Chapter 5 Gas Laws

Boyle’s Law: P1V1 = P2V2

V1 V2
Charles’s Law: =
T1
T2
P1 P2
Gay-Lussac’s Law: =
T1 T2
P1 V1 P2 V2
Combined Gas Law: =
T1 T2
Ideal Gas Law: PV=nRT; R = 0.0821 L X atm/ mol X K

STP: 1 atm and 0oC

1. A sample of air at 5.00 atm expands from 1.75 L to 2.50 L. If the

temperature remains constant, what is the final pressure?

2. Calculate the final volume when 125 mL of argon gas undergoes a pressure
change from 705 mmHg to 385 mmHg, assuming no temperature change.

3. Calculate the final Kelvin temperature when 5.00 L of fluorine gas at 50 oC is

cooled to give a volume of 3.75L, assuming no pressure change.
4. Calculate the final Celcius Temperature when 125 mL of chlorine gas at 25
o
C is heated to give a volume of 175 mL, assuming no pressure change.

5. Calculate the final Kelvin temperature of sulfur dioxide gas if 50.0 mL of the
gas at 20 oC and 0.450 atm is heated until the pressure is 0.750 atm.,
assuming no volume change.

6. Calculate the final Celcius temperature of nitrogen dioxide gas if 1.95 L of

the gas at 0 oC and 375 mmHg is cooled until the pressure is 225 mmHg,
assuming no volume change.

7. A sample of hydrogen chloride gas occupies 0.750 L at STP. What is the

pressure in atm if the volume is 0.100L at 25 oC?
8. A sample of hydrogen fluoride gas occupies 1250 mL at STP. What is the
pressure in mmHg if the volume is 255 mL at 300oC, 760 mmHg =1atm?

9. If 0.500 mol of hydrogen gas occupies 5.00 L at 298 K, what is the pressure
in atmospheres?

10. If 0.100 mol of argon gas occupies 2.15 L at 0.95 atm, what is the
temperature in degrees Celsius?

11. Assuming STP, how many milliliters of iodine vapor react with 125 mL of
hydrogen gas?
H2(g) + I2(g)  HI(g)
12. Assuming STP, how many milliliters of nitrogen gas react to give 45.0 mL
of ammonia gas?
H2(g) + N2(g)  NH3 (g)

13. Assuming STP, how many milliliters of chlorine gas react to yield 1.75 L of
dichlorine trioxide?
Cl2(g) + O2(g)  Cl2O3(g)

14. If 1.00 mol of nitrogen monoxide gas and 1.00 mol of oxygen gas react,
what is the limiting reactant and how many moles of NO2 are produced
from the reaction?
2 NO(g) + O2 (g)  2 NO2 (g)

15. If 70.0 mL of nitrogen gas reacts with 45.0 mL of oxygen gas, what is the
limiting reagent and what is the volume of N2O3 produce? Assume STP.
N2 (g) + O2 (g)  N2O3 (g)
16. If 3.00 L of sulfur dioxide gas reacts with 1.25L of oxygen gas, what is the
limiting reagent and what is the volume of sulfur trioxide gas produced?
Assume STP.
SO2(g) + O2(g)  SO3 (g)

17. If 50.0 L of hydrogen chloride gas reacts with 10.0 L of oxygen gas, what is
the limiting reagent and what is the volume of chlorine gas produced?
Assume STP.
HCl(g) + O2 (g)  Cl2(g) + H2O(g)

18. What is the density of CHCl3 vapor at 100OC and 1.00 atm?

19. A sample of gas has a mass of 0.239 g and exerts 600 Torr at 14OC in a 100
mL flask:
a. What is the molar mass of the halogen?
b. What is the density of the gas at 1.00 atm and 298 K?
20. Calculate the partial pressure of each gas in a mixture that contains 0.015
mol H2, 0.001 mol He, and 0.030 mol NH3, given the total pressure of the
mixture is 2.06 atm.