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Q1. To produce characteristic X -rays using a tungsten target in an X -ray generator the
accelerating voltage should be greater than………. volt and the energy of the
characteristic radiation is………. eV .
(The binding energy of the innermost electron in tungsten is 40 keV .)
Solution: Binding energy of innermost electron = 40keV
This is in fact the ionization potential of tungsten.
⎛1 1 ⎞
40 × 103 ⎜ 2 − 2 ⎟
∴Vmin = ⎝ 1 2 ⎠ = 30, 000 volt
⎛1 1⎞
⎜ 2− ⎟
⎝1 ∞ ⎠
∴Energy=30,000 eV.
β − particle is −1 e0 , Z = −1, A = 0
∴ n1 × 4 = 238 − 206 = 32 or n1 = 8
For Z ,
( n1 × 2 ) − ( n2 ×1) = 92 − 82
or ( 8 × 2 ) − 10 = n2 or n2 = 6
Q8. The binding energies per nucleon for deuteron ( H ) and helium (
1
2
2 He 4 ) are 1.1 MeV
and 7.0 MeV respectively. The energy released when two deuterons fuse to form a
( )
Solution: 2 1 H 7 →2 He 4
Q9. The wavelength of the characteristic X-ray K α line emitted by a hydrogen like element is
0
0.32 Α . The wavelength of the K β line emitted by the same element will be……………
Solution: Kα correspondence to : n = 2 to n = 1
K β correspondence to : n = 3 to n = 1
1 ⎡1 1⎤
=C⎢ 2 − 2⎥
λα ⎣ n1 n2 ⎦
1 ⎡ 1 1 ⎤ 8C
or =C⎢ 2 − 2⎥=
0.32 A ⎣1 3 ⎦ 9
1 ⎡ 1 1 ⎤ 8C
→ =C⎢ 2 − 2⎥=
λβ ⎣1 3 ⎦ 9
λβ 3C 9 27
∴ = × or λβ = × 0.32 A
0.32 A 4 8C 32
or λβ = 0.27 A
Q10. The Bohr radius of the fifth valence electron of phosphorous atom (atomic number = 15)
0
acting as a dopant in silicon (relative dielectric constant = 12) is ……….. Α .
Solution: The fifth valence electron of phosphorous lies in its third shell i.e. n = 3
∴ Bohr radius = rn
⎡ n2 ⎤ ⎡ 32 ⎤
∴ rn = ⎢ Er ⎥ r0 or rn = ⎢ × 12 ⎥ × 0.53 A
⎣Z ⎦ ⎣15 ⎦
or rn = 3.81A
Q11. In an X-ray tube, electrons accelerated through a potential difference of 15,000 volt strike
a copper target. The speed of the emitted X-rays inside the tube is …………… m/s.
Solution: X − rays are electromagnetic waves which travel with speed 3 ×108 m / s in vacuum.
The speed of emitted X − rays does not depend on the accelerating potential applied to
electrons.
∴ The speed of X -rays =3 ×104 m / s
Q12. In the Bohr model of the hydrogen atom, the ratio of the kinetic energy to the total energy
of the electron in a quantum state n is
Solution: The kinetic energy of an electron in nth orbit of hydrogen atom is
me 4
K= 2 2 2
8ε 0 h n
The total energy of an electron in nth orbit of hydrogen atom is
− me−4
E= 2 2 2
8ε 0 h n
K
∴ = −1
E
Q13. In the nuclear process, 6 C11 → 5 B11 + β + + X , X stands for ……………
6 C11 →5 B11 + ( +1 )
e0 + υ (neutrino)
X stands for neutrino.
Q14. A potential difference of 20 kV is applied across an X − ray tube. The minimum
wavelength of X − rays generated is………Ǻ.
Solution: λmin =
hc
=
(
6 ⋅ 63 × 10−34 × 3 ×108 ) (
= 0.62 Ǻ
)
eV (
1.6 ×10−19 × 20 ×103 ) ( )
Q15. The wavelength of Kα X − rays produced by an X − ray tube is 0.76Ǻ. The atomic
number of the anode material of the tube is………
Solution: For ( Kα ) X - rays
1 2 ⎡ 1 1⎤
− R ( Z − 1) ⎢ 2 − 2 ⎥ where n1 = 1, n2 = 2
λ ⎣ n1 n2 ⎦
⎡1 1 ⎤
( Z = 1)
2 −1
⎢⎣12 − 22 ⎥⎦ where RR = 1.1×10 m
7
( Z − 1) × 3 ×1.1×107
2
1
=
0.76 ×10−10 4
4
or ( Z − 1) =
2
−10
0.76 ×10 × 3 ×1.1×107
or ( Z − 1) = 40 or Z = 41
ΔE = 2.1×10−18 J
ΔE ΔE
∴ mv = or v=
c mc
2.1× 10−18
or v= = 4.19 m / s
( ) (
1.67 ×10−27 × 3 × 108 )
Q18. The kinetic energy of photoelectrons emitted by a photosensitive surface depends on the
intensity of the incident radiation.
Ans. False
Solution: Kinetic energy of photoelectron = Incident energy - workfunction
Kinetic energy = hυ − φ
1 2Ze 2
∴ rmin =
4πε 0 5 ×1.6 × 10−13
or rmin =
5 × 1.6 × 10−13
or rmin = 5.3 × 10−14 m
or 5.3 × 10−12 cm
The distance of closest approach is of the order of 10−12 cm
The half life of radioactive radon is 3.8 day. The time at the end of which (1 / 20) of the
th
Q22.
radon sample will remain undecayed is (given log10 e = 0.4343 )
(a) 3.8 day (b) 16.5 day (c) 33 day (d) 76 day
Ans. (b)
0.693
Solution: N = N 0 e− λ / t where λ = = 0.18
3.8
N0
= N 0 e −018t or log10 20 = 0.18 × t × log10 e
20
or 1.3 = 0.18 × 0.4343 × t
1.3
or t = or t = 16.5 day
0.18 × 0.4343
0 n1 →1 H 1 + ( 1 β 0 )
A neutron disrupts into a proton and a beta particle. The beta particle is ejected from the
nucleus. The beta particles are fast moving electrons.
Q24. If elements with principal quantum number n > 4 were not allowed in nature, the number
of possible elements would be
(a) 60 (b) 32 (c) 4 (d) 64
Ans. (a)
Solution: The maximum number of electrons in an orbit are 2n 2
If n > 4 is not allowed, the maximum number of electrons that can lie in first four orbits
are
2 (1) + 2 ( 2 ) + 2 ( 3) + 2 ( 4 ) = 2 + 8 + 18 + 32 = 60
3 2 2 2
( )
Solution: 4 11 H + →42 He2+ + 2e−1 + 26MeV represents fusion reaction. The reaction represents
atom is
(a) 38.2 (b)49.2 (c)51.8 (d)79.0
Ans. (d)
Solution: When One of the electrons is removed from a neutral helium atom, energy is given by
En
13.6Z 2
En = − eV
n2
For helium ion, Z = 2 , when doubly ionized
For first orbit, n = 1
13.6
× ( 2 ) = −54.4 eV
2
∴ E1 = −
(1)
2
or log 4 = ( λ1 + λ2 ) t log e
0.693 0.693
Now λ1 = λ2 =
1620 810
⎡ 1 1 ⎤
∴ 2.303[ 2 × 0.3] = 0.693 ⎢ + t
⎣1620 810 ⎥⎦
2.303 × 0.6 ×1620
or t = or t = 1080 year
0.693 × 3
Q31. The Kα X − ray emission line, of tungsten occurs at λ = 0.021 nm . The energy difference
between K and L levels in this atom is about
(a) 0.51 MeV (b)1.2 MeV (c) 59 keV (d) 13.6 eV
Ans. (c)
Solution: Consider the transition of an electron from L − shell to K − shell.
12375
E L − EK = where E is in eV and λ is in Ǻ.
0.21
12375
Or ΔE = = 58928 eV or .ΔE = 59 keV
0.21
Q32. Masses of two isobars 29 Cu 64 and 30 Zn 64 are 63.9298 u and 63.9292 u respectively. It
can be concluded from these data that
(a) both the isobars are stable
(b) Zn 64 is radioactive, decaying to Cu 64 through β -decay.
29 Cu 64 →10 Zn64 + ( −1 e0 )
∴ E1 =
(1)
2
= −13.6 × 9
or E1 = −122.4 eV
Q34. The maximum kinetic energy of photoelectrons emitted from a surface when photons of
energy 6 eV fall on it is 4 eV. The stopping potential, in volt, is
(a) 2 (b) 4 (c) 6 (d) 10
Ans. (b)
Solution: Stopping potential is the negative potential which stops the emission of
( K .E )max electrons when applied.
∴ Stopping potential = 4 volt
Q35. In hydrogen spectrum the wavelength of H α line is 656 nm, whereas in the spectrum of a
distant galaxy, H α line wavelength is 706 nm. Estimated speed of the galaxy with
respect to earth is,
(a) 2 × 10 8 m / s (b) 2 × 10 7 m / s (c) 2 × 10 6 m / s (d) 2 × 10 5 m / s
Ans. (b)
Solution: Since the wavelength increases from 656nm to 706 nm in respect of Hα line, the
50 × 3 × 108
or v = m/s or v = 2 ×107 m / s
656
Q36. A particle of mass M at rest decays into two particles of masses m1 and m2 , having
nonzero velocities. The ratio of the de Broglie wavelengths of the particles, λ1 / λ 2 , is
Ans. (c)
h λ1 p1
Solution: de-Broglie wavelength λ = ∴ =
p λ2 P2
λ1
Since momentum p is conserved in the decay process, p2 = p1 ∴ =1
λ2
Q37. Which of the following is a correct statement?
(a) Beta rays are same as cathode rays
(b) Gamma rays are high energy neutrons
(c) Alpha particles are singly ionized helium atoms
(d) Protons and neutrons have exactly the same mass
Ans. (a)
Solution: (a) Beta rays are same cathode rays are same as cathode rays they are streams of
electrons.
(b) Gamma rays are electromagnetic waves. They are not neutrons
(c) Alpha particles are doubly ionized helium atoms, not singly ionized helium atoms
(d) Protons have mass slightly less than that of neutrons. Masses are not exactly the same
Option (b), (c) and (d) are incorrect.
Option (a) is correct
Q38. [
Order of magnitude of density of uranium nucleus is, m P = 1.67 × 10 −27 kg ]
(a) 10 20 kg / m 3 (b) 1017 kg / m 3 (c) 1014 kg / m 3 (d) 1014 kg / m 3
Ans. (b)
Solution: Nuclear density is of the order of 1017 kg / m3
Q39. 22
Ne nucleus, after absorbing energy, decays into two α -particles and an unknown
nucleus. The unknown nucleus is
(a) nitrogen (b) carbon (c) boron (d) oxygen
Ans. (b)
Solution: 10 Ne22 → 2 ( 2 He 4 ) + 6 X 14 . The unknown nucleus ( X ) is carbon =6 C14
Q40. Binding energy per nucleon vs. mass number curve for nuclei is shown in the figure.
W , X , Y and Z are four nuclei indicated on the curve. The process that would release
energy is Y
8.5 X
8.0 W
Binding Energy 7.5
in MeV
Nucleon 5.0
0 30 60 90 120
Mass number of nuclei
(a) Y → 2 Z (b) W → X + Z (c) W → 2Y (d) X → Y + Z
Ans. (c)
Solution: When total binding energy of products is more than that of reactants, energy is released
in the process. Effectively the total binding energy is increased.
Total B.E. = B.E. per nucleon × number of nucleons
Y
8.5 X
8.0 W
Binding Energy 7.5
in MeV
Nucleon 5.0
0 30 60 90 120
Mass number of nuclei
Reaction Reactant Product
(a) Y → 2 Z 60 × 8.5 = 510 MeV 2 × 30 × 5 = 300 MeV
(b) W → X + Z 120 × 7.5 = 900MeV ( 90 × 8 + 30 × 5) = 870 MeV
(c) W → 2Y 120 × 7.5 = 900MeV 2 × 60 × 8.5 = 1020 MeV
2 Rhc
For hypothetical particle, energy = −
n2
The hypothetical particle has double the mass of the electron and same charge as the
electron
The longest wavelength of photon = λmax
1 KZe2
Total energy (T.E.) of electron − =
2 r
When an electron undergoes transition from excited state to ground state , r decreases.
∴K .E. increases
P.E. decreases as it becomes more negative
T .E. decreases as it becomes more negative.
Option (a) is correct.
Q43. Two radioactive materials X 1 and X 2 have decay constants 10λ and λ respectively. If
initially they have the same number of nuclei, then the ratio of the number of nuclei of
X 1 to that of X 2 will be 1 / e after a time
1 1 11 1
(a) (b) (c) (d)
10λ 11λ 10λ 9λ
Ans. (d)
N1 1
Solution: Given = Q N = N 0 e − λt
N2 e
N 0 e−10λ t 1 1 1
∴ = or = or 9λ t = 1
N 0e− λ t e e 9λ t
e
1
or t =
9λ
Q44. Electrons with energy 80 keV are incident on the tungsten target of an X-ray tube. K
shell electrons of tungsten have 72.5 keV energy. X-rays emitted by the tube contain only
(a) a continuous X-ray spectrum (Bremsstrahlung) with a minimum wavelength of
0
0.155 Α
(b) a continuous X-ray spectrum (Bremsstrahlung) with all wavelengths
(c) the characteristic X-ray spectrum of tungsten
(d) a continuous X-ray spectrum (Bremsstrahlung) with a minimum wavelength of
0
0.155 Α and the characteristic X-ray spectrum of tungsten
Ans. (d)
Solution: For continuous X − ray spectrum (Bremsstrahlung),
λmin ⎛⎜ in A ⎞⎟ =
0 12375 12375 0
∴ λmin = A
⎝ ⎠ E ( in eV ) 80 ×103
0
∴ λmin = 0.155 A
Again,
Energy of incident electron = 80keV
Ionization energy of K − shell -electron = 72.5 keV
Since incident energy of electrons is greater than ionization energy of electrons in
K − shell, the K − shell electrons will be knocked off.
Hence characteristic X − ray spectrum will be obtained. Option (d) represents correct
answer.
Q45. The electron emitted in beta radiation originates from
(a) inner orbits of atoms
(b) free electrons existing in nuclei
(c) decay of a neutron in a nucleus
(d) photon escaping from the nucleus
Ans. (c)
Solution: For beta emission from nucleus, a neutron of nucleus decays into a proton and a beta
particle.
Q46. The transition from the state n = 4 to n = 3 in a hydrogen-like atom results in ultraviolet
radiation. Infrared radiation will be obtained in the transition
(a) 2 → 1 (b) 3 → 2 (c) 4 → 2 (d) 5 → 4
Ans. (d)
Solution: In hydrogen like atoms:
1 ⎛ 1 1 ⎞
= R⎜ 2 − 2 ⎟
λ ⎝ n1 n2 ⎠
transition of electron occurs from n2 to n1
1
is proportional to energy
λ
from n = 4 to n = 3 , ultraviolet radiation is obtained
1 ⎛ 1 1 ⎞ 7R
= R⎜ 2 − 2 ⎟ = = 0.048 R
λ ⎝ 3 4 ⎠ 144
1 ⎛ 1 1 ⎞ 3R 1 ⎛ 1 1 ⎞ 5R
(a) = R⎜ 2 − 2 ⎟ = = 0.75R (b) = R⎜ 2 − 2 ⎟ = = 0.14 R
λ ⎝1 2 ⎠ 4 λ ⎝ 2 3 ⎠ 36
1 ⎛ 1 1 ⎞ 3R 1 ⎛ 1 1 ⎞ 9R
(c) = R⎜ 2 − 2 ⎟ = = 0.2 R (d) = R⎜ 2 − 2 ⎟ = = 0.02
λ ⎝ 2 4 ⎠ 16 λ ⎝ 4 5 ⎠ 400
λ is smaller than ultra violet in (a), (b) and (c)
λ is greater than ultra violet in (d).
greater the λ , less the energy of radiation
infrared radiation has less energy and greater λ as compare to ultra violet radiation.
Hence option (d) is correct.
Q47. The intensity of X − rays from a Coolidge tube is l
plotted against wavelength λ as shown in the
figure. The minimum wavelength found is λC and
between cathode and anode in Coolidge tube. Options (c) and (d) are therefore incorrect
Minimum wavelength of X − rays emitted = λc
accelerating voltage.
∴( λK − λC ) increases when V is increased.
N N
(a) (b)
τ t τ t
N N
(c) (d)
τ t τ t
Ans. (d)
Solution: The total number of radioactive nuclei, as a function o time, during decay process, will
continuously decrease. This is correctly depicted in (d).
Figure (a) shows that the total number ( N ) remains constant for some time. This is
incorrect.
Figure (b) and figure (c) indicate fall and rise in ( N ) at some instants during decay. Rise
in ( N ) is never possible during decay. The options (b) and (c) are therefore incorrect.
∴n =
( 3.2 ×10 ) ×1
−3
or n = 2 ×1016
−19
1.6 ×10
Q50. A hydrogen atom and a Li ++ ion are both in the second excited state. If lH and lLi are
their respective electronic angular momenta, and EH and ELi their respective energies,
then
(a) lH > lLi and EH > ELi (b) lH = lLi and E H < ELi
(c) lH = lLi and E H > ELi (d) lH < lLi and E H < ELi
Ans. (b)
Solution: In the second excited state, n = 3
⎛ h ⎞
∴lH = lLi = 3 ⎜ ⎟
⎝ 2π ⎠
Z H = 1, Z Li = 3, E ∝ Z 2 ∴ ELi = 9 EH
or EH < ELi
Q51. The half-life of 215
At is 100 μs . The time taken for the radioactivity of a sample of
215
At to decay to 1 / 16 th of its initial value is
(a) 400 μs (b) 6.3 μs (c) 40 μs (d) 300 μs
Ans. (a)
Solution: For radioactive disintegration,
n
⎛1⎞
N = N 0 ⎜ ⎟ , where n = number of half lives.
⎝2⎠
n 4 n
N0 ⎛1⎞ ⎛1⎞ ⎛1⎞
= N0 ⎜ ⎟ or ⎜ ⎟ = ⎜ ⎟
16 ⎝2⎠ ⎝2⎠ ⎝2⎠
∴n = 4
∴ t = n × half life or t = 4 ×100 μ s or t = 400 μ s
Q52. Which of the following processes represents a γ -decay?
(a) A
X Z + γ → A X Z −1 + a + b
(b) A
X Z + 1 n0 → A−3 X Z − 2 + c
(c) A
X Z →AX Z + f
(d) A
X Z + e−1 → A X Z −1 + g
Ans. (c)
Solution: During a γ − decay, Z and A do not change.
This condition is fulfilled in option (c)
⎛r⎞
Q53. The electric potential between a proton and an electron is given by V = V0 ln ⎜ ⎟ , where
⎝ r0 ⎠
r0 is a constant. Assuming Bohr’s model to be applicable, write variation of rn with n, n
being the principal quantum number?
1
(a) rn ∝ n (b) rn ∝
n
1
(c) rn ∝ n 2 (d) rn ∝
n2
Ans. (a)
r
Solution: Given: V = V0 ln
r0
∴ Potential energyU = eV
r dU ⎛r ⎞ 1
or U = eV0 ln ∴ = eV0 ⎜ 0 ⎟
r0 dr ⎝ r ⎠ r0
eV0
or force =
r
This force provides the necessary centripetal force.
mv 2 eV0 eV0
∴ = or v= (1)
r r m
nh
By Bohr’s postulate, mvr =
2π
nh
or v =
2π m r
nh eV0 nh m
From (i) and (ii), = or r = ×
2π m r m 2π m eV0
⎡ h 1 ⎤
or r = ⎢ ⎥×n
⎣⎢ 2π meV0 ⎦⎥
∴ rn ∝ n
Q54. If the atom 100 Fm 257 follows the Bohr model and the radius of 100 Fm 257 is n times the
( 5)
2
Q56. A nucleus with mass number 220 initially at rest emits an α - particle. If the Q value of
the reaction is 5.5 MeV , calculate the kinetic energy of the α - particle
(a) 4.4 MeV (b) 5.4 MeV (c) 5.6 MeV (d) 6.5 MeV
Ans. (b)
Solution: Linear momentum is conserved.
∴ p1 = p2
∴ 2 ( 216m ) K1 = 2 ( 4m ) K 2
or 216 K1 = 4 K 2 or K 2 = 54 K1 (i)
5.5
or 55K1 = 5.5( MeV ) or K1 = MeV
55
1
or K1 = MeV (iii)
10
54
∴ K 2 54 × K1 or K 2 = MeV
10
or K 2 = 5.4 MeV (iv)
Q58. A 280 day old radioactive substance shows an activity of 6000 dps, 140 day later its
activity becomes 3000 dps. What was its initial activity?
(a) 20000 dps (b) 24000 dps (c) 12000 dps (d) 6000 dps.
Ans. (b)
Solution: For radioactive disintegration,
1 N 0 1 ⎛ A0 ⎞
λ = ln = ln
t N t ⎜⎝ A ⎟⎠
1 ⎛ A ⎞
or λ = ln ⎜ 0 ⎟
280 ⎝ 6000 ⎠
1 ⎛ A ⎞
also λ = ln ⎜ 0 ⎟
( 280 + 140 ) ⎝ 3000 ⎠
1 ⎛ A ⎞ 1 ⎛ A ⎞
∴ ln ⎜ 0 ⎟ = ln ⎜ 0 ⎟
280 ⎝ 6000 ⎠ 420 ⎝ 3000 ⎠
⎛ A ⎞ ⎛ A ⎞
or 3ln ⎜ 0 ⎟ = 2 ln ⎜ 0 ⎟
⎝ 6000 ⎠ ⎝ 3000 ⎠
A3 ( 6000 )
3 2 3
⎛ A ⎞ ⎛ A ⎞
∴⎜ 0 ⎟ = ⎜ 0 ⎟ or 02 =
⎝ 6000 ⎠ ⎝ 3000 ⎠ A0 ( 3000 )2
6 × 6 × 6 × 109
or A0 = or A0 = 24 ×103
3 × 3 × 106
or A0 = 24000
∴Initial activity =24000dps
Q59. A proton has kinetic energy E = 100keV which is equal to that of a photon. The
λ2
wavelength of photon is λ2 , and that of proton is λ1 . The ratio is proportional to
λ1
or 2m p K = p 2
2
⎛h⎞
or 2m p K = ⎜ ⎟ , by de Broglie equation
⎝ λ1 ⎠
K = K .E = Energy E
h h
or λ1 = = (ii)
2m p K 2m p E
λ1 hc 2m p E
= ×
λ2 E h
λ2 c × 2m p λ1
or = = c 2m p × E −1/ 2 or ∝ E −1/ 2
λ1 E λ2
Q60. Kα wavelength emitted by an atom of atomic number Z = 11 is λ . Find the atomic
(a) Z = 6 (b) Z = 4
(c) Z = 11 (d) Z = 44
Ans. (a)
Solution: According to Moseley’s law,
c
f = a 2 ( Z − b ) where f = frequency =
2
λ
c
= a 2 ( z − 1)
2
For Kα line, b = 1 ∴
λ
c
= a 2 ( Z1 − 1)
2
For one atom,
λ1
λ a ( Z − 1)
2 2
c
= a ( Z 2 − 1)
2
For other atom, 2
or 1 = 2 2
λ2 λ2 a ( Z1 − 1)2
λ ( Z 2 − 1) ( Z 2 − 1)
2 2
or ( Z 2 − 1) = 25
2
or = =
4λ (11 − 1) 2
100
or Z 2 − 1 = 5 or Z 2 = 6
Q61. A photon collides with a stationary hydrogen atom in ground state inelastically Energy of
the colliding photon is 10.2 eV. After a time interval of the order of micro second another
photon collides with same hydrogen atom in elastically with an energy of 15 eV. What
will be observed by the detector?
(a) One photon of energy 10.2 eV and an electron of energy 1.4 eV
(b) Two photons of energy 1.4 eV
(c) Two photons of energy 10.2 eV
(d) One photon of energy 10.2 eV and another photon of 1.4 eV.
Ans. (a)
Solution: For hydrogen atom,
13.6
E1 = −13.6 eV , E2 = − = −3.4 eV
4
∴E2 − E1 = −3.4 − ( −13.6 )
or ( E2 − E1 ) = 10.2 eV
Due to inelastic collision of photon with stationary hydrogen atom, the photon will be
absorbed with its energy 10.2 eV . The electron will jump from ground state (first orbit) to
second orbit.
The electron falls back to its original state in less than a microsecond and releases a
photon of energy 10.2 eV . Another photon collides with same hydrogen atom inelastically
with an 15eV . This photon on absorption will knock out an electron and will ionize the
atom as the ionization energy is only 13.6 eV .
∴ Balance energy = 15 - 13.6
or Balance energy 1.4 eV
The knocked out electron will retain energy 1.4 eV with It.
The detector will observe one photon of energy 10.2 eV and an electron of energy 1.4 eV.
Option (a) represents the answer.
Q62. A beam of electrons is used in an Young double slit. experiment. The slit width is d .
When the velocity of electron is increased, then
(a) no interference is observed
(b) fringe width increases
(c) fringe width decreases
(d) fringe width remains same.
Ans. (c)
h
Solution: de Broglie wavelength λ =
mv
Wavelength λ will be associated with the electron
When speed v of electron increases, λ decreases.
λD
∴Fringe widthβ =
d
∴ As λ decreases, β also decreases
∴ Fringe width decreases.
Q63. If a star can convert all the He nuclei completely into oxygen nuclei, the energy released
per oxygen nucici is [Mass of He nucleus is 4.0026 amu and mass of oxygen nucleus is
15.9994 amu]
(a) 7.6 MeV (b) 56.12 MeV (c) 10.24 MeV (d) 23.9 MeV
Ans. (c)
Solution: 4 ⎡⎣ 2 He 4 ⎤⎦ →8 O16
= 10.24 MeV
∴ Energy released per oxygen nuclei = 10.24 MeV
221
Q64. 87 Ra is a radioactive substance having half life of 4 day. Find the probability that a
nucleus undergoes decay after two half lives.
(a) 1 (b) 1 / 2 (c) 3 / 4 (d) 1 / 4
Ans. (c)
N0 N
Solution: After one half life remains, 0 decays.
2 2
N0 3N
After two half lives, remains, 0 decays.
4 4
3
∴ The probability that a nucleus undergoes decay after two half lives is .
4
Q65. The largest wavelength in the ultraviolet region of the hydrogen spectrum is 122 nm. The
smallest wavelength in the infrared region of the hydrogen spectrum (to the nearest
integer) is
(a) 802 nm (b) 823 nm (c) 1882 nm (d) 1648 nm
Ans. (b)
Solution: The largest wavelength in the ultraviolet region of the hydrogen spectrum corresponds
to the transition n = 2 to n = 1 . How? That is
1 ⎛1 1 ⎞
= R⎜ 2 − 2 ⎟ (i)
122 ⎝1 2 ⎠
where R is the Rydberg constant in consistent units.
And the transition from n= ∞ to n = 3 will produce the smallest wavelength in infrared
region of the hydrogen spectrum. So,
1 ⎛1 1⎞
= R⎜ 2 − ⎟ (ii)
λ ⎝3 ∞⎠
Equation (i) and (ii) give λ = 823.5 nm.
Q66. In the options given below, let E denote the rest mass energy of a nucleus and n a
neutron. The correct option is
(a) E ( 236
92 ) ( I ) + E ( Y ) + 2 E (n)
U >E 137
53
97
39
(b) E ( 236
92 U ) < E ( I ) + E ( Y ) + 2 E (n )
137
53
97
39
(c) E ( 236
92 U ) < E ( Ba ) + E ( Kr ) + 2 E (n )
140
56
94
36
(d) E ( 236
92 U ) = E ( Ba ) + E ( Kr ) + 2 E (n )
140
56
94
36
Ans. (a)
Solution: Rest mass energy of U will be greater than the rest mass energy of the nuclei into
which it breaks. The constituent nuclei and neutrons will have kinetic energy also, as a
result of conservation of linear momentum.
Q67. Electrons with de-Broglie wavelength λ fall on the target in an X-ray tube. The cut-off
wavelength of the emitted X-rays is
2mcλ2 2h 2 m 2 c 2 λ3
(a) λ0 = (b) λ0 = (c) λ0 = (d) λ0 = λ
h mc h2
Ans. (a)
Solution: Let K be the kinetic energy of the incident electron. Its linear momentum p = 2mK .
The de-Broglie wavelength is related to the linear momentum as
h h h2
λ= = or K =
p 2mK 2mλ 2
The cut-off wavelength of the emitted X − ray is related to the kinetic energy of incident
electron as
hc h2 2mcλ 2
=K= ⇒ λ =
λ0 2mλ 2
0
h
Q68. The shortest wavelength of X − rays emitted from an ray tube depends on
(a) the current in the tube
(b) the voltage applied to the tube
(c) the nature of the gas in tube
(d) the atomic number of the target material.
Ans. (b), (d)
Solution: X − rays emitted from an X − ray tube depend upon:
(i) The accelerating voltage applied to tube. When accelerated, the electrons acquire
greater energy before striking the target.
X − rays emitted from target therefore possess greater energy. X − ray with shorter
wavelength possess greater energy. Hence wavelength of emitted X − rays depends on
the voltage applied to tube.
(ii) According to Moseley’s law,
Q69. The threshold wavelength, for photoelectric emission from a material is 5200Ǻ
Photoelectrons will h emitted when this material is illuminated with monochromatic
radiation from a
(a) 50 watt infrared lamp (b) I watt infrared lamp
(c) 50 watt ultraviolet lamp (d) I watt ultraviolet lamp.
Ans. (c), (d)
Solution: Threshold wavelength = 5200Ǻ
This is the maximum wavelength of the incident radiation which produce photoelectric
effect.
Wavelengths less than 5200Ǻ will produce the effect.
Wavelength of infrared light is of the order of 8000 Ǻ.
Wavelength of ultraviolet light is about 4000 Ǻ.
Hence ultraviolet lamp can produce the effect.
Options (c) and (d) represent the correct answer.
Q70. From the following equations pick out the possible nuclear fusion reactions:
(a) 6 C13 + 1 Η 1 → 6 C14 + 4.3 MeV
0 (
n1 →1 H 1 + 1 β 0 )
→ Proton + beta particle (electron)
Q76. During a nuclear fusion reaction
(a) a heavy nucleus breaks into two fragments by itself.
(b) a light nucleus bombarded by thermal neutrons breaks up
(c) a heavy nucleus bombarded by thermal neutrons breaks up
(d) two light nuclei combine to give a heavier nucleus and possibly other products.
Ans. (d)
Q77. The potential difference applied to an X - ray tube is increased. As a result, in the emitted
radiation
(a) the intensity increases
(b) the minimum wavelength increases
(c) the intensity remains unchanged
(d) the minimum wavelength decreases
Ans. (c), (d)
Solution: for X − ray tube,
12375
λm ⎛⎜ in A ⎞⎟ =
0
⎝ ⎠ V
As accelerating voltage is increased, λm will decrease.
Number of electrons bombarding the target determine the intensity (or quantity) of
emitted radiation. Accelerating voltage does not change the intensity of X − rays emitted.
Q78. A freshly prepared radioactive source of half life 2 hr emits radiation of intensity which is
64 times the permissible safe level. The minimum time after which it would be possible
to work safely with this source is
(a) 6 hr (b) 12 hr (c) 24 hr (d) 28 hr
Ans. (b)
Solution: The intensity of radiation omitted is proportional to rate of decay of radioactive
material.
ln 2 N0
N = N 0 e − λl where λ = or λ t = ln
2 N
⎛ ⎞
1 ⎜ N ⎟ 2
× ln ( 2 )
6
or t = ln ⎜ 0 ⎟ =
λ ⎜ N 0 ⎟ ln 2
⎜ ⎟
⎝ 64 ⎠
= 2 × 6 = 12 hour
Q79. The decay constant of a radioactive sample is λ . The half-life and mean-life of the
sample are respectively given by
(a) 1 / λ and (ln 2 ) / λ (b) (ln 2 ) / λ and 1 / λ
(c) λ (ln 2 ) and 1 / λ (d) λ / (ln 2 ) and 1 / λ
Ans. (b)
0.6931 ln 2
Solution: Half-life T = =
λ λ
1
Mean life τ =
λ
Q80. When a monochromatic point source of light is at a distance of 0.2m from a photoelectric
cell, the cut off voltage and the saturation current are respectively 0.6V and 18.0 mA . If
the same source is placed 0.6 m away from the photoelectric cell: then
(a) the stopping potential will be 0.2 volt
(b) the stopping potential will be 0.6 volt
(c) the saturation current will be 6.0 mA
(d) the saturation current will be 2.0 mA.
Ans. (b), (d)
Solution: The stopping potential depends on the frequency incident radiation and not on the
intensity of incident radiation The source is same, though placed at different distances
consequently the stopping potential remains unchanged. The saturation current depends
on the radiation-intensity incident on cathode of photocell. The radiation-intensity
depends on the distance between the source and the cathode Infact, inverse square law
applies to intensity.
1 1
intensity ∝ ∴ Saturation current ∝
r2 r2
1 ( I S )2 r12
or I S ∝ ∴ =
r2 ( I S )1 r22
star is 1016 W , the deuteron supply of the star is exhausted in a time of the order of
(a) 106 s (b) 108 s (c) 1012 s (d) 1016 s
The masses of the nuclei are as follow:
( ) ( )
M H 2 = 2.014 amu ; M ( p ) = 1.007 amu; M ( n ) = 1.008 amu; M He 4 = 4.001 amu .
Ans. (c)
Solution: 1 H 2 +1 H 2 →1 H 3 + p
1 H 2 +1 H 3 →2 He 4 + n
by adding
( )
3 1 H 2 →2 He 4 + p + n
or Δm = 0.026 amu
Mass is converted into energy
1 amu = 931.5 MeV
3
E = 1.29 ×1028 J
Energy Energy
∴Power= or time =
Time Power
1.29 × 1028
Time = 16
sec = 1.29 × 1012 sec
10
Time is of the order of 1012 sec.
Q82. When photons of energy 4.25eV strike the surface of metal A ,, the ejected
photoelectrons have maximum kinetic energy, TAeV and de Broglie wavelength λ A . The
maximum kinetic energy of photoelectrons liberated from another metal B by photons of
energy 4.70eV is TB = (TA − 1.50 ) eV . If the de Broglie wavelength of these
photoelectrons is λB = 2λ A , then
(d) TB = 2.75 eV
Ans. (a), (b), (c)
Solution: Consider metal A
Incident energy = work function + Kinetic energy of photoelectrons
∴ 4.25 ( eV ) = WA + TA
PA2
Kinetic energy = where P = momentum
2m
PA2 1 ⎛ h ⎞
∴TA = = ⎜ ⎟ , by deBroglie equation
2m 2 m ⎝ λ A ⎠
2
1 ⎛ h ⎞
∴TA = ⎜ ⎟ (ii)
2m ⎝ λ A ⎠
consider metal B
4.7 = (TA − 1.5 ) + WB (iii)
2 2
1 ⎛ h ⎞ 1 ⎛ h ⎞
Also TB = ⎜ ⎟ = ⎜ ⎟ (iv)
2m ⎝ λB ⎠ 2 m ⎝ λB ⎠
TA = 2.00eV (v)
from (i), WA = 4 − 25 − TA
= 4.25 − 2 = 2.25eV
The mass defect is more in case of heavier nucleus where in binding energy needed is
more
∴ 20 ( m p + mn ) − M 2 = B.E.for 20Ca 40
10 ( m p + mn ) − M 1 = B.E.for 10 Ne 20
∴ 20 ( m p + mn ) − M 2 > 10 ( m p + mn ) − M 1
Q85. The electron in a hydrogen atom makes a transition n1 → n2 , where n1 and n2 are the
principal quantum numbers of the two states. Assume the Bohr model to be valid. The
time period of the electron in the initial state is eight times that in the final state. The
possible values of n1 and n2 are
(a) n1 = 4, n2 = 2 (b) n1 = 8, n2 = 2
(c) n1 = 8, n2 = 1 (d) n1 = 6, n2 = 3
Ans. (a), (d)
Solution: According to Bohr model,
rn ∝ n 2 (i)
1
vn ∝ (ii)
n
2π 2π rn rn
now Tn = = or Tn ∝
ω vn vn
n2
or Tn ∝ , by (i) and (ii). Or Tn ∝ n3
1
n
(Tn )1
3
n13 ⎛n ⎞
∴ = 3 or 8 = ⎜ 1 ⎟
(Tn )2 n2 ⎝ n2 ⎠
or n1 = 2n2
∴λmin =
( 6.63 ×10 ) × ( 3 ×10 )
−34 8
4 × 1.6 ×10−19
or λmin = 310 ×10−9 m
Q89. The half-life period of a radioactive element X is same as the mean-life time of another
radioactive element Y . Initially both of them have the same number of atoms. Then
(a) X and Y have the same decay rate initially.
(b) X and Y decay at the same rate always.
(c) Y will decay at a faster rate than X .
(d) X will decay at a faster rate than Y .
Ans. (c)
⎛1⎞
Q90. The graph between the stopping potential (V0 ) and ⎜ ⎟ is shown in the figure φ1 , φ2 and
⎝λ⎠
φ3 are work functions.
Which of the following is/are correct?
V0
Metal1 Metal 2 Metal3
φ1
φ1 φ3
θ 1
λ
(nm )
−1
(a) φ1 : φ2 : φ3 = 1: 2 : 4
(b) φ1 : φ2 : φ3 = 4 : 2 :1
hc
(c) tan θ is directly proportional to where h is Planck’s constant and c is the speed of
e
light
(d) Ultra violet light can be used to emit photoelectrons from metal 2 and metal 3 only.
Ans. (a), (c)
Solution: According to Einstein’s photoelectric equation,
hc
− φ = eV where φ = work function
λ
hc φ ⎛ hc ⎞ 1 φ
or V = − or V = ⎜ ⎟ −
eλ e ⎝ e ⎠λ e
⎛1⎞
V and ⎜ ⎟ relation represents a straight line.
⎝λ⎠
hc hc
∴ Slope of line = or tan θ =
e e
∴ Option (c) is correct (i)
φ1
φ1 φ3
At V0 = 0
hc hc hc
φ1 : φ2 : φ3 = : :
λ01 λ02 λ03
⎡1 1 ⎤ 13.6 Z 2 × 7
E 4 − E3 = −13.6 Z 2 ⎢ 2 − 2 ⎥ =
⎣4 3 ⎦ 9 × 16
13.6 × 25 × 7
= = 16.53 eV (ii)
9 × 16
(iii) λ for removing electron from n = 1 to n = ∞
13.6
Q E∞ = 0 E = − E1 = + × Z 2 eV
(1) 2
or λ =
(6.6 × 10 )× (3 × 10 )
−34 8
nh 1.66 × 10 −34
Angular momentum = =
2π 2x
= 1.05 × 10 −34 Js (vii)
(v) The radius of first Bohr orbit r1 :
n=4
n=3
n=2
n =1
12375
∴ Longest wavelength =
E (in eV )
12375
or λ max = = 1.875 × 10 −6 m (ii)
0.66
∴ Longest wavelength 1.875 × 10 −6 m
Q93. How many electrons, protons and neutrons are there in a nucleus of atomic number 11
and mass number 24?
(i) Number of electrons =
(ii) Number of protons =
(iii) Number of neutrons =
Solution: (i) Number of electrons = 0
(ii) Number of protons = Atomic number Z = 11
(iii) Number of neutrons = = ( A − Z ) = (24 − 11) = 13
Protons and neutrons reside in nucleus. Electrons revolve around the nucleus, Electrons
do not lie in nucleus.
Q94. A uranium nucleus (atomic number 92, mass number 238) emits an alpha particle and the
resultant nucleus emits β − particle. What are the atomic number and mass number of the
final nucleus?
(i) Atomic number = (ii) Mass number =
Solution: 92 U 238 → 90 X 234 + 2 He 4
⎛ hc hc ⎞
Solution: Kinetic energy in first case = ⎜⎜ − ⎟⎟
⎝ • λ1 λ0 ⎠
hc hc
∴ K1 = −
λ1 λ0
hc hc
Kinetic energy in second case = −
λ2 λ0
hc hc
∴ K2 = −
λ2 λ0
hc(λ 2 − λ1 )
or (K 1 − K 2 ) =
hc hc
∴ K1 − K 2 = −
λ1 λ2 λ1λ 2
(K1 − K 2 )λ1λ2 (K 2 − K1 )λ1 2
or h = =
c(λ 2 − λ1 ) (λ1 − λ2 )c
or h =
(4 − 1.8) × 1.6 × 10 −19 × (800 × 10 −10 )× (700 × 10 −10 )
(800 − 700) × 10 −10 × 3 × 108
h = 6.6 × 10 −34 Js
Q96. The ionization energy of a hydrogen like Bohr atom is 4 rydberg. (i) What is the
wavelength of the radiation emitted when the electron jumps from the first excited
state to the, ground state? (ii) What is the radius of the first orbit for this atom?
Solution: Given :The ionization energy of hydrogen like atom is 4 rydberg
1rydberg = 2.2 × 10 -18 J
(i) Wavelength when electron jumps from E2 to E1 state:
4R
QEn = −
n2
⎡1 1⎤ ⎛ 3⎞
∴ E 2 − E1 = −4 R ⎢ 2 − 2 ⎥ = (− 4 R ) × ⎜ − ⎟
⎣2 1 ⎦ ⎝ 4⎠
hc hc
or E 2 − E1 = 3R or = 3R or λ =
λ 3R
λ=
(6.6 × 10 )× (3 × 10 )
−34 8
3 × (2.2 × 10 ) −18
0
or λ = 3 × 10 −8 m or λ = 300 A
(ii) Radius of first orbit of the atom:
4R −18 2.2 × 10 −18
E1 = − 2 where R = 2.2 × 10 J = eV
1 1.6 × 10 −19
Let Z be the atomic number of given element
13.6Z 2 4R
∴ E1 = (eV ) Z2 =
(1) 2
13.6(in eV )
⎛ 2.2 × 10 −18 ⎞ 1
or Z 2 = 4 × ⎜⎜ −19 ⎟
⎟×
⎝ 1.6 × 10 ⎠ 13.6
or Z 2 = 4 or Z = 2
r0
Qrn = (where r0 is the Bohr’s radius)
Z
0.53 × 10 −10
or rn = or rn = 2.6 × 10 −11 m
2
Q97. A double ionized lithium atom is hydrogen-like with atomic number 3.
(i) Find the wavelength of the radiation required to excited the electron in Li from the
first to the third Bo orbit. (Ionization energy of the hydrogen atom equal 13.6 eV ).
(ii) How many spectral lines are observed in the emission spectrum of the above excited
system?
⎛ 13.6 ⎞
Solution: (i) For hydrogen like atom E n = ⎜ − 2 Z 2 ⎟eVλ of radiation excite electron from
⎝ n ⎠
n = 1 to n = 3 :
Given: Z = 3
13.6
× (3) = −13.6 × 9 eV
2
∴ E1 = −
(1) 2
13.6
× (3) = −13.6 eV
2
E3 = −
(3) 2
∴ E3 − E1 = −13.6 − (− 13.6 × 9)
or ΔE = 13.6 × 8
or ΔE = 108.8 eV = 108.8 × 1.6 × 10 −19 J
or
hc
λ
(
= 108.8 × 1.6 × 10 −19 )
or λ =
(6.6 × 10 )× (3 × 10 )
−34 8
n=2
n =1
or t = 4 × 10 −3 sec
3e 2
or rn = (i)
(4πε 0 )208me v 2
Since the Bohr model is applicable to this system,
nh
Angular momentum =
2π (208 m e )
nh rn −e
or mvrn = in the n th orbit.
2π
+ 3e
nh
or v =
2π × mrn
nh nh
or v = = (ii)
2π × 208me rn 416πme rn
∴ rn = ×
4πε 0 × 208me (nh )2
n 2 h 2ε 0
or rn = (iii)
624πme e 2
h 2ε 0
r1 of H − atom = Q rn = r1 of H − atom
πme e 2
n 2 h 2ε 0 h 2ε 0
∴ = [ from (iii)]
624πme e 2 πme e 2
or n 2 = 624 ≈ (25)
2
or n = 25 (iv)
(iii) λ when Mu-meson jumps from n = 3 to n = 1
1 ⎡1 1⎤
= 208 R × Z 2 ⎢ 1 − 2 ⎥
λ ⎣ n1 n2 ⎦
or
1
λ
( ) 2⎡ 1 1⎤
= 208 × 1.1 × 10 7 × (3) ⎢ 2 − 2 ⎥
⎣1 3 ⎦
208 × 1.1 × 10 7 × 9 × 8
1
or =
λ 9
1
or λ = = 0.000546 × 10 −7
208 × 1.1 × 10 7 × 8
0
or λ = 0..546 × 10 −10 m or λ = 0.546 A
0 0 0
Q100. A beam of light has three wavelengths 4144 A, 4972 A , 4972A and 62.16 A with a total
intensity of 3.6 × 10 −3 Wm −2 equally distributed amongst the three wavelengths. The beam
falls normally on an area 1.0cm 2 of a clean metallic surface of work function 2.3 eV .
Assume that there is no loss of light by reflection and that each energetically capable
photon ejects one electron. Calculate the number of photo electrons liberated in two
second.
12375
Solution: Energy of photon in eV = 0
λ in A
12375
∴ E1 = eV = 2.99 eV
4144
Similarly
12375 12375
E2 = eV = 2.49 eV , E3 = eV = 1.99eV
4972 6216
workfunction = 2.3 eV
First two wavelengths have energies great than work function of metallic surface. Hence
they can eject photoelectrons.
Total intensity = 3.6 × 10 −3 Wm −2
Number of wavelengths = 3
∴ (
Energy falling per second = 1.2 × 10 −3 × 10 −4)
= 1.2 × 10 −7 J / S
∴ Let number of photons of first wavelength = n1
and number of photons of second wavelength = n2
1.2 × 10 −7
∴ n1 = = 2.5 × 1011
(
2.99 × 1.6 × 10 −19
)
1.2 × 10 −7
n2 = = 3.0 × 1011
2.49 × 1.6 × 10 −19
∴ Total photons per second = (2.5 + 3.0)1011 = 5.5 × 1011
∴ Each capable photon ejects an electron
∴ Photoelectrons liberated in two sec 2 × 5.5 × 1011 = 1.1 × 1012
Q101. A gas of identical hydrogen like atoms has some atoms in the lowest (ground) energy
level A and some atoms in a particular upper (excited) energy level B and there are no
atoms in any other energy level. The atoms of the gas make transition to a higher energy
level by absorbing monochromatic. light of photon energy 2.7 eV . Subsequently, the
atoms emit radiation of only six different photon-energies. Some of the emitted photons
have energy 2.7 eV , some have energy more and some have less than 2.7 eV
(i) Find the principal quantum number of the initially excited level B .
(ii) Find the ionization energy for the gas atoms.
(iii) Find the maximum and the minimum energies of the emitted photons.
Solution: The atoms of a hydrogen-like gas absorb monochromatic light of photon energy.
Initially some atoms are in energy level A and some are in excited energy level B .
Subsequently the atoms emit radiation of only six diff photon energies.
Some of the emitted photons have energy 2.7 eV ,
some have energy more than 2.7 eV and
some have energy less than 2.7 eV .
(i) Principal quantum number of initial level B :
Since only six different transitions take place, the final state is n = 4
The energy levels of hydrogen atom are given by
13.6
En = − eV
n2
If n B is the principle quantum number of the initially excited state B , then
13.6 ⎛ 13.6 ⎞
E 4 − E nB = − − ⎜− ⎟
4 2 ⎜⎝ n B2 ⎟⎠
⎡1 1⎤
= 13.6 ⎢ 2 − ⎥
⎣ n B 16 ⎦
Now, E 4 − E nB = 2.7 eV
⎡1 1⎤
Thus 2.7 = 13.6 ⎢ 2 − ⎥
⎣ n B 16 ⎦
Which gives n B ≈ 2
The different transitions are as shown in the figure
n=4
n=3
B n=2
A n =1
(ii) Ionization energy for gas atoms: E 4 − E 2 = 2.7 eV
E1 E1 3
∴ − = 2 .7 or − E1 = 2.7
42 22 16
or E1 = −14.4 eV
∴ Ionization energy of gas atoms 14.4 eV
(iii) Maximum and minimum energies of emitted photons:
Maximum energy of the emitted photon corresponds to the transition n = 4 to n = 1
E max = E 4 − E1
E E 15 E1 (− 15)(− 14.4 )
or E max = 2
− 2 =− =
4 1 16 16
15
or E max = × (− 14.4) = +13.5 eV
16
or E max = 13.5 eV , for the emitted photon
Again,
Minimum energy of the emitted photon corresponds to the transition n = 4 to n = 3
E1 E1
E min = E 4 − E3 or E min = −
4 2 32
or E min =
− 7 E1
or E min =
(− 7 ) × (− 14.4) = 0.7 eV
16 × 9 16 × 9
∴ E min = 0.7 eV , for the emitted photon.
Q102. Electrons in hydrogen like atoms (Z = 3) make transitions from the fifth to the fourth
orbit and from, the fourth to the third orbit. The resulting radiations are incident normally
on plate and eject photoelectrons. The stopping potential for the photoelectrons ejected
by the shorter is 3.95 volt. Calculate the w of the metal and the stopping potential for the
photoelectrons ejected by the 1onger wavelength. (Rydberg constant = 1.094 × 10 7 m −1
Solution: The stopping potential for shorter wavelength is 3.95 volt i.e., maximum kinetic energy
of photoelectrons corresponding to shorter wavelength will be 3.95 eV . Further energy of
incident photons corresponding to shorter wavelength will be in transition from n = 4 to
n = 3.
− (13.6)(3) ⎡ − (13.6)(3)2 ⎤
2
E 4 →3 = E 4 − E 3 = −⎢ ⎥ = 5.95 eV
(4)2 ⎣ (3) 2
⎦
now from the equation, K max = E − W
= (5.95 − 3.95) eV = 2 eV
Longer wavelength will correspond to transition from n = 5 to n = 4 . From the relation
1 ⎛ 1 1 ⎞
= RZ 2 ⎜ 2 − 2 ⎟
λ ⎜n ⎟
⎝ f ni ⎠
The longer wavelength ,
1
λ
( )
2⎛ 1
= 1.094 × 10 7 (3) ⎜ − ⎟
1 ⎞
⎝ 16 25 ⎠
0
or λ = 4.514 × 10 −7 m = 4514 Α
Energy corresponding to this wavelength,
12375 eV
E= 0
= 2.74 eV
4514 A
∴ Maximum kinetic energy of photoelectrons
K max = E − W = (2.74 − 2) eV = 0.74 eV
or the stopping potential is 0.74 volt.
Q103. It is proposed to use the nuclear fusion reaction
2
1 H + 12 H → 42 He
in a nuclear reactor of 200 MW rating. if the energy from the above reaction is used with
“a 25 ,percent efficiency. the reactor, how many, gram of deuterium fuel will be needed
per day. (The masses 12 H and 42 He are 2.01.4.1 atomic mass unit d 4.0026 atomic mass
unit respectively).
Solution: Deuterium fuel needed per day in the reactor:
Mass defect provides the energy in the reactor:
Δm = 2(2.0141) − (4.0026 ) = 4.0282 − 4.0026 = 0.0256 amu
9.55 × 1013
Energy available per deuterium nuclei = J
2
Total energy needed = power × time
( )
= 200 × 10 6 × (24 × 60 × 60) = 1.728 × 1013 J (ii)
1.728 × 1013
Number of deuterium nuclei required = = 0.362 × 10 26
9.55
× 10 −13
2
∴ Mass of deuterium required = m
m × Avogardo number
∴ = 0.362 × 10 26
2
0.362 × 10 26 × 2
or m = or Mass = 120.26gram
6.02 × 10 23
Hence 120.26gram of deuterium fuel will be needed per day in the nuc1ear reactor
0
Q104. A monochromatic point source radiating wavelength 6000 A , with power 2 watt, an
aperture A of diameter 0.1 m and a large screen SC are placed as shown in figure. A
photoemissive detector D of surface area 0.5 cm 2 is placed. at the centre of the screen.
The efficiency of the detector for the photoelectron generation per incident photon is 0.9.
A SC
S
D
L
0.6 m
6m
(a) Calculate the photon flux at the centre of the screen and the photocurrent in the
detector.
(b) If the concave lens L of focal length 0.6 m is inserted in the aperture as shown, find
the new values of photon flux and photocurrent. Assume a uniform average transmission
of 80% from: the lens.
(c) If the work function of the photoemissive surface is1eV , ca1culate values of the
stopping potential in the two cases (without and with the lens in the aperture)
Solution: (a) Photon flux and photocurrent in the system:
Energy of photon radiated E
∴E =
hc
or E =
(6.6 ×10 )(3 ×10 )
−34 8
area of aperture = π l 2
2
⎛ 0.1 ⎞ −3
A = 3.14 × ⎜ ⎟ = 7.85 × 10 m
2
⎝ 2 ⎠
∴
Total photons
second
(
= An2 = 7.85 × 10 −3 1.34 × 1018 )
= 1.052 × 1016 per second
Area of detector = 4π (6 − 0.6) = 4π (5.4)
2 2
∴
Total photons on detector
time
( )(
= 0.5 × 10 − 4 2.87 × 1013 = 1.435 × 10 9 s −1)
Efficiency of detector = 0.9
Photoelectrons
∴ = 0.9 × 1.435 × 10 9 s −1
time
∴ charge per unit time = (1.6 × 10 −19 )× (0.9 × 1.435 × 10 9 )
1 1 1 1 1 2
or = + =− − =− 0.3m 0.3m
v u f 0.6 0.6 0.6
5.7 m
or v = −0.3 m 6.0 m
From (i),
Photons fallingon lens
= 1.052 × 1016 (80% of photons are only transmitted).
sec
⎛ 80 ⎞ 1.052 × 10
16
Photons fallingon detector
=⎜ ⎟× = 2.06 × 1013 s −1 m −2
area × time ⎝ 100 ⎠ 4π (5.7 )
2
( 4
2 He ) = 4.003u; m(11 H ) = 1.008 u.
Solution: (a) A = 228 + 4 = 232, Z = 92 − 2 = 90
mv 2
(b) The magnetic force qvB provides centripetal force to α − particle for its circular
r
motion.
mv 2 qr B
∴ = qvB or v =
r m
or v =
(2 × 1.6 × 10 )× 0.11× 3
−19
4.003 × 1.67 × 10 − 27
∴ v = 1.58 × 10 7 ms −1 (i)
Linear momentum is conserved in the process.
mY vY = mα vα (ii)
Nucleus X is initially at rest
Total kinetic energy = K α + K r
2
1 1 ⎡ mα vα ⎤ 1 1 mα2 vα2
= mα vα + mY ⎢
2
⎥ = mα vα +
2
2 2 ⎣ mY ⎦ 2 2 mY
1 ⎡ m ⎤
= mα vα2 ⎢1 + α ⎥
2 ⎣ mY ⎦
⎛ h ⎞ ⎛ h ⎞
or ΔL = 2⎜ ⎟ − 4⎜ ⎟
⎝ 2π ⎠ ⎝ 2π ⎠
h
or ΔL =
π
(d) Recoil speed of the emitting atom:
Momentum is conserved in the process
Momentum of hydrogen atom = mv
E E
Momentum of emitted photon = ∴ mv =
c c
E 2.55 × 1.6 × 10 −19
or v = or v =
mc (1.67 × 10 −27 )(3 × 108 )
or v = 0.814 m / s
∴ Recoil speed of emitting atom 0.814m / s
Q107. A neutron of kinetic energy 65 eV collides in elastically with a singly ionized helium
K = 65 eV 90
o
x
θ
m
4m
neutron K2
helium
4m
∴ 2mK = 2(4m )K 2 cos θ , along x − axis.
− 6.04 eV , n = 3
− 13.6 eV , n = 2
E1 E2 E3
− 54.4 eV , n = 1
He + (Z = 2 )
13.6 × (2)
2
for n = 1, E1 = − = −54.4 eV
1
13.6 × 4
for n = 2, E2 = − = −13.4 eV
(2)2
13.6 × 4
for n = 3, E3 = − = −6.04 eV
(3)2
13.6 × 4
for n = 4, E 4 = − = −3.4 eV
(4)2
Possible values of ΔE : case (1) i.e. 1 → 2 .
ΔE1 = −13.6 − (− 54.4 ) = 40.8 eV
From (ii), 65 = k1 + K 2 + 40.8 or K1 + K 2 = 24.2
From (i), (4 K 2 − K ) + K 2 = 24.2 or K 1 + K 2 = 24.2
24.2 + K 24.2 + 65 89.2
or K 2 = = = 17.84 eV
5 5 5
∴ K 1 = 24.2 − K 2 = 24.2 − 17.84 = 6.36 eV
case (2) i.e. 1 → 3
ΔE 2 = −6.04 − (− 54.4 ) = 48.36 eV
K 1 = 16.328 eV , K 2 = 0.312 eV
case (3) i.e. 1 → 4 .
ΔE3 = −3.4 − (54.4 ) = 51eV ; K 1 = 1.8 eV K 2 = 15.8 eV
Kinetic energy can never be negative. The electron therefore cannot jump to a 4.
.The electron can jump to a = 2 and a = 3.
Allowed values of K 1 of neutron, are 6.36 eV and 0.312 eV .
Similarly allowed values of K 2 of atom, are 17.84 eV and 16.328 eV .
The electron is allowed to its highest jump to a 3.
(ii) Frequencies of emitted radiations during dc-excitation:
De-excitation can occur in three ways. The possible emission lines are only three.
(a) Transition n3 → n2
E3 − E 2
Frequency v1 =
h − 3.4 eV , n = 4
n=3
− 6.04 eV
v1
n=2
− 13.6 eV
v2 v3
n =1
− 54.4 eV
∴ v1 =
[− 6.04 − (− 13.6)]× 1.6 × 10 −19
6.63 × 10 −34
or v1 = 1.82 × 1015 Hz
E3 − E 2
(b) Transition n 2 → n1 v 2 = = 11.67 × 1015 Hz
h
E 2 − E1
(c) Transition n 2 → n1 v3 = = 9.85 × 1015 Hz
h
During de-excitation, frequencies of emitted radiations are
1.82 × 1015 Hz,11.67 × 1015 Hz and 9.85 × 1015 Hz
Q108. A small quantity of containing Na 24 radio nuclide half life = 15hour)of activity 1.0 micro
curie is injected into the blood of a person A sample of the blood of volume 1cm 3 taken
after 5 hour shows an activity of 296 disintegration per minute. Determine the total
volume blood in the body of the person. Assume that radioactive solution mixes
uniformly in the blood of the person.
( 1curie = 3.7 × 1010 disintegration per second)
Solution: For radioactive decay, R = R0 e − λ t
or (− λ t ) = ln
R
R0
2.303 ⎛R ⎞ 0.693
or t = log10 ⎜ 0 ⎟ , where λ = per hour
λ ⎝ R⎠ 15
2.303 ⎛ R ⎞
∴t= log10 ⎜ 0 ⎟
0.693 ⎝ 296 ⎠
15
⎛ R ⎞ 5 × 0.693 R0
or log10 ⎜ 0 ⎟ = or = 0.10033
⎝ 296 ⎠ 2.303 × 15 296
373
or R0 = dps
60
Activity of one micro curie 10 −6 curie = 3.7 × 10 4 dps
⎛ 373 ⎞ 3
If activity is ⎜ ⎟ , volume of blood 1cm
⎝ 60 ⎠
3.7 × 10 4 × 60 3
If activity is 3.7 × 10 4 dps volume = cm
373
∴ Volume of blood = 5951.7 cm 3
or Volume of blood = 5.95 litre
∴ Total volume of blood in the body of person is 5.95 litre.
Q109. A hydrogen like atom (atomic number Z ) is in a higher excited state of quantum number
n . The excited atom can make a transition to the first excited state by successively
emitting two photons of energy 10.2 eV and 17.0 eV respectively. Alternately, the atom
froth the same excited state can make a transition to the second excited state by
successively emitting two photons of energies 4.25 eV and 5.95 eV respectively.
Determine the va1u of a and Z . (Ionization energy of H − atom 13.6 eV )
13.6 2
Solution: For hydrogen like atoms, E n = − Z eV
n2
Z = atomic number n = quantum number of excited state.
Given: E n − E 2 = (10.2 + 17 ) = 27.2 eV (i)
13.6 Z 2 ⎡ 13.6 Z 2 ⎤
or − − ⎢− 2 ⎥
= 17
(3)2 ⎣ (2 ) ⎦
13.6Z 2 13.Z 2 13.6(− 4 + 9)Z 2
or − + = 17 or = 17
9 4 36
17 × 36
or Z 2 = =9 or Z = 3 (iii)
13.6 × 5
Again,
E n − E 2 = 27.2 , from (i)
13.6 Z 2 ⎛ 13.6 Z 2 ⎞
or − − ⎜⎜ − ⎟⎟ = 27.2
n2 ⎝ 22 ⎠
⎛ 1 1⎞
or 13.6 Z 2 ⎜ − 2 + ⎟ = 27.2
⎝ n 4⎠
1 1 27.2 27.2 2
or − + = = =
n 2
4 13.6 × Z 2
13.6 × 9 9
1 2 1 8−9 1
or − 2
= − = =− or n 2 = 36
n 9 4 36 36
or n = 6 (iv)
∴n = 6 and Z = 3
Q110. An electron, in a hydrogen-like atom, is in an excited state. It has a total energy of
3 − 3.4 eV Calculate (i) the kinetic energy and (ii) the de Broglie wavelength of the
electron.
Solution: (i) In hydrogen like atoms,
Kinetic energy of electron = Total energy
λ = 0.0693 s −1
6.25
= e −0.0693 t
100
100
e 0.0693 t = = 16
6.25
0.0693 t = ln 16
= 2.303 log10 16
= 2.303 × 1.2041 = 2.773
2.733
or t = = 40 sec
0.0693
Q112. In an ore containing uranium, the ratio of U 238 to Pb 206 nuclei is 3. Calculate the age of
the ore, assuming that all the lead present in the ore is the final stable product of U 238
Take the half-life of U 238 to be 4.5 × 10 9 year.
Initial number of U 238 4 N 4
Solution: 238
= ∴ 0 =
Final number of U 3 N 3
2.303 N0 ⎛ 4.5 × 10 9 ⎞ 4
∴t = log10 = 2.303 × ⎜⎜ ⎟⎟ log10
λ N ⎝ 0.693 ⎠ 3
= 15 × 10 9 (log10 4 − log10 3)
= 15 × 10 9 (0.6021 − 0.4771)
N N N N N N N N N N N
p loops ( p + t ) loops
λ
two neighbouring nodes are separated by
2
⎛λ⎞ 0
∴ p⎜ ⎟ = 2 A
⎝2⎠
( p + 1) λ p + 1 2.5 5
0
= 2.5 A ∴ = =
2 p 2 4
or 4 p + 4 = 5 p or p = 4 (i)
2× 2 0 0
∴ λ= = 1A ∴ λ = 1A (ii)
4
(i) Energy of electrons:
h
de Broglie wavelength = λ =
p
h
or λ = where K denotes kinetic energy
2mK
h2 0
∴K = where λ = 1 A = 10 −10 m
2mλ2
=
(6.63 × 10 ) −34 2
= 2.415 × 10 −17 J
2 × (9.1 × 10 )× (10 )
−31 −10 2
2.415 × 10 −17
= eV = 151eV (iii)
1.6 × 10 −19
(ii) Least value of d for identical standing wave:
Distance d will be minimum when only one loop is formed.
λ 1 0 0
∴ d min = = A = 0.5 A
2 2
0
∴ Least value of d = 0.5 A (iv)
248
Q114. The element Curium 96 Cm has a mean life of second, its primary decay modes are
spontaneous fission and a-decay, the former with a probability of 8% and the latter with a
probability of 92%. Each fission releases 200 MeV of energy. The masses involved in
− α decay are as follows:
248
96 Cm = 248.072220 u , 94
244
Pu = 244.064100 u and 42 He = 4.002603 u . Calculate the power
MeV
output from a sample of 10 20 Cm atoms. 1u = 931 .
c2
Solution: The primary decay modes of 96 Cm 248 are
(i) Spontaneous fission (probability 8%)
(ii) − α decay (probability 92%).
The nuclear reaction is given below:
96 Cm 248 → 94 Pu 244 + 2 He 4
= 3.32 × 10 −5 W
Q115. Nuclei of a radioactive element A are being produced at a constant rate α . The element
has a decay constant λ . At time t = 0 , there are N 0 nuclei of the element.
limiting value of N as t → ∞
Solution: Nuclei of a radioactive element A are being produced at a c rate a.
Decay constant of element =
At t = 0 , nuclei of element present N 0
⎛ α − λN ⎞ α − λN
ln⎜⎜ ⎟⎟ = −λt or = e −λ t
⎝ α − λN 0 ⎠ α − N 0λ
or α − λN = e − λ t (α − λN 0 )
or N =
1
λ
[α − (α − N λ )e ]
0
−λ t
(i)
ln (2)
(b) (i) If α = 2λN 0 , t = half life =
λ
∴ N=
1
λ
[2λN 0 − (2λN 0 − λN 0 )
−λ t
]
λN 0
or N =
λ
[2 − e −ln(2 ) ] ⎡
⎢⎣Here e
− ln ( 2 )= 2 −1 1⎤
= ⎥
2⎦
λN 0 ⎡ 1 ⎤ 3N 0
or N = ⎢⎣2 − 2 ⎥⎦ = 2
λ
3
or N = N0
2
(ii) when t → ∞ and α = 2λN 0
α 2λ N 0
N= = = 2N 0 or N = 2N 0
λ λ
Q116. Photoelectrons are emitted when 400 nm radiation S incident on a surface of
workfunction 1.9eV . These photoelectrons pass through a region containing
α − particles. A maximum energy electron combines with an α - particle to form a He +
ion, emitting a single photo in this process. He + ions thus formed are in their fourth
excited state. Find the energies in eV of the photons lying in the 2 to 4 eV range, that are
likely to be emitted during and after the combination.
[Take h = 4.14 × 10 −15 eV .s. ]
λ (400 × 10 ) −9
13.6 × (2)
2
Similarly E 4 = − = −3.4eV
(4)2
13.6 × (2)
2
E3 = − = −6.04 eV
(3)2
13.6 × (2 )
2
E2 = − = −13.4 eV
(2)2
The possible transitions, after combination, are:
ΔE5→4 = E5 − E 4 = 1.2 eV . It is less than 2eV .
ΔE5→3 = E5 − E3 = 3.84 eV
ΔE 4→3 = E 4 − E3 = 2.64 eV
13.6Z 2
En = − eV
n2
Consider transition from 2n to 1
⎡1 1 ⎤
13.6 Z 2 ⎢ 2 − = 204
⎣1 (2n )2 ⎥⎦
⎡ 1 ⎤
or 13.6Z 2 ⎢1 − 2 ⎥ = 204 (i)
⎣ 4n ⎦
Consider transition from 2n to n
⎡ 1 ⎤
13.6 Z 2 ⎢1 − 2 ⎥ = 40.8
⎣ 4n ⎦
⎛ 3 ⎞
or 13.6 Z 2 ⎜ 2 ⎟ = 40.8 (ii)
⎝ 4n ⎠
⎡ 1 ⎤
13.6 Z 2 ⎢1 − 2 ⎥
or ⎣ 4n ⎦ = 204
⎡ 3 ⎤ 40.8
13.6 Z 2 ⎢ 2 ⎥
⎣ 4n ⎦
4n 2 ⎛ 1 ⎞
or ⎜1 − 2 ⎟ = 5 or 4n 2 − 1 = 15 ⇒ n 2 = 4
3 ⎝ 4n ⎠
or n=2 (iii)
13.6Z 2 × 3
put n in (ii), we get, = 40.8
4 × (2)
2
40.8 × 4 × 4
or Z2 = = 16
13.6 × 3
or Z =4 (iv)
for minimum energy, consider transition 4 to 3.
2⎛ 1 1 ⎞
∴ E min = 13.6 × (4) ⎜ 2 − 2 ⎟eV
⎝3 4 ⎠
13.6 × 16 × 7
or E min = eV or E min = 10.58 eV
9 × 16
hence n = 2, Z = 4, E min = 10.58 eV
Q118. When a beam of 10.6 eV photons of intensity 2.0W / m 2 falls on a platinum surface of
area 1.0 × 10 −4 m 2 and workfunction 5.6 eV , 0.53% of the incident photons eject
photoelectrons. Find the number of photoelectrons emitted per second and their minimum
and maximum energies (in eV ) Take 1eV = 1.6 × 10 −19 J .
Solution: Incident energy E = 10.6 eV = 10.6 × (1.6 × 10 −19 )J = 16.96 × 10 −19 J
Energy incident
= 2W / m 2
area × time
Number of incident photons 2
∴ = = 1.18 × 1018
area × time 16.96 × 10 −19
∴
Incident photons
time
( )
= 1.18 × 1018 × area
= 1.18 × 1014
∴
Number of photoelectrons ⎛ 0.53 ⎞
time
=⎜
100
(
⎟ × 1.18 × 10
14
)
⎝ ⎠
n = 6.25 × 1011 (i)
Minimum energy = zero (ii)
Maximum energy = E1 − work function
or K max = (10.6 − 5.6)eV
1000 × 10 6
Power input = = 1010 W
10 / 100
∴ Equivalent energy = Power input × time
= 1010 × 10 × 365 × 24 × 60 × 60 J
235 × 9.85 × 10 28
= kg
6.02 × 10 26
∴ Mass of U 235 = 38451 kg
Q120. A nucleus at rest undergoes a decay emitting an α − particle of de-Broglie wavelength
2 λ = 5.76 × 10 −15 m . If the mass of the daughter nucleus is 223.610 amu and that of the
α − particle is 4.002 amu , determine the total kinetic energy in the final state. Hence,
MeV
obtain the mass of the parent nucleus in amu. 1 amu = 931.470
c2
Solution: Let Z X A represent the parent nucleus
The parent nucleus decays emitting α − particles
∴ Z X A → Z − 2 Y A− 4 + 2 He 4
Mass of daughter nucleus Y = 223.610 amu
Mass of α − particle = 4.002 amu
Let Kα and K γ be the kinetic energies of α − particle and daughter nucleus. Then total
pα2 ⎛ 1 1 ⎞⎟
= ⎜ +
2 ⎜m ⎟
⎝ α Mγ ⎠
pα2 ⎛ M γ + mα ⎞
K= ⎜ ⎟
2 ⎜ M m ⎟
⎝ γ α ⎠
1amu = 1.67 × 10 −27 kg
substituting the values, we get
K=
(1.151× 10 ) −19 2
2
(4.002 + 223.610)(1.67 × 10 −27 )
(4.002 × 1.67 × 10 )(223.61× 1.67 × 10 )
− 27 − 27
K = 10 −12 J
10 −12
K= MeV = 6.25 MeV
1.6 × 10 −13
or K = 6.25MeV
6.25
mass equivalent to energy K = amu
931.470
or Δm = 0.0067 amu ∴ m X = mY + mα + Δm
⎛ 1 ⎞
Y further decays to a stable nucleus Z with a decay constant λY = ⎜ ⎟ s −1 Initially there
⎝ 30 ⎠
are only X s nuclei and their number is N 0 = 10 20 .
Set, up the rate equations for the populations of X , Y and. Z . The. Populations of
Y nucleus as a function ‘of time is given by
⎛ N 0λX ⎞
N Y (t ) = ⎜⎜ ⎟⎟{exp(− λY t ) − exp(− λ X t )}. Find the time at which N Y is maximum
⎝ (λ X − λY ) ⎠
and determine the populations of X and Z at that instant.
Solution: Radioactive nucleus X decays to a nucleus Y
Y further decays to a stable nucleus Z
Initially there are only X nuclei and there number is N 0 = 10
(i) Rate equations:
At an instant t ,
Let number of nuclei of Y = N Y and number of nuclei of = N 2
∴ Rate equations of populations of X , Y and Z are
⎛ dN X ⎞
⎜ ⎟ = −λ X N Y
⎝ dt ⎠
⎛ dN Y ⎞
⎜ ⎟ = λ X N X − λY N Y
⎝ dt ⎠
⎛ dN Z ⎞
⎜ ⎟ = λY N Y
⎝ dt ⎠
(ii) Time t at which N Y is maximum:
N 0λX
Given: N Y (t ) =
λ X − λY
[
e −λY t − e −λ X t ]
For N Y (t ) to be maximum, N Y (t ) = 0
d
dt
dN Y
From (ii), = λ X N X − λY N Y ∴ λ X N X = λY N Y
dt
N 0λX
( )
or λ X N 0 e −λ X t = λY
(λ X − λY )
[
e −λY t − e −λ X t ]
λ X − λY (e − λ t − e − λ
Y Xt
)
or =
λY e −λ t X
λX
or − 1 = e (λ X − λY )t
−1
λY
⎛λ ⎞
or ln⎜⎜ X ⎟⎟ = (λ X − λY )t
⎝ λY ⎠
⎛ ⎞
1 ⎛λ ⎞ 1 ⎜ 0.1 ⎟
or t = ln⎜⎜ X ⎟⎟ or t = ln⎜ ⎟
λ X − λY ⎝ λY ⎠ 0.1 −
1 ⎜ 1 ⎟
⎜ ⎟
30 ⎝ 30 ⎠
or t = 15 ln (3) or t = 16.48 sec
(iii) Populations of X and Z when N Y is maximum:
N X = N 0 e − λ X t or N x = (10 ) e − (0.1)(16.48 )
20
or N X = 1.92 × 1019
Since λ X N X = λY N Y according to equation (iv),
⎛ ⎞
N X λX ⎜ 0.1 ⎟
∴N Y =
λY
(
or N Y = 1.92 × 1019 ) ×⎜
⎜ 1 ⎟
⎟
⎜ ⎟
⎝ 30 ⎠
or N Y = 5.76 × 1019
Again N Z = N 0 − N X − N Y
(
or N Z = 10 20 − 1.92 × 1019 − 5.67 × 1019 ) ( )
or N Z = 1019 [10 − 1.92 − 5.76]
N Z = 2.32 × 1019
Hence (i) Rate equations for populations X , Y , Z are given in equations (i), (ii) and (iii)
(ii) Time at which N Y is maximum = 16.48 sec
E m = −0.85 eV
⎛ Z2 ⎞
or − 13.6⎜⎜ 2 ⎟⎟ = −0.85 , according to Bohr model
⎝m ⎠
Z represents the atomic number of atom.
Z 0.85 1 1 Z
or = = = = 0.25 ∴ = 0.25
m 13.6 16 4 m
similarly E m +3 = −0.544 eV
13.6Z 2
or − = −0.544
(m + 3)2
Z 0.544 1 1
or = = = = 0 .2
m+3 13.6 25 5
Z
∴ = 0.2 (ii)
m+3
Form (i) and (ii) we get
m = 12 and Z = 3
∴ Atomic number of the atom = 3
(b) Smallest. wavelength emitted in the transitions:
The smallest wavelength corresponds to maximum difference of energies.
∴ ΔE max = E m +3 − E m
A m+3
m+2
m +1
m
B
Q123. Two metallic plates A and B , each of area 5 × 10 −4 m 2 are placed parallel to each other at
a separation of 1 cm. Plate B carries a positive charge of 33.7 × 10 −12 C .A
monochromatic beam of light, with photons of energy 5eV each, starts falling on plate
A at t = 0 so that 1016 photons fall on it per square metre per second. Assume that, one
photoelectron is emitted for every 10 6 incident photons. Also assume that all the emitted
photoelectrons are collected by plate B and the workfunction of plate A remains
constant at the value 2eV . Determine
(a) the number of photoelectrons emitted up to t = 10 s
(b) the magnitude of the electric field between plates A and B at t = 10 s , and
(c) the kinetic energy of the most energetic photoelectron emitted at t = 10 s when it
reaches plate B .
Neglect the time taken by the photoelectron to reach plate B. Take
C2
ε 0 = 8.85 × 10 −12
N − m2
Solution: (a) Number of photoelectrons emitted up to t = 10 s
Area of each plate 5 × 10 −4 m 2
Separation between plates = 1cm = 10 −2 m
Photons incident
= 10 6
area × time
∴ No of photons incident = 1016 × area × time
( )
= 1016 × 5 × 10 −4 × 10 = 5 × 1013
5 × 1013
∴ No of photoelectrons emitted =
10 6
Number of photoelectrons = 5 × 10 7 (i)
(b) Magnitude of field between plates:
Charge on AQ A = 8 × 10 −12
( ) (
QB = charge = 33.7 × 10 −12 − 5 × 10 7 × 1.6 × 10 −19 )
= (33.7 − 8) × 10 −12 C
σB σA 1
∴E = − or E = (QB − Q A )
2ε 0 2ε 0 2 Aε 0
17.7 × 10 −12
or E =
( ) (
2 × 5 × 10 − 4 × 8.85 × 10 −12 )
E = 2000 N / C (ii)
Energy of photoelectrons on plate B :
Energy = E − W = (5 − 2 )eV = 3eV
( )(
Increase in energy = (Ed )eV = 2 × 10 3 10 −2 eV = 20eV )
∴ Energy of photoelectrons on plate B = (20 + 3)eV = 23eV (iii)
Q124. Frequency of a photon emitted due to transition of electron of a certain element from L
to K shell is found to be 4.2 × 1018 Hz . Using Moseley’s la find the atomic number of the
element, given that the Rydberg’s constant R = 1.1 × 10 7 m −1
Solution: Atomic number of element:
According to Bohr model, ΔE = hυ
2⎡ 1 1⎤
or Rhc(Z − b ) ⎢ 2 − 2 ⎥ = hυ
⎣ n1 n 2 ⎦
for K − series, b = 1
2⎡ 1 1⎤
∴ υ = Rc(Z − 1) ⎢ 2 − 2 ⎥
⎣ n1 n 2 ⎦
( )( )2⎡ 1 1⎤
or 4.2 × 1018 = 1.1 × 10 7 3 × 10 8 (Z − 1) ⎢ 2 − 2 ⎥
⎣1 2 ⎦
(
⇒ 0.75 = N 0 e −2 λ 1 − e −2 λ ) (ii)
solving equations (i) and (ii)
(
0.75n N 0 e −2λ 1 − e −2 λ
=
)
n (
N 0 1 − e −2λ )
3 4
or, e − 2λ = ⇒ e 2λ
4 3
( )
or, ln e 2 λ = ln 4 − ln 3
or, 2λ = 2 ln 2 − ln 3
or, 2λ = 2 × 0.6931 − 1.0986
or, λ = 0.1438 sec −1
1
∴ Mean life = = 6.954 second
λ
or mean life = 7 second
Q126. In a photoelectric, experiment setup, photons of energy 5eV fall on .the cathode having
workfunction 3eV . (a) If the saturation current is i A = 4 μA for intensity 10 −5 W / m 2 then
plot a graph between anode potential and current. (b) Also draw a graph for intensity of
incident radiation 2 × 10 −5 W / m 2
Solution: For photoelectric effect,
Incident energy (E ) = Workfunction (φ ) + K max
or K max = E − Workfunction (φ )
or eV0 = (5 − 3) = 2eV
or V0 = volt
∴ The saturation current depends on incident intensity
W
(a) Saturation current i A = 4 μA for intensity 10 −5
m2
W
(b) saturation current i A = 8μA for 2 × 10 −5
m2
The graphs (a) and (b) are shown in figure.
I n = 2 × 10 −5 W / m 2
8
6
I A = 1 × 10 −5 W / m 2
(in μA) 4
2
− 6 − 4 −2 0 2 4 6
V (in volts )
238
Q127. A radioactive sample of U decays to Pb through a process for which the half-life is
4.5 × 10 9 year. Find the ratio of number of nuclei of Pb to 238
U after a time of 1.5 × 10 9
year. Given (2)
1/ 3
= 1.26
⎛1⎞
1/ 3
⎡ ⎛ 1 ⎞1 / 3 ⎤
N Pb = N 0 − N U = N 0 − N 0 ⎜ ⎟ = N 0 ⎢1 − ⎜ ⎟ ⎥
⎝2⎠ ⎢⎣ ⎝ 2 ⎠ ⎥⎦
⎡ ⎛ 1 ⎞1 / 3 ⎤
N 0 ⎢1 − ⎜ ⎟ ⎥
N Pb ⎢⎣ ⎝ 2 ⎠ ⎥⎦ 1
= 1/ 3
= 1/ 3
−1
NU ⎛ ⎞
1 ⎛ ⎞
1
N0 ⎜ ⎟ ⎜ ⎟
⎝2⎠ ⎝2⎠
= 21 / 3 − 1 = 1.26 − 1 = 0.26
Q128. The photons from the Balmer series in Hydrogen spectrum, having wavelengths between
450 nm to 700 nm , are incident on a metal surface of workfunction 2eV . Find the
maximum kinetic energy of ejected electron. (Given hc = 1242eV nm )
Solution: For Balmer series,
hc ⎡1 1⎤
= 13.6⎢ 2 − 2 ⎥ eV where n = 3,4,5.....
λ ⎣2 n ⎦
1242 eV nm 13.6 × 5
when n = 3, =
λ3 9× 4
1242 × 9 × 4
or λ3 = = 657 nm
13.6 × 5
1242eV nm 13.6 × 3
when n = 4, =
λ4 16
1242 × 16
or λ4 = = 487 nm
13.6 × 3
In the allowed range, we have these two wavelength Maximum kinetic energy is
contained by wave of great frequency or smaller wavelength.
hc ⎛ 1242 ⎞
∴ K max = − work function = ⎜ − 2 ⎟eV
λ ⎝ 487 ⎠
= (2.55 − 2 ) eV = 0.55 eV
∴ Maximum K .E. of ejected electron = 0.55 eV
Q129. The potential energy of a particle of mass in is given by
⎧ E ; ≤ x ≤ 1⎫
V (x ) = ⎨ 0 ⎬
⎩ 0; x >1 ⎭
λ1 and λ 2 are the de-Broglie wavelengths of the particle, when 0 ≤ x ≤ 1 and x > 1
λ1
respectively. ‘If the total energy of particle is 2E 0 find
λ2
h
Solution: de Broglie wavelength λ = where K denotes kinetic energy of particle
2mK
Case (i): 0 ≤ x ≤ 1
Given: potential energy = E 0
h
∴Kinetic energy = 2 E 0 − E 0 = E 0 ∴ λ1 =
2mE0
∴ Kinetic energy = 2E 0
h λ1 2 E0
∴λ 2 = ∴ = = 2
2m(2 E 0 ) λ2 E0
λ1
∴ = 2
λ2
Q130. Highly energetic electrons are bombarded on a target of an element containing 30
neutrons. The ratio of radii of nucleus to that of helium nucleus is (14 )
1/ 3
. Find (a)
atomic number of the nucleus. (b) the frequency of K α line of X − ray produced.
(R = 1.1 × 10 7
m −1 and c = 3 × 10 8 m / s )
Solution: (a) Radius of nucleus r = r0 A1 / 3
Where A = mass number
r0 = a constant
Frequency of K α line = f
2⎡ 1 1⎤
∴ f = Rc(Z − b ) ⎢ 2 − 2 ⎥b = 1 for K α , Z = 26
⎣ n1 n2 ⎦
( )( 2⎡ 1
) 1⎤
or f = 1.1 × 10 7 3 × 10 8 (26 − 1) ⎢ 2 − 2 ⎥
⎣1 2 ⎦
3.3 × 1015 × 25 × 25 × 3
or f =
4
or f = 1.547 × 1018 Hz
Q131. In hydrogen-like atom (Z = 11) line of Lyman series has wavelength λ . The de-Broglie’s
wavelength of electron in the level from which it originated is also λ . Find the value of
n.
Solution: The wavelength of spectral series
1 ⎛ 1 1 ⎞
= RZ 2 ⎜⎜ 2 − 2 ⎟⎟
λ ⎝ n1 n 2 ⎠
1 2 ⎛1 1 ⎞
For Lyman series, = R(11) ⎜ − 2 ⎟ (given Z = 11 )
λ ⎝1 n ⎠
h h hrn
de-Broglie wavelength λ ′ = = =
p mv mvrn
nh
Since L = mvrn = (where rn = radius of n th orbit)
2π
2πhrn 2π rn
∴λ′ = =
nh n
1
Since rn = a0 n 2
Z
(Where a 0 = Bohr’s radius = 0.529 ×10 −10 n )
=
(0.529 × 10 )n−10 2
Z
2π × 0.529 × 10 −10 × n 2 2π × 0.529 × 10 −10 n
∴λ′ = =
11 × n 11
1 11
or =
λ 2π × 0.529 × 10 −10 × n
1 1
As per question, λ = λ ′ ∴ =
λ λ′
2⎛ 1 ⎞ 11
or R(11) ⎜1 − 2 ⎟ =
⎝ n ⎠ 2π × 0.529 × 10 × n
−10
1 11
or n − = = 25
n 2π × 0.529 × 10 × (11)2 × 1.1 × 10 7
−10
or n 2 − 1 = 25n
As 1 is very small as compared to n 2 . ∴ we neglect 1.
∴ n 2 = 25n or n = 25
Q132. Four physical quantities are listed in Column I. Their values are listed in Column II in a.
random order
Column I Column II
(a) Thermal energy of air molecules at room temperature. (e) 0.02 eV
(b) Binding energy of heavy nuclei per nucleon. (f) 2 eV
(c) X − ray photon energy (g) 1 keV
(d) Photon energy of visible light (h) 7 MeV
Ans. a → e, b → h, c → g , d → f
Q133. In the following, column I lists some physical quantities and the column II gives
approximate energy values associated with some of them. Choose the appropriate value
of energy from column I for each of the physical quantities in column I.
Column I Column II
(i) Energy of thermal neutrons (A) 0.025 eV
(ii) Energy of X − rays (B) 0.5eV
(iii) Binding energy per nucleon (C) 3eV
(iv) Photoelectric threshold of a metal (D) 20 eV
(E) 10keV
(F) 10 MeV
Solution: Column I Column II
(i) Energy of thermal neutrons A 0.025 eV
(ii) Energy of X-rays E 10 keV
(iii) Binding energy per nucleon F 8 MeV
(iv) Photoelectric threshold of a metal C 3 eV
Q134. Column I Column II
(i) Nuclear fission (a) Converts some matter into energy
(ii) Nuclear fission (b) Generally possible for nuclei with low atomic number
(iii) β − decay (c) Generally possible for nuclei with higher atomic
number
(iv) Exothermic nuclear (d) Essentially proceeds by weak nuclear forces
Solution:
(i) → (a),(b)
(ii) → (a), (c)
(iii) → (d)
(iv) → (a),(b), (c)
Q135. Some laws/processes are given in column I. Match these with the physical phenomena
given in column II.
Column I Column II
(a) Transition between two atomic energy levels (p) Characteristic X rays
(b) Electron emission from a material (q) Photoelectric effect
(c) Mosley’s law (r) Hydrogen spectrum
(d) Change of photon energy into kinetic energy (s) β -decay
of electrons
Ans. a → p, r; b → q, s; c → p; d → q
Assertion & Reason:
Q136. Statement-1: If the accelerating potential in an X − ray tube is increased, the wavelengths
of the characteristic X − rays do not change.
Statement-2: When an electron beam strikes the target in an X − ray tube, part of the
kinetic energy is converted into X − ray energy
Ans. (b)