A.

TITLE OF EXPERIMENT
Spot Test
B. OBJECTIVE OF EXPERIMENT
1. Identification to the mercury with Cu (II) Iodide.
2. Identification to the existence of Arsenic with the experiment of Gutzeit
method and Silver Nitric.
3. Identification to the existence of Cobalt with the Experiment of Ammonium
Thyosianat and testing with Iron.
4. Identification to the existence of Chloride using testing with precipitation as a
Silver Chloride and testing with volatilization of Chloride acid.
5. Identification to the existence of Sulphate using testing with Barium Carbonate
and phenolftalein.
6. Identification to the existence of Hydrogen peroxide using testing with
Ferrisianide and Lead sulphide.
C. LITERATURE REVIEW
Chemistry is the study of matter, Including its composition, structure,
physical properties, and reactivity. There are many approaches to studying
chemistry, but, for convenience, we traditionally divide it into five fields: organic,
inorganic, physical, biochemical, and analytical. Although this division is historical
and arbitrary, as witnessed by the current interest in interdisciplinary areas such as
bioanalytical and organometallic chemistry, Reviews These five fields Werner the
simplest division spanning the discipline of chemistry. We begin this section with
a deceptively simple question. What is analytical chemistry? Like all fields of
chemistry, analytical chemistry is too broad and active a discipline for us to Easily
or completely define in an introductory textbook. Instead, we will try to say a little
about what is analytical chemistry,
According to Kealey (2002: 1) Analytical chemistry is a scientific discipline
used to study the chemicalcomposition, structure and behavior of matter. Analytical
chemistry involves the application of a range of techniques andmethodologies to
Obtain and assess qualitative, quantitative and structuralinformation on the nature
of matter.
 a. qualitative analysisis the identification of elements, species and /
orcompounds present in a sample.
b. quantitative analysisis the determination of the absolute or relative
amountsof elements, species or compounds present in a sample.
c. structural analysisis the determination of the spatial arrangement of atoms
in an element or molecule or the identification of characteristic groups of
atoms (functional groups).
d. An element, compound or species that is the subject of analysis is known as
ananalyte,
e. The remainder of the material or sample of the which the analyte (s) form
(s) a partis known as the matrix,
As a broad outline chemistry analysis work can be classified two categories
large items, namely qualitative analysis and the quantitative analysis.Through the
qualitative and quantitative analysis, we can detect and identify the kind and
number of components Analyzed material or more commonly known as analite.
Composition analite who is learned in every process of analysis includes a variety
of species, can be elements, ions, molecules, radicals and isotope.The development
of the instrument as a result of technological development, an analysis Allows us
in various forms composition analite.The the main objective of qualitative analysis
is to identify the component in a chemical substance (Ibn 2004: 1).
Any chemical analysis can be broken down into a number of stages
thatinclude a consideration of the purpose of the analysis, the quality of theresults
required and the individual steps in the overall analyticalprocedure. quantitative
analysis.Preparation of standards containing known amountsof the analyte (s) or of
pure reagents to be reacted with the analyte (s) .Calibration of instruments to
Determine the responses to the standards under controlled conditions. Measurement
of the instrumental response for eachsample under the same conditions as for the
standards. All measurementsmay be replicated to improve the reliability of the data,
the andtime but this has cost implications. Calculation of results and statistical
evaluation (Kealey, 2002: 4).
 Precipitation Reaction Occurs when two or more soluble species combine to
form an insoluble product that we call a precipitate. The most common reaction is
metathesis reactio precipitate; in the which two compounds soluble ionic exchange
parts. When a solution of lead nitrate is added to a solution of potassium chloride,
for example, a precipitate of lead chloride forms. We usually write the balanced
reaction as a net ionic equation, in the which only the ions precipitate and Reviews
those Involved in the reaction are included. Thus, the precipitation of PbCl2 is
written as
Pb 2+ (aq) + 2Cl- (aq) PbCl2 (s)
In the equilibrium treatment of precipitation, how ever, the reverse reaction
describing the dissolution of the precipitate is more frequently encountered.
PbCl2 (s) Pb 2+ (aq) + 2Cl- (aq)
It is important to remember (Harvey, 2000: 139-140).
Inspection of a set of replicate measurements or results may reveal that one
ormore is considerably higher or lower than the remainder and Appears to be
outsidethe range expected from the inherent effects of indeterminate errorsalone.
Such values are termedoutliers, or suspect values, Because It is possiblethat they
may have a bias due to a determinate error. On occasions, the source oferror may
already be known or it is discovered on investigation, and the outlier an be rejected
without recourse to a statistical test. Frequently, however, this isnot the case, and a
test of significance such as the Q-test should be applied to asuspect value to
Determine whether it should be rejected and therefore not includedin any further
computations and statistical assessments of the Data (Kealey, 2002 : 35).
Analytes with high vapor pressures, such as volatile organics and dissolved
gases (eg, HCN, SO2) Easily can be lost by evaporation. Filling sample
containers to the brim so that they Contain no empty space (headspace) is the most
common method of minimizing volatilization. Solid samples can be topped with a
liquid to Eliminate headspace. The volatiles can not equilibrate between the sample
and the vapor phase (water) at the top of the container. The samples are Often held
at low temperature (40C) to lower the vapor pressure. Agitation Also during sample
handling should be avoided (Mitra, 2003: 19).
 Significance tests involve; a comparison between a calculated
experimentalfactor and a tabulated factor determined by the number of values in
the set (s) ofexperimental of data and a selected probability level that the conclusion
is correct.They Several are used for purposes, such as:
a. To check individual values in a set of the data for the presence of
determinateerrors (bias);
b. To compare the precision of two or more sets of the data using Reviews their
variances;
c. To compare the means of two or more sets of the data with one another or
withknown values to establish the levels of accuracy.
Tests are based on a null hypothesis an assumption that there is no
significantdifferenceCompared being between the values. The hypothesis is
acceptedif the calculated experimental factor is less than the corresponding
tabulatedfactor, calculated experimental factor is less than the corresponding
otherwise it is rejected and there is said to be asignificant differencebetween the
values at the selected probability level. The conclusion shouldalways Clearly and
unambiguously be stated (Kealey, 2002: 34).
Determination of Cu (II) in Environmental and Industrial WaterEach
filtered environmental water sample (1000ml) was evaporated nearly to dryness
with a mixture of 5 mL of concentrated H2SO4 and 10 ml of concentrated HNO 3
in a fume cupboard following a method recommended by Greenberg et al. and was
then cooled to room temperature. The residue was then heated with 10 ml of de-
ionized water in order to dissolve the salts. The solution was then cooled and
neutralized with dilute NH4OH in the presence of 1 ?? 2mL of a 0.01% (w / v)
tartarate solution. The the resulting solution was then filtered and quantitatively
transferred into a 25ml calibrated flask and made up to the mark with de-ionized
water. An aliquot (1 ?? 2mL) of this pre-concentrated water sample was pipette into
a 10 ml flask Ca librat ed a nd the Cu (II) content (Sarker, 2013: 10)
Factors that Affect the condition of the water quality, etc. items, namely the
chemical components in the water that can be toxic to the organisms that live in
them. Chemicals that Affect water quality items, namely arsenic (As) the which are
naturally sourced from nature itself, and Also from human activities. The results of
arsenic measurements in the form of suspension and dissolved at 3 sampling
locations are shown in. It appears, either as a form of suspension or dissolved
remains in very low concentrations (lower than the device detection limit (Lasut,
2016: 34).
According Kealey, (2002: 26), numerical Reviews These two characteristics of
the data are the most important and the most frequently confused. It is vital to
understand the difference between them, and this is best illustrated
diagrammatically as in. Four analysts have each performed a set of five titrations
for the which the correct titer is known to be 20:00 cm3. The titers have been plotted
on a linear scale, and inspection reveals the following:
1. The average titers for analysts B and D are very close to 20:00 cm3 - Reviews
These two sets are therefore said to have good accuracy;
2. The average titers for analysts A and C are well above and below respectively
cm3 20:00 - These are therefore said to have poor accuracy;
3. The five titers for Analyst A and the five for analyst D are very close to one
another within each set. Reviews These two sets therefore both show good
precision;
4. The five titers for the five analyst, B and C are for analyst Widely spread within
each set - Reviews These two sets therefore both show poor precision.
An analyte and an interferent can be separated if there is a significant difference
in least one of Reviews their chemical or physical properties. Provides a partial list
of Several separation techniques, classified by the chemical or physical property
that is exploited. The simplest of physical properties that can be exploited in a
separation is size. The separation is accomplished using a porous medium through
the which only the analyte or interferent can pass. Filtration, in the which gravity,
suction, or pressure is used to pass a sample through a porous filter is the most
commonly encountered separation technique based on size. If there is a difference
in the mass or density of the analyte and interferent, then a separation using
centrifugation may be possible. The simplest of physical properties that can be
exploited in a separation is size. The sample, as a suspension angular (Harvey, 2000:
205-206).
D. APPARATUS AND CHEMICALS
1. apparatus
a. Test tube (4 units)
b. Test tuberack (1 unit)
c. Stir bar (1 unit)
d. Spiritus Burner (1 unit)
e. Tripod and Gauze (1 set)
f. Spot Plate (1 unit)
g. Spray Bottle (1 unit)
h. Rough Cloth (1 unit)
i. Smooth Cloth (1 unit)
j. Spatula (1 unit)
k. Porcelain (1unit)
l. Clamp (2 units)
m. Drop pipette (19 units)
2. Chemicals
a. Potassium Iodide-Sodium Sulphate solution (KI-Na 2S2O3)
b. Copper (II) Sulphate solution (CuSO4)
c. Acid chloride solution (HCl)
d. Nitric Acid solution (HNO3)
e. Zink solid (granules) (Zn)
f. Sulfuric Acid solution (H2SO4)
g. Silver Nitric solution (AgNO3)
h. Ammonium hydroxide solution (NH4OH)
i. Hydrogen Peroxyde solution (H2O2)
j. Acetic Acid solution (CH3COOH)
k. Silver Nitric solution 1% (AgNO3)
l. Ammonium thiocyanate solution (NH4SCN)
m. Ammonium Fluoride solution (NH4F)
n. Oxyn (C6H9NOH)
o. Barium Carbonate solid (Baco3)
p. Phenolphtalein indicator (pp)
q. Solid Sodium Chloride (NaCl)
r. Hydrargirum (II) chloride solution (HgCl2)
s. AresenOxyde solution (As2O3)
t. Nitric solution Cobalt (Co (NO3) 2)
u. Distilled water (H2O)
v. tissue
w. matches
x. filter paper
E. WORK PROCEDURE
1. Mercury Test with Cu (II) Iodide
a. 1 drop of KI-Na2SO3 solution was added into the spot plate
b. 1 drop of CuSO4 was added into the spot plate
c. 1 drops of HgCl2 was added and the mixture solution was stirred
2. Arsenic Test
a. Gutzeit Method
1) 3 drops of As2O3 as the sample was added into a test tube
2) Solid Zn was added into the test tube
3) 3 drops of H2SO4 was added into the test tube
4) Filter paper was added with 1 drop of AgNO3and covered at test tube
b. Silver Nitric
1) 3 drops of As2O3 was added into porceline
2) 3 drops of H2O2 and 3 drops of NH3 was mixtured and heated
3) Added 2 drops of CH3COOH
4) 2 drops of AgNO3 was added into porceline
3. Cobalt Test
a. Ammonium Thiocyanate and Aceton
1) 1 drop of Co(NO3)2 was dropped into the spot plate
2) 1 drop of NH4SCN 10% was added into the spot plate
b. The Existence of Fe ion
1) 1 drops of Co(NO3)2 was dropped into the spot plate
2) Some mg of NH4F was added into the spot plate
3) 5 drops of NH4SCN 10% was added into test tube
4. Chloride Test
a. Silver Chloride Precipitation
1) 1 drops of HCl was dropped into a test tube
2) 1 drop of oxyn was added to the test tube and it was shaken
3) 1 drop of HNO3 was added into the test tube
4) 1 drop of H2O2 solution was mixed with above test tube
5) Heat was done during 4 minutes
6) 1 drop of 1% AgNO3 was mixed and it was shaken in a test tube
b. Volatilization of Chloride Acid
1) NaCl solid was put into a test tube
2) 1 drops of HNO3 was added into the test tube
3) 3 drops of AgNO3 was added again into test tube
4) Heat was done and shakeen until bubbly
5. Sulfuric Test with BaCO3 and pp
a. 1 drops of H2SO4 was dropped into porcelain
b. 1 drops of BaCO3 was added into porcelain
c. Heat until dry
d. Some drops of pp was added into porcelain and it was shaken
F. OBSERVATION RESULT
NO ACTIVITY RESULT

1 drop KI-Na2SO4 + 1 drop CuSO4 +

1 The color is orange
1 drop HgCl2

3 drops As2O3 + Zn Solid + 3 drops

2 H2SO4 + Closed with filtering paper + Yellow stein
AgNO3 1%
 3 drops As2O3 + 3 drops 3 drops NH3
+ H2O2 + heated + 2 drops CH3COOH colorless
+ 2 drops of 1% AgNO3

1 drop Co (NO3) + 1 drops NH4SCN The color is blue

3 1 drop Co(NO3) + 1 drop NH4F + 1

The color is green
drop NH4SCN

3 drops drops Ocine HCl + 3 + 3

drops 3 drops H2O2 + HNO3 + Heated Have white precipitate

4 AgNO3 + 3 drops 1%

Crystal NaCl + 2 drops of AgNO3

Have a bubbly and murky
HNO3concentrted + 1% + Heated

1 drop of H2SO4 + 1 drop of BaCO3 +

5 colorless
Heated until cleaning + 1 drop of pp

G. DISCUSSION
Spot test is a qualitative analysis used to test micro and semi-micro to
compounds or ions. Spot tests were used in this experiment because it can identify
the components in a chemical substance that produces sediment, color, and gas.The
basic principle in experiments spot test is the analysis of the levels of a substance
based on the intensity of color or precipitation of the complex formed solution.
While working principle that is by adding a reagent to a material suspected to
contain ingredients that will be identified, with the end result that a typical color
change or precipitate is formed.
1. Test mercury with Cu (II) Iodide
This experiment aims to identify the presence of mercury with a solution of Cu
(II) iodide.Solution to be tested, namely mercury. In this experiment used KI.
Na2SO3 solution that serves to liberate iodide then CuSO4 solution that frees Cu 2+
ions causing color changes to yellow solution. This color change occurs due to the
iodide ion that is as a reducing agent, so that the iodide ion will reduce copper (II)
to copper (I).
The next process solution was added with HgCl2. Addition with HgCl2 will
yield an orange. The addition of HgCl2 was caused by copper ions reduce mercury
(II) to their metal. That produce color depending on the amount of mercury
contained in the test solution HgCl2. The solution obtained shows the presence of
mercury in the solution of this. Its can show in a solution containing mercury. Occur
discoloration caused because iodide ions precipitate mercury (II) from the solution
as a precipitate orange (HgI2), this precipitate soluble iodide ion redundant because
of the formation of the complex tetra iodo merkurat (II) (HgI4)2.
This is consistent with the theory that if mercury is reacted with CuI2 will
change color to red or orange color (Sugiyanto, 2003: 164). The full reaction:
4KI.Na2SO3 + 6CuSO4 2CuI2 + 4CuSO3 + 4Na2S2O4 + 2K2SO4
(Potassium Iodide- (Copper (II) (Copper (II) (Copper (II) (Sodium (Potassium
Sodium Sulphate) Sulphate) Iodide) sulfites) Thiosulfate) Sulphate)
(colorless) (blue) (yellow)

2Cu2I2 + HgCl2 CuI2(HgI4) + Cl2 + 2Cu2+

(Yellow) (colorless) (Orange)

This is in accordance with the theory that a drop of solution or suspension

is generated and reacted with Nessler reagent will produce a stain red-orange or
yellow (Svehla, 1979: 215).
2. Arsenic Test
a. With the method Guitzeit
Guitzeit arsenic testing method, which aims to demonstrate the presence of
arsenic in the mix, marked by a yellow stain on the filter paper. The solution to be
tested is added to the metal Zn As2O3 with dilute H2SO4 in a test tube. H2SO4
function which gives the acid environment that donates H+ and Zn metal functions
to form a hydride vapor streamed arsenic filter Zn acts as a reducing agent, As for
the reaction:
As3 + 3Zn + 3H + → AsH3 + 3Zn2
(Colorless) (gray)
After the addition of H2SO4, the reaction tube mouth covered with filter
paper that had been instilled with AgNO3 and after a while to form a yellow stain
on the filter paper, so that a positive trial. This is consistent with the theory that the
presence of arsenic in a sample can be marked by a yellow stain on the filter paper
for their complex compounds AsAg3. AgNO3 (Svehla, 1982: 245). As for the
reaction:
AsH3 + 6Ag + As3 + + 3H + + 6Ag
AsH3 + 3AgNO3 AsAg3 + 3HNO3
(Arsin) (Silver Nitrate) (Arsenic (II) Silver) (Nitric Acid)

b. With silver nitrate

This experiment aims to identify the presence of arsenic in the sample
solution with silver nitrate. Test arsenic with silver nitrate when it contains arsenic
indicated by the sediment white with alkali to form silver arsenate arsenate white
and insoluble in acetic acid. The reaction occurs:
AsO43- + 3 Ag + Ag3SO4
Arsenic testing with silver nitrate is by As2O3 were then added to the NH3 and
H2O2 heated produce a colorless solution. The purpose of the addition of a solution
is to form arsenate that previously were shaped arsenit. Heating done so that the
reaction proceeds rapidly. As2O3 solution serves as a test solution, then a solution
of NH3 and H2O2 is used to change the form of acid arsenite arsenic, sulfides,
sulfoarsenit or sulfoarsenat into arsenate. The solution obtained is then added to the
CH3COOH and AgNO3 1%which produces a precipitate.1% AgNO3 solution serves
as a precipitating agent which binds or reacts with silver arsenate arsenate form,
then a solution of CH3COOH serves to provide the acid in solution in order to
accelerate the formation of deposits, while AgNO3 serves as settling will release
Ag+ reacts with arsenate form Ag3AsO4.In this experiment is not obtained brown
precipitate turbid Ag3AsO4, in this experiment, obtained a clear solution and no
precipitate, this is because the experiment used is NH3 while that should be used is
NH4OH as NH4OH can change the arsenic in the form of acid arsenite sulfite into
arsenate. As for the reaction:
H3AsO4 + 2 NH4OH + H2O2 + AsO43- + 2 NH3 + 2 H2 + 3H + AsO43- + 3 AgNO3
(Acetic acid) (Amonium (Hidrogen (Silver nitrate)
hidroksida) peroksida)
3. test cobalt
a. Test cobalt with ammonium thiocyanate in acetone
In this experiment was conducted to determine the element cobalt in the test
samples proved with the formation of blue-green solution. Testing of cobalt with
ammonium thiocyanate is done by inserting a solution of Co(NO3)2 color red to spot
plate, Co(NO3)2 here serves as a solution tested which according to a theory if it
contains cobalt color will appear green to blue depending on a lot of cobalt
contained in the test solution and the solution formed is green. Then add NH4SCN
and produces a blue color. With the change in the color of cobalt will undergo
ionization and ion complex formed tetrasianocobalt (II). This is consistent with the
theory that a solution containing cobalt, when reacted with NH4SCN will produce
green to blue (Svehla, 1979: 278). As for the reaction:
Co(NO3)2 CO2 + + 2NO32-
(Cobalt nitrate) (cobalt ions) (nitrate ion)
Co2 + 4SCN- [Co(SCN)4] 2-
(Ion cobalt (II)) (thiocyanate ions) (tetrasionocobalt (II))
Co(NO3)2 + 4NH4SCN [Co(SCN)4]2- + 4NH4 + + 2NO3
Complex ion cobalt thiocyanate
CoNO3 + NH4SCN → Co(SCN)4 (NH4)2 + NH4NO3
(Red) (colorless) (blue prusi)
b. Test cobalt with iron
This test aims to identify or test for the presence of cobalt in the sample
solution with ammonium thiocyanate forming a blue solution. Solution who will be
tested in this trial is Co(NO3)2 by introducing the solution Co(NO3)2 into a spot plate
which is then added with NH4F. NH4F addition of ferric salt serves to change into
ferric fluoride ion complexes are insoluble and not color. Addition NH4SCN serves
to provide a color change in the solution that is blue to green. The result of the
reaction between Co (NO3) 2, NH4F and NH4SCN yield a green color. NH4SCN
additional function that gives green color change and ionise tetratoisanato cobalt
and cobalt ions form (II), In this experiment, no added iron for test weak. Metal
nature hard to resemble the appearance of iron and metal fermeabilitas nikel. Cobalt
have amounted to 2/3 of iron. That is consistent with the theory that the presence of
iron cobalt test is marked in green to blue and no deposits. As for the reaction:
 Co (NO3) 2 CO2 + + 2NO32-
Co2+ + 4 SCN- [Co (SCN) 4] 2-
Co (NO3) 2 + 4 NH4SCN Co (SCN4) (NH4) 2 + 2NH4NO3
(Cobalt nitrate) (ammonium thiocyanate) (Ammonium nitrate)
4+
Co (NO3) 2 + 4NH4F [CoF4] 2- + 4NH + 2NO3-
(Cobalt nitrate) (ammonium fluoride) (Complex tetra- (ammonium ion) (nitrate ion)
flouridakobalt (II))

Co [F4] 2- + 4SCN- [Co (SCN) 4] 2- + 4 F-

(Tetraflouridakobalt complex (II)) (thiocyanate ions) (tetrasionatkobalt (II)) (fluoride ion)

In this experiment, no iron was added, but because cobalt has the same
2+
properties as the iron so that when the NH4F reacts with nitrate and Co cobalt
into cobalt ion Flurida which reacts with NH4 SCN forming cobalt tiosionat dark
green.
4. test chloride
In this experiment aims to identify the presence of chloride in the sample
with the two methods, namely precipitation as silver chloride in the presence of
other halide and testing with hydrochloric acid volatilization.
a. With sebaal precipitation of silver chloride in the presence of other halides
Test chloride by precipitation as silver chloride in the presence of other
halides, indicating a positive test containing chloride characterized by the formation
of white sediment and turbidity in the solution. Where HCl solution was treated
with a solution of H2O2 and HNO3 then heated and then added 1% AgNO3 produce
white precipitate and turbid solution. HCl solution serves as a test solution, a
solution H2O2 serves as an oxidant that will oxidize free halogen Bromide (Br) and
iodide (I-) becomes Brom and Iod. Oksin solution to function when progress will
halogenated phenolic compounds by halogen-free (Br- and I-). HNO3 solution
serves to provide an atmosphere in hydrochloric acid that does not oxidize by H2O2
and heating functions for vaporation other halides (Br- and I-) accelerate the
reaction and also causes the formation of salt stick to the porcelain crucible. AgNO3
solution serves to react with Cl- forming AgCl which precipitates and make the
solution cloudy, while the reaction is:
C6H9NOH C6H9NCl + HCl + H2O
 (Nodes) (nodes) (nodes)
C6H9NCl C6H9NOH + HCl + H2O2
(Nodes) (nodes) (nodes)
Cl + AgNO3 H+ AgCl + HNO3
(Clear) (white precipitate) (clear)

b. Testing with hydrochloric acid volatilization

Test chloride by volatilization of hydrochloric acid showed a positive test is
marked with a solution containing chloride turbid and white deposits on the stirrer
rod.Sampel used in these experiments are solid NaCl is added with HNO3 and
heatedwith stems that have previously been wetted stired After that enter the stir
bar that has been soaked with AgNO3. The function of HNO3 is giving the acid in
the solution while AgNO3 serves to generate Ag + ions which then binds to the ion
Cl. This mixture is heated to form a bubble, in a test tube to form a bubble, not just
by nitration chloride, but also produced silver chloride which is characterized by
turbid solution (Svehla, 1982: 358).
NaCl + HNO3 NaNO3 + HCl
HCl + AgNO3 AgCl + HNO3
(White precipitate)
5. Test sulfate with barium carbonate and pp
This experiment aims to identify sulfate. Barium sulfate trials with
carbonate and PP showed a positive test containing sulfate characterized by the
formation of red sludge. The solution test is CuSO4 which reacts with BaCO3. The
function of BaCO3 as contributor Ba2+ ion binds to SO42- of the compound CuSO4
and form BaCO3. In this experiment, a solution of H2SO4 reacted with BaCO3
produce a yellow solution. Then he added indicators PP heated and produces a red
colored solution. The H2SO4 serves as a test solution to be reacted with BaCO3.
While BaCO3 serves as a reagent that reacts quickly to form a solution containing
sulfuric white precipitate BaSO4 (Ibnu 2004: 49). The function of the indicator PP
itself is to detect the reaction results in a color change to red. PP indicator is used
as an indicator PP stretch alkaline with pH 8.0 with a color change from colorless
to red (Khopkar, 2007: 44). So indkator PP is used because the reaction products
obtained are BaSO4 and we know that BaSO4 alkaline. As for the reaction:
CuSO4 + BaCO3 PP BaSO4 + CuSO4
(Copper (Barium (Barium (Copper (II)
(II) carbonat sulfate) carbonate)
sulfate) e)
A. CONCLUSION AND SUGGESTION
1. Conclusion
Based on the result of experiment, can be conducted that:
1) Mercury test by Cu (II) iodide, that there is mercury in solution mixture which
marked by changing of color solution became red solution.
2) Arsenic test
a. By Gutzeit method, the solution not contain of arsenic because in filter paper not
formed of yellow spot because be found of mistake in experiment.
b. By silver nitrate, indicate of positive test that marked of changing the color of
solution is colorless and white precipitation
3) Cobalt test
a. By ammonium thicyanate and acetone, indicate of positive that marked with
formed of green-blue solution that means the solution contain of cobalt
b. By existance of iron, indicate of positive that marked with formed of green-blue
solution that means the solution contain of cobalt
4) Chloride test
a. Testing and precipitating as silver chloride with another halides is indicate of
positive test is chloride. Marked with changing of solution become white
precipitation
b. By volatilization chloride acid test is indicate of posistive test with there is Buble
formed, and clear yellow color solution
5) Sulphate test with barium carbonate and pp, that the solution not contain of
sulphate because the solution not become red because be found of mistake in
experiment.
2. Suggestion
 Before the experiment will be held, the apparatus and chemicals should be
prepared completely. So that the experiment can be held maximaly and gave
maximal result. For the next apprentice should be used the time efficiently.

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Lasut, henry e. Kawung, Nickson j. And Lasut markus t. 2016. The content of arsenic
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Mitra, Somenath. 2003.Sample Preparation Techniques in Analytical Chemistry,

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