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Amines Questions
Amines Questions
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Unit - 13
AMINES
1. Write IUPAC names of the following :
m
co
y.
da
to
es
di
tu
.s
w
w
w
m
5. Identify A and B in the following reactions :
co
373K
(i) CH3CH2Cl + NH3 (Excess)
OH–
→ A
373K
→ y.
da
(ii) CH3CH2Cl + NH3 OH–
(excess)
to
es
m
co
y.
da
to
es
di
tu
.s
w
compounds :
w
m
(vii) amines are soluble in dilute HCl.
co
(viii) amines have lower boiling point than alcohols of comparable molecular
masses.
(ix) y.
1° amines have higher boiling points than 2° amines which in turn,
da
are higher boiling than 3° amines.
(x) The pKb value of benzeneamine is 9.33 while that of ammonia is
to
4.75.
es
ferric oxide.
w
(xv) diazonium salt of aromatic amines are more stable than the diazonium
w
m
heating yield B. Compound B on reaction with Br2 and alc. NaOH gives
compound C (C2H7N). Compound C forms a foul smelling compound D on
co
reaction with chloroform and NaOH. Identify A, B, C, D and the write the
equations of reactions involved.
[Hint : (A) CH3CH2COOH y.
(B) CH2CH2CONH2
da
(C) CH3CH2NH2 (D) CH3CH2NC.]
to
es
di
tu
.s
w
w
w