Class__________________ Name: ________________________HT.NO.

________________
HINDI MAHAVIDYALAYA
(AUTONOMOUS)(Affiliated to Osmania University)
Nallakunta, Hyderabad-44

B.Sc. (BtMbC/BcMbC) III YEAR –V-SEMESTER

SUBJECT & PAPER No.: Chemistry - V
Slip test - 2
Time: 30 Minutes Max. Marks: 15

I MCQ's
1 In colourimeter the lamp used is [ ]
(a) Hg Lamp (b) W lamp ( c) Na Lamp (d) None
2 For measurements using coloured solutions, the cells are made of [ ]
(a) Pyrex glass (b) quartz (c )filters (d) Fibre
3 Compared to visible lightwave, the energy content of a UV light wave is [ ]
(a) eqal (b) More (c ) Less (d) Zero
4 The Ratio of intensity of incident light and transmitted light is [ ]
(a) Transmittance (b) absorbance ( a) Molar absorptivity (d) None
5 In Globar source, radiation source is made up of [ ]
(a) Na vapour (b) Quartz ( c ) SiC rod (d) Ni wire

6 In IR spectroscopy, in handling the sample by mull method the mineral oil used is [ ]
(a) Palm Oil (b) Nujol Oil (c ) Coconut Oil (d) both a & c
7 Absorbance is [ ]
(a) - Log T ( b) Log T (c ) % T (d) None
8 Units of molar absorptivity are [ ]
(a) Lit.cm.mol (b) Mol-1 . cm/lit ( C) Litcm-1 . Mol (d) Mol-1 . Cm-1 . Lit
9 The Estimation of Iron in water sample is done by [ ]

(a) KCN (b) AgCN ( C) SCN (d) HNO3

10 In IR spectrum, the plot is of absorbance (Vs) [ ]

(a) Wave lenth (b) Wave number ( c) Transmittance (d) none

II Fill in the Blanks :-

11 Devices used to hold sample solution are _______________

12 __________________ is a study of measurement of amount of light passing through the sample .

13 ________________ spectrophotometer measures the ratio of intensities of sample and reference beam.
14 The main disadvntage of Nernst Glower is its ___________________
15 Solvents used in IR are _______________
16 In IR , Gas Sample cells are made up of _________________
17 FT- IR spectroscopy operates on ___________________
18 In the estimation of Mn is steel, the oxidising agent used is ________________

19 Absorption in the IR region is due to changes in the __________________ and rotational levels of a molecule.
20 In the estimaton of Cr in steel, Cr is oxidised to dichromate ion by _________________________
III Define the following
21 Absorbance . 25. Detectors
22 Beer Lambert's Law .
23 Molar absorptivity.
24 Colorimetry.
 Class__________________ Name: ________________________HT.NO.________________
HINDI MAHAVIDYALAYA
(AUTONOMOUS)(Affiliated to Osmania University)
Nallakunta, Hyderabad-44

B.Sc. (BtMbC/BcMbC) III YEAR –V-SEMESTER

SUBJECT & PAPER No.: Chemistry - V
Slip test - 2
Time: 30 Minutes Max. Marks: 15

SECTION-A
I. MULTIPLE CHOICE QUESTIONS: (10 X 1/2 = 5M)

1. The IUPAC name of H3C – N- CH2 – CH3 is [ ]

C2H5
(a) N- methyl N- ethyl ethanamine (b) N- Ethyl N- Methyl Propanamine (c) N- ethyl N- Methyl ethanamine (d) none
2 . The hybridisation of N- atom in amines is [ ]
(a) SP2 (b) SP (c) SP3 (d) dsp2
3. In Holfmann bromamide reaction, an amide is treated with [ ]
a) Br2 +KOH (b) Br2 +HCl (c) Br2 + HNO3 (d) Br2 + H2O
+Cl – on
4. C6H5N2 reaction with HBF4 gives [ ]
(a) Fluorobenzene (b) Chlorobenzene (c) Nitrobenzene (d) None
5. With phenol, Bemzene diazonium chloride gives [ ]
(a) O – Toluic acid (b) P- Hydroxy azobenzene (c) Aniline (d) Sodium Phenoate
6. Aldoximes on dehydration with acetic anhydride gives [ ]
(a) Phenylcyanide (b) Methyl Cyanide (c) Methyl Iso cyanide (d) all the above
7. Alkyl Isocyanides on reduction with H2/ Ni gives [ ]
0 0 0
(a) 1 amines (b) NH3 (c) 2 amines (d) 3 amines
8. Which of the following compound act as Diene [ ]
(a) Pyrrole (b) Furan ( c) Pyridine (d) Thiophene
9. In Pyridine , nucleophilic substitution takes place at [ ]
(a) 2nd Position (b) 3rd Position (c) 4th position (d) none
10. n - * transition is found in which of the following molecule [ ]
(a) Methane (b) Ethane (c) Ethanol (d) Propane.

SECTION-B
II. Fill in the Blanks
11. In Gatterman reaction the catalyst used is _____________________
12. The Reactivity order of furan , Pyrrole and thiophene is _______________
13. In Chichibabin reaction Pyridine is treated with _________________________
14. In Carbonyl compounds ____________________ transition is observed.
15. According to Woodward –Fieser rule, max for butadiene system is _____________
16. The wave length of UV – radiations used in UV – spectra is _______________
17. Auxochrome shifts the absorption band towards _______________
18. In Pyrrole , Furan Thiophene electrophillic substitution takes place at _____________________
19. 1,4 – dicarbonyl compound on heating with P 2S5 gives _______________
20. Amines are separated by _________________ method
SECTION-C
III Explain the following
21. Diazotization
22. Diel’s - Alder reaction
23. Bathochromic shift
24. Chromphore
25. Hypsochromic shift.
****
 Class__________________ Name: ________________________HT.NO.________________
HINDI MAHAVIDYALAYA
(AUTONOMOUS)(Affiliated to Osmania University)
Nallakunta, Hyderabad-44

B.Sc. (BtMbC/BcMbC) III YEAR –V-SEMESTER

SUBJECT & PAPER No.: Chemistry - V
Slip test - 2
Time: 30 Minutes Max. Marks: 15

SECTION-A
I. MULTIPLE CHOICE QUESTIONS: (10 X 1/2 = 5M)

1.

..

10

SECTION-B

II. FILL IN THE BLANKS: (10 X 1/2 = 5M)

11.

12

..
 Class__________________ Name: ________________________HT.NO.________________
HINDI MAHAVIDYALAYA
(AUTONOMOUS)(Affiliated to Osmania University)
Nallakunta, Hyderabad-44

B.Sc. (BtMbC/BcMbC) III YEAR –V-SEMESTER

SUBJECT & PAPER No.: Chemistry - V
Slip test - 2
Time: 30 Minutes Max. Marks: 15

20

SECTION-C

III. SHORT NOTE ANSWERS: (5 X 1 = 5M)

21.

22

..

25