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Lapres KF 3 PKU
Lapres KF 3 PKU
25 mL corn oil
Reaction :
𝒆𝒏𝒆𝒓𝒈𝒚
R1-CH2-CH=CH-CH2-R2 → R1-CH*-CH=CH-CH2-R2 + H* (free radical)
NUMBER OF PEROXIDE
I2 + 2e → 2I-
2S2O32- → S4O62- + 2e -
RANCIDITY OF OIL
Known :
⍴ corn oil = ⍴ linoleat acid = 0,902 gram/mL
Mass of corn oil = Volume of corn oil x ⍴ corn oil
= 2 mL x 0,902 gram/mL
= 1,804 gram
Mr linoleat acid = 280,4472 gram/mol
Mol corn oil (a) = 6,432 mmol (a)
Volume of blanko = 0.3 mL
Volume of Na2S2O3 =
15 minutes : 0,8 mL
30 minutes : 1,3 mL
45 minutes : 1,6 mL
60 minutes : 2,3 mL
100 minutes : 2,8 mL
1. Peroxide Value
𝑉 𝑁𝑎2𝑆2𝑂3 𝑥 𝑁 𝑁𝑎2𝑆2𝑂3 𝑥 1000
Peroxide Value = 𝑚𝑎𝑠𝑠 𝑜𝑓 𝑐𝑜𝑟𝑛 𝑜𝑖𝑙
a. Titration 15 minutes
(0,8−0,3)𝑚𝐿 𝑥 0,2 𝑁 𝑥 1000
Peroxide value = 1,804 gram
= 55,43 moleq/gram
b. Titration 30 minutes
(1,3−0,3)𝑚𝐿 𝑥 0,2 𝑁 𝑥 1000
Peroxide value = 1,804 gram
= 110,86 moleq/gram
c. Titration 45 minutes
(1,6−0,3)𝑚𝐿 𝑥 0,2 𝑁 𝑥 1000
Peroxide value = 1,804 gram
= 144,13 moleq/gram
d. Titration 60 minutes
(2,3−0,3)𝑚𝐿 𝑥 0,2 𝑁 𝑥 1000
Peroxide value = 1,804 gram
= 221,73 moleq/gram
e. Titration 100 minutes
(2,8−0,3)𝑚𝐿 𝑥 0,2 𝑁 𝑥 1000
Peroxide value = 1,804 gram
= 277,16 moleq/gram
Time (s) Peroxide Number (moleq O2/100g)
900 55,43
1800 110,86
2700 144,13
3600 221,73
6000 277,16
- 15 minutes
- 45 minutes
moleq corn oil = moleq Na2S2O3
= 0,2 N x 1,6 mL
= 0,32 mmol
- 60 minutes
moleq corn oil = moleq Na2S2O3
= 0,2 N x 2,3 mL
= 0,46 mmol
- 100 minutes
moleq corn oil = moleq Na2S2O3
= 0,2 N x 2,8 mL
= 0,56 mmol
b. Determine orde reaction
- Orde reaction 1
1 𝑎
k = 𝑡 𝑙𝑛 𝑎−𝑥
- Orde reaction 2
1 1 1
k = 𝑡 ((𝑎−𝑥) − 𝑎)
- Orde reaction 3
1 1 1
k = 𝑡 (2(𝑎−𝑥)2 − 2𝑎2 )
1,800
1,790
1,780
1,770 y = -0.0131x + 1843.9
R² = 0.9513
1,760
0 1000 2000 3000 4000 5000 6000 7000
time (s)
Orde 2
0.172
0.17 y = 2E-06x + 0.1581
R² = 0.953
0.168
1/(a-x)
0.166
0.164
0.162
0.16
0.158
0 1000 2000 3000 4000 5000 6000 7000
times (s)
Orde 3
0.015
y = 4E-07x + 0.0125
0.0145 R² = 0.9553
1/2(a-x)2
0.014
0.0135
0.013
0.0125
0 1000 2000 3000 4000 5000 6000 7000
times (s)
Documentation
Blanco Titration
3,6 glacial acid + 2,4 mL
chlorofom and let it in 1
minutes
- 2 mL sample 30 minutes
boiled + 3,6 glacial acid
+ 2,4 mL chlorofom + 3
drops of KI saturated
solution + 6 mL aquadest
while shaking + 2 drops of
amylum 1%
- 2 mL sample 45 minutes
boiled + 3,6 glacial acid
+ 2,4 mL chlorofom + 3
drops of KI saturated
solution + 6 mL aquadest
while shaking + 2 drops of
amylum 1%