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Lithium air battery is a fascinating energy storage system. The effective exploitation of air as a battery
electrode has been the long-time dream of the battery community. In the particular case of lithium air
system, energy levels approaching that of gasoline have been suggested or accepted. It is then not
surprising that, in the course of the last decade, great attention has devoted to this battery by various top
academic and industrial laboratories worldwide. The intense investigation, however, has soon highlighted
a series of issues that prevent a rapid development of the lithium air (li/air) electrochemical system.
Although several breakthroughs have been achieved recently, the question on whether this battery will
have effective economic and societal impact is not yet certain.
SEMINAR REPORT 2019-2020
CHAPTER 1
INTRODUCTION
A breakthrough in Li-air battery technology would significantly increase the possibility of extending the
electric range of these vehicles,
This research work is confined within the topic of lithium-air battery using the non-aqueous lithium-air
battery as a case study which identifies how it works, history associated with the research work, area of
application, limitations etc.
1.6 LIMITATION
1.7 GLOSSARY
1. Battery: A battery is a device consisting of one or more cells that can produce a direct current by
converting chemical energy to electrical energy.
2. Lithium-air battery: Is a metal air battery chemistry that uses oxidation of lithium at the anode and
reduction of oxygen at the cathode to induce a current flow.
3. Anode: One of the electrodes (objects that electricity moves through) in a piece of electrical equipment;
the negative electrode in a battery and the positive electrode in an electrolytic cell
4. Cathode: One of the electrodes (object that electricity moves through) in a piece of electrical
equipment; the positive electrode in a battery and the negative electrode in an electrolytic cell
5. Lithium peroxide: It is the inorganic compound with the formula Li2O2. It is a white, nonhygroscopic
solid.
CHAPTER 2
LITERATURE REVIEW
2.1 HISTORICAL BACKGROUND
Lithium-air battery or li-air is a metal air battery chemistry that uses oxidation of
lithium at the anode and reduction of oxygen at the cathode to induce a current flow.
Lithium batteries have received attention since 1970s. the first commercial lithium cells
emerged in the mid 1990s,when kuzhikalial .M. Abraham and his co-workers demostrated
the first non-aqueous lithium-air battery with the use of lithium negative electrode (anode),
porous carbon positive electrodes (cathode), and a gel polymer electrolyte membrane that
served as both the seperator and ion-transporting medium. It is an all-solid-state battery; it
recaptured scientific interest in the late 2000s due to advances in materials technology and
an increasing demand for renewable energy sources
According to researchers from (Kaist, 2013) the lithium air batteries are
hindered by some problems surrounding the high-energy free radicals generated at their
cathodes and they are also working to extend the life time of the lithium-air battery.
According to (R.E Williford, 2013)
According to researchers at IBM, the electric cars of today can typically travel for only
100 miles on current battery technology (lithium-ion battery). Lithium-ion battery stands
little or no chance of being light enough to travel 500 miles on a single charge and cheap
enough to be practical for a typical family car which is creating a significant barrier to the
adoption of electric vehicle. IBM having this in view started the battery 500 project in
2009 to develop a new type of lithium-air battery technology that is expected to improve
energy density tenfold, thereby increasing the amount of energy these batteries can
generate and store which presently IBM researchers have successfully demonstrated the
fundamental chemistry of the charge-and-discharge process of lithium-air battery (IBM)
According to some researchers at Yale and MIT, the way to alleviate two of the batteries’
biggest problems have been found, that is their efficiency and inability to be recharged
many times. They developed a nanostructure membrane that reduces the needed energy to
recharge the battery. They also said the battery uses pure oxygen as such would require the
development of a system that works in air to be able to realize its theoretical potential
(Bulls, 2015).(Kaushal, 2011)He saw the future of lithium-air batteries in continued
development of the components such as the air cathode, anode, electrolyte and the
separator, and also trying to increase the number of charge and discharge cycles of the
battery.
CHAPTER 3
ENERGY CONVERSION METHODS
Energy conversion methods are essential for developing a sustainable materials and key in
renewable energy sources. Renewable energy sources describes about the advanced conversions.
There are several ways to tune the electrochemical self-assembly through lattice match between
the electrode surface and NWs, or use nanostructured templates such as anodized alumina or track-etched
polycarbonate followed by removing the template. Figure 1,shows an example of Titanium oxide NTthin
film for photocatalysis conversion of carbon di oxide to hydrocarbon. The porous Titanium oxide NT
membrane promotes carbon di oxide interaction with Titanium oxide sensitized by Copper cocatalyst and
activated by light, providing the optofluidic synergy between the trapped light and flow reactants.
Titanium nanostructures increase the photocatalytic efficiency by at least ten times when compared with
the commercially available TiO2 product.
Figure 3.2 .Graphene has high tensile strength and high electrical conductivity
CHAPTER 4
ENERGY STORAGE METHODS
Here the nanomaterials are also used for storage of energy. We can expected that the
nanomaterials using advanced energy storage and recovery solutions will become much more widely used
in the coming years as the efficiency and energy density of semiconductor increases and manufacturing
cost decreases. In the next few decades, our fossil-fuelled cars and home-heating will need to switch over
to electric power as well if we're to have a hope of averting catastrophic climate change. Electricity is a
hugely versatile form of energy, but it suffers one big drawback: it's relatively difficult to store in a hurry.
Batteries can hold large amounts of power, but they take hours to charge up. Capacitors, on the other
hand, charge almost instantly but store only tiny amounts of power. In our electric-powered future, when
we need to store and release large amounts of electricity very quickly, it's quite likely we'll turn
to supercapacitors (also known as ultracapacitors) that combine the best of both worlds.
We can store electric charges by different sources such as batteries and capacitors do a similar
job—storing electricity—but in completely different ways:
4.1 BATTERIES
Batteries havetwo electrical terminals (electrodes) separated by a chemical substance called an
electrolyte. When you switch on the power, chemical reactions happen involving both the electrodes and
the electrolyte. These reactions convert the chemicals inside the battery into other substances, releasing
electrical energy as they go. Once the chemicals have all been depleted, the reactions stop and the battery
are flat. In a rechargeable battery, such as a lithium-ion power pack used in a laptop computer or MP3
player, the reactions can happily run in either direction—so you can usually charge and discharge
hundreds of times before the battery needs replacing.
Capacitors have many advantages over batteries: they weigh less, generally don't contain harmful
chemicals or toxicmetals, and they can be charged and discharged millions of times without ever wearing
out. But they have a big drawback too: kilo for kilo, their basic design prevents them from storing
anything like the same amount of electrical energy as batteries. Broadly speaking, you can increase the
energy a capacitor will store either by using a better material for the dielectric or by using bigger metal
plates. To store a significant amount of energy, you'd need to use absolutely whopping plates.
Thunderclouds, for example, are effectively super-gigantic capacitors that store massive amounts of
power—and we all know how big those are!
4.3 SUPERCAPACITOR
CHAPTER 5
FINDING OF LITHIUM AIR BATTERY
In the course of this research, I was able to find out some things about lithium-air battery
A team of engineers at the UK’s university of Cambridge have thought and found a new way of
resolving one of the technology’s problems. They adjusted the general design of the lithium-air battery by
using a highly porous, spongy carbon electrode made from grapheme. The new design includes the use of
lithium iodide as a stabilizing additive. (Green, 2015). Which they say helps to reduce unwanted chemical
reactions that cause cells in the battery to die and improve battery longevity.
5.2 ARCHITECTURE
A lithium-air cell creates voltage from the oxygen molecules available (O2) at the positive
electrode. Oxygen reacts with the positively charged lithium-ions to form lithium peroxide (Li2O2) and
generate electric energy (cordis, 2015).
The lithium-air battery can be applied in our portable storage devices but its main application driving
interest is transportation, where specific energy and energy density are most important, although
applications in portable electronics and grid energy storage are also of interest. Of particular interest in
the context of transportation is the fact that, with the specific energy and energy density of today’s
automotive Li-ion cells, one’s driving range is limited to about 70 miles for a 200 kg pack, (kojic, 2011)
CHAPTER 6
Three-series and four-series cell Li-Air battery packs are commonly used in portable applications
with high energy-storage needs, because it is more efficient to store high energy using multiple batteries
connected in series. Series-connected cells also present efficiency advantages over single-cell packs,
because they reduce current for equivalent-power applications. The series-cell voltage can deliver energy
to the system more efficiently than a single high-current cell with similar resistance, which in tum lowers
the cost and bulk of high-current distribution. Typical applications that store energy in series include
laptop computers, portable printing equipment, handheld printers, portable test equipment, portable
mobile-phones, portable video-games, portable DVD players and portable medical instruments.
CHAPTER 7
7.1 Comparison
CHAPTER 8
LITHIUM-AIR BATTERIES
Lithium-AIR batteries are comprised of cells that employ lithium intercalation compounds as
the positive and negative materials. The positive electrode material is typically a metal oxide with either a
layered structure (such as lithium cobalt oxide (LiCoO2)) or a tunneled structure (such as lithium
manganese oxide (LiMn2O4)) on a current-collector of aluminum foil. The negative electrode material is
typically a graphite carbon on a copper current-collector. The first Lithium-Ion batteries to be marketed
(and themajority of those currently available) utilize lithium cobalt oxide as the positive electrode. This
materialoffers good electrical performance, is easily prepared, has good safety properties and is relatively
insensitive to process variation and moisture. More recently, lower-cost (lithium manganese oxide) or
higher performance materials, such as lithium nickel cobalt oxide (LiNiXCo1-XO2), have been
introduced, permitting development of batteries with improved performance. The first Lithium-Ion
batteries employed cells with coke negative electrode materials. As better quality graphite became
available, the industry shifted to graphite carbons as negative electrode materials because oftheir higher
specific capacity, with improved life and rate capability. Until 1990, NiCd batteries dominatedthe
portable, rechargeable market. Environmental concerns led to the development of NiMH and Lithium-
Air batteries. Lithium is the lightest metal in the periodic system and features the greatest electrochemical
potential.
CHAPTER 9
APPLICATIONS
Vehicles
Li–air cells are of interest for electric vehicles, because of their high theoretical specific and volumetric
energy density, comparable to petrol. Electric motors provide high efficiency (95% compared to 35% for
an internal combustion engine). Li–air cells could offer range equivalent to today's vehicles with a battery
pack one-third the size of standard fuel tanks assuming the balance of plant required to maintain the
battery was of negligible mass or volume.
Grid backup
In 2014, researchers announced a hybrid solar cell-battery. Up to 20% of the energy produced by
conventional solar cells is lost as it travels to and charges a battery. The hybrid stores nearly 100% of the
energy produced. One version of the hybrid used a potassium-ion battery using potassium–air. It offered
higher energy density than conventional Li-ion batteries, cost less and avoided toxic byproducts. The
latest device essentially substituted lithium for potassium.
The solar cell used a mesh made from microscopic rods of titanium dioxide to allow the needed oxygen to
pass through. Captured sunlight produced electrons that decompose lithium peroxide into lithium ions,
thereby charging the battery. During discharge, oxygen from air replenished the lithium peroxide.
CHAPTER 10
1. Wide variety of shapes and sizes efficiently fitting the devices they power.
2. Much lighter than other energy-equivalent secondary batteries.
3. High open circuit voltage in comparison to aqueous batteries (such as lead acid, nickel-metal
hydride and nickel-cadmium).This is beneficial because it increases the amount of power that can
be transferred at a lower current.
4. No memory effect.
5. Self-discharge rate of approximately 5-10% per month, compared to over 30% per month in
common nickel metal hydride batteries, approximately 1.25% per month for Low Self-Discharge
NiMH batteries and 10% per month in nickel-cadmium batteries. According to one manufacturer,
lithium-ion cells (and, accordingly, "dumb" lithium-ion batteries) do not have any self-discharge
in the usual meaning of this word. What looks like a self-discharge in these batteries is a
permanent loss of capacity . On the other hand, "smart" lithium-ion batteries do self-discharge,
due to the drain of the built-in voltage monitoring circuit.
6. Components are environmentally safe as there is no free lithium metal.
CHAPTER 10
1. Charging forms deposits inside the electrolyte that inhibit ion transport. Over time, the cell's
capacity diminishes. The increase in internal resistance reduces the cell's ability to deliver current.
This problem is more pronounced in high-current applications. The decrease means that older
batteries do not charge as much as new ones (charging time required decreases proportionally).
2. High charge levels and elevated temperatures (whether from charging or ambient air) hasten
capacity loss. Charging heat is caused by the carbon anode (typically replaced with lithium
titanate which drastically reduces damage from charging, including expansion and other factors).
CHAPTER 11
CONCLUSION
The non-aqueous lithium-air batteries represent a class of potentially ultrahigh energy density power
sources useful for military and civilian applications. When fully developed could exhibit practical specific
energies of 1000-3000 Wh/kg. It is rechargeable as such efforts should be made to fully develop them. It
has been predicted that Li/air batteries will primarily remain a research topic for the next several years.
However, if the fundamental challenges can be met, the lithium air (Li/air) battery has the potential to
significantly surpass the energy storage capability of today’s Lithium-ion (Li-ion) batteries.
A lot of researches have been going on for decades now by researchers both from the battery
companies and researchers from higher institution as regards developing the battery of the future (lithium-
air) which has been said to be environment friendly and more efficient than the lithium-ion. I recommend
relentless effort both from the researchers and the scientists in overcoming the challenges of the lithium-
air battery which includes the cathode can be improved as an asymmetric structure in which the porosity
is not uniform distribution.
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Publishers, 2004.
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