MATERIAL SAFETY DATA SHEET

Glyphosate IPA 41% SL

SECTION 1 — CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Identifier
Glyphosate IPA 410 g/kg SL
Product Use
Herbicide
Manufacturer’s Name Supplier’s Name
GOKER TARIMSAL YILIA SAM AVARAN CHEMICAL TRADIG PJSC
Street Address Street Address
SULEYMANBEY MAH. MINAR SINAN CAD. No: 27/12 3F, NO. 46 SHADMEHR STREET,AZADI AVENUE

City Country City Country

ADANA TURKEY TEHRAN IRAN
Postal Code Emergency Postal Code Emergency
4020014821 Telephone 1456656917 Telephone
+90 226 811 46 03 + 98 21 6619 8603
Date MSDS Prepared MSDS Prepared By Phone Number
2016.03.01 YILIA SAM AVARAN CHEMICAL TRADIG PJSC +98 21 6619 8592
+98 21 6619 8597

SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS

Common Name: Glyphosate Formulation: Glyphosate IPA 410 g/kg SL
CAS No.: 38641-94-0 Water soluble liquid (SL)
Chemical family: Glycine N-(phosphonomethyl)glycine-isopropylamine
Molecular Formula: C6H17N2O5P Hazardous components:
Product use: Systemic and non-selective Glyphosate 480 g/L Equivalent 410 g/Kg
herbicide Other ingredients: 59%

SECTION 3 — HAZARDS IDENTIFICATION

Emergency Overview: Appearance and Odour
Clear, yellow to amber colour liquid with faint amine odour.
Warning Statements CAUTION. Keep out of reach of children. Causes moderate eye irritation. Harmful if swallowed
or inhaled. Avoid breathing spray mist. Avoid contact with eyes, skin and clothing
Potential Health Effects: Ingestion
Slightly toxic based on toxicity studies. No significant adverse health effects are expected to develop if only small
amounts (less than a mouthful) are swallowed.
Eye Contact The undiluted product may cause pain, redness and tearing based on toxicity studies.
Skin Contact Slightly toxic and slightly irritating based on toxicity studies.
Inhalation Low inhalation toxicity.
Potential Environment Effects
Available data on similar formulations suggest that this product would be slightly to moderately toxic to aquatic
organisms and practically non-toxic to avian species, honeybees and earthworms.

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MATERIAL SAFETY DATA SHEET
Glyphosate IPA 41% SL
SECTION 4 — FIRST AID MEASURES
Ingestion
If swallowed do NOT induce vomiting; seek medical advice immediately and show this container or label or contact
the National Poison Centre. Make every effort to prevent vomit from entering the lungs by careful placement of
the patient.
Eye
Hold eyelids open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if present,
after the first 5 minutes, then continue rinsing eye. Call National Poison Centre or doctor for treatment advice.
Skin
Remove contaminated clothing. Rinse skin immediately with plenty of water for 15 to 20 minutes. Wash affected
area with soap and water. Call National Poison Centre or doctor for treatment advice.
Inhalation
Remove affected person to fresh air until recovered. If the person is not breathing, call an ambulance, then give
artificial respiration, preferably by mouth-to-mouth, if possible.
Call National Poison Centre or doctor for further treatment advice.
Advice to Doctor
Treat symptomatically.

SECTION 5 — FIRE FIGHTING MEASURES

Flammable Flash point
▯YES ▮NO Non-combustible material
Extinguishing Media Suitable Extinguishing Media
If involved in fire, the product will not burn. Choose Water, foam carbon dioxide or dry chemicals.
extinguishing media to suit the burning material
Special Fire Fighting Procedures Unusual Fire and Explosion Hazard
Fire-fighters should wear NIOSH/MHSA approved This product, or spray solutions of this product, can
self-contained breathing apparatus and full fire- react with galvanized steel or unlined steel (except
fighting turn out gear. Dike area to prevent runoff and stainless steel) containers and tanks, to produce
contamination of water sources. Dispose of fire hydrogen gas which may form a highly flammable gas
control water later. mixture. If involved in a major fire, could evolve oxides
of nitrogen or phosphorus.
Hazardous Combustion Products
May emit toxic fumes of hydrogen chloride, oxides of phosphorus or phosgene if involved in fires or exposed to
extreme heat.

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MATERIAL SAFETY DATA SHEET
Glyphosate IPA 41% SL
SECTION 6 — ACCIDENTAL RELEASE MEASURES
Personal precautions
Spills and Disposal: Contain spill and absorb with clay, sand, soil or proprietary absorbent (vermiculite). Collect
spilled material and waste in sealed open-top type containers for disposal. Final clean up with degreasing agent or
detergent is advised.
Environmental precautions
Prevent material from entering public sewer systems or any waterways. Do not flush to drains.

SECTION 7 — HANDLING AND STORAGE

Handling
Do not get in eyes. Avoid contact with skin or clothing. Avoid breathing spray mist. Users should wash hands before
eating, chewing gum, using tobacco, or using the toilet. Remove Personal Protective Equipment (PPE) immediately
after handling this product. Wash the outside of gloves before removing. As soon as possible, wash thoroughly and
change into clean clothing.
Storage
Store in the closed, original container in a dry, well-ventilated area out of direct sunlight. Store in a safe place away from
foodstuffs, seeds or fertilizers. Store out of the reach of children. Do not contaminate water, food, or feed by storage or
disposal.
Other Information
DO NOT MIX, STORE OR APPLY THIS PRODUCT OR SPRAY SOLUTIONS OF THIS PRODUCT IN GALVANISED STEEL OR UNLINED
STEEL (EXCEPT STAINLESS STEEL) CONTAINERS OR SPRAY TANKS.
This product or spray solutions of this product react with such containers and tanks to produce hydrogen gas which may form
a highly combustible gas mixture. This gas mixture could flash or explode, causing serious personal injury, if ignited by open
flame, spark, welder’s torch, lighted cigarette or other ignition source.

SECTION 8 — EXPOSURE CONTROL / PERSONAL PROTECTION

Exposure Limits
No exposure limits have been set for this product.
Engineering Controls
Handle in well-ventilated area, generally natural ventilation is adequate.
Personal Protective Equipment
Eye/ Face Protection
To avoid contact with eyes, wear chemical goggles or shielded safety glasses. An emergency eyewash or water supply should
be readily accessible to the work area.
Skin Protection
To avoid contact with skin, wear cotton overalls buttoned to the neck and wrist and washable hat, and elbow length PVC
gloves. An emergency shower or water supply should be readily accessible to the work area.
Respiratory Protection
Not normally required. If vapors or mists exceed acceptable levels, wear NIOSH approved air-purifying respirator with
cartridges/canisters approved for use against pesticides.

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MATERIAL SAFETY DATA SHEET
Glyphosate IPA 41% SL
General Hygiene Considerations
Personal hygiene is an important work practice exposure control measure and the following general measures should be taken
when working with or handling this materials: 1) do not store, use and/or consume foods, beverages, tobacco products, or
cosmetics in areas where this material is stored; 2) wash hands and face carefully before eating, drinking, using tobacco,
applying cosmetics or using the toilet.

SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES

Physical State
Liquid
Appearance
Clear, yellow to amber colour liquid with faint amine odour
Boiling Point
> 100 ℃
Vapour Pressure
Active ingredient as salt in aqueous solution. Vapour pressure is negligibly low.
Solubility in water
Soluble in water
Partition Coefficient, noctanol/water
Log Pow = - 3.2 at 25oC (glyphosate)
Specific Gravity (H20=1)
1.17
Flammability
Non-combustible material
Explosion Properties
Not explosive

SECTION 10 — STABILITY AND REACTIVITY

Stability
Stable under normal handling and storage conditions.
Condition to avoid
Excessive heat. Do not store near heat or flame.
Materials to Avoid
Corrosive to mild steel, galvanized steel and zinc.
Hazardous Reaction
Avoid contact with strong oxidizing agents: bases and acids; such contact may release isopropylamine vapour with
a strong fish like odour, irritant to eye. Isopropylamine has oral LD50 (rat) 820 mg/kg and workplace exposure
standard is 5 ppm (TWA) and 10ppm STEL. If involved in strong fires can release nitrogen oxides and oxides of
phosphorus.
Hazardous Polymerization
Hazardous polymerization will not occur.

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MATERIAL SAFETY DATA SHEET
Glyphosate IPA 41% SL
SECTION 11 — TOXICOLOGICAL INFORMATION
Acute oral toxicity Toxicology Information
LD50 (rat): > 5000 mg/kg for similar formulation No harmful effects are expected if the precautions on
the label and this MSDS are followed. Ingestion The
Acute inhalation toxicity concentrate is of low toxicity if swallowed. Amounts
LC50 (rat, 4h): > 1.03 mg/L swallowed incidental to normal handling procedures
and use are not expected to cause injury. Possible
Acute dermal toxicity symptoms of exposure include: nausea, vomiting and
LD50 (rabbit): > 5000 mg/kg for similar formulation gastrointerestinal discomfort and diarrhoea. Ingestion
of a large quantity of the undiluted product may result
in hypotension and pulmonary oedema.

Inhalation Chronic Effects

When applying the product as a spray, avoid breathing No information available, no chronic effects expected.
in spray mists. May cause irritation to mucous
membranes and respiratory tract. Mutagenicity
Eye Glyphosate is not considered to be mutagenic.
The concentrate may cause irritation to the eyes.
Prolonged contact with the concentrate may cause Carcinogenicity
Glyphosate is not considered to be carcinogenic.
damage to the eye.
Skin
Reproductive Toxicity
May cause reddening of the skin and some irritation if
Glyphosate is not considered to be teratogenic or a
contact is prolonged.
reproductive toxin.
Eye Irritation Slight Irritant (rabbit).
Skin Irritation Slight irritant (rabbit).
Skin Sensitization Not a contact sensitizer (guinea pig).

SECTION 12 — ECOLOGICAL INFORMATION

Acute Toxicity - Fish Acute Toxicity - Daphnia
Glyphosate: Not toxic to fish Glyphosate: Immobilization: EC50 (48 hours) > 100
LC50 (bluegill sunfish, 96hr): 120 mg/L mg/L
LC50 (rainbow trout, 96hr): 86 mg/L
LC50 (harlequin, 96hr): 168 mg/L Acute Toxicity – Other Organisms
Not toxic to bees. LD50 (bee): > 100 μg/bee
Not toxic to birds.
LD50 (bobwhite quail): > 3850 mg/kg
Other Precautions
DO NOT spray in high winds.
DO NOT contaminate dams, rivers or streams with pesticide or used containers.
Environmental Protection
Do not use on or in situations where damage to susceptible crops plants such as cotton, tobacco, tomatoes,
flowers, vines, fruit trees or other susceptible crops plants may result from direct application or drift.
Persistence /Degradability
Adsorption studies indicate that glyphosate has very low mobility. Average field half-life of glyphosate is 47 days.
Others Information
Moderately toxic to fish and other aquatic species (mainly due to the surfactant). Not toxic to birds or bees.

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MATERIAL SAFETY DATA SHEET
Glyphosate IPA 41% SL
SECTION 13 — DISPOSAL CONSIDERATIONS
Product Disposal
Ideally the product should be used for its intended purpose. If there’s a need to dispose of the product, approach
local authorities who hold periodic collection of unwanted chemical. On site disposal of the product is not
acceptable.

Container Disposal
Do not use this container for any other purpose.
Triple rinse containers, add rinsate to the spray tank, then offer for recycling / reconditioning or puncture top,
sides and bottom and dispose of in landfill in accordance with local regulations. If no landfill is available, bury the
containers below 500mm in a disposal pit specifically marked and set up for this purpose clear of waterways,
desirable vegetation and tree roots. Empty containers and product should not be burnt.

SECTION 14 — TRANSPORT INFORMATION

UN NUMBER: 3082
Transport Information
Product not classified as a dangerous good for transport by road, rail, sea or air. It is a good practice to separate
this product from food, food related materials, animal feedstuffs, seed or fertilizers during transport.
IMO Class/Packing Group
Class 9, Packing Group III
IMO Marine Pollutant
Marine Pollutant
IMO Proper Shipping Name
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (containing glyphosate isopropyl ammonium)

SECTION 15 — REGULATORY INFORMATION

Risk Phrase
R41: Risk of serious damage to eyes.
R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Phrase:
S2: Keep out of reach of children.
S13: Keep away from food, drink and animal feeding stuffs.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical attention.
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
S46: If swallowed, seek medical advice immediately and show this container or label.
Hazard Category
Class III
Packaging and Labeling
KEEP AWAY FROM FOODSTUFF AND CHILDREN/ READ THE LABEL BEFORE USE

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MATERIAL SAFETY DATA SHEET
Glyphosate IPA 41% SL
SECTION 16 — OTHER INFORMATION
Packaging
Packed in 1 L HDPE containers and labelled according to Iranian regulations and guidelines.
Disclaimer
The information on this sheet is not a specification; it does not guarantee specific properties. The information is
intended to provide general guidance as to health and safety based upon our knowledge of the handling, storage
use of the product. It is not applicable to unusual or non-standard uses of the product nor where instructions or
recommendations are not followed.
All information is given in good faith but without guarantee in respect of accuracy, and no responsibility is
accepted for errors and omissions or the consequence thereof.