
dey iation to enthalpy at saturation
/ / / --L / 1,100
~o0;0
~, 550 I I / / 7 ---- -...;. A"
1.050
l- r-./ I 7 --::
~
-
\....'f--s.~~o~;:/'
1.000
/ I ~
--- 7- / / c
I -
/
-
Q)
.950
450
/ ~i 'YVOlu 17A I. / 7 .900
Cl
e
~~~ -~O~ / / V
/ / /'K
17
.850
'c
~o
0' rr-- .L V /
/ ~
F;Z..: .30 ~
YL
~~ 400 ~~ J. .800 "0
C:>~ C:>~.::>
/ 7 R r- V
/ /
--
( / Cl
/
Q~ ~~ 350
~ ~
.750
~v ~..:§0 - 11""""-- /
V V Cl
i} ~ ~~ / ~ ~
-
.700
/ / V r-
---
/
<y\;' 300 ~&"
,0~R0
20/ / .650 >-
L / 17
I /
/ / 77 I--- r-- -...,..
L .600
'6
'E
7---. /
/ /,v I
..
Z
/ /' . -.. . - · ·r ·· ::J
.. ..
~
.550 .s:::.
/ / / /V ' / t:----- .. ' '
./
'
... / Q)
/'
.. .500 "5
/ 'JY / / /' r--.,... . .
/
'
---- k
....
L L / / (Jl
~ // / ../ / . , .. .. .c
.'
... \tr, haen)
.... I
' '
.400 «
.7 ~
-
150L 10/ 1/ / / tie" atj9Jl-
~\I ... ... ._0-
-;>
--::::::
<,.../
,/
./
./ V / /" c.(\
----
°/~ ~ . .
.. ' ><:::::::
./
/" n" / 1····· ~
/" .350
10~L
./
./ v.: .. ~;. ...... ..- .- __ 0- .. .. ' .. ' .300
.....-
----
"".' ..-? ... . --
-
~ ~ ><:.
----
. '
--- -----
.'
..
----
L ___ I
.' . ' ' .'
---- f><'-.----
~
A(\ of. . '
. . . . ;.P' ~ n .. ,
-
-::,..
50 ~ ..... ... -
------ .' ---
.' . '
.... -- :..- .200
--:.. . -,-
-- ---..
L ._.0. - .' .-:;.
L -"
.' .'
1-:"".....
.. .' ._0" ~
><:: ..i .' ..
' 0
... - .150
.' .. -.-
'
o .. .' . - .. - ._.-
... , .
.. .' I
. ' ,
'
.' .' w·P"
.. - ._ 0- - . "
. .... 0- . .. ..
,
.' I
0
' - .0 •
. 0 " '-;
... ._-- .. ._- .. .
._'.' .. .050
. -- -- . ...
-
0"-
..
.0 0 -
-- . -- ._.,- .
. . __ 0-
..
.000
o
"
-10 10 20 30 40 50
-- --
To obtain true enthalpy add enthalpy
260 / / 11( r-- i - - r- V
~9-s'
.520
.500
--t--:-I-r-
/ '/. /
--r
dey iation to enthalpy atsaturation 30/ / ~
~, 240 .480
) / ~V /
-
~e "-.. .460
<f0 220 / l'"--. V / ~ /
.440
\..'*'
':>~O;
o~
200
/~ 4-
/
} '--- ~ ./'-...... V
/
/
V -V / ~
~n.
eiriL
~ lJIl)",
/
7 r-- I-- L
V
"'/ :--
'-.......: ~6
.420
,400
g
c
Q)
en
' O~ 180 .380
~ / / ..........
K r-r:- hL ~ /]/.f-o, 'c
r-
/
~,..;§ '-K -=::::::,,: i'Y "Ii~ / .360 ~
/ i - - fL- L
160 ' O~ V
-
~'i3 ~ "0
.340
~.j.~ (0' en
f8:.~4,
~
A / / 7 ~ / 7 ~ J-!". :y:
-
140 'i3~ e .320 en
---
«,,~~ ~v ~..;§ 20 / / ~ f.L
-L / ~ -ri - - ~ .300 :y:
120
~~ f$'~
,~ 0....~ I( 1/ / -.......... ,(
-..... ../
/p"-- r--- ~ '"'- / L' .280 ::-
,e £.. / r7- /' 7" ~ r--- /"
-
/ .260
'5
/ ;; "'- 'E
/
- t:7 r--- ~r- I'-...... V
100 /'
............ ~ IX ..:: -..... .240 ::J
l>< /' / ·s;, .s:::;
I---- c::::-......
-. . . . K ····
2-
./I nO"Y ~ .220 Q)
~ V /' ./' 7 ~ V ............
'--"
./
-Ul
..... • -_ 0'- -_ ...
..........
.200
S
'0
60 ~0 ~ ./' 7- -lZ -..... V .. '
i -..- .' ~
.1 80
(/)
.c
1 0~ / «
,
L V , ~ r-........ ~ L ,...-..:..:.
r-- b.Z
-- :--.....:::::: ....- -
.........
.... +
/
/ ~.
.1 60
40 ........-
~/
....".,....
L 6 Q'y ~~
V
i>< "7
........-
L' _"'° ........... . .
.. ~ ............ , ~ m) .. s:... .140
--
'
I? n lk HI<C .....
--
- - "-
20 .....- ........- 01
.1 20
--- '"'- -..c--- J:::~ ~
K "
. "
U~
~ "", . '
-- --
~ ..- ~
---- -- --
0...<"" ....- .....::::::.
- ---
, .... 0
.... .1 00
o~ _ I :-------.... .~ '""'-- ::::--... .... k"
.... - .080
.. ' :.- ..
,. - - ........
- -
~ .. .',j~ . '
,
, '
~ ~
"'-
./ -Iv ,- .' .060
.. ' .'
.' ... .. ..... ........
0
.......... ..v
.. ' .. --
•• 0-
·<18
.. I
.0' -
::---.... .'
-20 r- .' . ' .0·-
'
.., ~
... .. :-......:. .040
.. ' . .. - . . _ ... -
.....
r- .
.l .. ··· . . ReI.<
.... 0
.......
'
... -
-
.' .0 0 -
....... . ~ .' .. -
I---
"
700
ACETONE- NITROGEN SYSTEM 680
660
40 50
tFt-h-IIil--J / -
1.20 atm pressure 640 1.200
620 I 1.150
Enthalpy datum: liquid acetone 25.0°C, 0.2920 atm
580
600
/ 7 t--.. / ~
-----..
17~ :"V
1.1 00
dry nitrogen 25.0°C, l.00 atm
560 / ) r-J / 1.050
t-f ti-- t-...
540 .......
520 / t------(1- t-- ~ l - .1" /
To obtain true enthalpy add enthalpy
de viation to enthalpy at saturation 500
1 / / --- tl- I J r;- 1.000
/ r---- ~
30 .950
~0~
:\ 480
L I /
---/
460 .900
;?o / / r----V /
I
--v-. -- II
440 . 10
I /
~~ ~;z7
.850
L / / c
~
Q)
')~~ 400 J .800 OJ
j- l--J I / / g
~~~i? r
/ .750 'c
~o~ 360
/
f-- LL t--- V V / t----- ~ ~
~~~i!
/
.700
L / / / F I--- /
"0
~C:JC:J 320 ·o~ - / OJ
~ .650 ~
~~ 300
/ / / ---- ~ /-- V""'" t--- V ""-
,;}~ 00' / OJ
~~~ 2~ - C:Jf§ \..: - / ~ / , ,."
,600
~
'fJeCit V
'v
/
I-7t--
--
~u ,;}0 b. V
<V~4~ / ~
~ f§ .550 ,~
240 .~ 0' - 20/-
V. / 1 V V V r--.:...-- r"9
/. ./ "0
,0_
~'&I ~~ / ./ CIt
---.....: ,500 'E
/ / V- ~ V ~ ~ V,95
oL
./
27
/ y ,450
::J
.c
-- -/ .....-.-.""""
Q)
180 A ./ / V L
I
/'
t-,..( I
I
,/
S
r:-:-:- ~ V
w" - " --
.. ----
I
.400 (5
16:8L /' IY ../' K ./
1 _/ II)
./ ~ / .- . -.-y .0
«
~I/' .L. I?
---Vt----: ED'....--:
14~ . -' .350
/ 1 /v
V
---'
/
12~ 10/h.<:: /' A!\ V ·-· t-...c' 1 -~n'
.300
/ V v .0- -V ....< 2.0 (' ~J/I\.~ _ I. ~ -_ ., .-
V
•• __
10~ / .. ,- -
---
/ ",()~i>< _·· ·· v nthal ~
--- .250
--
80 L ....... ........... ~-- .. --- ----- I
....-< ~ ~"ofJ' .:;: I
~
- --- -
60
. ' . - '
.200
.. -- .- - ... --- ... - I
---
-
2'< ------
I· O~
• • 0-
.'
---
IF .......-'" I 1-
------.. - . --.:- ro:::::::::
--
4~/ .' 40~ !...---" ..!-- --- . 0- -
. .- .. ' .v .150
.'
- ' .--~
2~"" .. .- . . -
~- .-
< -;-..
-'
-'
1. ----
'
-- --
1 _ro-..-- .
._0'-
,-'-'- .1 00
.1'
.' . •• -_0-
o --
--
-- . p O _
._ 0 -
.. ._ . -_0-
. - __ 0 -
,
. -.. -.- . -
r--,., • . _ . 0 - .-
On
.. -- - I
_. -_.-
-_.- .. .. ... .-.- -_ .. .050
•• 0 -
-20 - .-
.. .. , .- I
_. -" - -
::5
.- ---_.-
~
-"
.. ,. _.- " - _. .. -.
_ .
_ a __
_.-- .- ' - .. - _
_ . . -. -
. .
- _.. - . -.
.
-'"
520
ACETONE- NITROGEN SYSTEM
500
1.5o atm pressure
40 ,
50
480 .900
l1It
" , "
460
/ I/ /
/ Ii 7 f- _ It - --
Enthalpy datum: liquid acetone 25.0·C, 0.2920 atm
440
.850
25.0·C, 1.00 atm ~
dry nitrogen t-.........
/ ;-~
420 .800
r-- lL J
-
400 ·8S
......
1 I-
To obtai n true enthalpy add enthalpy .750
t--
-/-
380
deyiation to enthalpy at saturation
360 7 ............. I~o / /
~ r--
-I-~~ i /
~, 30 .700
O~0 340
/'---
L / / / / /~ -
.~ me (f)
o<A~ 320
~
/ .650
c
r-r7 - 7 -
";)~~ 300 --;r-- '(Jell) ,
OJ
.....e
.600
17
Cl
/ r/
~
........
'-.~ 280 ~
/ 1/ - V- 7 ~
· o~ ~ ~. .L .550
'c
~ 260 ......... !.{
/
I /V
~, ~
~ "0
z . . . . . . 1/ -
e;,?} 240
,L
· o~ - .500
~-
Cl
~
.0' / /
............
1
~ / V / .......
~
<v~~ e2.:
i;~4, ..:§'If
e;,W 0 '- - /
/
L ~
Cl
/1
.450
/
~v ~.,;§
/ / --.........: . --s--
180 :Q'lf
&'If Q0
~'lf _ 20/ / ><............ ../....... v / r--:.... .400
.?:-
'0
16~ ~ .....0~ / / / V
./
./
D.(
/
........
V /v
/
.350
'E
::J
.c
1 4~ /' /' / /'
/ /"
129L / 1Cl)IJ;>< /'"
V
1/ /
/ 1
~ :--....
/'
;;-- K
Kol - . . ....
.300
S
OJ
(5
B,L7
..
V
1, / / l"-::.<:' / .--- .. . , . -
/" / I ~
(f)
... .. --
./ 7- .' V ,..- ./
t::::-...... ('.10
.250
.0
«
.---- r><:
10......- 1/ > t-...... .' ._.0'- V
./ ~
..-/ / 1/
V ......-:-: . _. 0'- I V
6°L c- ...........- ~ .----
,..-
/ c.(\ Od......-
......- ....--
~:-.
,..-
?Y.\'~~: ;.: ;;.:-
.. -- •• 0 ' -
.200
....-- ,.....-
--
iation
nu ,w ~ ... rI<>'
,.....,..- ..-/" ?f ;.;:? . .. ' t--
-- -------
.----
r:.(\
-
40£ ~ ..
....-
-
' ::'--
-- -
.150
-
'
- J...... ..' .-
u ....-
.- --:: ... . - I ._,,1"1
.- -
--
1----- ~
r-......
.-
--
20£
...- ,-----
- • • 0 . 0 -
f
"
•• 0-
>l\0 --..".,.... .- ,
. . ..
--- -=---
'
.' .. '
- . " .. .. - . __ _ . 0 -
0- 0' -
.. ' .. .'
..
... - '
. .. ... .. _- .050
-20 .. . .. . _.0- .. , _w·-
. ... ,-
'
.... . _._ 0-
. . .. ... . ..
.. ._ 0- . .. .. _ .. ····r· '.'." .. . . .
.. _ .
. . . ... .. .. . -
'
' . , ,. .000
-10 o 10 20 30 40 50
140
ACETONE-NITROGEN SYSTEM
50
5.00 atm pressure .220
.210
Enthalpy datum: liquid acetone 25.0·C, 0.2920 atm
dry nitrogen 25.0·C, 1.00 atm .200
.190
To obtain true enthalpy add enthalpy
.180
deviation to enthalpy at saturation
.170
.160
c
-e
.150 Q)
Cl
.140
'c
.130 ~
""C
.120 ~
-.
Cl
~
-
.110
>.
.100 '5
.090
'E
-
::J
..c
Q)
.080
::J
.070
"0
(/)
.0
.060
«
.050
.040
.030
-30 .020
.010
.000
-10 o 10 20 30 40 50
BENZENE-NITROGEN SYSTEM
750
50 , . 60 ,.. 70
0.80 atm pressure 1.600
1.550
Enthalpy datum : liquid benzene 25.0°C, 0.1249 atm 1.500
dry nitrogen 25.0°C, 1.00 atm 650 1.450
1.400
To obtain true enthalpy add enthalpy 1.350
deviation to enthalpy at saturation 1.300
1.250
1.200
1.150
c
1.100 Q)
-
Ol
1.050 0....
1.000 'c
.950 ~
"1:l
.900 C>
.850 -....
.!<:
C>
.!<:
-
.800
.750 >.
.700 '6
'E
.650 ::I
..c
.600 Q)
.550 "5
(5
.500 .c
(/)
.450 <l:
- .400
.350
-
~
-- .. . . ·1- -. . .300
.250
.200
_ - - . T.,,:!(\.
.150
I .100
o ~ - •• - I- - •
.050
.000
10 20 30 40 50 60 70
BENZENE-NITROGEN SYSTEM
1.00 atm pressure 650
;7,
,~ 50 .. .. .,',. , 60 70
1.400
/----l[ /~ -/.. r --:-[-1 ! 1.350
Enthalpy datum: liquid benzene 25.0°C, 0.1249 atm 600
1.300
dry nitrogen 25.0°C, 1.00 atm
1.250
550
1.200
To obtain true enthalpy add enthalpy
1.150
deviation to enthalpy at saturation
1.100
1.050
1.000
c
.950 Ql
e
0'>
.900 :t:::
c
.850
~
.800
"
~
Ol
.750
---Ol
~
.700
.650 ~
-----/
'5
.600 'E
:::J
.550 .c
Ql
..... . / / .500 -S
.450 '0
(J)
--~
.0
...........-- ---- '. '-'"
.400 «
.350
- ""-.:.::. -- .200
1 n,
.150
o ........ .. ...... .... ... . -- --- ~
n ___ .100
-
o .050
.000
10 20 30 40 50 60 70
500
BENZENE-NITROGEN SYSTEM
50 60 70
1.20 atm pressure 1.000
450
Enthalpy datum: liquid benzene 25.0°C, 0.1249 atm .950
.750
.700 t:
Q)
OJ
0
.650 .!:;
'c
.600 ~
-c
--
OJ
.550 ~
OJ
~
.500
~
.450 'C
'E
='
-
.400 ..c
(J)
.350 ='
(5
C/)
.300 .0
«
.250
--. ~~...
..... 1-- -
-. . _- .. - . . .. . .
.200
.150
._ .. . -.--,.;: - I • • • • • __ __ __ •• •••••••• •
I
--I--.
.. . _._ -.... .-:-;;::::: ..... ..[j£;:
.100
"'Q-
I
.000
10 20 30 40 50 60 70
380 60 70
1.50 atm pressure ". I • I •
.800
360
Enthalpy datum: liquid benzene 25.0°C, 0.1249 atm / / ",y.: "' " : --I... -.......... o'~
.760
.600
o~ 260
~~ 40 / Y / / ""~r-
: ', 7--- /. ~80 .560 c::
\..'t-.'S 240 ~ 7 1'7 / 'J<.. -~ -.. . . . . / '. i.i' "'" Q)
g
~ 220 ~~ 0' /r--.... : /'";--
/ "-.... / ~ /............~
~,:§ ~~v (: / ~J 1/ b< / .~ / -.. . . . . .,o' /'1> 'c
.480
~~ 200 ~v J.0 _ _ / / ~ 7r---r---..L r-.... 1
/ 'DZ. [---I- ')Z:: ~
"0
~ :.Q~ ~~ -----,~LL / 'A 1/ : - / ............
~~
--
C)
/'
K I-~
............... . /
-,<:::::--
' .. ~/
V
''/
~
./
17""---
....z ~
........
r--.... ... ' n
- .360
~
:c
'E
::l
.320 ..c::
12~ /" /'- f~.o7 ?<--.. ~
zL
/.- ./' / '" V .280
...-
Q)
::l
./ ....... /' 110Y I ··· ·.~. o " V- (5
~ V ~ .---r ?<-. en
8<tL 20/
./ V
t>< /'
/' .('\ 0
.240 .0
<t.:
60 .~ __ I .200
40f
1............-
-- - --
--< .............. I ~k::: ~
.160
-
L lU"-< l
/
....
7-""';::::::-::;;-
"':::::: ~-
.....--
.--
-
K
-- -:..1.U .-:;
-.--. -.. - ~
. rl' w ali(] 1 . ....., - -
.120
-
-- ......., ... .. .. " ' : " . '='! .. ~~"': . ~I. ...... . .~
.080
o- .., ..,
- I--- o
-.... ...... .040
.,
... :--:.;: .. . .~ . . . ..... . ... .... 1"3. ......... .. . ... ... . ....,) :-- - .000
10 20 30 40 50 60 70
BENZENE-NITROGEN SYSTEM
70
2.00 atm pressure .540
.520
Enthalpy datum: liquid benzene 25.0"C, 0.1249 atm
.500
dry nitrogen 25.0"C, 1.00 atm
.4BO
.460
To obtain true enthalpy add enthalpy
.440
deviation to enthalpy at saturation
.420
.400
.3BO c
Q.l
.360 0)
a
!::
.340 'c
.320 ~
-c
.300 0)
---
~
0)
.2BO ~
.260 >.
......
.240 '5
.220
'E;::,
..c
.200 Q.l
:5
60 .1 BO "0
(/)
.1 60 ..c
«
.140
.1 20
.100
20
.OBO
.060
o .040
.020
.000
10 20 30 40 50 60 70
BENZENE-NITROGEN SYSTEM
70
5.00 atm pressure .200
.170
To obtain true enthalpy add enthalpy
deviation to enthalpy at saturation .160
.150
.140 c:
Q)
Cl
.130 0
!:;
'c
.120 ~
"0
--
Cl
.110 ..::s:.
Ol
..::s:.
.100
~
.090 'C
'E
::J
.OBO ..c:
'J ....-
Q)
.070 ::J
(5
10 rn
.060 .D
<d::
.050
.040
.030
-10
.020
.010
.000
10 20 30 40 50 60 70
220
TOLUENE-NITROGEN SYSTEM
210
0.8a atm pressure
50 60
200
/ .~ : 1' ;
/ / -:- r--.: .360
--
~ I' I I:' ~ i'-/"
0<:\
150
/ , " '\(' "'!--- i' :
~~ /.~'J' /Jr--.... ...
'
/ --; ~' I /
140 .260
~'S / / -:-... / ;'\. :
---
.250 c
/. IV:' / ~:' / i-..L '\. / " / : r------ : '\. )': /
\. 130 Cll
---
·O~ · O~ ...,~/ .240 OJ
~
~y>\"lf 120
~ / V -..,.::, / :' j 'l): ' ~~ / : ,'.
~ .230
0
!:;
~.j-"lf \..V' / :7 ~K !/ / '\. -L : 'c
----- :'"
c,.,"lf 30/ :' I
--
c,.,"lf .220
i'\ ~ 110 ~(j ~y>\e J'---...t. :')\ 7 )!--. / :"-... I f ---:-- / ~
-- : y
.210
/ 7 .7" ~ /.: / 1.: / 7 r-- '0
-----
~~ :
. t§> 0' "
--
.200 OJ
<v~~ 100 ~~ ~~ f--- /' / ~--- f:,.(. . / ; ,'. / ~ : /
.190
~
,e
/ 7 Y. OJ
---
I X ~ -.:.. /. ,''\.. ~ ~
90
~<--..... /' / ~ ,.( '\.. :' / :
r -i--. ---:." V : t-- :
.180
.170 >-
/ \7 '5'S :....... :'/ "X- :>Z: "
.'!:
--
80 .160
V ----:.. '--
'0
/ ~ '\. / "7- / ~,--- /. 'E
-- :--- --
" / ;
> '.
.150
/ V 7" ~ 7,: "'7--: Y
--- ----.
-
70 ~ :J
.140 .!:.
2 0 / ~~ -LI ?\ / ' --:-:- / 1 ./ ~' ;:--. ./ V Cll
: '\. v--;
---
.1 30
/. ~ ,<c--.'.
60 =~ V "
~ .,,019- 7- ~ : / :J
. / r-- A
----
.1 20 (5
7' ~ '---- /; ----.;.: /"\J ~ . / '\. ...
---
-
(/)
50 "- -/
.11 0 ..c
/ ' Y /<- ~ .7- ~ / .~ 7 - --.:......... / : :,....-
..... ~.,:),
---
~ ,./ , ':'-- ~
~~ <-- ' .
'" ---
.100
40 . / 7- X ../ ~(\ oJo ~ 7" : ~
~ ~ --:. ~
>< <-
,./
.---
~ ~ ~ / ~ "h '.
----
~ .... r--:;" ~ < ----
.080
30 10/ j:>< >< ~ ? <. .:,9./ ~
,./
·S ~ .070
~ ...?""-'><:." .............. ~ ~ A~ ><]' ><
---- ~ 'i:--- ~ --- '. ~~r,;; ><:::"" ..
'.
-- ----.. ,050
<....--..... 0 >< .::.-:::= -<::::. ",...
--
...-J><- ->"'" ?< .-::>< '3~ ,, ~ "-.:-
-----
~
- -- ---
--
~
.040
:>- i<C ~ -< -.:.. ..:>< '..2.0% '\:":::-
-
><
- -------
':-: ~~
------
~"
~>-< ~
----
"-:-- ~
10 ---- F"-<-
-r---
.030
>-< ::>- :::::::. '\ '\.
---
...
-----r==:::
\. ~ ~@,., ~ :--.
i:-c:-
---
h.
.020
. ~,
--- '''~
.:-- r-----:.P-... .010
TOLUENE-NITROGEN SYSTEM
1.00 atm pressure
.250
Enthalpy datum: liquid toluene O.O·C, 0.00893 atm
.240
dry nitrogen O.O·C, 1.00 atm
.230
.220
To obtain true enthalpy add enthalpy
deviation to enthalpy at saturation .210
.200
.190
.180 c:
Q)
Ol
.170 e
:t::
.160 c:
~
.150 "0
--
Ol
.It:
.140
Ol
..!o::
.130
60
.120 ....>.
'C
.110 ·E
::J
50 .100 L:
.090
....::J
Q)
40 (5
(/)
.080 .0
<{
.070
.060
.050
.040
10 .030
.020
.010
.000
o 10 20 30 40 50 60
TOLUENE-NITROGEN SYSTEM
60
1.20 atm pressure .260
.250
Enthalpy datum: liquid toluene O.O°C, 0.00893 atm
.240
dry nitrogen O.O°C, 1.00 atm
. 2. 30
.. .220
To obtain true enthalpy add enthalpy
deviation to enthalpy at saturation .210
.200
.190
.180 c
-e
Q)
Cl
.170
.160 'c:
~
.150 "0
0>
.140 ..:.::
.......
Cl
..:.::
.130
.120 £"0
.110 'E
::J
.100 ..c
Q)
.090 "5
0U)
.080 .0
<{
.070
.060
.050
.040
10 .030
: .020
o - .010
.000
o 10 20 30 40 50 60
150
TOLUENE-NITROGEN SYSTEM
60
1.50 atm pressure .200
:
Enthalpy datum: liquid toluene O.O"C, 0.00893 atm .190
.170
To obtain true enthalpy add enthalpy
deviation to enthalpy at saturation .160
.1 50
.140 c
Q)
OJ
.130 g
·c
.120 ~
""C
OJ
.110
-..
..::.!
OJ
..::.!
.100
.090 .~
""C
·E
-
.080 :J
..c.
Q)
.070 :J
"0
(J)
.060 ..c
«
.050
.040
.030
.020
.010
.000
o 20 30 40 50 60
120
TOLUENE-NITROGEN SYSTEM
2.00 atm pressure
.110
c::
Q)
.100 0)
0
-=
'c
.090 ~
"0
--
0)
~
.080 0)
~
.070
->.
'0
'E
.060 :::J
..c::
30 Q)
+-'
:::J
.050 "0
(/)
.0
<
.040
.030
.020
o .010
.000
o 10 20 30 40 50 60
TOLUENE-NITROGEN SYSTEM
60
5.00 atm pressure
Z ,X\I ., [v ·A 1 .068
-e
Q)
.032
.~
20 "0
.028
'E
-
::l
..c
Q)
.024 : :l
10
"0
(/)
D
.020 «
.016
o .012
.008
.004
o 10 20 30 40 50
1700
N- PENTANE-METHANE SYSTEM
1600 20
0.8o atm pressure ' , , ,
4.000
( 'I--/.. 1- !-I- / /
1500 ( / ,'.
/ ----.., t-- l!- i - - /
Ent halpy datum: liquid water O.D"C, 0.2413 atm 3.800
-
dey iation to enthalpy at saturation 1200 l / I~: II I : Ir-----., ~Wn....
0' f::::::::. J_ " I : / If --:. ":1.ne) I'<ae- 3.200
0-<:::
r- l ~~ / / / r---::.
-- --
0.;s' 1100 3.000
/ I ~. It- ~ 1/ / /
;?j
~{' L L / r-- / /
." 1
/ 2.800 Q)
/ /
~
c· . / :/ ~ c
cu
r--.- h( I
e-Y / / / / 3.nn
.-
£
\.: 2.600 Q)
f I.t
----
'0(;:- 900 ' 0(;:- .,, / / /
----r-..L
E
.0'-
-- -
~
v,'lf
~ ~ I( / 2.400
,j.'lf / 7 -tr, / / ,r- - -L ~
~ 800 t§ 0 \.. '0
"' Y - s:
c:> ) hJQ; ,
~
Co // 1/ 2.200 OJ
·CJ
/ 7 r--., ~:' / r--
fl:'~-
2.80 .!I:::
: / .......
dY~ 700 . ~,§' 0/ / / f;: r-:... V /
OJ
--
.!I:::
~<f' "?-~.....0~~ 2.000
---
/ -
--'E>-
-
1/
-
/ / / / / / 1.800 is
/
/ L
50aL
I
/ / / ~ /
" /' ~ .60 1.600 ::J
/ "7-
----/ /'
/
/I ./ / 1 £
--
/ /. :::--,::
L
-
~y / / ,/ Q)
./ 1.400 'S
400 / ' --:
/ / .' / " ,/ ./
L
"6
-
-
/' / ~ 7,.'
.
,/ / 1 7- .., 1.200 .0
en
.10/ / ./ ,...:::" / ,/ : ---..J ...:..'u «
3~
() 00 1 ,/
. / ,/
,/ T :?' -;7 /" /"'" ,/
-L' ....-1
=--- / 1.000
-
,/" / "J'I°1o / :'
,/
,/" I
:;::><... ~ ,....-:: ..
==-----
L ./
I
,/ ..........
200 ...........
.800
--
. . . ..
--
........-
- --- -
~ ........... ,.--/ ~ ,..:?
--- ' ~ 1____ ~' '''''' ;:> ..,,,
- -
L =><
---
·~u_........- ........- ,n /9 ....
-----
0
.600
-
L
,-
........-
-
100 L ......-< ..,.- ~ ;:::c I
1:::--" . 1
L. ..-r- .' " 3U
.£. .400
-
-"1.1 1 I
z: -'
- ,," , I n,
o .'
"
"
.200
.'
""'"
," .. ,.'
, '
"
.000
·30 ·20 ·10 o 10 20 30
1300
N- PENTANE-METHANE SYSTEM
1200 20 30
r
.,
1.00 atm pressure
j ~ / r. -;- 3.000
2.900
---. /1
10/ /
- -! /
- ---+
Ent halpy datum: liquid water O.O' C, 0.2413 atm 1100 :' ~
- --
o<A~e
J'--- bL-.L J:
2.200
800
I II ---;----:J6ry rnA' / 2.1 00 <1>
/
-
:
~~ / I; ' : / ~ : / ~ ; :f1 e) ~n c:
«l
2.000 .s::::.
\...'*"':> 700
L / ;j :' /
~
/ :' 7 '--- f-.-..,L
1.900 iii
-- -
·o~ , 0<::-
~~
~
;§'If 00'
/ ~ D i-,. / :/ / E
~-v 600 t§- \... / / / -y-... /"1- -?4 I /
"S' :
1.800 ~
--- / -
"C
e
- ---
~<:j 1.700
"'-- -,L ~.: V
<:j
J '---
/ :' C>
~0 ~..§
--
'If
-
~
~~~ ~ ~'lf
7-
1.600
«.-~'(;'~
500
Qe
i;y'lf 0/ / / / lJ. ,<t./ ~ ~ ::::- / 1.500 ~
C>
~ ,e<$" ....m.<-
- / / 7 -L L / / 1.400
4~
/-- /-.... / /.: / 7- ~
1.300 '0
I :
./I"C) ;/
/ /
/ /
7"-.
/ r-- -L
L /
/' :
:/
/
- 1.200
'E
:::J
.s::::.
3~
1.100
/' ./
/ /'
..../ I ./'
:::-- /' /" "5
<1>
-
./ 1.000 "0
-------.---
./ / I ~ // ./ /' .... ~ <::: !/)
L
.900 .0
- 10C:-b.Z /1 1()~ /-. /' /t Wn <X:
.800
200 L / 1/ 1/ ~ ,..c'"
/"" ,,-/ ~ -...::::::
/."
L!-
.'
.700
I .---
./' ;:::;;:;?
./ ,,-/ / .' ....... ......... ...............
~n..9~
./
.......- .--- ..---- .600
-
L ........... .,;'::":-- .---
':;:7
--:---- I
--- I
-
............ .......
--
100 .500
--- ---
-
-~u .......
--
L. - -:' .··· 1---- 0
I
~
----.
0
T.6n
o .' I "-'
:l< .. ' .200
I .' I I
.. .100
.. .,
.. .'
..r -, I
."
'
,. ., " ,
. , " . .000
-30 -20 -10 o 10 20 30
11 00
- ------
2.500
/ / II
r+ ---- L
;' / ~ 2.400
Ent halpy datum : liquid water O.O·C, 0.2413 atm 900 / V- hi:I 2.300
dry methane O.O·C, 1.00 atm
/ r--I lis" / ~~ 2.200
r--- L ! ~ "'~}o
10/
/ V
r
800 ~Ih.
Too btai n true enthalpy add enthalpy 2.100
dey iation to enthalpy at saturation L I - ~ ~ t?kg ch,- : /
1::
I
-. ~ '>'/. 2.000
f- J / /
-
0'
~'l>-~ 700
:---.:; t::efl~
i/
1.900
~0
/ bL- t:::--.L ~
I I ~
o~
L /
~
V ~:
0:
I I ~ -::t t--- t--- V I I
1.800
Q)
..y.'I:-~
i r;: V c
f.--
/ r----. k , -......
600 1.700
I -~ 171
(\j
~ : .c
\...'*' ~:
. 0<:- . 0<:-
/ /. ~ . -..:~. .. / 1 0
1.600 Q)
-
~ ~ / 1- --/- - : { 70 E
.;S~ 00'
C:J~.;§ 500 t§ \. / -I--
~ -
~
--..,L., / V '-':'::: 1.400 1.500 ~
-
/ c ' "'0
--
<;j 0
~~~
~
:9
~v ~,§
~~ S--- 7 / .§ '/ / ~ -7-- L 1.300
OJ
---OJ
~
~~ &~ ~0
7 ~ / 7: ~ :----- Lf ..... ~
--
~
~
<v~ ~ .....0~
--- ;:::--
400 0/ ........
1.200
/ / ~ -A ~ -::/.. ~ / '.- ?--J- ·(50
:::-:;%: ~
1. 100 '6
2~
/
7 7 .// t<';S'? .: ' / L
----=;: /"' 'E
z:- ><
./ 1.000
~ r<-- --f-..
::J
-
300 ./ "'--- ~
1,/ .c
L ./
./
./ ::r\
Y / ../
./
./
:::;z....... 1 /
:'/
- /
../
/ /'
--1 ;srr-
.900
.800 (5
Q)
:;
20~ -1 0
./
/- ./
/'
:< 15?
'9 /' / " b4---- ./ /'
--...:.......
.700
(f)
.0
«
L!-
/ .........
/ 1/ / / 1/ .. ' ' / 7' I I......... ~,
~
.600
. / ./ I/ I ~ \)\J...;.-:
~><-- /j L ...........
/1 --.:: ...... 1
100 L ..........
...... ............ ...........
...... nL ...- >< 1 ___
.500
-
-r--- I
----
,.--?
L .......--- ?-C ...--- ...--- ~ 7.40
- -- --
~" I -.:::::
L!-
- ~u • I
...- ::;:;- .400
-
::><:: :::t-===: =--:-'1'
--
-4~
--- J....-- --t .. ' 1-
-
..- I
L 0
.300
--= -
.. . , -><.. r---- .....
,L , -< ,. :-
I , :-- I I .. ··
I .--;
o , .. .' , Q
.
I
,
I
I
.200
I I
., R.. '
--
1 I :r--:::: I .100
.. - I I I :--.
--- -- , , , I
.'
..
.1..-
.'
, .
"
, . .000
o
'
800
N-PENTANE-METHANE SYSTEM
20 30
1.50 atm pressure 700 1.800
1.300
Q)
-
c
~
1.200 ..c
Q)
1.100 E
~
"0
--
1.000 OJ
.:x
OJ
.:x
.900
~
.800 '6
'E
::J
200 .700 .c
Q)
"S
.600 (5
(J)
..c
.500 «
.400
.300
- I
,
I
..
- o .J: e
"',mi \
--
- I
-
.200
.100
; .. , .
' .~
7 n. -
·30 ·20 ·10 o 10 20
N-PENTANE-METHANE SYSTEM
2.00 atm pressure
1.150
Enthalpy datum: liquid water O.O"C, 0.2413 atm
1.100
dry methane O.O"C, 1.00 atm
1.050
To obtain true enthalpy add enthalpy 1.000
deviation to enthalpy at saturation
.950
.900
.850 Q)
-
c
ctl
.800 .s::
Q)
.7S0 E
.700 ~
"C
0>
.650 ~
""-
0>
~
.600
.550
.soo 'E
->-
'6
-
::I
.s::
.4S0 Q)
::I
.400 (5
(/)
.3S0 .0
<l::
.300
.2S0
.200
.lS0
.100
-so .OSO
.000
-30 ·20 ·10 o 10 20 30
N-PENTANE-METHANE SYSTEM
30
5.00 atm pressure .460
.400
To obtain true enthalpy add enthalpy .380
deviation to enthalpy at saturation
.360
.340
Q)
.320
-
c
ctI
.300 ..c
Q)
.280 E
~
"0
.260
--
0>
.::s:.
.240 0>
.::s:.
20
.220
.200 '6->.
·E
-
~
.180 ..c
Q)
.160
o ~
"0
If)
.140 ..0
<t:
.120
.100
.080
.060
.040
.020
.000
-30 -20 -10 o 10 20 30
2200
N-HEXANE-METHANE SYSTEM 2100
40 50 60
0.80 atm pressure rr--::::
2000
/ / i---rf- I II
4.400
I
1 ..-
---
- -
.600
I
~ .
.400
J2 !)n
.200
, I
0 -' .000
o 10 20 30 40 50 60
50
1.0a atm pressure
1700 , . 60
l V:' I -r+- r--- /
3.600
-
40/ /
dry methane O,O°C, 1.00 atm 1500 -/.&: --r--J /
---
f-I- --:--
3.200
/ ."r:.:' 7 / /
To obtain true enthalpy add enthalpy
1400
/ I 0; : / / : r ~ :i ..... 3.000
dey iation to enthalpy at saturation 1300 / I e:' I / /
e' ~ 1-= ~ / .' / / 2.800
~
e~1j 1200 / ~ J I r-.:.. -I... I
--
L 4":' j 'j r----" :' I I ir--
-
~~ -"r-:J: /
2.600
/
-- -r
l~ ~.,9
~<0?3 1100 c
Q.l
- ---
~ \: 1000 / / ~ / / :
: ,40
Qi
~o '0(;:'0 J __ -- ~ ~ / /: / / E
~ 2.200
~1j
~\) 900 ~,;§ 00' / / 1&' 1"---- i---. / I ~
",,'?f \: 7 / :' / / L , "C
~"" ~CJ ~.j.e
~ So",,; . I
2.000
--
Ol
A'
--
A'?f / I~ -.. : I"'~ rnA
/ : ,. ~
~~~~~~
. r§> e''?f 30// ~arl' /
'\>-~ f$'~ 7 /1 / / I
1.800 ~
Ol
,e
- / / 7 -:-:-- ;/ --r __ "f ane;1?,,-:-
_ 1--.::
70~ A / / : / / / : / ~
1.600 '5
/ 7 ;>Z::: : 71 -
--,k:: , A V : / 7' 'E:;,
--
600 L 7 ./ ./ / ./
/- ~o /
/' 1.400 ..c
50~ /'
/ ./ /' Q.l
/ / 015' 7" // :~ <....--.... ./ "5
-
.C\ /. 1.200 "0
/' -::---:,.. /
./'1 1/
20L /' (/)
40~ 7 .0
()~ / : / 1"1,
./ ./ ./ ./ I I ""tt"
1.000 <{
~ ,..:;.c >-
-
/
./ /' ~
v C'I ... .-/' I
- -- --
L /' ,/" ~/ :.....----- ~
--
/ /"" ~ /'
/'
.800
-----
300 L ;:::>< .. ,' ...---
.-/'
/ .,/ .....-;-:"··1c.() 0/0 ,....?
L /'
.....-
- - -----
lU.-/' .-/' L..--...
.-P ---:-:'" I
-
200 L L .- .600
--
---::;:;: I AU':":'-
------
><-1. .'
~
L ,..,., 0
L 1\.
..z. --- .'
~
'v .400
100
I
, . . .. I
..
.. , ..
.200
.. ..
o "
.. ,
.000
o 10 20 30 40 50 60
--
--- -
.600
V . r---
- -
~(\:-' ~
I ~
-
-
~
.400
~
I 0 '
.200
o .000
o 10 20 30 40 50 60
N-HEXANE-METHANE SYSTEM
1000
50 60
1.50 atm pressure 2,000
800 1,700
To obtain true enthalpy add enthalpy
devIation to enthalpy at saturation 1.600
1.500
1.400 Q)
c
('Ij
.s::::.
1.300 Q)
E
1.200 ~
"0
en
1.100 .:.::
......
en
1.000 .:.::
400
.900 '6
i:!'
'E
.800 ::J
.s::::.
Q)
.700 ~
(5
en
.2"'-- V~ /' ,,,~ 7 .l"
V ... c..-
/ --L
_...........--- ......
r---.. ::::s......
........·.. ,7'---'--r~~
""""'-
4- ""-_~
,600 .0
«
£-
200 ~- - / / 1 I ...........
/'..J, -
,500
10..-/ ; ; ............ 1.........- ><:::::~ I __ ....-7 - ....-""- _ ....-'<..::::1_ .400
.L .........- . . . . . . .?-
-
- -I Ir\"T< ~ ~ "'-
00
r~ v
__
_
-
- 1--
I
,......<: .....- ...........
'"<::
-
L--
-
_ --
-
" '-
~ "' 1
_
;-
'>;C -rq _ _
-+-
I --
T
I'
-<:.:
~
-
-- :::::d,
::-0 ... . ...... ......
-- "
'l-\l .....
- - .300
.200
, , '--.... I 1 ,~'o I, hi m,,,;
I
.. .1 00
.. .. 1
0-
_ I
I · J •• ' . t-- v
"
0 10 20 30 40 50 60
1.000 Q)
c
(Ij
.c
.900 Q)
E
~
.800 ""C
--
OJ
.::.:.
0>
.700 .::.:.
300
~
'C
250
.600 'E
:::J
.c
Q)
200
.500 ::;
"0
en
.0
150
.400 «
10
.7""'--__
.300
100
X .........
......... I ?"' ~ ~ -- >~() ~ --~ - - - '------ ~-_ -
~ __ S h l
""':>?" -
--: ., -~..c.::::: .. ,;.::.- ~r:::=- .~~ I _ - __ ~ ===
<-- v __ ~
I
_ b-<::::1 .....
--.:: .--.::... - - --,.
--=""""'
....
" --~
I ............ =-=-
....:..:...'"-.. -
~ ---- - : - : -.. : : : . . . . : - I
_- 1- .200
I--
-
- - . ~.. ~
'_"'o-<r--_
~
_ . . .,
~
~ ..... -: . - .' I ' - I --
.100
-
_ ~"'- . ___ ' --4- l""Ie,.
-
0
t-- In
or=: t-- .- .- r.::.::::- .000
o 10 20 30 40 50 60
380
N-HEXANE-METHANE SYSTEM
5.00 atm pressure
340
.580
Enthalpy datum: liquid water O.O·C, 0.0597 atm
.560
dry methane O.O·C, 1.00 atm .540
.520
To obtain true enthalpy add enthalpy .500
deviation to enthalpy at saturation .480
.460
.440
.420 CI>
c
ctI
.400 .s=
.380 Q)
E
.360 ~
"0
.340
--
01
.320
.::s:
01
.::s:
-
.300
.280 >.
.260 '5
·E
-
.240 ::J
.s=
.220 CI>
::J
.200 (5
(J)
.180 .0
.160
«
.140
.120
.100
.080
20
.060
.040
o .020
.000
o 10 20 30 40 50 60
1500
BENZENE-METHANE SYSTEM
1400
60 70
0.80 atm pressure . . . . ... ,,. . .""":z:-..~-:-'t-""-"i-V-+--"-""""""'--r--r-""c...:.; 3.000
I~~A""""-....:::::;:::/~~.:'--../",",",=,~
Enthalpy datum: liquid benzene 25.0°C, O, l249 atm
1300 /--+-J-I-+----7I-'-/-f-+--++:'Vf---l--:
~
L' ~
lL "1
~~ 2.900
I--+-~!::---"'-f--+---'-fr-------jr---t-----;+---f--"--;"=--=+~"r+ 2.800
dry methane 25,O°C, ] .00 atm ~'---=A'-i~---:--.f--..=:·-f-'=""'!o-I-/+-----r---,i1ut"1_+----+-t/'---r-_ _-l.n_ ·:!..-++v
1
' . 2.700
1200
/ II 7/r-- t-,£.:~1-- I.Qj : 'I I.... /
1-i7I/~=:::.:~~d~r---r---;---,'IV
/ M--/-k----+. ./_!--_A-~+--f-I/_--';;":--f~
T-i r----t 2.600
To obtain true enthalpy add enthalpy
deviation to enthalpy at saturation
/
L
I-+-+-+--Tl-:
/ I
.
- - ----r;~ ~
/.
L ':
/
~Y--",(f!l<"'-R-;;n;t"?'I(' T-r-
/
".
r
~cbt /1).1 7;-- 2.400
2.500
"'e) '..,
--,,:~
., "0
t-1-----;1I-I!~r:r=:=::::r~t~:v=t:::==:::j::::tLI-t --\I'---f">'-:~
~__:+ 2,300
-/ / / ---"r---
40 /
/ rr--- V'"/. - - / / .. /
/. ------..---. .
2200
L 2,100 a>
- / r"----L :/ / /
/
7j--..:·'-.
'7"
// 1 / . Q>
"O-t-- t 2,000
c:
~
/1 - --.:.,~.~~ . 1.900 E
/ /;( /L / 7r---__ / )< /.'
Y / /
", 1 ' . --'
1.800 ~
/ 1 / 1/ / Y / ~__ / ' :~O / - ~::~~ ~
/ Y-~.--..LAI / / / -:::- V 1.500 ~
/ / I /--=, / V
/ ol~ / / / /---~ /'
./ .../ ./ / >--
";>::- / .../
--
1/ I . .... :<".~ ...
1.000
,(\~
.900
.."c / , / - - " / / / I / 1
20/ / / ' ----". --" ? / . . . . .(. . . . -----t-. I .800
.700
/ 1
---
/ .../ / ./ 1< I;Q'jJ../ ~ J-- .600
../ -----..__./ ......... ' A' >r<- I 1 ......... "-- .-,--" .2 dfl
- ---
.. .. -r.... .. .500
-
___ __ ---- I ___ .o .. . ....~ --:-:-J. ~ ~ ... ~ .. ........ .. ..... . .. - . "~~'~ ..... ~
100
... - ..
~
\IV
....... .........." . . . . . . . .200
-
- - I
o
~
.•••• - 1- • •• --
.100
.000
10 20 30 40 50 60 70
1000
BENZENE- METHANE SYSTEM
9S0
ro
r......
.. ~ 60 .,
1.00 atm pressure 900 '----J "J. / ,' / I 2.000
/ I -r.- ~ j / "/ ~ / 1.9S0
Enthalpy datum: liquid benzene 2S.0°C, 0.1249 atm 8S0 / I / :' I "''::::-;- -I- "/ . . . . . ~40 1.900
dry methane 2S .0°C, 1.00 atm /... I I ,'. : ~e" ~_ ' 1.8S0
800 r-- 'I-... / ,' / :/ ~olL r:--f-t-- 1.800
I
I
~
/;---....
/
/..............
1--11-;...
/
/:
',
/
f7C t-- "
~ n'}k,
~ 'Yfh~
I.
r f..!..<'if)e"
1.7S0
1.700
r
1.6S0
deviation to enthalpy at saturation
0~ 700 t+- / . / t--.. !7-t-- ~u 1.600
)"'<:\~6S0 ~ / I--,~ 1/ '. r--J /
r--- /' ..
/ 1.SS0
v / 'K / / r---:.L 1.S00
~O; 1.4S0
\'*:S .L / ~ : / ' ~ li
600
r--- r--r-.- 1.400
Q>
-
" / I 7'"-1-- : V / / -"':t-:-, c
1.3S0 m
,t--., ::L.. 1.300 .!:
'. '0 r-:-:::. . 1.2S0 Q>
-I-- '. / E
1.200 ~
V 1.1 SO '0
/
--
0)
1.100 .::£
1.0S0 0 )
.::£
-
1.000
.950 >.
.900 ' 6
.850 'E
.800 ::J
.!:
.7S0 Q>
.700 '5
.. ' . .6S0 '0
CIJ
.600 .0
.SSO «
.SOO
1 Q~
---
.4S0
-.. .400
.3S0
.300
.2S0
so . --. -. -
- it I -_
1--''' ' .... -- -- . . .. ......... .. .200
.- - - -- -- - _.. -_ .
.. -l -- · .... · ..
-.
.... j--... .. .150
O ~
Q"latlv~ --
. .. ... .. .. <.:..: -- -
~- n .. __ .. .100
.. .. .. f -- .. · . -
I .050
.~ -- ..... --_._.
. ; .. ,.... .. .000
10 20 30 40 so 60 70
850
BENZENE-METHANESYSTEM
800 50 60 70
1.2o atm pressure 1.700
~ Y :----f ~ I .L / ~ / ............
1.650
En thalpy datum: liquid benzene 25.0' C, 0.1249 atm
750
I '. . . . . 1 l ~r:- 1-1- : ~
~
r r--=:::: 1.600
,
/ / r.......... : I I~ ~ '.
-
dry methane 25.0'C, 1.00 atm 700
:/ 1.SS0
I ~~ ~ / ............
I ". ""'l!! 1.S00
6S0 / '-..J / ~ t--. / / '. /
1.450
--y. ~S..o1O
To obtain true enthalpy add enthalpy
dey iation to enthalpy at saturation ~
'0......
1>-<:'-
600
/
J
/
- f-- -L
/ ~
~ /
/
/ : ...... ~v. {"
;I- ....:... ~ /",
'. I~ 1' D,
1.400
1.3S0
1/ I / ~ f17Jt. I /
'"
"-......j
-
: ~ ~V : ~
- -r-
1.300
---
40/
~o<A 5S0 '- / '-....,t. / 7 r---..... ~ ~~"" 1.2S0
-s.~ / ~' / ~ ~~ _1
1.200 a>
/ I'-/:. / 1: / 1.... I /'.
-
\...'i-' SOO i'""---7 -...........
~.
c
-::-r--
-- _
1.150 ro
'0" . 0"
~
} ~ / :
'------ l-L-1 / / --:;: :::-... ". ~ ..c
~ ~S-'lf .0' ..( / 1.100
~,.§ 4S0 / "7 ~ ~ / -.. . . :::,.:--- -L ~ .
a>
E
-
'i:J'lf 0 \... ---""""'t-.
/'" r-- ........ ,...::.../
1.050
~'i:J )<..... / / ~ ~ ""/$ 1.000 2:-
'If
:.o~V ~~.;§ / / V ......... 7' - / ", / V "'·
-
~~.::.. 400 ~ -r-.. /. "0
~
~ &'If Q0 ~f-=- / / r ......... / ::-r-r: ::::--.. / . ..............r-../ - ~
.9S0 0>
-.
~
~ .....0~ / /~ 7 , .900
-L ><......::: r-- ~
-
-
OJ
~ 3S0 ............... . ,/ -........... 1 >.
_ ':: ---.: '
~
.850
/ r:;;: k ,/ I -"""""V ~f'-; V ............... , /0 ::-::=,
.800
300
30 ........
~ / / .......:::". ~
/' -:-;....
--/ r-- -Z. .......... .7S0
£"0
/ ./ 01;;:; ~ /j / ~ :---.
"7- -:, t'--....... /' .........' '.7- -,-.
~.
·E
-
- -
-....:; .700
'-........l ./ :::---.k A " :.:.&
-
:::l
250 /- "--- ~ / ' ~ ~
I
.6S0 ..c
/"--- V "~olg, V
.//1
)/
........
~ ./' 0::::::::...: ~L I """ ~ ~ a>
200 L / / ~ 1/ r--.:::::: ---,.<
"""> /' ~
·v :------- I
.600 :::l
(5
>< / .~oJo ::><...... y ..:::><-:.::: ...... "'" r---..:. ~
.5S0 (J)
150~
/" /'" ~ --"
.0
..,:,:-:-:
.500
«
-
/' :;::::,s:
wE /---
""----> ......-
/" /' - "-
2 0 / 1/ /"
.450
-
.........
/" I ../ <-......... :---......
.
~ > 1<- 'SOp ~
- -
-..,;:;::
'><
--- ""-----
~
...... .350
....... ....,.. ....... 1........- .......... "-.......
----- ........
---
;:::'~
.300
t'" :.-- .......... ~nt -----
--::-:-:-.:::-
1 ::------... ~ UPv
so '- --
",",
.- . - .. -. - -_ ._. . .... ..... - .. _- ... ... . - ..
II.
.2S0
.... .----
. _0'-- - ne
-;- ........
.. ~ .--- ~
.---" ......
--- 0- ~
. --,;.- .. --a .•
.200
:::---...
':-,
I -.:.~ :::--"'11.50'
-
••• 0 - -
I
,v .1S0
o- - .---- . ..~ .---- ._ ---- ---.- . ... _-- "'
.'
, . -.- ---_.. -..::: . -- ....:.:..: .:1-- --.. .. ."'-. ' -{: <ld -'-- ... ... ·---· i----
..
• • - _0"
__ 0' '. ~v '
.., . .000
'"
" ., . . , .. .• " . I " ,
." "' "
10 20 30 40 50 60 70
BENZENE-METHANE SYSTEM
70
1.50 atm pressure ..,.....-,..,."""",--+ 1.400
...-+~-tl--'='t-'~"""'""""'7",",+'--t".........-it-.......,...+--,"_..................
1-+--+P-.;;.-t--/--+---+"-:~......"jd-4~+--¥--f----r- 1.350
Enthalpy datum: liquid benzene 25.0·C, 0.1249 atm
dry methane 25 .0·C, 1.00 atm
~o<A 450
1.050
~~ 1.000
Q)
\..'*' .950 c
. o~ 400 co
..c
~v,
~ .900 1ii
E
~":J?f 350 .850
~
.800 ""0
~~~
~
OJ
.l<:
<v~ 300 .750 .......
0>
.l<:
-
.700
.650 >.
:g
.600
E
:::J
.550 ..c
Q)
.500
"5
.450 (5
en
.c
.400 ~
.350
.300
.250
.200
.150
o .100
.050
.-_, _0-
. .. , .000
10 20 30 40 50 60 70
BENZENE-METHANE SYSTEM
70
2.00 atm pressure 1.000
.850
To obtain true enthalpy add enthalpy
deviation to enthalpy at saturation .800
.750
.700 a>
c
co
.J::
.650 Q)
E
.600 c:-
"0
.550 OJ
......
~
OJ
~
.500
~
.4S0 '0
'E
.400 ::J
.J::
a>
.3S0 '5
'0
tJ)
.300 .0
«
.2S0
.200
.1S0
o .100
m .OSO
.000
10 20 30 40 50 60 70
70
5.00 atm pressure .400
.340
To obtain true enthalpy add enthalpy
deviation to enthalpy at saturation .320
.300
.280 Q)
-
c
ct!
.c
.260 Q)
E
.240 ~
"C
.220 0>
80 -....
~
0>
~
.200
~
.180 ii
'E::J
40 .160
.c
Q)
.140 :;
20 '0
(/)
.120 .0
<{
.100
.080
-20 .060
.040
.020
·40
.000
10 20 30 40 50 60 70
TOLUENE-METHANE SYSTEM
60
0.80 atm pressure .680
.660
Enthalpy datum: liquid toluene O.O·C, 0.00893 atm · .640
dry methane O.O·C, 1.00 atm ~ .620
.600
.580
To obtain true enthalpy add enthalpy
.560
deviation to enthalpy at saturation
.540
.520
.500
.480 <1l
c:
.460 ell
.!:
.440 ai
.420 E
.400 ~
"0
.380 Cl
.360 ......
..l<:
Cl
..l<:
.340
.320 Z,
.300 '6
.280 'E
:::J
· .260 ..c:
<1l
.240 "5
.220 (5
(/)
.0
.200
«
.180
.160
.140
.120
.100
.080
20 .060
.040
· .020
.000
o 10 20 30 40 50 60
TOLUENE-METHANE SYSTEM
60
1.00 atm pressure ~~~~-+-+~~~~~~~~~~~~.500
~~++~~~+-~~~~~--~~+---~~.480
Enthalpy datum: liquid toluene O.O°C, 0.00893 atm
~-+~-r~*---~~~-~~+-~~~~~--~. 460
dry methane O.O°C, 1.00 atm
r+--~=-~~r-~---+'~~~+-~~++--~+-4 .440
260
To obtain true enthalpy add enthalpy ~~~~~~~~~ __~--~--~~~r+--A-~~.420
deviation to enthalpy at saturation /-r~~~'A~~~+--h~d-~~~~-t~~~~~.400
/-~~~~~~~-+--A-~~~~~--~~~~~~. 380
r+~~~~~~~~~~~--~~~~--~=-+-~~~.360
~~~~~~~~~~~~~-+--~~d-~~~~~--~~~~~~~~~~~~~--~~d-~. 120
~~~~~~~-+~~--~~~~~~~~--~~~~--~--~~F--4~~~~~+-~~~~~~~~ .100
~~~~~~~~~~~~~~~~~~~~~~-+~~~~~~~~+---~~--~--~~~~~~+-~~~.080
20 ~~~T-~~~~~~~~~-±~~~~~~~---+~~~~~~~---P~~--~~~~~~~~~h--+--~~~~~-+. 060
o §~~~~tmtte~~'040 .020
.000
o 10 20 30 40 50 60
TOLUENE-METHANE SYSTEM
60
1.20 atm pressure .400
.340
To obtain true enthalpy add enthalpy
deviation to enthalpy at saturation .320
.300
.280 C1l
c:
en
..c::
.260 Q3
E
.240 C!:-
"0
C)
.220 ~
"OJ
~
.200
>-
.t =
.180 "0
'E
.160 :::l
..c::
C1l
.140 "5
"0
IJ)
.120 .0
<!
.100
.080
20
.060
.040
.020
o
.000
o 10 20 30 40 50 60
TOLUENE-METHANE SYSTEM
60
1.50 atm pressure .320
.240
<1l
-
.220 c
<tl
.c
<1l
.200 E
~
"0
.1BO 0'1
.:x
.160
---0'1
.:x
~
.140 '5
'E
-
:::J
..c
.120 <1l
:::J
(5
.100 en
.0
c::x::
.OBO
.060
.040
.020
o
.000
o 10 20 30 40 50 60
TOLUENE-METHANE SYSTEM
2.00 atm pressure
.250
Enthalpy datum: liquid toluene O.O°C, 0.00893 atm
.240
dry methane O.O°C, 1.00 atm
.230
.220
To obtain true enthalpy add enthalpy
deviation to enthalpy at saturation .210
.200
.190
(l)
.180 c:
en
.170 ..c::
Q)
.160 E
C!'
.150 "0
--en
C>
.140 ~
~
.130
.120 ~
'6
.110 'E
-
::J
.100 ..c::
(l)
.090 ::J
(5
.080 II)
.0
.070
«
.060
.050
10 .040
.030
.020
.010
.000
o 10 20 30 40 50 60
TOLUENE-METHANE SYSTEM
5.00 atm pressure
.090
Q)
-
c
.080 ctS
.c
Q)
E
.070 ~
"C
Ol
-..
~
Ol
~
.060
~
'5
.050 'E
::J
.c
Q)
:5
.040 a
(J)
..c
«
.030
o .020
.010
.000
o 10 20 30 40 50 60
practice, John Wiley and Sons, New York Palmatoer E.P. (1963) Construction of the normal temperature
Hayduk, W., (1982), Solubility Data Series - Volume 9 - Ethane, ASHRAE psychrometric chart, ASHRAE Transactions 69,7-12
Pergamon Press, Oxford Pitzer, K.S. (1990) Second virial coefficients for mixed gases of
Hayduk, W., (1986), Solubility Data Series - Volume 24 - Propane, low polarity. Fluid Phase Equilibria 59, 109-13
butane and 2-methylpropane, Pergamon Press, Oxford Orbey, H. and Vera, 1.H. (1983) Correlation for the third virial
Hyland, RW. and Wexler, A. (1983a) Formulations for the coefficient using Tc' Pc and ro as parameters. American Institute
thermodynamic properties of dry air from 173.15 K to 473.15 of Chemical Engineers Journal 29(1), 107-13
K, and of saturated moist air from 173.15 K to 372.15 K at Reid, RC., Prausnitz, J.M. and Sherwood, T.K. (1977) The
pressure to 5 MPa. ASHRAE Transactions 89(2A),520-35 Properties of Gases and Liquids, 3rd edn, McGraw-Hill Book
Hyland, RW. and Wexler, A. (1983b) Formulations for the Company, New York
thermodynamic properties of the saturated phases of H20 from Shallcross, D.C. and Low, S.L. (1994) Construction of
173.15 K to 372.15 K at pressure to 5 MPa. ASHRAE psychrometric charts for systems other than water vapour in air,
Transactions 89(2A), 500-19 Chemical Engineering Research and Design, 72 763-76
Keenan, J.H., Keyes, F.G., Hill, P.G. and Moore, J.G. (1978) Steam Shallcross, D.C. (1996) Psychrometric Charts for Hydrocarbon
Tables Thermodynamic properties of Water Including Vapour, Vapours in Nitrogen. Calphad 20(3) 273-88
Liquid and Solid Phases John Wiley and Sons, New York Taylor, F.W. (1988) The Dynamics of the Atmosphere of Venus, in
Kehianian, H.V. (1996) Virial coefficients of selected gases, in CRC The Physics of the Planets, (ed S.K. Runcom), John Wiley and
Handbook of Chemistry and Physics, ??th edn, (ed D.R.Lide), Sons, 144
CRC Press, Boca Racon, Florida, 6-27 - 6-46 Threlkeld, J.L. (1975) Thermal Environmental Engineering, 2nd
Kell, G.S. (1975), Density, thermal expansivity, and compressibility edn, Prentice-Hall Inc., Englewood Cliffs, New Jersey
of liquid water from 0 0 to 150°C: correlations and tables for Vargaftik, N.N. (1975) Handbook of Physical Properties of Liquids
atmospheric pressure and saturation reviewed and expressed on and Gases, 2nd edn, Hemisphere Publishing Company,
1968 temperature scale', Journal of Chemical Engineering Data Washington
20(1) 97-105 Weast, Re. and Astle, M.J. (1980) CRC Handbook of Chemistry
Kertes, A.S. (1987) Solubility Data Series - Volume 27128 - and Physics, 60th edn, CRC Press, Boca Racon, Florida, D-174
Methane, Pergamon Press, Oxford Yaws, C.L. (1992) Thermodynamic and Physical Property Data,
Lee, B.I. and Kesler, M.G. (1975) A generalised thermodynamic Gulf Publishing Company, Houston
correlation based on the three-parameter corresponding states,
American Institute of Chemical Engineers Journal 21(3) 510-
27
McGowan, J.e. (1980) Isothermal compressibility of liquids, in
CRC Handbook of Chemistry and Physics, 60th edn, (eds RC.
Weast and M.1. Astle), CRC Press, Boca Racon, Florida, F-16 -
F-20
Morrison, D. and Owen, T. (1988) The Planetary System, Sddison-
Wesley Publishing Company, Reading, 297
30°C to 120°C 61
3.00 atm ooe to 50°C 62
30°C to 120°C 63
4.00 atm ooe to 50°C 64
Index of Psychrometric Charts 30°C to 120°C 65
5.00 atm ooe to 50°C 66
30°C to 120°C 67
6.00 atm ooe to 50°C 68
30°C to 120°C 69
8.00 atm ooe to 50°C 70
Water-Air 0.50 atm ooe to 50°C 36 30°C to 120°C 71
30°C to 120°C 37 10.00 atm ooe to 50°C 72
0.80 atm ooe to 50°C 38 30°C to 120°C 73
30°C to 120°C 39 Water-Nitrogen 0.80 atm ooe to 50°C 74
0.90 atm ooe to 50°C 40 30°C to 120°C 75
30°C to 120°C 41 1.00 atm ooe to 50°C 76
0.95 atm ooe to 50°C 42 30°C to 120°C 77
30°C to 120°C 43 1.10 atm ooe to 50°C 78
1.00 atm ooe to 50°C 44 30°C to 120°C 79
30°C to 120°C 45 1.20 atm ooe to 50°C 80
1.05 atm ooe to 50°C 46 30°C to 120°C 81
30°C to 120°C 47 1.50 atm ooe to 50°C 82
1.10 atm ooe to 50°C 48 30°C to 120°C 83
30°C to 120°C 49 2.00 atm ooe to 50°C 84
1.20 atm ooe to 50°C 50 30°C to 120°C 85
30°C to 120°C 51 3.00 atm ooe to 50°C 86
1.40 atm ooe to 50°C 52 30°C to 120°C 87
30°C to 120°C 53 4.00 atm ooe to 50°C 88
1.60 atm ooe to 50°C 54 30°C to 120°C 89
30°C to 120°C 55 5.00 atm ooe to 50°C 90
1.80 atm ooe to 50°C 56 30°C to 120°C 91
30°C to 120°C 57 8.00 atm ooe to 50°C 92
2.00 atm ooe to 50°C 58 30°C to 120°C 93
30°C to 120°C 59 10.00 atm ooe to 50°C 94
2.50· atm ooe to 50°C 60 30°C to 120°C 95
Index of Psychrometric Charts 3/3
Water-Methane 0.80 atm ooe to 50°C 96 Water-21 % CO2 / 79 % N2 0.80 atm ooe to 50°C 132
30°C to 120°C 97 30°C to 120°C 133
1.00 atm ooe to 50°C 98 1.00 atm ooe to 50°C 134
30°C to 120°C 99 30°C to 120°C 135
1.20 atm ooe to 50°C 100 1.20 atm ooe to 50°C 136
30°C to 120°C 101 30°C to 120°C 137
1.50 atm ooe to 50°C 102 1.50 atm ooe to 50°C 138
30°C to 120°C 103 30°C to 120°C 139
2.00 atm ooe to 50°C 104 2.00 atm ooe to 50°C 140
30°C to 120°C 105 30°C to 120°C 141
3.00 atm ooe to 50°C 106 3.00 atm ooe to 50°C 142
30°C to 120°C 107 4.00 atm ooe to 50°C 143
4.00 atm ooe to 50°C 108 5.00 atm ooe to 50°C 144
30°C to 120°C 109 30°C to 120°C 145
5.00 atm ooe to 50°C 110 Water-lO % eo2 / 90 % N2 0.80 atm ooe to 50°C 146
30°C to 120°C 111 30°C to 120°C 147
10.00 atm ooe to 50°C 112 1.00 atm ooe to 50°C 148
30°C to 120°C 113 30°C to 120°C 149
Water-Helium 1.00 atm ooe to 50°C 114 1.20 atm ooe to 50°C 150
30°C to 120°C 115 30°C to 120°C 151
2.00 atm ooe to 50°C 116 1.50 atm ooe to 50°C 152
30°C to 120°C 117 30°C to 120°C 153
5.00 atm ooe to 50°C 118 2.00 atm ooe to 50°C 154
30°C to 120°C 119 30°C to 120°C 155
Water-Neon 1.00 atm ooe to 50°C 120 3.00 atm ooe to 50°C 156
30°C to 120°C 121 4.00 atm ooe to 50°C 157
2.00 atm ooe to 50°C 122 5.00 atm ooe to 50°C 158
30°C to 120°C 123 30°C to 120°C 159
5.00 atm ooe to 50°C 124 Water-Natural Gas A 0.80 atm ooe to 60°C 160
30°C to 120°C 125 1.00 atm ooe to 60°C 161
Water-Argon 1.00 atm ooe to 50°C 126 1.20 atm ooe to 60°C 162
30°C to 120°C 127 1.50 atm ooe to 60°C 163
2.00 atm ooe to 50°C 128 2.00 atm ooe to 60°C 164
30°C to 120°C 129 5.00 atm ooe to 60°C 165
5.00 atm ooe to 50°C 130 Water-Natural Gas B 0.80 atm ooe to 60°C 166
30°C to 120°C 131 1.00 atm ooe to 60°C 167
314 Index of psychrometric charts
1.20 atm ooe to 60°C 168 1.20 atm -10°C to 40°C 204
1.50 atm ooe to 60°C 169 1.50 atm -10°C to 40°C 205
2.00 atm ooe to 60°C 170 2.00 atm -10°C to 40°C 206
5.00 atm ooe to 60°C 171 5.00 atm -10°C to 40°C 207
Water-Martian Atmosphere 0.80 atm ooe to 60°C 172 Ethanol-Air 0.80 atm ooe to 60°C 208
1.00 atm ooe to 60°C 173 1.00 atm ooe to 60°C 209
1.20 atm ooe to 60°C 174 1.20 atm ooe to 60°C 210
1.50 atm ooe to 60°C 175 1.50 atm ooe to 60°C 211
2.00 atm ooe to 60°C 176 2.00 atm ooe to 60°C 212
5.00 atm ooe to 60°C 177 5.00 atm ooe to 60°C 213
n-Pentane-Air 0.80 atm -30°C to 30°C 178 n-Propanol-Air 0.80 atm ooe to 60°C 214
1.00 atm -30°C to 30°C 179 1.00 atm ooe to 60°C 215
1.20 atm -30°C to 30°C 180 1.20 atm ooe to 60°C 216
1.50 atm -30°C to 30°C 181 1.50 atm ooe to 60°C 217
2.00 atm -30°C to 30°C 182 2.00 atm ooe to 60°C 218
5.00 atm -30°C to 30°C 183 5.00 atm ooe to 60°C 219
n-Hexane-Air 0.80 atm ooe to 60°C 184 n-Butanol-Air 0.80 atm ooe to 60°C 220
1.00 atm ooe to 60°C 185 1.00 atm ooe to 60°C 221
1.20 atm ooe to 60°C, 186 1.20 atm ooe to 60°C 222
1.50 atm ooe to 60°C 187 1.50 atm ooe to 60°C 223
2.00 atm ooe to 60°C 188 2.00 atm ooe to 60°C 224
5.00 atm ooe to 60°C 189 5.00 atm ooe to 60°C 225
n-Heptane-Air 0.80 atm ooe to 60°C 190 Acetone-Air 0.80 atm -10°C to 40°C 226
1.00 atm ooe to 60°C 191 1.00 atm -10°C to 40°C 227
1.20 atm ooe to 60°C 192 1.50 atm -10°C to 40°C 228
1.50 atm ooe to 60°C 193 2.00 atm -10°C to 40°C 229
2.00 atm ooe to 60°C 194 5.00 atm -10°C to 40°C 230
5.00 atm ooe to 60°C 195 1.00 atm 20°C to 70°C 231
n-Octane-Air 0.80 atm ooe to 50°C 196 1.50 atm 20°C to 70°C 232
1.00 atm ooe to 50°C 197 2.00 atm 20°C to 70°C 233
1.20 atm ooe to 50°C 198 5.00 atm 20°C to 70°C 234
1.50 atm ooe to 50°C 199 Benzene-Air 0.80 atm 10°C to 70°C 235
2.00 atm ooe to 50°C 200 1.00 atm 10°C to 70°C 236
5.00 atm ooe to 50°C 201 40°C to 100°C 237
Methanol-Air 0.80 atm -10°C to 40°C 202 1.50 atm 10°C to 70°C 238
1.00 atm -10°C to 40°C 203 40°C to 100°C 239
Index of Psychrometric Charts 315
2.00 atm lOoC to 70°C 240 1.20 atm lOoC to 70°C 276
40°C to lOO°C 241 1.50 atm lOoC to 70°C 277
5.00 atm lOoC to 70°C 242 2.00 atm 10°C to 70°C 278
40°C to lOO°C 243 5.00 atm lOoC to 70°C 279
Toluene-Air 0.80 atm O°C to 50°C 244 Toluene-Nitrogen 0.80 atm O°C to 60°C 280
30°C to 90°C 245 1.00 atm O°C to 60°C 281
1.00 atm O°C to 50°C 246 1.20 atm O°C to 60°C 282
30°C to 90°C 247 1.50 atm O°C to 60°C 283
1.20 atm O°C to 50°C 248 2.00 atm O°C to 60°C 284
30°C to 90°C 249 5.00 atm O°C to 60°C 285
1.50 atm O°C to 50°C 250 n-Pentane-Methane 0.80 atm lOoC to 80°C 286
30°C to 90°C 251 1.00 atm lOoC to 80°C 287
2.00 atm O°C to 50°C 252 1.20 atm lOoC to 80°C 288
30°C to 90°C 253 1.50 atm lOoC to 80°C 289
5.00 atm O°C to 50°C 254 2.00 atm lOOC to 80°C 290
30°C to 90°C 255 5.00 atm lOoC to 80°C 291
Carbon Tetrachloride-Air 0.80 atm O°C to 60°C 256 n-Hexane-Methane 0.80 atm lOoC to 60°C 292
1.00 atm O°C to 60°C 257 1.00 atm lOoC to 60°C 293
1.20 atm O°C to 60°C 258 1.20 atm lOoC to 60°C 294
1.50 atm O°C to 60°C 259 1.50 atm lOoC to 60°C 295
2.00 atm O°C to 60°C 260 2.00 atm lOOC to 60°C 296
5.00 atm O°C to 60°C 261 5.00 atm lOOC to 60°C 297
Diethyl Ether-Air 0.80 atm -40°C to 20°C 262 Benzene-Methane 0.80 atm lOoC to 70°C 298
1.00 atm -40°C to 20°C 263 1.00 atm lOoC to 70°C 299
1.20 atm -40°C to 20°C 264 1.20 atm lOoC to 70°C 300
1.50 atm -40°C to 20°C 265 1.50 atm 10°C to 70°C 301
2.00 atm -40°C to 20°C 266 2.00 atm lOoC to 70°C 302
5.00 atm -40°C to 20°C 267 5.00 atm lOoC to 70°C 303
Acetone-Nitrogen 0.80 atm -lOoC to 50°C 268 Toluene-Methane 0.80 atm O°C to 60°C 304
1.00 atm -lOoC to 50°C 269 1.00 atm O°C to 60°C 305
1.20 atm -lOoC to 50°C 270 1.20 atm O°C to 60°C 306
1.50 atm -lOoC to 50°C 271 1.50 atm O°C to 60°C 307
2.00 atm -lOoC to 50°C 272 2.00 atm O°C to 60°C 308
5.00 atm -10°C to 50°C 273 5.00 atm O°C to 60°C 309
Benzene-Nitrogen 0.80 atm lOoC to 70°C 274
1.00 atm lOoC to 70°C 275
Humidity ratio, see Absolute humidity
Interpolation 8
Isothermal compressibility 11-2, 25-6
Index
Latent heat of vaporization 28-9
Water
isothermal compressibility 25-6
latent heat of vaporization 28
molar volume 27
second virial coefficient 21
specific enthalpy 29
third virial coefficient 23
vapour pressure 24
Wet bulb temperature 3, 14
see also Adiabatic saturation temperature