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Determination of Water Content in Silicone Oil Using Karl Fischer Titration
Determination of Water Content in Silicone Oil Using Karl Fischer Titration
This product group comprises the most diverse products. Depending on solubility, their behaviour in the KF solution and
water content, different Karl Fischer methods apply.
Special Information concerning the sample and the methods
Oils show inadequate solubility in methanolic KF solvents. Oils on silicone basis require the addition of long chain
alcohols or chloroform as solubilisers or utilisation of specific KF solvents for oils. In the case of complete dissolution of
the sample both the volumetric as well as the coulometric KF method may be used. The most suitable method will
depend in that case on the water concentration of the sample. Volumetry is prefered in case of titration in suspended
solution.
1) Titration one component system
Reagents:
Titrant
188005 Aquastar® - CombiTitrant 5 - One component reagent for volumetric Karl Fischer titration, 1 mL = approx. 5 mg
water
or
188002 Aquastar® - CombiTitrant 2 - One component reagent for volumetric Karl Fischer titration, 1 mL = approx. 2 mg
water
Solvent
50 mL 188020 Aquastar® - CombiSolvent oils - Solvent for volumetric Karl Fischer titration with one component reagents
for oils
or
30 mL / 30 mL 188009 / 102445 Aquastar® - Combi Methanol / Chloroform - solvent mixture for one component
titration
Titration Parameters:
Stirring time: 120 sec.
Default titration settings, e.g.:
I(pol) = 20 - 50 µA, U(EP) = 100 - 250 mV
Stop criterion: drift < 20 µL/min
Sample size:
appr. 5 g
Procedure:
The titration medium is first placed into the titration cell and titrated dry by means of the titrant. Then the sample is added
with a syringe with or without hollow needle (exact sample weight determination by weighing of syringe before and after
injection) and the titration is started. For complete dissolution of the sample a stirring time of 120 seconds is
recommended.
Procedimiento:
El medio de titulación se coloca primero en la celda de titulación y se titula en seco por medio del titulador. Luego se
agrega la muestra con una jeringa con o sin aguja hueca (determinación exacta del peso de la muestra pesando la
jeringa antes y después de la inyección) y se inicia la titulación. Para la disolución completa de la muestra se requiere
un tiempo de agitación de 120 segundos recomendado.