Sample Calculations:

 Actual Concentration KMnO4

1 𝑚𝑜𝑙 𝑁𝑎2 𝐶2 𝑂4 2 𝑚𝑜𝑙 𝐾𝑀𝑛𝑂4
0.1000 𝑔 𝑁𝑎2𝐶𝑂4 × ×
134 𝑔 𝑁𝑎2 𝐶2 𝑂4 5 𝑚𝑜𝑙 𝑁𝑎2 𝐶2 𝑂4

= 2.985074627 × 10−4 𝑚𝑜𝑙 𝐾𝑀𝑛𝑂4

2.985074627 × 10−4 𝑚𝑜𝑙 𝐾𝑀𝑛𝑂4
𝐶𝐾𝑀𝑛𝑂4 =
1𝐿
11.94 𝑚𝑙 × 1000 𝑚𝐿

𝐶𝐾𝑀𝑛𝑂4 = 0.0250 𝑀 𝐾𝑀𝑛𝑂4

 % C2O4 (w/w) of unknown sample

𝑚𝑚𝑜𝑙𝐾𝑀𝑛𝑂4 = (9.65 𝑚𝐿)(0.0250 𝑀)

𝑚𝑚𝑜𝑙𝐾𝑀𝑛𝑂4 = 0.24125 𝑚𝑚𝑜𝑙 𝐾𝑀𝑛𝑂4

5 𝑚𝑚𝑜𝑙 𝐶2 𝑂4 88.02 𝑚𝑔 𝐶2 𝑂4
0.24125 𝑚𝑚𝑜𝑙 𝐾𝑀𝑛𝑂4 × ×
2 𝑚𝑚𝑜𝑙 𝐾𝑀𝑛𝑂4 1 𝑚𝑚𝑜𝑙 𝐶2 𝑂4
= 53.0870625 𝑚𝑔 𝐶2 𝑂4
53.0870625 𝑚𝑔 𝐶2 𝑂4
% 𝐶2 𝑂4 = × 100 %
1000 𝑚𝑔
0.1013 𝑔 ×
1𝑔
% 𝐶2 𝑂4 = 52.40 %