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Ceramic CAD/CAM Materials: An Overview of Clinical Uses and Considerations
Ceramic CAD/CAM Materials: An Overview of Clinical Uses and Considerations
Ceramic CAD/CAM Materials: An Overview of Clinical Uses and Considerations
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Luiz Meirelles
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Clinically Relevant.
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in posterior crowns and fixed dental prostheses (FDPs), which layering or powder-condensation technique to CAD/CAM
are subjected to higher load levels than anterior crowns. Despite technology. With CAD/CAM systems, the oral environment is
having a more natural appearance than their metal-based captured using intraoral or laboratory scanners, and the data
predecessors, there is always a trade-off between strength is used to design and mill the restoration digitally. This process
and translucency in dental ceramics. Higher strength ceramics reduces human error and labor, and can allow for faster, more
are predominantly crystalline, which gives a more opaque consistent restoration processing. Unlike traditional methods,
appearance. As a result, crystalline ceramics are often used as CAD/CAM materials are available as “green stage,” or partially
a framework in a bilayer restoration with a feldspathic porcelain sintered blanks, which are porous and enable fast cutting
veneer. On the other end of the spectrum, highly aesthetic without fracture. Once milled, additional sintering is necessary
dental ceramics are predominantly glassy, which allows them to obtain the material’s desired mechanical properties.
to be more translucent (Figure 2), but can make them relatively
There are a wide variety of materials available for CAD/CAM
weaker when compared to crystalline ceramics. The continued
restorations, each differing in terms of their microstructure,
search for strong, natural-looking ceramic materials has led to
strength, translucency, and clinical indications. In light of
the development of glass-ceramics and polycrystalline ceramics,
these differences, the material selection plays an important
which can be used in a single layer.
role in the esthetics and long-term success of restorations.
Along with newer materials, there has been a simultaneous The following sections explore three major classes of ceramic
advancement in fabrication techniques for ceramic materials for CAD/CAM restorations – zirconia, crystalline
restorations. There has been a shift from the traditional hand glass-ceramics and resin-ceramic composites. n
Framework zirconia
Full-contour zirconia
1000 Feldspathic porcelain
A
800
Flexural strength (MPa)
Glass-ceramics
Translucency
400
LDS
Polycrystalline ceramics (zirconia)
C
200
RCC
P
0
I/O/V Single 3-Unit FDP 3-Unit FDP Multi-unit
crowns (No molars) (with molars) FDP
KEY: Flexural strength
I/O/V (Inlay, Onlay, Veneer) RCC (Resin-ceramic composites)
LDS (Lithium disilicate-based ceramics) FDP (Fixed dental prostheses)
P (Feldspathic porcelains) s Figure 2. From (A) to (C), the crystal content increases, while the
glass phase content decreases. The strength of a ceramic increases
s Figure 1. Manufacturers base their clinical indications in large with an increase in crystal content, while the translucency decreases
part on minimum strength requirements established by ISO 6872. with a decrease in glass content. Feldspathic porcelain with the
However, strength is only one of the many factors to consider highest glass (silica) content shows the most translucency, while
when choosing restorative materials. zirconia with the highest crystal content shows the most strength.
Zirconia ceramics were introduced in dentistry more than Evolution of Zirconia Ceramics
a decade ago and quickly gained popularity due to their
outstanding mechanical properties and the availability of 2014
similar flexural strength and fracture toughness. While the Monochromatic versus Chroma Gradient
wear of antagonist enamel was first thought to be a concern
when using monolithic zirconia, this has been shown to be A B
Incisal third
alleviated by the maintenance of a polished surface finish.
Middle third
Polished zirconia results in less of wear of antagonist enamel
Cervical third
(and the material itself) versus glazed zirconia, and causes
less antagonist wear than feldspathic porcelain or glass-
ceramics1. s Figure 4. This figure illustrates two color options for zirconia
restorations. While some manufacturers utilize monochromatic blocks
Format and Processing: (A), others offer blocks with a chroma gradient, which decreases in
saturation from cervical area to incisal edge and mimics the more
Zirconia is available in partially sintered blocks or discs that natural color gradations of teeth (B).
are available in a variety of sizes to accommodate different
restoration sizes and can be used for dry or wet milling. retention form, the use of resin cement may improve the
Some blocks and discs require specific milling machines, so bonding and integrity of the tooth-crown complex. While
it is important to verify a particular product’s compatibility. there is no consensus regarding the bonding protocol
The milled restorations are sintered at a high temperature for zirconia, one common approach is a combination of
(1400-1600ºC) and that typically take several hours to mechanical roughening (sandblasting with alumina or
complete. The sintering protocol is specific to the product, silica-coated alumina) followed by the use of a primer or
and a strict adherence to those guidelines is necessary to resin cement containing 10-methacryloxydecyl dihydrogen
achieve optimal strength, translucency and color. phosphate (MDP)2. The roughening increases the surface
area for bonding, while MDP improves the resin cement’s
Shade Options: chemical bonding. It is important to note that the use
Traditionally, tooth color reproduction with zirconia has of large alumina particles and high air pressure while
been a challenge, and manufacturers have approached it sandblasting may have a negative impact on the strength.
in several ways. Some manufacturers offer zirconia in 16 Therefore, using an abrasive particle size of less than
classic VITA shades, while other manufacturers offer a few 50µm and an air pressure of 0.1-0.25 MPa (15 -36 psi) is
base shades that can be combined with coloring liquids to recommended. n
provide the desired look. However, these liquids may result
in non-uniform surface coloring, caused by the porosity Clinical Note: Some zirconia materials are susceptible
variation (gradient) that occurs during processing. Another to surface degradation at body temperature in the
concern with coloring liquids is the grinding for occlusal presence of water. This spontaneous transformation of
adjustments, which may result in lighter colored areas. tetragonal to monoclinic phase can potentially degrade
Another way that some manufacturers approach coloring the strength of the material, leading to premature
is to mimic the decreasing intensity of color (chroma) failure. This phenomenon is called low temperature
from the cervical to incisal area found in natural teeth. degradation (LTD). The decrease in strength has been
This is done with multilayered discs, which provide a color observed after small amounts of monoclinic content
gradient from the cervical to incisal area of the restoration, present in the initial stages increases to approximately
and is intended to give the restoration a more life-like fifty percent. Grain size can be another factor in LTD.
appearance. Figure 4 provides a schematic diagram of a Reducing the grain size of zirconia increases stability
cross-section of such a disc. of tetragonal phase, increasing the resistance to LTD3.
Since cubic zirconia has a higher yttria content and only
Cementation and Bonding: a small amount of tetragonal phase, it is less susceptible
In preparations with adequate retention form, zirconia to LTD than the other types of zirconia.
restorations can be cemented using traditional cements
following the protocol used for metal crowns. The bonding
1. In vitro wear behavior of zirconia opposing enamel: a systematic review.
of zirconia to tooth structure is problematic due to a lack
2. Bonding to oxide ceramics—laboratory testing versus clinical outcome.
of glassy phase for acid etching and lack of silica for resin 3. Low temperature degradation -aging- of zirconia: A critical review of the
bonding. However, where there is less than optimum relevant aspects in dentistry.
The first CAD/CAM ceramic used in dentistry was technicians polish the restoration to remove the
composed of feldspathic porcelain, which has a similar milling marks before sintering.
composition as that of the traditional hand-layered
Zirconia-reinforced lithium silicate (ZRS) and
porcelain. Feldspathic CAD/CAM materials are still
lithium silicate (LS):
available on the market, and because of their excellent
Indications and Key Properties: Zirconia-reinforced
esthetic properties, are mainly indicated for veneers
lithium silicate (ZRS) and lithium silicate (LS) were
and inlays. The feldspathic porcelains were followed by
both developed as alternatives to LDS. Unlike LDS,
leucite-reinforced porcelains with improved flexural
the glassy matrix of ZRS has 10% dissolved zirconia in
strength (~160 MPa). However, feldspathic porcelains
addition to lithium disilicate and lithium metasilicate
and leucite-based porcelains are being replaced with
crystals. Because these materials have similar
even stronger glass-ceramics. Glass-ceramics have
translucency, flexural strength and fracture toughness
a glassy matrix similar to feldspathic porcelains and
to LDS, they have similar clinical indications.
a crystal phase embedded in the matrix. The glassy
component creates a translucency similar to that of a Format and Processing:
natural tooth, while the crystal phase imparts better Glass-ceramics are available in partially crystallized
mechanical properties. This section focuses on three blocks and can be easily milled in this stage. The heat
of the most commonly used glass-ceramics, which treatment they receive in this phase is how they
have a crystalline lithium disilicate embedded in the attain their final strength and translucency. LDS is
glassy matrix (i.e. “lithium disilicate-based ceramics”). available in blue-colored blocks (“blue state”), which
have lithium meta-silicate and lithium disilicate nuclei.
Types: Once milled, the restorations are then heated to
Lithium disilicate ceramics (LDS): 850ºC (in vacuum) for 20-25 minutes. The material
Indications: LDS is a versatile material that has ~70% lithium disilicate crystals by volume at this
provides an excellent combination of strength and stage, which changes the material from blue to tooth-
translucency. LDS is available in both high and low colored. The processing of ZRS differs from LDS in
translucency blocks. The high translucency blocks are that it can be used with or without sintering. However,
recommended for anterior veneers, inlays or onlays, the strength of pre-sintered ZRS is lower (~200 MPa)
while the low translucency blocks are preferred for than its sintered counterpart (300-400 MPa).
anterior single crowns and three-unit anterior bridges.
Additionally, LDS could be considered for posterior Shade Options:
single crowns with limited retention or patients with LDS blocks are available in VITA A-D shades and a
higher esthetic demands. variety of translucencies, including low translucency
Key properties: LDS was first introduced as a (LT), high translucency (HT), and medium opacity
substructure material to be veneered with feldspathic (MO). MO blocks are recommended for masking a
porcelain. Later improvements in optical and discolored tooth stump or as a substructure, but
mechanical properties allowed it to be used in a single, require a feldspathic porcelain veneer.
monolithic layer, avoiding the problems of veneer
chipping. The material was later introduced as a CAD/ Cementation and Bonding:
CAM material, which could be also used for chairside Because of the presence of glassy phase, LDS
milling. LDS is more translucent than all three types of restorations can be used with adhesive cementation
zirconia and stronger than other glass-based ceramics. but require a prior surface treatment. The
Its flexural strength ranges between 250-400 MPa, recommended surface treatment is etching with 5%
while its fracture toughness is approximately 2-2.5 hydrofluoric acid (HF) followed by the application of
MPa.m1/2. Glazed ceramics wear opposing dentition a silane primer. While manufacturers recommend the
more than polished ceramics. Additionally, milled same surface treatment for ZRS and LS materials,
LDS is more abrasive than its pressed counterpart. there is no long-term history of clinical use available
Therefore, it is recommended that dentists or for either material. n
While the information above can be used to make decisions Anterior Single Crowns:
on the best material for a specific clinical situation, Figure 5 For anterior single crowns, LDS restorations provide an
provides an easy-to-use reference guide for the materials excellent combination of esthetics and strength. They
discussed, while Figure 6 looks at the conventional materials provide better mechanical properties than feldspathic
and ceramic CAD/CAM alternatives for five key clinical or leucite-reinforced porcelains and improved esthetics
indications. compared to the traditional PFM.
Anterior Three-Unit Fixed Dental Prostheses (FDP): Posterior Three-Unit/Multi-Unit Fixed Dental
The adequate strength and excellent esthetics of LDS make it Prostheses (FDP):
a good option for anterior three-unit FDPs, while a bi-layered Strength is a primary requirement in the posterior region. Full-
option - such as porcelain-fused-to-zirconia (PFZ) - can be contour zirconia is a high-strength, single-layer restorative
used in situations where strength is more important than material that can be used instead of more conventional metal
esthetics. or PFM options. The bi-layered PFZ also provides adequate
strength and esthetics in such situations. n
Links of Interest
ISO 6872: 2015, Dentistry – Ceramic Materials
Current status of zirconia restoration
Making yttria-stabilized tetragonal zirconia translucent Join us at ADA 2017!
The Product Evaluation team hopes to see you in
Damage and reliability of Y-TZP after cementation surface
Atlanta for networking events and valuable clinical
treatment.
information on CAD/CAM solutions, including:
Fatigue behavior in water of Y-TZP zirconia ceramics after
abrasion with 30 µm silica-coated alumina particles. Continued Education
• State-of-the-Art Surface Treatments for Luting
Low-temperature degradation of Y-TZP ceramics: of All-Ceramic Restorations (Multiple Sessions)
A systematic review and meta-analysis.
• Material Selection for CAD/CAM Restorations
Ceramic dental biomaterials and CAD/CAM technology: (Course Code: 5809)
state of the art
ACE Panel Reception
From Artisanal to CAD-CAM Blocks: state of the art of Learn more about the ACE Panel and network with
indirect composites current members on Thursday, October 19 from
Resin-composite blocks for dental CAD/CAM applications 5:00 - 6:30 p.m. at the Omni Hotel International,
Ballroom E.
Effect of elasticity on stress distribution in CAD/CAM dental
crowns: Glass ceramic vs. polymer-matrix composite. Visit ADA.org/meeting for full course and speaker
information.
Low Translucency
Flexural 900 - 1400 900 - 1400 500 - 700 250 - 400 100 - 200
Strength (MPa)
Relative H HH HHH HHHH HHHH
Translucency
Fracture 5-9 5-9 NR 2 - 2.5 0.8 - 1.2
Toughness
(MPa.m1/2)
Machinability HH HH HH HHH HHHHH
Processing Time H HH HH HHH HHHHH
Adhesion to H H H HHH HHH
Tooth Structure
Chairside Option No Possible No Yes Yes
Ease of Retrieval H H HH HHH HHHH
Commercial • Cercon (Dentsply • BruxZir NOW • BruxZir Anterior • Celtra Duo (Dentsply Sirona) • CAMouflage NOW
Examples Sirona) (Glidewell Laboratories) (Glidewell • IPS e.max CAD (Ivoclar (Glidewell
• Clinical Zirconia • BruxZir Shaded Laboratories) Vivadent) Laboratories)
(Glidewell Laboratories) (Glidewell Laboratories) • Cercon xt (Dentsply • Obsidian (Glidewell • CERASMART
• In-Ceram Classic • BruxZir Shaded 16 Sirona) Laboratories) (GC America)
Zirconia (VITA North (Glidewell Laboratories) • Katana ST (Kuraray • VITA Suprinity (VITA North • LAVA Ultimate (3M)
America) • Cercon HT Noritake) America) • Paradigm MZ100
• In-Ceram YZ (VITA (Dentsply Sirona) • LAVA Esthetic (3M) (3M)
North America) • CEREC Zirconia • Nexxzr+ (Sagemax) • Shofu Block
• inCoris ZI (Dentsply (Dentsply Sirona) • ORIGIN Beyond (B&D (Shofu Dental)
Sirona) • GC Initial Zirconia Technologies) • VITA Enamic
• IPS e.max ZirCAD (GC America) • Prettau Anterior (Vita Zahnfabrik)
(Ivoclar Vivadent) • inCoris TZI (Zirkonzahn)
• LAVA Zirconia (3M) (Dentsply Sirona) • Vericore ZR HTX
• Nexxzr S (Sagemax) • inCoris TZI C (Whip-Mix
• VITA YZ T (Dentsply Sirona) Corporation)
(VITA Zahnabrik) • Katana ML/HT (Kuaray • Zenostar MT (Wieland
• Zenostar MO (Wieland Noritake) Dental)
Dental) • LAVA Plus (3M)
• Nexxzr T (Sagemax)
• ORIGIN Beyond Plus
(B&D Technologies)
• ORIGIN LIVE
(B&D Technologies)
• Prettau Zirconia
(Zirconzahn)
• Vericore ZR HT
(Whip-Mix Corporation)
• VITA YZ HT (VITA North
America)
• Zenostar T (Wieland
Dental)
• Zirlux FC2 (Zahn Dental)
KEY:
H Least Favorable
H H H H H Most Favorable Single Crown Veneer Inlay/Onlay Posterior 3-unit FDP Anterior 3-unit FDP
NR: Not Reported
s Figure 5. Clinical indications and key properties of CAD/CAM ceramic materials.
KEY Esthetics Strength Ease of Process Emerging Product Low Cost Bonding
s Figure 6. CAD/CAM ceramics, with their strength and esthetics, can be great alternatives to more traditional materials in a variety of clinical
scenarios. Other considerations, such as cost or ease of processing, can help guide your selection process, and determine the best fit for your
patients’ needs.