CHEMISTRY (Mock Test-1)

41. Which of the following compounds has

the least tendency to form hydrogen
bonds between molecules ? Mock Test–1 (Chemistry)

(a) NH4OH (b) CH3F

(c) NH3 (d) HF

42. The ratio of the difference in energy

between the first and second Bohr orbit
to that between second and third Bohr
atom in H-atom is :
(a) 4/9 (b) 1/3 (c) 27/5 (d) 1/2

43. How many molecules are present in one

gram of hydrogen ?
(a) 3⋅01 × 1023 (b) 1⋅5 × 1023
(c) 2⋅5 × 1023 (d) 6⋅02 × 1023

44. The shape of covalent molecule AX3 is :

(a) T-shape
(b) triangular
(c) pyramidal
(d) Any of the above three depending
upon the number of lone pairs on
A

45. Which of the following molecular orbital

has the lowest energy ?
(a) π∗ 2pz
(b) π∗ 2py
(c) σ 2px
(d) σ∗ 2px

46. The enthalpy of formation for

o
C2H4(g), CO2(g) and H2O(l)at 25 C and
1 atm pressure be 52, -394, -286
kJ mol−1 respectively. The enthalpy of
combustion of C2H4(g) will be :
(a) −141⋅2 kJ mol−1 (b) −1412 kJ mol−1
(c) +141⋅2 kJ mol−1 (d) +1412 kJ mol−1

47. When equal volumes of the following

solutions are mixed, precipitation of
AgCl (Ksp = 1⋅8 × 10−10) will occur only
with :
(a) 10−10 M (Ag+) and 10−10 M (Cl−)
(b) 10−4 M (Ag+) and 10−4 M (Cl−)
(c) 10−5 M (Ag+) and 10−5 M (Cl−)
(d) 10−5 M (Ag+) and 10−6 M (Cl−)
 Mock Test–1 (Chemistry)

48. The heats of combustion of C2H4, C2H6

and H2 are−1400⋅5 kJ, −1558⋅3 kJ and
−285⋅6 kJ. The heat of hydrogenation of
ethene is :
(a) 273⋅6 kJ (b) 1⋅368 kJ
(c) –136⋅8 kJ (d) 13⋅68 kJ

49. In which of the following binary

compound, the ratio rcation ⁄ ranion is
least ?
(a) CsF (b) LiF
(c) LiI (d) CsI

50. BF3 is a :
(a) Bronsted acid (b) Bronsted base
(c) Lewis acid (d) Lewis base

51. What is the order of reaction which has

a rate expression
Rate = K [A]3 ⁄ 2 [B]−1 ?
1
(a) (b) 3/2
2
(c) Zero (d) None of these

52. For a reversible process at equilibrium,

the entropy change can be expressed as :
ΔH
(a) ΔS = (b) ΔS = T ΔH
T
qrev
(c) ΔS = (d) Δ = T⋅qrev
T

53. The rate of a reaction :

(a) depends upon temperature
(b) is not equal to its molecularity
(c) is equal to its molecularity
(d) can not be predicted

54. A compound formed by element A and

B crystallises in cubic structure in which
A atoms are at the corners of the cube
while B atoms are in the centre of cube.
Formula of the compound is :
(a) A2B3 (b) AB2
(c) AB3 (d) AB

55. pH of 10−9 M HCl is :

(a) >7 (b) < 7
(c) 7 (d) 8

56. The emf of the cell involving the reaction :

2Ag+(aq) + H2(g) → 2Ag(s) 2H+(aq)
is 0⋅80V. The standard oxidation
potential of silver electrode is :
(a) 0.20 V (b) 0.40 V
(c) –0.80 V (d) 0.80 V
 Mock Test–1 (Chemistry)

57. The solution containing 4⋅0 g of PVC in

one litre of dioxane was found to have
osmotic pressure of 6⋅0 × 10−4 atm at
300K. The molecular mass of polymer is :
(a) 5⋅6 × 104 (b) 1⋅6 × 105
(c) 3⋅0 × 10−2 (d) 6⋅4 × 102

58. Calculate the molality of solution

prepared by dissolving 18 g of
glucose (molecular mass= 180) in 500g of
water :
(a) 0.2 M (b) 0.1 M
(c) 0.4 M (d) 1.2 M

59. What would happen when a small

quantity of H2O2 is added to solution of
FeSO4 ?
(a) An electron is added to Fe2+
(b) An electron is lost by Fe2+
(c) Colour disappear
(d) H2 is evolved

60. Which of following method is not

employed for the purification of colloids?
(a) Ultracentrifugation
(b) Peptisation
(c) Dialysis
(d) Electrodialysis

61. If the mass defect of 4X9 is 0⋅09 a.m.u,

then the binding energy per nucleon is :
(a) 8.38 MeV (b) 83⋅8 MeV
(c) 931⋅5 MeV (d) 9⋅315 MeV

62. From the following enthalpies of

combustion, deduce which of the quoted
expressions gives the heat of formation
of CH4 at a fixed temperature.
C + O2(g) → CO2(g) ; ΔH = c
H2(g) + 1 ⁄ 2 O2(g) → H2O(l) ; ΔH = h
CH4(g) + 2O2(g) → CO2(g) + 2H2O(l) ;
ΔH = m :
(a) c + 2h − m (b) −1 ⁄ 2c—h + 1 ⁄ 2m
(c) c + h − m (d) −c − h + m

63. Copper can be extracted from :

(a) kupfer nickel (b) dolomite
(c) malachite (d) galena
 Mock Test–1 (Chemistry)

64. The phenomenon of syneresis is :

(a) migration of colloid in an electric field
(b) process of converting gel into a true
solution
(c) separation of the dispersed phase
from the gel
(d) formation of a sol from a gel

65. Which of following members of nitrogen

family does not show negative oxidation
state ?
(a) Bi (b) Sb
(c) As (d) P

66. The freezing poing of heavy water is :

(a) −3⋅82oC (b) −4oC
(c) 3⋅82oC (d) 0oC

67. Plaster of Paris is :

(a) CaSO4⋅H2O (b) 2CaSO4⋅2H2O
(c) CaSO4⋅2H2O (d) CaSO4⋅1 ⁄ 2H2O

68. Composition of Kopper’s gas is :

(a) CO (14−16%) + H2 (35−42%)
+ CO2 (30%) + CH4 (10−15%)
(b) CO (51⋅1%) + CO2 (12⋅6%) + H2 (34%)
+ N2 (1⋅9%) + O2 (0⋅1%) + CH4
(c) CO (46%) + H2(36.6%) + CO2 (14%) +
N2 (1.1%) + CH4(2.4%)
(d) none of the above

69. Which one of the following combines

with Fe(II) ions to form brown complex ?
(a) N2O3 (b) N2O5
(c) N2O (d) NO

70. H2S2O8 is :
(a) Marshall’s acid
(b) a peroxy compound
(c) an intermediate in the manufacture of
H2SO4
(d) (a) and (b) both

71. Liquid oxygen is :

(a) pale yellow (b) dark blue
(c) pale blue (d) colourless
 Mock Test–1 (Chemistry)

72. Decomposition of H2O2 is a first order

reaction. A 16 volume solution of H2O2
having half life 15 minutes is present
initially. When will the solution become
‘‘1 volume’’ :
(a) after 120 minutes
(b) after 150 minutes
(c) after 60 minutes
(d) after 90 minutes

73. Lucas reagent is :

(a) Na + H2O
(b) H2SO4 + HCl
(c) MnO2 + H2O
(d) ZnCl2 + HCl (conc.)

74. Potassium is kept in :

(a) ammonia (b) alcohol
(c) kerosene (d) water

75. The correct formula of Borax is :

(a) Na2B4O7⋅8H2O
(b) Na2 [B4O5 (OH)4 ]⋅10H2O
(c) Na2B4O7⋅4H2O
(d) Na2 [B4O5 (OH)4 ]⋅8H2O

76. Which of the following metal is obtained

by the electro-metalluragy ?
(a) Ag (b) Na
(c) Fe (d) Pb

77. Which of the following has highest

ionisation energy ?
(a) Cu (b) Au
(c) Ag
(d) All have equal ionisation energies

78. Chemical reduction is not suitable for :

(a) conversion of bauxite into
aluminium
(b) conversion of cuprite into copper
(c) conversion of haematite into iron
(d) conversion of zinc oxide to zinc

79. Toluene on oxidation with chromyl

chloride produces :
(a) benzaldehyde (b) benzoic acid
(c) chlorobenzene (d) none of these

80. Which of the following is an important

constituent of transistors ?
(a) Osmium (b) Radium
(c) Germanium (d) Silver